February Attempt Online JEE Main 2021 01

25 FEB SHIFT-II MATHEMATICS

1 −α  π π
1. (b) Given, A = 
β 
2 2
α  4. (a) In = ∫ cot xdx = ∫ cot n− 2x(cot 2 x)dx
n

 1 α π π
⇒ AT =   4 4
 −α β  π π

Given, AAT = I 2 i.e. 2

n− 2
2
n− 2
In = ∫ cot xcosec xdx − ∫ cot
2
xdx
1 −α   1 α  1 0 π π
α =
 β   −α β   0 1  4 4
π
 1 + α 2 α − αβ  1 0 2
= n− 2
 2 2
α − αβ α + β   0 1 
 In + In − 2 = ∫ cot x.cosec2xdx
π
Equating these matrices, 4

1 = α 2 + 1 gives, α = 0 Now, let cot x = t , then cosec2xdx = − dt , limit will be

0 n− 2
α(1 − β) = 0 In + In − 2 = ∫1 − t dt
α2 + β2 = 1 0
−(t ) n − 1   0 (1) n− 1 
Put α = 0 in α 2 + β 2 = 1, we get =  = − − 
n − 1 1  n − 1 n − 1
0 + β 2 = 1, gives β = ± 1
1
where we take β 4 = 1 In + In − 2 =
n −1
∴ α + β = 0 + 1=1
4 4 4

a bc Now, put n = 4

2. (c) Let A = d ef
 ⇒
1
I 2 + I 4 = , then
1
=3 …(i)
 g h i  3 I2 + I4
Put n = 5
2 a 2 b 2 c 
1 1
Then, 2 A = 2d 2 e 2 f  ⇒ I5 + I 3 = , then =4 …(ii)
  4 I 3 + I5
2 g 2h 2i 
Put n = 6
Now, perform the operation 1 1
⇒ I6 + I4 = , then =5 …(iii)
R2 → 2R2 + 5R3 on 2A, we get 5 I4 + I6
 2a 2b 2c  Here, from Eqs. (i), (ii) and (iii), we conclude
B =  4d + 10g 4 e + 10h 4 f + 10i  1 1 1
  , and are in AP with common difference 1.
 2 g 2h 2i  I 2 + I 4 I 3 + I5 I4 + I6
2a 2b 2c 5x 52 − x
5. (c) Given, f ( x) = , then, f (2 − x) = 2 − x
|B| = 4d + 10g 4 e + 10h 4 f + 10i 5 +5
x
5 + 5
2g 2h 2i 5
⇒ f (2 − x) =
Using property of invariance to calculate |B|, apply 5x + 5
R2 → R2 − 5R3 5x + 5
This gives, f ( x) + f (2 − x) = =1
2 a 2 b 2 c  a b c 5x + 5
|B| =  4d 4 e 4 f  = 2 × 4 × 2 d e f 
f   + f  2 −  = f   + f   = 1
    1 1 1 39
⇒
2 g 2h 2i   g h i   20   20   20   20 
= 16 × det( A) Similarly,
f   + f   = 1 and so on,
= 16 × 4 = 64 [Q det( A) = 4] 2 38
 20   20 
3. (b) The given system of equations is non-homogeneous and it can be
f   + f   + K + f   + f  
1 2 38 39
written as, ∴
 20   20   20   20 
2 3 2   x  9 
3 2 2  y  = 9  = 1 + 1 + K + 1 + f   = 19 + f(1) = 19 + =
20 1 39
      20  2 2
1 −1 4   z  8 
i.e,. AX = B 6. (c) We have, x2 − 6 x − 2 = 0
Now,|A| = 2(8 + 2) − 312( − 2) + 2( −3 − 2) Given, α and β are roots of above quadratic equation, then
= 20 − 30 − 10 = − 20 ≠ 0 α 2 − 6α − 2 = 0 …(i)
Q|A|≠ 0, then this system have unique solution. β − 6β − 2 = 0
2
…(ii)
02 Online JEE Main 2021 February Attempt

a10 − 2 a8 ⇒ x2 + y 2 + 2 xy = 1 …(i)
Also, given an = α n − β n, then
3a9 We can write Eq. (i) as,
(α10 − β10) − 2(α 8 − β 8) α10 − 2α 8 − β10 + 2β 8 x2 + 2y 2 − 2(1) 2 = 0
= =
3(α − β ) 9 9
3(α 9 − β 9) ⇒ x2 + 2y 2 − 2( x + y ) 2 = 0 [using Eq. (ii) in Eq. (i)]
α 8(α 2 − 2) − β 8(β 2 − 2) ⇒ x + 2y 2 − 2 x2 − 2y 2 − 4 xy = 0
2
=
3(α 9 − β 9)
⇒ − x2 − 4 xy = 0 ⇒ − x( x + 4y ) = 0
[from Eqs. (i) and (ii) α 2 − 2 = 6α, β 2 − 2 = 6β] −1
Gives, x = 0 and x + 4y = 0 or y = x
α 8(6α) − β 8(6β) 6α 9 − 6β 9 6(α 9 − β 9) 4
= = =
3(α 9 − β 9) 3(α 9 − β 9) 3(α 9 − β 9) −1
Draw the line y = x on graph and take arbitrary point (any one) as
=2 4
follows,
7. (c) We already know, Arithmetic mean ≥ Geometric mean, From given graph,
x x
Let us take AM and GM of two terms a a and a1 − a , Y
x x
1− a
a a
+ a x x
⇒ AM = and GM = a a . a1 − a
2
x x 4
a a + a1 − a x x x x
θ X
Q AM ≥ GM ⇒ ≥ a a . a1 − a ⇒ a a + a1 − a ≥ 2 a1 1
2
x x
∴Minimum value of f ( x) = a a + a1 − a is 2 a. –1 y=–1/4x
e 3 log e ( 2x )
+ 5e 2 log e ( 2x )
8. (b) I = ∫ e 4 log ( x ) + dx
5e 3 loge ( x ) − 7 e 2 loge ( x ) ⇒ θ = tan−1  
e 1 1
tanθ =
log e ( 2x )3 log e ( 2x )2 4  4
e + 5e
= ∫ log e x 4 log e ( x )3 2
dx 1
We have two lines, y = − x and x = 0 (i.e. Y - axis). Thus, any line
e + 5e − 7 e loge ( x ) 4
[using property a log x = log xa] π
joining these two curves makes an angle + θ at origin.
2
8 x3 + 5(2 x) 2
= ∫ x4 + 5( x) 3 − 7 x2
dx [using property a loga x = x] π
∴Answer is + tan−1   .
1
2  4
8 x3 + 20x2 4 x2(2 x + 5)
= ∫ x4 + 5x3 − 7 x2
dx = ∫ x2( x2 + 5x − 7)
dx 11. (b) Let ( x, y ) be any arbitrary point on curve x2 = 2y and find the
tangent line equation at this point, such that tangent line at ( x, y ) is
4(2 x + 5) parallel to line x − y = 1.
= ∫ x2 + 5x + 7
dx
To find tangent equation, differentiate the following equation so that
Let x2 + 5x − 7 = t , then (2 x + 5)dx = dt we can find slope,
4dt x2 − 2y = 0 …(i)
I= ∫ t
= 4 log e t + c
dy dy
2x − 2 = 0 gives =x
Put t = x2 + 5x − 7 dx dx
Slope (say m1) = x
I = 4 log e|x2 + 5x − 7| + c
Also, slope of line x − y = 1 or y = x − 1 is 1 (say m2). Since, x − y = 1
9. (d) Given, root of z 2 + αz + β = 0 is1 − 2 i. and tangent line is parallel,
Since, it is quadratic equation and one root is complex in nature, its therefore, their slope be equal.
another root is complex conjugate. Hence, m1 = m2 gives, x = 1
∴ Two roots are 1-2i and1 + 2i. Put x = 1 in Eq. (i), we get y = 1 / 2
α
Thus, ( x, y ) = 1, 
1
Now, sum of roots = − = − α
1  2
= (1 − 2i) + (1 + 2i) = 2
Perpendicular distance between line x − y = 1 and point 1,  is
1
Gives, α = − 2  2
β given as,
Product of roots = = β
1 (1)(1) +  1  ( −1) − 1
= (1 − 2i)(1 + 2i) = 1 + 4 = 5  
 2 
P = 
Gives, β = 5  (1) 2
+ ( − 1) 2

∴ α − β = − 2 − 5 = −7  
10. (a) Curve x2 + 2y 2 = 2 intersect the line x + y = 1 at points P and Q.  −1 
=
First we have to find any common relation between these two 2 2
curves. Use substitution for the same as follows, 1
= (∴ using perpendicular distance formula)
x2 + 2y 2 = 2 …(i) 2 2
x + y = 1, then ( x + y ) = 1 2 2
 February Attempt Online JEE Main 2021 03

12. (a) Given, ellipse is

x2
+
y2
=1 = $i ( −1 + 4) − $j( −1 + 2) + k$(2 − 1)
25 16
= 3$i − $j + k$
x2 y2
or + =1
( 5) 2
( 4) 2 n = 3$i − $j + k$

x2 y2 Let P be any point on normal vector and O be origin. Then refer the
Compare it with standard equation 2
+ 2
= 1, diagram, projection of OP on plane have length OM.
a b
we get a = 5, b = 4
Now, focus of ellipse = ( ± c , 0) where P (2, –1, 1)
θ
c= a2 − b 2
n
Put the values of a and b, we get
c= 52 − 4 2 = 25 − 16 = 9
∴Focus = ( ± 3, 0)
O M
According to question, hyperbola passes through the focus of Plane
ellipse.
Let equation of hyperbola be OP = 2 $i − $j + k$ and n = 3$i − $j + k$
x2 y 2 OP. n = |OP||n|cosθ
− =1
a2 b 2 (6 + 1 + 1) = 4 + 1 + 1( 9 + 1 + 1) cosθ
Since, it passes through ( ±3, 0), we get 8
8 = 6 11 cosθ ⇒ cosθ =
( ±3) 2 0 66
− 2 = 1, gives a = ± 3 or a 2 = 9
a2 b |OM|
Again, sinθ = , gives|OM| = sinθ.|OP|
Also, given that product of eccentricities is 1. |OP|
Now, (Eccentricity of ellipse ) (Eccentricity of hyperbola) = 1
⇒ |OM| = 1 − cos2 θ|OP|
 16   b 2 
⇒  1−  1+ =1 64
 25   9  = 1− 4 + 1 + 1 (use cosθ = 8 66)
66
(using formula of eccentricity of ellipse and hyperbola) 2
= . 6
 9  b 2  66
⇒    1 + =1
 25   9  2
∴ |OM| =
11
Squaring on both sides,
b 2 25 1 + n
+
n
+K
1+ =  n (n + 1) 2 (n + 2) 2 
9 9 14. (b) Let L = lim  
n→∞  n 
⇒ b 2 = 16 +
 (2n − 1) 2 
x2 y 2  
Thus, equation of hyperbola is − = 1.
9 16  n +
n
+K+ 
 (n + 0) 2 (n + 1) 2 
13. (b) Refer diagram, the normal vector be n and it is perpendicular to or L = lim  
n→∞  n n n 
both AB and AC. + −
 (n + n − 1) 2 (n + n) 2 (n + n) 2 
AB × AC = n  
n  n n n 
= lim  + +K + 
n→∞ (n + 0) 2 (n + 1) 2
(n + n) 2 

B  n 
A − lim  
n→∞ (n + n) 2
 
C
n

Plane
= lim Σ n
− lim
1
n→∞ r = 0 (n + r) 2 n→∞ 4n
Now, A(1, 2 , 3), B(2 , 3, 1) and C(2 , 4 , 2) n
= lim Σ n
− 0  since, lim = 0
1
Then, AB = (2 − 1) $i + (3 − 2) $j + (1 − 3)k$ n→∞ r = 0 (n + r) 2  n→∞ n 
= $i + $j − 2k$ Now, for solving limit summation, we integrate it using some
replacement.
AC = (2 − 1) $i + ( 4 − 2) $j + (2 − 3)k$ n

= $i + 2 $j − k$ L = lim Σ 1
n→∞ r = 0 n(1 + r / n)
$i $j k$ Take
r 1
as x and as dx.
Now, AB × AC = 1 1 −2 n n
r
1 2 −1 Lower limit is obtained by putting r = 0 in , we get Lower limit = 0
n
04 Online JEE Main 2021 February Attempt

x + y  x − y  − 4 cos2  x + y 
⇒ 4 cos
r
Upper limit is obtained by putting r = n in , we get  cos   
n  2   2   2 
Upper limit = 1 1 ( x − y) ( x − y)
1 = × 2 = 1 = cos2 + sin2
−1 
= −  − 1 =
1 1 1 1 2 2 2
∴ L= ∫0 (1 + x) 2
dx =
(1 + x)  0 2  2 2
 x − y  x + y   + sin2  x − y  = 0
⇒  cos  − 2 cos   
∴ L=
1   2   2    2 
2 x − y
⇒ sin  x − y  − 2 cos x + y  = 0
 = 0 and cos   
15. (c) Let ‘A’ be the event of smokers and non-vegetarian.  2   2   2 
Let ‘B’ be the event of smokers and vegetarian. ⇒ x = y and cos 0 − 2 cos x = 0 (use x = y )
Let ‘C’ be the event of non-smokers and vegetarian. 1
Gives, cos x = = cosy
Let ‘E’ be the event of chest disorders. 2
According to question, 1 3
∴sin x = 1 − cos2 x = 1 − =
160 2 100 1 140 7 4 2
P( A) = = , P(B) = = , P(C ) = =
400 5 400 4 400 20 3 1 1+ 3
∴sin x + cosy = + =
P   = 35% =
35  E 
, P   =
E 20 E 10
, P  = 2 2 2
 A 100  B  100  C  100
18. (a) x = {f : A → B, f is one - one}
P( A). P  
E
 A  A y = {g : A → A × B, g is one one}
Thus, P   =
E Number of elements in A = 3 i.e.|A| = 3
P( A). P   + P(B)P   + P(C )P  
E E E
 A  B C  Similarly,|B| = 5
2 35 Then, |A × B| =|A|×|B| = 3 × 5 = 15
.
= 5 100 Now, number of one-one function from A to B will be
2 35 1 20 7 10 5! 5!
. + . + . 5
P3 = = = 5 × 4 × 3 = 60
5 100 4 100 20 100 ( 5 − 3)! 2 !
14
∴ x = 60
100 14 28
= = = Now, number of one-one function from A to A × B will be
7 7 45
14 + 5 + 15! 15!
14
+
5
+ 2 2 = 15P3 = =
100 100 100 (15 − 3)! 12 !
= 15 × 14 × 13 = 2730
16. (c) Here, we have four digit natural numbers, then total cases will
exclude those number which contain zero at thousands place. ∴ y = 2730
Hence, total cases will be Thus, 2 × (2730) = 91 × (60)
= ( 4 C 1 × 9 × 9 × 9) − ( 3C 1 × 9 × 9) = 2673 2y = 91x

Again, only those numbers will have remainder 2 when divided by 19. (c) cosec [2 cot −1( 5) + cos−1( 4 / 5)]
5 either they have 2 at its unit place or 7 at its unit place.  4   −1  1  
= cosec 2 tan−1   + cos−1   
1 −1
When unit digit is 2, then total number of four digit numbers will be  5  5  Q tan x = cot  x  
  
= ( 3C 1 × 9 × 9) − ( 2C 1 × 9) = 225
   1  
When unit digit is 7, then total number of four digit numbers will be   2   
  −1  4    −1  2θ  
= cosec  tan−1 
= 8 × 9 × 9 = 648 5  −1
+ cos   ∴ 2 tan θ = tan  1 − θ 2  
  1 
2  5   
Now, total favourable cases = 225 + 648 = 873   1 −    
Total favourable cases    5  
Required probability =
= cosec  tan−1 + cos−1 
Total number of cases 5 4
=
873
=
97  12 5
2673 297
Let tan−1   = x, then tan x =
5 5 5 12
gives sin x = , cos x =
17. (d) Given, cos x + cosy − cos( x + y ) =
3  12  12 13 13
2 −1  4  4 3
Let cos   = y, then cosy = gives, siny =
x + y  x − y  − 2 cos2  x + y  − 1 = 3
⇒ 2 cos  cos   
 5 5 5
 2   2    2   2
 1 1
Now, cosec ( x + y ) = =
[Use formula, sin( x + y ) sin x cosy + cos x siny
 a + b  a − b 1 65
cos a + cos b = 2 cos   cos  , = =
 2   2   5   4  +  12   3  56
     
cos2 x = 2 cos2 x − 1]  13   5   13   5 

x + y  x − y  − 2 cos2  x + y 
⇒ 2 cos  cos   
 2   2   2  20. (c) Contrapositive of p → q is~ q →~ p
3 1 p : you will work
= −1 =
2 2 ⇒~ p : you will not work
 February Attempt Online JEE Main 2021 05

q : you will earn money = 10p + ( −1) t = 10p ± 1

⇒~ q: you will not earn money If n = even, then 7 n + 3n will never be multiple of 10.
Then, ~ q →~ p : if you will not earn money, you will not work
This implies n = odd
21. (5) For this particular problem, try to draw graph in the region ( −3,3), n = 11, 13, 15, K 99 (since, n is two digit)
it will be as follows, ⇒ 10 < n < 100
Total possible ‘n’ are 45.
2
ax − ( e 4 x − 1)  0 form
24. (5) lim = L (say)
x→ 0 ax( e 4 x − 1)  0 
1
–√2 Apply L - Hospital rule,
√2
a − 4 e4x
–3 –2 –1 1 2 3 L = lim
x→ 0 a( e 4 x − 1) + ax( 4 e 4 x )

[Limit exist everywhere except a = 4]

Again, apply L-Hospital rule,
Thus, points of discontinuity will be at −2 , 2 because the curve −16 e 4 x
breaks at these points and at −1, 0, 1 because curve has sharp points. L = lim
x→ 0 a( 4 e 4 x ) + a( 4 e 4 x ) + ax(16 e 4 x )
∴Point of discontinuity are −2 , − 1, 0, 1, 2 i.e. 5 points.
−16 −2
22. (1) Given, (2 xy 2 − y )dx + xdy = 0 = =
4a + 4a a
⇒
dy y
− = − 2y 2 −2 −1
= = (use a = 4)
dx x 4 2
−1 dy 1 −2 −1
⇒ + =2 …(i) [divide by y 2] Given, L = b ⇒ = =b
y 2 dx xy a 2
−1
Let
1 1 dy dv
= v , then − 2 ⋅ = , putting in Eq. (i) Then, a − 2 b = 4 − 2   = 4 + 1 = 5
y y dx dx 2 

+ v   = 2 25. (4) If the curves cut at right angle, then product of slopes will be −1.
dv 1
(this is a linear form)
dx  x First curve x = y 4
1
∫ dx Differentiate it, we get
Now, integrating factor (IF) = e x = e log x = x
dy
x2 1 = 4y 3
∴ (IF)v = ∫ 2.(IF)dx = ∫ 2 xdx = 2 +C dx
2 dy 1
⇒ =
∴ (IF)v = x2 + C dx 4y 3
1 1
Put v = , this gives Slope of first curve ( m1) = [at point ( x1 ,y1)]
y 4y13
x
x2 + c = Second curve xy = k
y
dy
Now, first find point of intersection of lines Differentiate it, 0 = x +y
dx
2 x − 3y = 1 and 3x = −2y + 8 by elimination method, we get x = 2,
y =1 dy −y
⇒ =
1 dx x
∴The curve x2 + c = passes through (2, 1).
y −y1
Slope of second curve ( m2) = [at ( x1 , y1)]
Put x = 2 , y = 1, we get c = − 2 x1
x ⇒ m1. m2 = − 1
= x2 − 2
y 1  −y1  −1
⇒   = −1 ⇒ = −1
x 4y13  x1  4y12x1
or y = 2
x −2 −1
⇒ = −1 [using x1 = y14 ]
1 4(y1) 6
Put x = 1, we get y(1) = = −1
1− 2 1
⇒ y16 =
∴ |y (1)| = 1 4
23. (45) We may write, 7 n = (10 − 3) n or 7 n = 10k + ( −3) n (using Also, x1y1 = k, using x1 = y14 , we get k = y15 or k 6 = (y1) 30
expansion) 5
, then y130 =  
1 1
10k , n = odd Q y16 =
∴7 n + 3n = 10k + ( −3) n + 3n =  4  4
10k + 2.3 n
, n = even 5
∴ ( 4k) 6 = 4 6.k 6 = 4 6(y1) 30 = 4 6   = 4
1
Let n = even = 2 t, t ∈ N  4
Then, 3n = 32t = 9 t = (10 − 1) t
∴ ( 4k) 6 = 4
06 Online JEE Main 2021 February Attempt

2
26. (19) ∫ |3x2 − 3x − 6|dx = I (say) Let equation of common tangent be
−2
2
I = 3∫ |x2 − x − 2|dx
−2 (c, d)
 −1 2  (a, b)
= 3  ∫ (x2 − x − 2)dx + ∫ ( − x + x + 2)dx
2

 −2 −1 
  x3 x2 −1
 
2
  x3 x2
= 3  − − 2 x −  − − 2 x  3
 3 2  −2  3 2  −1 
 
= 19
27. (1) Given, when x is divided by 4, the remainder is 3.
Let x = 4 p + 3, then a
y = mx +
(2020 + x) 2022 = (2020 + 4 p + 3) 2022 m
= (2024 + 4 p − 1) 2022 ⇒ y = mx +
1
(Q y 2 = 4 x)
m
= ( 4k − 1) 2022
(Q 2024 is divisible by 4)
⇒ m2x − my + 1 = 0
= C 0( 4K) 2022( −1) 0 +
2022 2022
C 1( 4K) 2021
The above line is tangent to circle.
( −1) + .... +
1 2022
C 2022( 4 A) 0( −1) 2022
∴Perpendicular from (3, 0) to line = 3
On expansion (2020 + x) 2022, we get the form of 8 λ + 1. Since, each (3m2 − 0 + 1)
terms have 2022 and 4k, so if we take 2 common from 2022 we get ⇒  = 3
 m + m 
2 4
8. Thus, each term have 8 in common.
Hence, remainder is 1. 1
⇒ (3m2 + 1) 2 = 9( m2 + m4 ) ⇒ m = ±
x−3 y −3 z −4 3
28. (44) Let L1 ⇒ = = = u (say)
1 2 2 1
Tangent is y = x+ 3
⇒ Direction ratios of L1 = 1, 2 , 2 3
x −3 y − 3 z − 2 1
L2 ⇒ = = = v (say) ⇒ m=
2 2 1 3
Direction ratios of L 2 = 2 , 2 , 1 ( −1)
or y = × ( − 3) (rejected)
Line L passing through origin is perpendicular to L1 and L 2. 3
For parabola, point of contact is ( c , d ) =  2 ,
Hence, direction ratios of L is parallel to (L1 × L 2). a 2a 

⇒ ( −2 , 3, − 2) m n
x y z ∴ ( c , d ) = (3, 2 3)
Equation of L ⇒ = = = λ (say)
2 −3 2
Again, solve circle and line equation, we get
Solve L and L1, we get 2
 1 
(2 λ , − 3λ , 2 λ) = (µ + 3, 2µ − 1, 2µ + 4) ( x − 3) 2 +   x + 3   = 9
Gives, λ = 1, µ = − 1  3 

So, intersection point P(2 , − 3, 2). 1

⇒ x2 + 9 − 6 x + x2 + 3 + 2 x = 9
Let Q(2v + 3, 2v + 3, v + 2) be required point on L 2. 3
Now, PQ = 17 (given) 4 2
⇒ x − 4x + 3 = 0
3
PQ = (2v + 1) + (2v + 6) + (v )
2 2 2
3
⇒ x= =a
= 17 2

2( a + c) = 2  + 3 = 9
⇒ (2v + 1) 2 + (2v + 6) 2 + v 2 = 17 (squaring on both sides) 3
∴
2 
⇒ 9v 2 + 28v + 20 = 0
−10 30. (2) Area of parallelogram = |a × b|
On solving, we get v = − 2 (rejected), (accepted)
9 = |( $i + α$j + 3k$) × (3$i − α$j + k$)|
∴ Q is  , , 
7 7 8
(64)(3) = 16α 2 + 64 + 16α 2 (given, area = 8 3)
9 9 9
(squaring on both sides)
∴18( a + b + c) = 18  + +  = 44
7 7 8
9 9 9 ⇒ α2 = 4
Now, a. b = 3 − α 2 + 3
29. (9) Given, circle ⇒ ( x − 3) 2 + y 2 = 9
= 6 − α2 = 6 − 4 = 2
Parabola ⇒ y 2 = 4 x
 February Attempt Online JEE Main 2021 01

25 FEB SHIFT-II CHEMISTRY

·· F F
3. (c) Statement (c) is false whereas other statements are true. Corrected
1. (c) (a) ·· XeF4 Þ statement is as follows :
Xe
F F Viscosity of hydrophilic sols is higher than that of the dispersion
medium, i.e. H 2O, because there is a high concentration of
dispersed phase in water.
Xe (sp 3d 2-hybridised)
4. (c) Among halogens ( F2, Cl2, Br2 and I2), bond dissociation enthalpy (
Geometry : Octahedral
D dissHº) of I 2, is minimum because of larger size of I-atom there is a
Shape : Square planar
steric repulsion between bonded I-atoms, which makes
It has four equivalent Xe ¾ F bonds in the same plane. I ¾I bond weakest.
F Whereas, smaller size and highest electronegativity of F-atom cause
highest electron density on F-atom of F2 molecule. As a result, F ¾ F
(b) SiF4 Þ bond becomes weaker due to electrostatic repulsion between
Si bonded
F F F-atoms.
F Thus, the order of D dissH° (in kJ mol -1) is
Si ( sp 3-hybridised) Cl ¾ Cl > Br ¾Br > F ¾F > I ¾I
(242.6) (192.3) (158.8) (151.1)
Geometry and shape : Tetrahedral Electrostatic Steric
repulsion repulsion
It has four equivalent Si ¾ F bonds.
(c) ·· SF4 Þ F 5. (c) Zone refining method is very helpful for producing
semiconductor and other metals of high purity,
F
Axial e.g., Si, Ge, B, Ga, In etc.
S bonds
F 6. (c) Water (steam) can produce CO on reacting with CH 4 , C and
Equatorial C3H 8 as,
bonds F 1270 K
CH 4 + H 2O ¾¾® CO + 3H 2
Ni
S (sp 3d -hybridised) 1270 K
C + H 2O ¾¾® CO + H 2
Geometry : Trigonal bipyramidal
1270 K
Shape : see-saw C3H 8 + 3H 2O ¾¾® 3CO + 7H 2
Ni
Axial S ¾ F bonds are longer than equatorial bonds.
But, water on reaction with CO2 produces carbonic acid (H 2CO3),
F
not CO.
CO2 + H 2O ¾® H 2CO3
(d) BF4- Þ B 7. (c) Two crystalline allotropic forms of sulphur (Sa and Sb) can
F F
change reversibly between themselves with slow heating (above 369
F K) or cooling.
B (sp 3-hybridised) > 369 K

Geometry and shape : Tetrahedral

Sa - Sb
(Rhombic) Cooling (Monoclinic)
It has four equivalent B ¾ F bonds.
So, statement I is true.
Hence, among given species only SF4 has unequal bond lengths.
At room temperature or at standard conditions of pressure and
2. (a) Let, solubility of Ca(OH) 2 in pure water = S mol/L temperature, rhombic sulphur is the thermodynamically most stable
crystalline allotrope of sulphur ( D f H º = 0).
Ca(OH) 2 q Ca 2+ + 2OH -
S mol/L 2 ´ S (mol/L) So, statement II is false.
Ksp = [Ca 2+ ] [OH - ]2 = S ´ (2 S) 2 = 4 S 3 (mol/L)
8. (b) The major components of German silver are
The expression of Ksp can also be written as, Cu : 25-30%, Zn : 25-30% and Ni : 40-30%.
Ksp = xx × y y × S x + y
9. (a) Spin only magnetic moment, m = n(n + 2) BM
= 11 × 2 2 × S1 + 2
where, n = number of unpaired electrons and m µ n.
= 4S 3
[Q For Ca(OH) 2 : x = 1, y = 2] (i) [FeF6 ]3- Þ Fe3+ = (3d 5) + 6 ´ F- (weak field ligand).
x and y are the coefficients of cations and anions respectively Thus, pairing of electron does not take place.
1/ 3 1/ 3
æ 5.5 ´ 10 -6 ö 3d 4s 4p 4d
æK ö
S = ç sp ÷ =ç ÷
è 4 ø è 4 ø
= 1.11 ´ 10- 2 mol/L sp3d2 (Fe), n=5
02 Online JEE Main 2021 February Attempt

Å
(ii) [Co(NH 3) 6 ]3+ Þ Co3+ = (3d 6) + 6 ´ NH 3 (strong field ligand). H— C== O
(ii) CH 3CH 2 — CH== CH 2 ¾¾¾®
Thus, pairing of electron takes place. Slow
But -1-ene
3d 4s 4p Å
CH 3CH 2 — CH — CH 2 — CHO
Fast ½ Hs
¯
d2sp3 (Co), n=0
CH 3CH 2CH 2CH 2CHO (major)
(iii) [NiCl4 ]2- Þ Ni2+ = (3d 8) + 4 ´ Cl- (weak field ligand). Thus, Pentanal
pairing of electron takes place.
14. (b) Benzene on reaction with CH 3COCl / AlCl3 gives acetophenone
3d 4s 4p
which on reduction with Zn-Hg/HCl gives ethyl benzene.
Bromination of ethyl benzene give 4-bromo-ethylbenzene which
upon nitration gives 4-bromo-2-nitroethyl benzene.
sp3 (Ni), n=2
2+ 2+ 9 CH3— C==O CH2CH3
(iv) [Cu(NH 3) 4 ] Þ Cu (3d ) + 4 ´ NH 3(strong field ligand).
Thus, pairing of electron takes place. CH 3COCl/AlCl 3 Zn-Hg/HCl
3d 4s 4p (Friedel-Craft (Clemmensen
acylation) reduction)
Benzene Acetophenone Ethyl benzene

sp3 (Cu), n=1 Bromination Br2/AlCl3

So, the decreasing order of m is CH2CH3 CH2CH3

m i > m iii > m iv > m ii 1
( n = 5) ( n = 2) ( n = 1) ( n = 0) 6
2 NO2
HNO3/H2SO4
3 (Nitration)
10. (a) The pH of rain water is normally 5.6. If it pH drop below 5.6, it is 5
4
called acid rain.
Br Br
\ Both statements are correct. 4-bromo-2-nitro 4-bromo-ethyl
ethyl benzene benzene
11. (c) Nitric acid is added to sodium extract before addition of silver (Major)
nitrate for testing halogens. Because it decomposes NaCN and Na 2S
[-I-effect of Br directs NO-2 at its meta-position]
or else they interfere in the test.
So, option (b) is the correct sequence of reagents used.
The reaction are as follows :
15. (c) OH COOH COOH COOH
NaCN + HNO3 ¾® NaNO3 + HCN ­
Na 2S + HNO3 ¾® NaNO3 + H 2S­
Sodium extract Nitric acid

12. (b) The reaction take place as follows : (–R)

NO2(–I) CH3(+I)
NO2 (I) (II) (III) (IV)
+
H
Step I Acidity of phenol (I) is weaker than any carboxylic acid.
Electron withdrawing nature (-R, - I ), of ¾NO2 group at para
NO2 NO2
+ + position increases acidic strength of (II), whereas + I effect of ¾ CH 3
CH3  CH  CH  CH3 + CH3  CH  CH2  CH2 group at para position decreases acidic strength of (IV).
(More stable intermediate) (Less stable intermediate) So, the order of acid character is II > III > IV > I.
2° carbocation 1° carbocation
16. (c) When ethylene glycol is heated with oxalic acid at 210ºC, first
NO2 we get an unstable cyclic-diester (ethylene oxalate) which readily
⊕ decarboxylate to give ethylene as the major product.
CH3 CHCH  CH3 (For major product)
Step II +
O O
CH2O H OH CH2 O
CH3 CHCH2  CH2 (For minor product) C 210ºC C –2CO2 CH2
+
NO2 –2H2O CH2
CH2O H OH C CH2 O C
NO2 O O
Ethylene
NO2 Ethylene Oxalic Ethylene (Major)
glycol acid oxalate
+
17. (d)
(Major product) NH2 NH2 NH2 NH2
HNO3, NO2
13. (a) The major product of the reaction is CH 3CH 2CH 2CH 2CHO. H2SO4
+ + +
Here, electrophilic addition of H — C== O (formylation) take place 288K
NO2
to the alkene through Markownikoff addition. Aniline (B) (C)
NO2
·· Å
[47%] [2%]
Rh (A)
(i) H 2 + ·· C== O ·· ¾¾¾® [H — C== O] H
s m-nitroaniline o-nitroaniline
(Catalyst)
[51%]
Water gas
p-nitroaniline
 February Attempt Online JEE Main 2021 03

During nitration, in strongly acidic medium, aniline gets protonated Note n-factor of NaOH = 1
Å
to form the anilinium ion i.e, ( C6H5 ¾ N H 3) which is meta-directing n-factor of H 2C2O4 = 2 (oxalic acid)
Å N=M´n
as ¾ N H 3 is an electron withdrawing ( - I) group. As a result, we get
Z ´M
meta-nitro aniline (B) as the major product. 22. (9077) Density of copper, d =
a 3 ´ NA
18. (c) Aniline on carbylamine reaction produces a foul smelling gas,
phenyl isocyanide (C6H5NC). Given, Z = 4, for fcc lattice,
M = 63.54 g mol- 1
NH2 NC
∆
+ CHCl3 + 3KOH – 3 KCl = 63.54 ´ 10- 3 kg mol- 1,
Ethanolic – 3 H2O a = 3.596 Å = 3.596 ´ 10- 10m,
Aniline Phenyl
[1º amine] isocyanide NA = 6.022 ´ 1023 mol-1

Carbylamine test is used to detect aliphatic and aromatic primary On putting given values, we get
amines. 4 ´ (63.54 ´ 10-3)
Þ d = kg / m3
19. (c) Maltose is a disaccharide which is made of two a-D-glucose units (3.596 ´ 10-10) 3 ´ (6.022 ´ 1023)
in which C1 (anomeric carbon) of one glucose (I) is linked to C4 of = 9076.26~ - 9077 kg / m3
another glucose unit (II).
23. (180) Energy of EMR = IE of the metal (A)
6 6
hc hc
CH2OH CH2OH = hn = atom-1 = - ´ NA mol-1
5 5 l l
O H O H
H H (6.63 ´ 10-34 ) ´ (3 ´ 108) ´ (6.02 ´ 1023)
H H = J mol-1
4 1 4 1 (663 ´ 10-9)
OH H OH H
OH
O
OH [Q l = 663 nm = 663 ´ 10- 9m]
3 2 3 2 -1
= 180600 J mol = 180.6 kJ mol-1 ~
- 180 kJ mol-1
H OH H OH
(I) C1-C4 (II) Free anomeric 24. (15) The gas performs isothermal irreversible work (W ).
Glycosidic carbon (C1) to
linkage show reducing where, DU = 0 (change in internal energy)
property From, 1st law of thermodynamics,
Þ DU = DQ + W
Maltose
Þ 0 = DQ + W
20. (a) Both statements are true. Dimethyl glyoxime (DMG) is a neutral Þ DQ = - W
bidentate ligand (DMG - ).
Now, W = - p ext (V2 - V1)
Ni2+ ion is identified with DMG in presence of NH 4 OH to give a red
æ nRT nRT ö æ1 1ö
ppt. Its reaction is as follows. = - p ext ç - ÷ = - p ext ´ nRT ç - ÷
è p2 p1 ø è p 2 p1 ø
OH Given, p ext = 4.3 MPa, p1 = 2.1 MPa, p 2 = 1.3 MPa,
CH3—C N n = 5 mol,T = 293 K and R = 8.314 J mol-1 K -1
2.
NH4OH
+ Ni2+ 1 1ö
CH3—C N = - 4.3 ´ 5 ´ 8.314 ´ 293 æç - ÷
è1.3 21
.ø
O– H—O
–
O—H = - 15347.70 J mol-1
(DMG ) CH3—C N N C— CH3 = - 15.347 kJ mol-1 ~
- - 15 kJ mol-1
Ni2+
CH3—C N N C— CH3 Þ DQ = 15 kJ mol-1
O—H O– 25. (3) As AB is a binary electrolyte,
or [Ni(DMG)2] \ AB q A + + B- , n = 2
(Red ppt.)
75
i = 1 + a (n - 1) = 1 + (2 - 1) = 1.75
21. (6) Average burette reading = Volume of NaOH solution (V1) 100
4.5 + 4.5 + 4.4 + 4.4 + 4.4 Given, DTb = 2.5 K
=
5 Kb = 0.52 K kg mol-1
= 4.44 mL
\ DTb = Kb ´ m ´ i
Strength of NaOH solution = S1(M) (say) = S1 (N)
DT b 2.5
Volume of oxalic acid solution (V2) = 10 mL Þ m= =
Kb ´ i 0.52 ´ 175
.
Strength of oxalic acid solution ( S2) = 125
. M
= 125
. ´2N = 2.74~
- 3 mol / kg
So, V1S1 = V2S2 (Q Law of equivalence) 26. (4) Cell-I (HNO3 ¾® NO)
V2S2 10 ´ (1.25 ´ 2)
Þ S1 = = = 5.63 N 3Cu + 2NO-3 + 8H + ¾® 3Cu2 + + 2NO + 4H 2O
V1 4.44
[Cu2+ ]3 ´ ( p NO) 2
~- 6 M= 6 M Q1 =
[NO3- ]2 ´ [H + ]8
04 Online JEE Main 2021 February Attempt

E1º = 096
. - ( - 034
. ) = 13
. V Ea 25
Q log 5 = ´
0.059 2.303 ´ 8.319 300 ´ 325
E1 = 1.3 - log Q1
6 Ea = 52194.78 J mol-
Cell-II (HNO3 ® NO2) = 52.194 kJ mol- 1
Cu + 2NO-3 + 4H +
¾® Cu 2+
+ 2NO2 + 2H 2O - 52 kJ mol- 1
~
[Cu2+ ] ´ ( p NO ) 2 28. (1) Given metals (Li, Na, Rb, Cs) are alkali metals (Group 1). Their
Q2 = 2

[NO-3 ]2 ´ [H + ]4 ionisation energy (IE) decreases down the group.

Q E2º = 0.79 - ( - 0.34)V = 1.13 V Here, Cs has lowest IE, i.e. it has lowest value of threshold energy
(E0) or work function (W ). Hence, it can be used as electrode in
0.059 photoelectric cell.
E2 = 1.13 - log Q 2
2 -
29. (2) Z = 29 [Cu] ¾-¾¾
2e
® Cu 2+ = [Ar] 3d 9
Now, E1 = E2
0.059 0.059 3d 9= ;
1.3 - log Q1 = 1.13 - log Q 2
6 2 Number of unpaired electron, n = 1
0.059 0.059 Q \ Spin only magnetic moment,
. =
017 [log Q1 - 3log Q 2 ] = log 1
6 6 Q2 m = n(n + 2)BM = 1(1 + 2) BM = 3 BM
0.059 [Cu2+ ]3 ´ ( p NO) 2 [NO3- ]6 ´ [H + ]12 = 1.73 BM~
- 2 BM
= log ´
6 [NO3- ]2 ´ [H + ]8 [Cu2+ ]3 ´ ( p NO ) 6 30. (1) Structure of given compounds are as follows
2

0.059 [H + ]4 ´ [NO3- ]4 SO3H

= log [Q p NO = p NO2 ]
6 ( p NO ) 4
2
(i) (Sulphanilic acid) ⇒
0.059 [HNO3 ]4
= log
6 ( p NO ) 4
2
NH2
Now, p NO2 º [HNO3 ] OH
0.059
So, 0.17 = log [HNO3 ]8 O2N NO2
6
0.059 (ii) (Picric acid) ⇒
= ´ 8 log [HNO3 ]
6
log[HNO3 ] = 2.16 NO2
[HNO3 ] = 102.16M = 10x M COOH
\ x = 2 .16 OCOCH3
Þ 2 x = 2 ´ 2 .16 = 4.32 ~
- 4 (iii) (Aspirin) ⇒
27. (52) T1 = (273 + 27) = 300 K, T2 = (273 + 52) = 325 K
Given, temperature coefficient of the reaction, OH–
K
aT = 325 = 5 HO CH—CH2OH
K300
KT 2 Ea æ T - T1 ö (iv) (Ascorbic acid) ⇒ O
log = ´ç 2 ÷
KT1 2 .303R è T1T2 ø HO
K Ea æ 325 - 300 ö
log 325 = ç ÷
K300 2.303 ´ 8.314 è 300 ´ 325 ø Only one compound (iii) contains ¾ COOH group.
 February Attempt Online JEE Main 2021 01

Solutions
25 FEB SHIFT-II PHYSICS

1. (c) Dimensional formula of [ e ] = [IT ] 2

1 2 -1
[h] = [M L T ] l
[ c ] = [M 0L1T - 1 ] h
a v0 v0 cos θ
é 1 ù 1 3 - 4 -2
ê 4 pe ú = [M L T I ] θ
ë 0û 1 v0
1
where, is Coulomb’s constant. v0 sin θ
4 pe0
Therefore, dimensional formula of By using law of conservation of energy,
1 |e|2 [IT]2 Total energy at 1 = Total energy at 2
= [M1L3T - 4 I-2 ] × 1 2 - 1
4 pe0 hc [M L T ] [M 0LT -1 ] \ PE1 + KE1 = PE2 + KE2
= [M L T I ] or [M 0 L 0 T 0 ]
0 0 0 0 Þ 0 + 1 / 2 mv 02 + 1 / 2 Iw 2 = mgh … (i)
v
2. (a) Let the total height of building be x. As, v 0 = aw Þ w = 0
a
T 1 1 æ2 2
2 2ö v0
\ mv 0 + ç ma ÷ 2 = mgh
5m Ist particle 2 2 è5 øa
A U 1 2
25m Þ mv 0 (1 + 2 / 5) = mgh
2
x 20m 7v 02
Þ = gh … (ii)
10
B 2nd particle As, sin q = h / l
Þ h = l sin q
G (ground)
Put this value in Eq. (ii), we get
TA = 5 m 7 2 7v 02
Þ v 0 = gl sin q Þ l =
TB = 25 m 10 10 g sin q
\ AG = x - 5 and BG = x - 25
4. (b) Given, radius of circle, R = 036
. m
For initial conditions, from second equation of motion under gravity,
Angular distance, q = 30º = p / 6 rad
s = ut + 1 / 2 gt 2
Let l be the arc length.
where, g = 10 ms- 2
Q l = Rq
\ 5 = 0 + 1 / 2 ´ 10t 2 Þ t = 1s
36 p 6p
Þ l= ´ = m
Now, by first equation of motion under gravity, 100 6 100
v A = u + gt As, speed on circular track (v ) = Arc length (l) / Time (t )
= 0 + 10 = 10 ms- 1
6p 6p
From second equation of motion, Þ v = = ms- 1
100 ´ 0.1 10
x - 5 = v At + 1 / 2 gt 2 … (i)
If F be the restoration force and ar be the radial acceleration
Similarly, x - 25 = 1 / 2 gt 2 ( = v 2 / R), then
Put the above value in Eq. (i), we get F = mar
2
x - 5 = 10t + x - 25 F v 2 æ6 p ö 100
ar = = =ç ÷ ´
20 = 10t Þ t = 2s m R è 10 ø 36
Put the value of t in Eq. (i), we get 36 ´ 9.87 100
= ´ = 9.87 N
x - 5 = 10 ´ 2 + 1 / 2 ´ 10 ´ 4 100 36
Þ x - 5 = 20 + 20 5. (b) Here, p1 and p 2 , T1 and T2 , V1 and V2 are initial and final
Þ x = 45 m pressures, temperatures and volumes, respectively.

3. (*) Given, radius of sphere is a, mass of sphere is m, horizontal Given, V2 = 2V1

speed of sphere is v 0 . pV 1 / 2 = constant
Moment of inertia of solid sphere, I = 2 / 5 ma 2 From graph, g = adiabatic constant = 1 / 2
Let, h be the height of inclined plane and l be the length of inclined 1/ 2

plane. p1 æ 2V1 ö
Þ p1V11 / 2 = p 2V21 / 2 Þ =ç ÷ = 21 / 2
p 2 è V1 ø
02 Online JEE Main 2021 February Attempt

Also, p1 - g T g = constant (for adiabatic process) Let, v1 and v 2 be the incoming and outgoing velocities of electron
Þ p11 - g T1g = p12 - g T2g into the capacitor and out of the capacitor, respectively.
1-g Since, electric field is along X-axis, hence electric force on electron
1-g g
æ p1 ö æT ö æp ö g T2 along Y-axis, (Fy ) = 0
Þ ç ÷ = ç 2÷ Þ ç 1÷ =
è p2 ø è T1 ø è p2 ø T1 \ Change in momentum along Y-axis,
1 - 0.5 Dp y = 0
\ T2 / T1 = (21 / 2 ) 0.5 = 2 i.e. p1 = p 2 (along Y-axis)
6. (c) According to Statement 1 : In diatomic molecule the rotational Þ m1v1 cos a = m2v 2 cosb
energy at a given temperature obeys Maxwell’s distribution is Þ v1 / v 2 = cosb / cos a
correct.
Q Kinetic energy (K) = 1 / 2 mv 2
But, according to Statement 2 : In diatomic molecule, the rotational
If mass is same, K µ v 2
energy at a given temperature equals translational energy for each 2 2
K1 æ v1 ö cosb ö cos2 b
molecule is false. \ = ç ÷ = æç ÷ =
f K2 è v 2 ø è cos a ø cos2 a
Because kinetic energy (KE) of gaseous molecule is KBT .
2
11. (b) Since, in ferromagnetic material, with increase in temperature
where, f is the degree of freedom, susceptibility decreases,
and f(diatomic atom) = 5 = [3 (translational) and 2(rotational)] \ Ferromagnetic material below Curie temperature will show
3 saturation magnetisation.
Therefore, translational KE of gas = KBT … (i)
2 Hence, option (b) is the correct i.e. domain is defined as a
and rotational KE of gas = 2 / 2 KBT = KBT … (ii) macroscopic region with saturation magnetisation.
Q Eq. (i) is not equal to Eq. (ii)
12. (c) Given, resistance, R = 110 W
Hence, option (c) is the correct. Supply voltage (V ) = 220 V
7. (c) Let spring constants of two springs be k1 and k2 . Since, two and angular frequency ( w ) = 300 rads-1
springs are connected in parallel connection and parallel equivalent Q Current lag and lead by same angle.
spring constant, keq = k1 + k2 \ Circuit is in resonance i.e. X L = X C
Þ keq = 2k + 2k = 4k
XL–XC
m Z
As, time period, T = 2p
keq
m 2p m m 45º
Þ T = 2p = =p R
4k 2 k k
8. (c) Given, displacement-time equation,
Y = A sin( wt + f 0 )
Here, A is amplitude, w is angular frequency, t is time taken and f 0 As, Z = R2 + ( X L - X C ) 2
is the phase constant.
= (110) 2 + ( X L - X L ) 2 = 110 [Q X L = X C ]
At t = 0,Y = A / 2
Vrms220
\ Y = A / 2 = A sin( 0 + f 0 ) = A sin f 0 and I rms = = =2 A
Z 110
Þ sin f 0 = 1 / 2
13. (c) Given, stopping potential (V1 ) = 0.710 V
Þ f0 = p / 6 Incident wavelength of electrons ( l1 ) = 491 nm
9. (d) Given, charge q is at one of the corner of the cube. = 491 ´ 10- 9 m
\ Contribution of q in cube will be q enclosed = q / 8 Let l 2 will be the new incident wavelength of electrons.
As, only 3 faces of cube is allowing the flux lines to pass through it. Stopping potential (V2 ) = 1.43V
q 1 q /8 q 1240
\ Flux ( f) = enclosed = = As, energy (E ) = = f 0 + eV
e0 3 e0 24 e0 l1
10. (d) The given situation can be shown as below where, f 0 is work-function and V is applied potential
1240
v1 sin α \ E1 = = f 0 + 071. … (i)
α+v1 491
– 1240
and E2 = = f 0 + 143
. … (ii)
v1 cos α + –
l2
+ –
+ α – Now, subtracting Eqs. (i) from (ii), we get
+ –
æ1 1 ö
v2 sin β + – E2 - E1 = 1240ç - ÷ = 072
.
+ β – è l2 491ø
+ – 1
+ – Þ = 0.00058 + 0.00204= 0.00262
l2
+ –
v2 cos β \ l 2 = 3817
. nm
v2 l2 ~- 382 nm
 February Attempt Online JEE Main 2021 03

14. (c) Given, diameter of pinhole, a = 01 . ´ 10- 6 m

. mm = 01 So, the correct match is

Q Path difference ( Dx) = a sin f = nl …(i) A ® 2 , B ® 4 , C ® 1 and D ® 3.

where, f is the phase difference and l be the wavelength. 20. (b) Here A and B be the input and Y be the output.
2
As, I = 4I 0 cos f A
A
AB
nl AND
and sin f = [from Eq. (i)]
a B Y=AB + AB
NOR
If a increases « sin f or f decreases
A
As f decreases « cosf increases
AND
\ Intensity increases. B AB
B
Hence, on decreasing diameter of pinhloe, the size of diffraction
pattern decreases and intensity increases. QY = AB + AB = AB × AB = ( A + B ) × ( A + B )
= ( A + B) ( A + B ) = AA + AB + AB + BB
15. (b) Given, mass of proton ( mp ) is 1836 times the mass of electron
( me ) and velocity of proton (v p ) is equal to velocity of electron (v e ). = 0 + AB + AB + 0 = AB + AB
h h According to the truth table
As, wavelength ( l) = =
p mv
A B A B AB AB Y = AB + AB
where, h is Planck’s constant and p is momentum.
1 0 0 1 1 0 1 1
\ lµ
m
le m 1836 me 0 1 1 0 0 0 0
Þ = p = = 1836
lp me me 1 0 0 1 0 0 0

16. (a) Given, electron is moving from n = 2 to n = 1. 1 1 0 0 1 0 1

From Bohr’s hydrogen spectrum (Rydberg formula)
21. (1) Given, mass of particle A , mA = 4 g
1 é1 1ù
= R ê 2 - 2ú Mass of particle B , mB = 16 g
l n
ë f n i û
Kinetic energy of A and B is same
where, l = wavelength, i.e. KEA = KEB
R = 1097
. ´ 107 m-1 (Rydberg’s constant)
As, kinetic energy (KE) = p 2 / 2 m
1 1 1
Þ = 1097
. ´ 107 é 2 - 2 ù where, p is momentum and m is mass.
l ëê1 2 ûú
( p A ) 2 ( p B2 ) p A2 p2 pA 1
1 1 3 \ = Þ = B Þ =
= 1097
. ´ 107 é - ù = ´ 1097 . ´ 107 mA mB 4 16 pB 2
êë1 4 úû 4
4 Q linear momentum is n : 2.
l= = 1215
. ´ 10- 7
3 ´ 1097
. ´ 107 \ n =1

. ´ 10- 9 ~
= 1215 - 1218
. nm 22. (10) By using law of conservation of energy,
Energy on the surface of earth (ESurface) = Energy at height (h = 10R)
17. (c) Let l be the wavelength of carrier signal. - GMm
- GMm 1 - GMm
speed ( c) Þ + mv i2 = + 0=
Since, frequency ( fc ) = R 2 R + 10R 11R
wavelength ( l)
11 GMm GMm
c Þ 1 / 2 mv i2 = -
\ l= 11 R 11R
fc
1 2 10 GMm 20GM
Þ mv i = Þ v i2 =
18. (b) In case of n-type semiconductor, the energy level diagram will be 2 11R 11R
CB Conduction band 10 2GM
Þ vi = ve (Q v e = = escape velocity)
Eg 11 R
= Intrinsic Hence, x = 10
Eg 2 fermi level
23. (2) Error in tension is 4%.
VB Valence band Tension (T )
Speed of transverse wave, v =
In case of n-type semiconductor n > p, so the fermi level will go Mass per unit length (m)
upward. On squaring both side
Similarly, in case of p-type semiconductor p > n, so the fermi level T
Þ v2 =
will go downward. m
19. (b) Rectifier devices are used to convert AC to DC. By using the concept of % error calculation
2Dv DT Dv 1 DT
Stabiliser is an electronic device which gives constant output even if Þ = Þ =
input changes. v T v 2 T
Transformer is used to step up or down the AC voltage. Dv 1 DT 4
\ ´ 100 = ´ 100 = = 2%
Filter device which removes ripple in rectified output. v 2 T 2
04 Online JEE Main 2021 February Attempt

24. (180) Given, P ´ Q = Q ´ P 27. (7.56) Given, q1 = 21 . ´ 10- 9 C, q 2 = -01

. nC = 21 . ´ 10- 9 C
. nC = - 01
Þ P ´ Q = - P ´ Q Þ 2(P ´ Q) = 0 Separation (d ) = 0.5 m
or P ´ Q = 0 By Coulomb’s law,
It is possible only, if P = 0 or Q = 0, kq q
Force (F) = 12 2
angle between them is 180°. d
\ q = 180° where, k = 9 ´ 109 N - m2 C- 2 = Coulomb’s constant
9 ´ 109 ´ 21. ´ 10- 9 ´ ( - 01
. ´ 10- 9 )
25. (104) Given, initial efficiency ( h1 ) = 1 / 4 \ F= 2
= - 7.56 ´ 10- 9 N
( 0.5)
T2 1 T 1 3
Þ h1 = 1 - = Þ 2 =1- =
T1 4 T1 4 4 28. (2) Given, radiation power (P) = 8W
When temperature of sink is reduced by 50 K, Distance (d ) = 10 m
T - 52 1 Power (P)
h2 = 2 h1 = 1 - 2 Q Intensity (I) = c e0E 2 = … (i)
T1 2 Area ( A)
1 T2 52 1
Þ 2 ´ =1- + where, c = = speed of light in vacuum … (ii)
4 T1 T1 m 0 e0
1 3 52 1 1 52 and E = electric field
Þ =1- + Þ - =
2 4 T1 2 4 T1 From Eq. (ii), we get
2 52 1
Þ = e0 =
4 T1 m 0c 2
Þ T1 = 104 K Put this value of e0 in Eq. (i), we get
1 1 2 P 1 1 2 P
26. (630) Given, mass of each spheres, m = 10 mg = 10 ´ 10 -3
g I= c E = Þ E =
2 m 0c 2 A 2 m 0c A
Length of thread (l) = 0.5 m 2P m 0 c 2P m 0 c 2P m 0c
Separation between charges, d = 0.2 m Þ E= = =
A 4 pd 2 4d 2 p
a
Charge of each sphere, q = ´ 10- 8 C 2 ´8 m 0c 2 m 0c
21 = = = V/m
4 ´ 100 p 10 p
Acceleration due to gravity ( g ) = 10 ms- 2
The situation can be shown as below, \ x=2
29. (2) Let resistances be R1 , R2 , R3 and R4 and I1 current is passing
θθ through R4 as shown in figure
\ I 2 = (6 - I1 ) is passing through R2
T As, same current is flowing through R4 and R3 .
l T cos θ
\ R4 and R3 are in series.
θ
d 6A
qE
T sin θ 2Ω R1
P
mg I1 I2
Taking component of tension (T )
2Ω R2
T cosq = mg …(i) R4 2Ω
kq 2
T sin q = qE = 2 …(ii)
d R3
d /2 01. 1 Q
sin q = = = 2Ω R
l 0.5 5
and series equivalent resistance, Req = R4 + R3
24 \ Req = 2 + 2 = 4 W
cos q = 1 - sin2 q = 1 - 1 / 25 =
5 Voltage through Req and R2 will be same.
sin q kq 2
\ tan q = = 2 [using Eqs. (i) and (ii)] Þ I1R eq = I 2R2 Þ I1 4 = (6 - I1 ) 2
cos q d mg
1/ 5 kq 2
Þ 2I1 = 6 - I1 Þ I1 = 2 A
Þ = 2
24 / 5 d mg 30. (10) Given, wavelength of X-rays,
1 9 ´ 109 ´ q 2 l = 10Å = 10 ´ 10- 10 m
Þ =
. ) ´ 10 ´ 10- 3 ´ 10
24 ( 02 2
Speed of light in free space, c = 3 ´ 108 m/s
2
. ) ´ 10
( 02 -1 hc
Þ q= Þ q = 3 ´ 10- 7 C Since, energy (E) = = mc 2 … (i)
24 ´ 9 ´ 109 l
h h h 10 h
Þ
a
´ 10- 8 = 30 ´ 10- 8 Þ m= = = = kg
21 cl 3 ´ 108 ´ 10 ´ 10- 10 3 ´ 10- 1 3
a = 630 \ x = 10