CLASS : 12th (Sr. Secondary) Code No.

4329
Series : SS-M/2019
Roll No. SET : B
jlk;u foKku
CHEMISTRY
[ Hindi and English Medium ]
ACADEMIC/OPEN
(Only for Fresh/Re-appear Candidates)

Time allowed : 3 hours ] [ Maximum Marks : 70

• d`i;k tk¡p dj ysa fd bl iz'u-i= esa eqfnzr i`"B 16 rFkk
iz'u 21 gSaA
Please make sure that the printed pages in this
question paper are 16 in number and it contains 21
questions.
• iz'u-i= esa nkfgus gkFk dh vksj fn;s x;s dksM uEcj rFkk lsV dks
Nk= mÙkj-iqfLrdk ds eq[;-i`"B ij fy[ksaA
The Code No. and Set on the right side of the
question paper should be written by the candidate
on the front page of the answer-book.
• d`i;k iz'u dk mÙkj fy[kuk 'kq: djus ls igys] iz'u dk Øekad
vo'; fy[ksaA
Before beginning to answer a question, its Serial
Number must be written.

4329/(Set : B) P. T. O.
 (2) 4329/(Set : B)
• mÙkj-iqfLrdk ds chp esa [kkyh iUuk / iUus u NksMsa+A
Don’t leave blank page / pages in your answer-book.
• mÙkj-iqfLrdk ds vfrfjDr dksbZ vU; 'khV ugha feysxhA vr%
vko';drkuqlkj gh fy[ksa vkSj fy[kk mÙkj u dkVsaA
Except answer-book, no extra sheet will be given.
Write to the point and do not strike the written
answer.
• ijh{kkFkhZ viuk jksy ua0 iz'u-i= ij vo'; fy[ksaA
Candidates must write their Roll Number on the
question paper.
• d`i;k iz'uksa dk mÙkj nsus lss iwoZ ;g lqfuf'pr dj ysa fd iz'u-i=
iw.kZ o lgh gS] ijh{kk ds mijkUr bl lEcU/k esa dksbZ Hkh nkok
Lohdkj ugha fd;k tk;sxkA
Before answering the question, ensure that you
have been supplied the correct and complete
question paper, no claim in this regard, will be
entertained after examination.

lkekU; funsZ'k % &

(i) LkHkh iz'u vfuok;Z gSaA
(ii) ç'u la[;k 1 esa pkSng (i - xiv) oLrqfu"B iz'u gSAa izR;sd
iz'u 1 vad dk gSA funsZ'kkuqlkj bu iz'uksa ds mÙkj
nhft,A
(iii) ç'u la[;k 2 ls 11 rd vfry?kq mÙkjh; ç'u gSaA çR;sd
iz'u 2 vadksa dk gSA izR;sd iz'u dk mÙkj yxHkx 30
'kCnksa esa nhft,A

4329/(Set : B)
 (3) 4329/(Set : B)
(iv) ç'u la[;k 12 ls 18 rd y?kq mÙkjh; ç'u gSaA çR;sd
ç'u 3 vadksa dk gSA izR;sd iz'u dk mÙkj yxHkx 40
'kCnksa esa nhft,A
(v) ç'u la[;k 19 ls 21 rd nh?kZ mÙkjh; ç'u gSaA çR;sd
ç'u 5 vadksa dk gSA izR;sd iz'u dk mÙkj yxHkx 70
'kCnksa esa nhft,A
(vi) iz'u-i= esa lexz :i ls dksbZ fodYi ugha gSA rFkkfi 5
vadksa okys lHkh nh?kZ mÙkjh; iz'uksa esa vkarfjd p;u iznku
fd;k x;k gSA ,sls iz'uksa esa ls vkidks dsoy ,d gh iz'u
djuk gSA
General Instructions : –
(i) All questions are compulsory.
(ii) Question Number 1 consists of Fourteen (i-xiv)
objective type questions carrying 1 mark
each. Answer these questions as per
instructions.
(iii) Question Numbers 2 to 11 are very short
answer type questions of 2 marks each.
Answer these in about 30 words each.
(iv) Question Numbers 12 to 18 are short answer
type questions of 3 marks each. Answer
these in about 40 words each.
(v) Question Numbers 19 to 21 are long answer
type questions of 5 marks each. Answer
these in about 70 words each.

4329/(Set : B) P. T. O.
 (4) 4329/(Set : B)
(vi) There is no over all choice. However, internal
choice is given in all long answer type
questions of 5 marks each. You have to
attempt only one of the given choice in such
questions.

[ oLrqfu"B iz'u ]
[ Objective Type Questions ]

fuEufyf[kr cgqfodYih; iz'uksa ds lgh fodYi pqudj mÙkj-

iqfLrdk esa fyf[k, %
Choose the correct option of the following
multiple choice questions and write in answer-
book :

1. (i) fuEu esa ls fdl mRÑ"V xSl dk iz;ksx foKkiu izn'kZu gsrq
fd;k tkrk gS \ 1

(A) Rn (B) Ne
(C) Xe (D) He
Which of the following Noble gas is used for
advertisement display ?

(A) Rn (B) Ne
(C) Xe (D) He

4329/(Set : B)
 (5) 4329/(Set : B)
(ii) fuEu esa ls izcyre vEy dkSu&lk gS \ 1
COOH COOH
(A) (B)

NO2

COOH COOH
(C) (D)

OCH3 CH3

Which of the following is most acidic ?

COOH COOH
(A) (B)

NO2

COOH COOH
(C) (D)

OCH3 CH3

(iii) eksyy mUu;u fLFkjkad dks bl uke ls Hkh tkurs gSa % 1

(A) Øk;ksLdksfid fLFkjkad

(B) xSl fLFkjkad
(C) ,cqfyvksLdksfid fLFkjkad
(D) fgekad voueu fLFkjkad

4329/(Set : B) P. T. O.
 (6) 4329/(Set : B)
Molal elevation constant is also called as :
(A) Cryoscopic constant
(B) Gas constant
(C) Ebullioscopic constant
(D) Freezing point depression constant

(iv) fuEu esa ls v/kZ&la'ysf"kr cgqyd dk mnkgj.k gS % 1

(A) lsyqyksl ukbVªsV (B) LVkpZ
(C) lsyqyksl (D) C;wuk-S
Example of semi-synthetic polymer is :
(A) Cellulose nitrate (B) Starch
(C) Cellulose (D) Buna-S
H 2SO4
(v) CH 3 − CH 2 − OH   
→ X ; X D;k gS \ 1
413K

(A) CH 2 = CH 2
(B) C 2H 5 − O − C 2H 5
(C) CH 3 − O − CH 2 − CH 3
(D) CH 3CH 2 HSO 4
H 2SO4
CH 3 − CH 2 − OH   
→ X ; what is X ?
413K

(A) CH 2 = CH 2
(B) C 2H 5 − O − C 2H 5
(C) CH 3 − O − CH 2 − CH 3
(D) CH 3CH 2 HSO 4

4329/(Set : B)
 (7) 4329/(Set : B)
fuEufyf[kr iz'uksa ds mÙkj ,d ;k nks okD;ksa esa nhft, %
Answer the following questions in one or two
sentences :

(vi) nks /kkrqvksa dk uke crkb, ftudk fu"d"kZ.k oS|qr~ vi?kVu

ls gksrk gS \ 1

Name two metals which are extracted

electrolytically.

(vii) tfVy vfHkfØ;k,¡ D;k gksrh gSa \ 1

What are complex reactions ?

(viii) ,LikVsZe dk iz;ksx dsoy BaMs [kk| ,oa is; inkFkksZa rd

lhfer D;ksa gS \ 1

Why is use of aspartame limited to cold

foods and drinks ?

(ix) vipk;h 'kdZjk D;k gksrh gS \ 1

What are reducing sugars ?

(x) foVkfeu K dh deh ls gksus okyh chekjh dk uke crk,¡A1

Name the disease caused by deficiency of
Vitamin K.

(xi) vifeJ.k ls vki D;k le>rs gSa \ 1

What do you mean by Doping ?

4329/(Set : B) P. T. O.
 (8) 4329/(Set : B)
(xii) Ldanu dks ifjHkkf"kr dhft,A 1
Define coagulation.
(xiii) K 4 [Mn (CN )6 ] dk IUPAC uke fyf[k,A 1

Write IUPAC name of K 4 [Mn (CN )6 ] .

(xiv) ,sfYdy gSykbMksa dh β-foyksiu vfHkfØ;k dk ,d mnkgj.k
nhft,A 1
Give an example of β-elimination reaction of
alkyl halides.

[ vfry?kq mÙkjh; iz'u ]

[ Very Short Answer Type Questions ]

2. dkfcZy,sehu vfHkfØ;k ij ,d y?kq fVIi.kh fyf[k,A 2

Write a short note on carbylamine reaction.

3. vki ,suhyhu dks fuEu esa dSls ifjofrZr djsaxs \ 1+1=2

How will you convert aniline into the following ?
(a) p-czkseks,sfuyhu
p-bromoaniline
(b) p-gkbMªkWDlh,stkscsUthu
p-hydroxyazobenzene

4. ukbVªkstu f}ijek.kqd v.kq ds :i esa ik;k tkrk gS rFkk

QkWLQksjl P4 ds :i es]a D;ksa \ 2
Nitrogen exist as diatomic molecule and
phosphorous as P4, why ?
4329/(Set : B)
 (9) 4329/(Set : B)
5. 293 K ij ty dk ok"i nkc 17.535 mm Hg gSA ;fn
25 g Xywdksl dks 450 g ty esa ?kksys]a rks 293 K ij ty dk
ok"i nkc ifjdfyr dhft,A 2
Vapour pressure of water at 293 K is 17.535 mm
Hg. Calculate the vapour pressure of water at
293 K when 25 g of glucose is dissolved in 450 g
of water.

6. QSjkMs ds oS|qr&~ vi?kVu ds izFke fu;e dks O;Dr dhft,A 2

State Faraday's first law of electrolysis.

7. NaCl, HCl ,oa NaAc ds fy, ∧ om Øe'k% 126.4,

425.9 ,oa 91.05 cm2 mol–1 gSA HAc ds fy, ∧ o dk
ifjdyu dhft,A 2
o
∧ m for
NaCl, HCl and NaAc are 126.4, 425.9
and 91.05 cm2 mol–1 respectively. Calculate ∧ o
for HAc.

8. gsujh fu;e dh lgk;rk ls fpfdRlh; voLFkk csaM~l dks

le>kb,A 2
With the help of Henry's law, explain the medical
condition known as bends.

9. iz'kkard D;k gksrs gSa \ budk mi;ksx D;k gS \ 2

What are Tranquilizers ? What is their use ?

10. lecgqyd vkSj lgcgqyd inksa ¼'kCnksa½ esa foHksn dj izR;sd dk

,d mnkgj.k nhft,A 2
Distinguish between the terms homopolymer
and copolymer and give one example of each.

4329/(Set : B) P. T. O.
 ( 10 ) 4329/(Set : B)
11. DNA rFkk RNA esa pkj varj fyf[k,A 2

Write four differences between DNA and RNA.

[ y?kq mÙkjh; iz'u ]

[ Short Answer Type Questions ]

12. (a) dkWij fcc tkyd :i esa fØLVyhÑr gksrk gS] ftlds dksj
dh yackbZ 3.61 × 10 −8 cm gSA ;g n'kkZb, fd x.kuk
fd, ?kuRo ds eku rFkk ekis x, ?kuRo 8.92 g/cm3 esa
lekurk gSA 2

Copper crystallizes in fcc lattice with edge

length 3.61 × 10 −8 cm. Show that the
calculated density is in agreement with its
measured value of 8.92 g/cm3.
(b) var%dsafnzr tkyd dh ,dd dksf"Bdk esa fdrus tkyd
fcUnq gksrs gSa \ 1

How many lattice points are there in one

unit cell of body centered lattice ?

13. ^^larqfyr jklk;fud lehdj.k] vfHkfØ;k dSls gks jgh gS( bldk
lgh fp=.k dHkh Hkh izLrqr ugha djrhA** bl dFku dks ,d
lVhd mnkgj.k nsdj U;k;laxr fl) dhft,A 3
"A balanced chemical equation never gives us a
true picture of how a reaction takes place."
Justify the statement by taking a suitable
example.

4329/(Set : B)
 ( 11 ) 4329/(Set : B)
14. vf/k'kks"k.k lerkih oØ D;k gS \ ÝkW;UMfyd vf/k'kks"k.k lerkih
oØ dk o.kZu dhft,A 3
What is an adsorption isotherm ? Describe
Freundlich adsorption isotherm.

15. fuEu vfHkfØ;k dh fØ;kfof/k nhft, % 3

Br
|
HBr
CH 3 − CH − CH − CH 3  →CH 3 − C − CH 2 − CH 3
| | |
CH 3 OH CH 3
Give mechanism for following reaction :
Br
|
HBr
CH 3 − CH − CH − CH 3  →CH 3 − C − CH 2 − CH 3
| | |
CH 3 OH CH 3

16. le>kb, D;ksa %

(a) ,sfYdy gSykbM /kzqoh; gksrs gq, Hkh ty esa vfeJ.kh; gSa \ 2
(b) fxzxukMZ vfHkdeZd dk fojpu futZyh; voLFkkvksa esa
djuk pkfg, \ 1

Explain why :
(a) Alkyl halides, though polar, are immiscible
with water ?

(b) Grignard reagent should be prepared under

anhydrous conditions ?

4329/(Set : B) P. T. O.
 ( 12 ) 4329/(Set : B)
17. (a) [Fe (CN )6 ] 4 − rFkk [Fe (H 2O )6 ] 2 + ds ruq foy;uksa
ds jax fHkUu gksrs gSaA D;ksa \ 2

[Fe (CN )6 ] 4 − and [Fe (H 2O )6 ] 2 + are of

different colours in dilute solution. Why ?
(b) [Co(NH 3 )Cl (en )2 ] 2 + ds izdkf'kr leko;oksa dh
lajpuk cukb,A 1

Draw structures of optical isomers of

[Co(NH 3 )Cl (en )2 ] 2 + .

18. (a) lksus ds fu"d"kZ.k esa fu{kkyu dk D;k egÙo gS \ 1½

What is the significance of leaching in the

extraction of Gold ?
(b) dkWij esV dks flfydk dh ijr p<+s gq, ifjorZd esa D;ksa
j[kk tkrk gS \ 1½

Why copper matte is put in silica lined

converter ?

[ nh?kZ mÙkjh; iz'u ]

[ Long Answer Type Questions ]

19. (a) O3 ,d izcy vkWDlhdkjd dh rjg D;ksa fØ;k djrh

gS \ 2

Why does O 3 act as powerful oxidizing

agent ?

4329/(Set : B)
 ( 13 ) 4329/(Set : B)
(b) ¶yqvksjhu dh bysDVªkWu yfC/k ,UFkSYih Dyksjhu dh rqyuk esa
de _.kkRed D;ksa gksrh gS \ 2

Why does electron gain enthalpy of fluorine

is less negative as compared to chlorine ?

(c) fuEu vfHkfØ;k dks iwjk dhft, % 1

XeF2 + H 2O → ?
Complete the reaction :
XeF2 + H 2O → ?

vFkok
OR

fuEufyf[kr dks Li"V dhft, %

(a) ghfy;e dks xksrk[kksjh ds midj.kksa esa mi;ksx fd;k tkrk
gSA 1½

(b) H 3 PO 4 f={kkjdh; vEy gSA 2

(c) gSykstu izcy vkWDlhdkjd gksrs gSaA 1½

Account for the following :

(a) Helium is used in diving apparatus.

(b) H 3 PO 4 is tribasic acid.

(c) Halogens are strong oxidizing agent.

4329/(Set : B) P. T. O.
 ( 14 ) 4329/(Set : B)
20. (a) dkj.k nsrs gq, Li"V dhft, %
(i) laØe.k /kkrq ds vkWDlks_.kk;uksa esa mPpre
vkWDlhdj.k voLFkk iznf'kZr gksrh gSA 2

(ii) dkWij ds fy, E o (M 2 + / M ) dk eku /kukRed

(0.34 V) gSA 2

Explain giving reasons :

(i) The highest oxidation state is exhibited
in oxoanions of a transition metal.
(ii) The E o (M 2 + / M ) value for copper is
positive (0.34 V).
(b) ySUFksuk;Mksa }kjk dkSu&dkSu&lh vkWDlhdj.k voLFkk,¡
iznf'kZr dh tkrh gSa \ 1
What are different oxidation states
exhibited by the lanthanoids ?

vFkok
OR

(a) fuEu jklk;fud lehdj.kksa dks iwjk dhft, % 1+1=2

(i) MnO 4− + I − + H + → ?
(ii) Cr2O72− + Sn 2+ + H + → ?
Complete the following chemical equations :
(i) MnO 4− + I − + H + → ?
(ii) Cr2O72− + Sn 2+ + H + → ?

4329/(Set : B)
 ( 15 ) 4329/(Set : B)
(b) izFke laØe.k Js.kh esa dkSu&lh /kkrq cgq/kk rFkk D;ksa +1
vkWDlhdj.k voLFkk iznf'kZr djrh gS \ 1

Which metal in the first series of transition

metals exhibits +1 oxidation state most
frequently and why ?

(c) La(OH )3 vkSj Lu(OH )3 esa vf/kd {kkjh; dkSu&lk gS

vkSj D;ksa \ 2

Which out of La(OH )3 and Lu(OH )3 is more

basic and why ?

21. (a) csUtSfYMgkbM ,oa ,lhVksQhuksu esa foHksn djus ds fy, ,d

ljy jklk;fud ijh{k.k nhft,A 2

Give a simple chemical test to distinguish

between benzaldehyde and acetophenone.

(b) fuEu vfHkfØ;k dks iwjk dhft, % 1

O [ Ag (NH 3 )2 ] +OH −
     → ?
CHO
Complete the reaction :
O [ Ag (NH 3 )2 ] +OH −
     → ?
CHO

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 ( 16 ) 4329/(Set : B)
(c) csUtksbd vEy vkSj Qsfuy,slhfVd vEy esa ls dkSu&lk
izcy vEy gS vkSj D;ksa \ 2
Out of benzoic acid and phenylacetic acid,
which is stronger acid and why ?

vFkok
OR

(a) ,d dkcZfud ;kSfxd ^d* ¼vkf.od lw= C 8 H16O 2 ½ dks

ruq H 2SO 4 ds lkFk ty vi?kfVr djus ds mijkar ,d
dkcksZfDlfyd vEy ^[k* ,oa ,d ,sYdksgkWy ^x* izkIr gq,A
^x* dks Øksfed vEy ds lkFk vkWDlhÑr djus ij ^[k*
mRiUu gksrk gSA ^x* futZyhdj.k ij C;wV&1&bZu nsrk gSA
vfHkfØ;kvksa esa iz;qDr gksus okys lHkh jklk;fud
lehdj.kksa dks fyf[k,A 3½
An organic compound 'A' (molecular
formula C 8 H16O 2 ) was hydrolysed with dil.
H 2SO 4 to give a carboxylic acid 'B' and an
alcohol 'C'. Oxidation of 'C' with chromic
acid produced 'B'. 'C' on dehydration gives
but-1-ene. Write equations for the reactions
involved.
(b) oksYQ&fd'uj vip;u ij ,d y?kq fVIi.kh fyf[k,A 1½
Write a short note on Wolf-Kishner reduction.

S
4329/(Set : B)