Calcite la de vapor

Ej ,

utopia de Pb a 15°C
y
1 atm

partie de la information :
a
siguiante
• Entre 900K
y
1600K la
presior de
raper del Pb ( en torr)

la ewacion
Signe :

Pb

9,8-51
TIK
log # 7.822 -

= ,
,

it solo
gas online
ploho
760 for =
1 atm

É not
"
•
A 25 °C ,
5m ( Pb , S , 25°C ) =
64.98 J

• Por
debajo de 900 K :

" "
20.8 JÑ mom
C-pls ) JÉ moi
g- (g)
=
=
28.0
"

Ep JÑ not
"
(l ) 26.4
=
 K' mom
^
• TEs =

600kg bass 7600 K) = 7.95J

298K 298K
5m ( Pb g 25°C )
, ,
=
Smo ( Pb S
, ,
25°C) t Drug 5m ( 25°C )

Nissin Dvapsin
s -
l →
tbvapsfnc25.CI
25°C 25°C
g 298K

bassinet )
T ds
f d Dassin
/ b¥p
DT DT
of
= → =

600K
9fus5m(600K)

DµsSm°C298K) Bµs5m(600K)
-

=
Bfgcp In 29-8
600
↓
GQ ) CpG ) -
 In 7.95 I
Dassin ( 298K ) =
( 26.4 -
28.0
)¥g
.

2,9¥
t
Kmol

= 9.07 ]
^
K' molt

Dvapsi =

bvaptt
Trap

d brain dig Dvapvm ≈

Vmcg)
Rf
= =

brown

¥ a¥ᵗm ¥
= .

ᵈ¥ P¥gpHn_
= →
 107822 98¥ dd¥ a×
-

Ina
;
=

p
. -

"
¥
"

107.822
-

dy Inno
ass¥
= .
.

IT

1h10 107822-9,8=54/1 nF¥ osvapltin

=)
98¥24
. - = .

RTX

(900K -1600K ) In
apH°m
= 10 '

9854K '
R

= 8.314 J # moi "

-

9854¢ . Into
"
=
188.6426J moi

Bvaps'm Attn
188.gg#HH--
" "
=
=
209.603k moi
took)
Trap
 ( 298K) la hecesita
tvapsm que
is se .

d) gvapsni
"f Brayed
"" "

[ =
dt

) 900K
bvapsnicaook

bvapsni ( 298K )
bvapsni ( 900K ) Dvapcp In 298
- =

Too
↓
Cplg )
Cpll )
-

hi 291
Buap 8m ( 298K ) = (20.8-26.4) ] . t 209.601
Kmt 900 Knot

" "
Dvapsni ( 298K) =
215.79 JÑ moi
Rebman do :
( 298K)
sm° ( Pb g, ,
298K ) =
Smo ( Pb, s
,
298k) t Bassin ( 298K)
ttvapsm
215.791
64.98 J
9.07¥ +
=
+
, , Knot

' ^
Snicpb g
,
298K) =
289.84 J E moi
,
Ej 2 .
En un
proceso de manufacturer que involucre Cambias en el

Sistema de DU DS
DU
, y
se da
ingreso de Calor 9 a
temperature
Constante Ts Durante el proceso se libera calor a los
.

go
alrededores a
temperature ypresian constant es To
y Po .

Demuestre que si el proceso es reversible se wmple :

To BS )
÷q
( BUT Po DV
=
0
9-
-

si irreversible
y es

9- ( But Po AV -
To BS ) > 0

Ts -

To

ds
d_9¥ ≥ 0 All =
9kt + w
;
-
9kt =
9
-

go

9th
=
Ah -
w

9- % Du w
-

%
=
But w
g-
% =
9- DU -

Po AV

BS
5 : ¥.
9%+9%70
-

9-bU,;P
+
¥
DS -
≥ 0

-
+ 9- ( DU +
PODV -
To DS ) ≥ 0

, To
q-CDUtpobv-T.BIZ ,
To

Ts 9 -

Ts C BUT Po DV -

To DS ) ≥ To 9

Ts CAN + BV To DS ) ≥ Cts To )
Po g
-
- -
-

I C But
po DV To DS ] ≥
9
- -
-

Ts
-
To

9- ( but pobv -

To DS
④ 0

Ts To
↓
-

=
0 Reversible
> 0 irreversible