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TYPICAL SPECIFICATIONS:

Sustainable So lutions L1050


TYPICAL PROPERTIES FREIGHT CLASSIFICATION
Not Regulated
Appearance: CLEAR LIQUID
Color: YELLOW TO AMBER SHIPPING
Flash Point (ASTM D 93): 159 C o Available in 200 liter non-returnable steel drums and in
20 liter plastic pails.
Pour Point (ASTM D 97): < -21oC
Specific Gravity: 0.89 g/ml
Weight Drum Pail
Viscosity in cSt (ASTM D445):
Net 182 kg 18.2 kg
20oC: 21.5
Gross 202 kg 19.4 kg
Solubility in:
Petroleum products: MISCIBLE CUSTOMS CLASSIFICATION
Water: INSOLUBLE Harmonized Tariff System: 3811.90

HANDLING
DESCRIPTION Normal precautions for handling petroleum products
Government regulations concerning emissions have should be observed:
forced refineries to modify certain properties of diesel fuel. • If skin contact does occur: Wash affected areas with
The result is that today’s diesel fuel has reduced lubricity. soap and water.
ADERCO L1050 is an additive specially formulated • If eye contact does occur: Immediately wash with
to improve lubricity in ultra low sulfur diesel fuels. This copious amounts of clean water or an eyewash solution
lubricity is essential for proper operation of injection for at least 10 minutes.
pumps and injectors in diesel engines.
STORAGE
DOSAGE ADERCO Fuel Oil Treatments are chemically very stable
The normal dosage for 1 liter of ADERCO L1050 varies and will remain in storage for prolonged periods; typically
between 10,000 to 40,000 liters of fuel depending on the shelf life will be 24 months. Recommended Storage and
severity of the base fuel. Some diesel fuel can demand Handling Temperature: 15-35 oC
higher dosage of additive. Please contact your ADERCO
representative for specific recommendations. For specific safety, handling and toxicity information
. please refer to the current Material Safety Data Sheet.
BLENDING
Simply add the required quantity of ADERCO L1050 to
the diesel tank before fuelling. The movements of the
vessel will be sufficient to adequately mix the additive.

iL1050can
February 2012. The values reported above are given as indicative only. The numbers could vary slightly from one batch to another. 1/1
ADERCO L 1050
GASOIL LUBRICITY IMPROVER

ADERCO EUROPE S.A.


CHAUSEE DE LOUVAIN 275 - BTE 2 • B-1410 WATERLOO • BELGIUM
TEL: 32 2 354 46 72 • FAX: 32 2 354 54 10 • Email: info@adercosa.be

July 2010
ADERCO L 1050 –
LUBRICITY IMPROVEMENT ADDITIVE

Poor lubricity is an inherent property associated with certain light


density and low viscosity fuels – for example naphtha, kerosene and
gas condensates. Recently, the introduction of Ultra Low Sulphur
Distillate marine fuels has raised again the issue, especially for fuels
below 0,01% sulphur content.

These type fuels provide little or no lubrication to metal surfaces so that


critical components such as fuel pumps are likely to experience serious
wear and premature failure. Furthermore the ignition delay in the boiler
can increase the risk of a boiler explosion on board of the vessels.

ADERCO L 1050 is a lubricity improvement additive which has been


especially developed to address friction & wear problems in fuel pumps
and to alleviate excessive operational and maintenance issues when
burning low lubricity distillate fuels.

Unlike earlier-generation products that are available on the market,


ADERCO L 1050 has been specifically developed to address the unique
technical requirements of the marine industry. This additive also
overcomes certain undesirable properties associated with earlier
products, such as solubility, stability and incompatibility. Taking all this
into consideration during the development stage, this has resulted in
the following product features and benefits:

• Highly concentrated product


• Helps to protect wear on fuel pumps and injectors
• High Flash point - no extra storage required
• Easy to transport – no airfreight restrictions
• Considered a non-dangerous, non-hazardous product
• Excellent mixing and compatibility with gas oil
• No tendency to form troublesome gum deposits
• No interaction with other fuel additives

July 2010
AVERAGE DOSAGE:
1 litre per 30 tonnes of fuel.

DOSAGE:
Aderco L 1050 ranges from 1 litre per 10 tonnes up to 40 tonnes

Why is the dosage rate not fixed?


ISO has created a specification for the fuel. According to the results on
measurement from HFFR, the dosage of the lubricity improver can be
calculated. In practical terms, therefore, the scar test and the dosage has
to be calculated accordingly after each bunkering!

A new product assisting to deal with the official Emission


Requirements

The limits applicable in Sulphur Emission Control Areas (SECAs) will be


reduced to
1.0 % effective from 1st July 2010 (from the current 1.5 %; being
further reduced to 0.10 % effective from 1st January 2015.).
The last change which will have immediate effects from 1st January 2010,
is the reduction to 0.10 % of sulphur for those vessels operating in ports
of the SECAs area.

A new grade of distillate fuel is born.

The DMZ is a new grade of distillate fuel. The difference between DMX –
DMA and DMZ is the minimum viscosity of 3.000 mm²/S @40°C
This DMZ is made to respect the minimum requirements of engine
builders at the level of viscosity in Gas Oil.

Do not confound viscosity and lubricity which are total different items
without any link between the one and the other.
For exemple:
You can have a high viscosity with a low grade of lubricity and the inverse
is possible too: a low viscosity and a high grade of lubricity
The use of ADERCO L 1050 will help you highering the level of lubricity
The both following diagrams are showing the results

July 2010
DISTILLATE FUEL STANDARD
ISO 8217-2010

July 2010
How is Diesel Fuel evaluated for lubricating properties:

Diesel fuel and other fluids are tested for lubricating ability using a device
called a “High Frequency Reciprocating Rig” or HFRR. The HFRR is
currently the internationally accepted, standardized method ISO 12156-1
to evaluate fluids for lubricating ability. It uses a ball bearing that
reciprocates or moves back and forth on a metal surface at a very high
frequency during 90 minutes. The machine does this while the ball bearing
and metal surface are immersed in the test fluid (in this case, treated
diesel fuel). At the end of the test the ball bearing is examined under a
microscope and the “wear scar” on the ball bearing is measured in
microns. The larger the wear scar, the poorer the lubricating ability of the
fluid. The independent lab runs every sample twice and averages the size
of the wear scar.

TESTS CONDUCTED WITH SGS ANTWERP IN SEPTEMBER 2009


HFFR TEST ISO 12156-1 @ 60°C during 90’

Max standard following ISO 8217-2010


Out of specs sample tested by SGS
Out of specs sample after treatment with
L1050

July 2010
INSTRUCTION SHEET

ADERCO L 1050 LUBRICITY IMPROVER

1. ADERCO L 1050 CAN HELP YOU

IMPROVE THE LUBRICATING ABILITY OF ULTRA


LOW SULPHUR MGO. IT PREVENTS EXCESSIVE
WEAR ON FUEL PUMPS AND INJECTION
SYSTEM.

2. DOSAGE INSTRUCTIONS

1 LITER ADERCO L 1050 PER 30 TONS OF MGO.

TO BE POURED IN THE STORAGE TANKS THROUGH THE


FEEDLINE, VENT-PIPES OR THE SOUNDING-PIPE BEFORE
BUNKERING.

IF USING A SOUNDING PIPE, BE SURE THAT THE


ADERCO L 1050 HAS BEEN POURED INTO THE TANK.
COMPRESSED AIR CAN BE USED TO BLOW IT INSIDE.

IF THE TANK IS ALREADY FILLED, POUR INTO THE TANK


AND CIRCULATE 5 TIMES THE QUANTITY BY USING A
CIRCULATION PUMP.

AS SOON THE ADERCO L 1050 IS INTRODUCED


INTO THE FUEL, LUBRICITY WILL IMPROVE.

July 2010
TYPICAL SPECIFICATIONS: ADERCO L1050

BLENDING
TYPICAL PROPERTIES
Simply add the required quantity of ADERCO
Appearance: CLEAR LIQUID L 1050 to the diesel tank before fuelling. The
movements of the vessel will be sufficient to
Color: YELLOW TO AMBER adequately mix the additive.

Flash Point (ASTM D 93): 100 oC min. FREIGHT CLASSIFICATION

Pour Point (ASTM D 97): < -9oC Not Regulated

Specific Gravity: 0.91 g/ml SHIPPING


Viscosity in cSt (ASTM
Available in 200 litre non-returnable steel
D445) 16
drums and in 20 litre plastic pails.
40oC

Solubility in: Weight Drum Pail


Petroleum products MISCIBLE Net 185 kg 18.5 kg
Water INSOLUBLE Gross 205 kg 19.7 kg

DESCRIPTION CUSTOMS CLASSIFICATION

Government regulations concerning emissions Harmonized Tariff System: 3811.90


have forced refineries to modify certain
properties of diesel fuel. The result is that
today’s diesel fuel has reduced lubricity. HANDLING
ADERCO L 1050 is an additive specially
formulated to improve lubricity in ultra low Normal precautions for handling petroleum
sulfur diesel fuels. This lubricity is essential products should be observed :
for proper operation of injection pumps and
injectors in diesel engines. - If skin contact does occur: Wash
affected areas with soap and water.

DOSAGE - If eye contact does occur: Immediately


wash with copious amounts of clean
The normal dosage for 1 liter of ADERCO water or an eyewash solution for at
L 1050 varies between 10,000 to 50,000 least 10 minutes.
litres of fuel depending on the severity of the
base fuel. Some diesel fuel can demand
higher dosage of additive. Please contact your STORAGE
ADERCO representative for specific
recommendations. ADERCO Fuel Oil Treatments are
chemically very stable and will remain in
Average dosage: 1 litre per 30 tonnes of fuel. storage for prolonged periods; typically
shelf life will be 24 months. Recommended
Storage and Handling Temperature :
15-35 oC

For specific safety, handling and toxicity


information please refer to the current
Material Safety Data Sheet.

July 2010
Page 1/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Trade name: ADERCO L1050
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the preparation: Fuel Additive
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Aderco Chemical Products Inc.
2572 Boul. Daniel-Johnson
Laval, Quebec
Canada H7T 2R3
Phone: +1 450 902 2600 ; Fax: +1 450 902 2610
email: info@aderco.com
Further information obtainable from:
B-Lands Consulting
WTC, 5 Place Robert Schuman, BP 1516
38025 Grenoble, FRANCE
Tel: +33 476 295 869
Fax: +33 476 295 870
services@reachteam.eu
www.reachteam.eu
1.4 Emergency telephone number
UK - National Poisons Emergency: +44 870 600 6266 (24h - health professionals only).
Ireland - National Poisons Information Centre: +353 1 8379964.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
This product is not classified as hazardous according to Regulation (EC) No 1272/2008.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
This product is not classified as dangerous according to Directive 67/548/EEC or Directive 1999/45/EC.
Information concerning particular hazards for human and environment:
Not applicable.
The product does not have to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
2.2 Label elements
Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product is not subject to identification regulations under EU Directives and the Ordinance on
Hazardous Materials (German GefStoffV).
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description: Mixture consisting of the following components.
Hazardous components: Not applicable.
(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

Trade name: ADERCO L1050

(Contd. of page 1)
Non-hazardous components:
CAS: 129813-58-7 Benzene, mono-C10-13-alkyl derivs. 15-40%
EC number: 603-362-3
Additional information: For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General information: No special measures required.
After inhalation: Supply fresh air. Consult a doctor if symptoms persist.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: Do not induce vomiting; call for medical help immediately.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
No further relevant information available.
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Remove persons from danger area.
6.2 Environmental precautions Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
Information about fire - and explosion protection:
Protect from heat.
Keep ignition sources away - Do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

Trade name: ADERCO L1050

(Contd. of page 2)

Information about storage in one common storage facility: Not required.


Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
Store receptacle in a well ventilated area.
Store in a cool place.
7.3 Specific end use(s): No further relevant information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Ensure that washing facilities are available at the work place.
Respiratory protection: Not required.
Protection of hands:

Protective gloves

PVC gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
Penetration time of glove material:
The exact break through time must be determined by the manufacturer of the protective gloves.
Eye protection: Goggles recommended during refilling
Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid.
Colour: Yellow.
Odour: Undetermined
Odour threshold: Not determined.
(Contd. on page 4)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

Trade name: ADERCO L1050

(Contd. of page 3)

pH-value: Not determined.


Melting point/Melting range: < - 21 °C
Boiling point/Boiling range: Not determined.
Flash point: 159 °C
Flammability (solid, gaseous): Not applicable.
Ignition temperature: Not determined.
Decomposition temperature: Not determined.
Self-igniting: Not determined.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Oxidizing properties Not determined.
Vapour pressure: Not determined.
Density at 20 °C: 0.8 g/cm³
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic at 20 °C: 21.45 cSt
9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
10.1 Reactivity No data available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions
Reacts with oxidizing agents.
Reacts with reducing agents.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products Carbon monoxide and carbon dioxide.
(Contd. on page 5)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

Trade name: ADERCO L1050

(Contd. of page 4)

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
LD/LC50 values:
129813-58-7 Benzene, mono-C10-13-alkyl derivs.
Oral LD50 34 g/kg bw (Rat)
Primary irritant effect:
on the skin: May cause irritation.
on the eye: May cause irritation.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information
Use according to the good working pactice. Avoid transfer into the environment.
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Must be specially treated adhering to official regulations.
Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information
14.1 UN Number
ADR, ADN, IMDG, IATA Not applicable.
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA Not applicable.
14.3 Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class Not applicable.
(Contd. on page 6)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.05.2013 Version number 1 Revision: 09.05.2013

Trade name: ADERCO L1050

(Contd. of page 5)

14.4 Packing group


ADR, IMDG, IATA Not applicable.
14.5 Environmental hazards
Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II
of MARPOL 73/78 and the IBC Code Not applicable.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning
the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent

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