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CLASS : 12th Sr. Sec.(Academic) Code No. 3029

Series : SS-M/2016
Roll No. SET : C

jmeeÙeve efJe%eeve
CHEMISTRY
[ Hindi and English Medium ]
ACADEMIC
2nd SEMESTER
(Only for Fresh/Re-appear Candidates)
Evening Session

Time allowed : 2½ hours ] [ Maximum Marks : 60

• ke=âheÙee peeBÛe keâj ueW efkeâ Fme ØeMve-he$e ceW cegefõle he=‰ 16 leLee
ØeMve 18 nQ~
Please make sure that the printed pages in this
question paper are 16 in number and it contains
18 questions.

• ØeMve-he$e ceW oeefnves neLe keâer Deesj efoÙes ieÙes keâes[ vecyej leLee mesš keâes Úe$e
Gòej-hegefmlekeâe kesâ cegKÙe-he=‰ hej efueKeW~
The Code No. and Set on the right side of the
question paper should be written by the candidate
on the front page of the answer-book.
• ke=âheÙee ØeMve keâe Gòej efueKevee Meg™ keâjves mes henues, ØeMve keâe ›eâceebkeâ DeJeMÙe
efueKeW~
Before beginning to answer a question, its Serial
Number must be written.
3029/ (Set : C) P. T. O.
 (2) 3029/ (Set : C)
• Gòej-hegefmlekeâe kesâ yeerÛe cesb Keeueer hevvee/hevves ve ÚesÌ[W~
Don’t leave blank page / pages in your answer-
book.

• Gòej-hegemf lekeâe kesâ Deefleefjkeäle keâesF& DevÙe Meerš veneR efceuesieer~ Dele:
DeeJeMÙekeâleevegmeej ner efueKeW Deewj efueKee Gòej ve keâešW~
Except answer-book, no extra sheet will be given.
Write to the point and do not strike the written
answer.

• hejer#eeLeea Dehevee jesue veb0 ØeMve-he$e hej DeJeMÙe efueKeW~

Candidates must write their Roll Number on the
question paper.

• ke=âheÙee ØeMveeW keâe Gòej osves mes hetJe& Ùen megefveefMÛele keâj ueW efkeâ ØeMve-he$e hetCe&
Je mener nw, hejer#ee kesâ Ghejevle Fme mecyevOe ceW keâesF& Yeer oeJee mJeerkeâej
veneR efkeâÙee peeÙesiee~
Before answering the questions, ensure that you
have been supplied the correct and complete
question paper, no claim in this regard, will be
entertained after examination.

meeceevÙe efveoxMe :
(i) meYeer ØeMve DeefveJeeÙe& nQ~
(ii) ØelÙeskeâ ØeMve kesâ Debkeâ Gmekesâ meeceves oMee&S ieS nQ~

3029/ (Set : C)
 (3) 3029/ (Set : C)
(iii) ØeMve mebKÙee 1 ceW yeejn (i-xii) yengefJekeâuheerÙe/Skeâ Meyo Jeeues
ØeMve nQ~ ØelÙeskeâ ØeMve kesâ efueS 1 Debkeâ nw~ mener Gòej Deheveer
Gòej-hegefmlekeâe ceW efueKeW~
(iv) ØeMve mebKÙee 2 mes 10 lekeâ DeefleueIeg GòejerÙe ØeMve nQ~
ØelÙeskeâ ØeMve 2 DebkeâeW keâe nw~ ØelÙeskeâ ØeMve keâe Gòej ueieYeie
30 MeyoeW ceW oerefpeS~
(v) ØeMve mebKÙee 11 mes 15 lekeâ ueIeg GòejerÙe ØeMve nQ~
ØelÙeskeâ ØeMve 3 DebkeâeW keâe nw~ ØelÙeskeâ ØeMve keâe Gòej ueieYeie
40 MeyoeW ceW oerefpeS~
(vi) ØeMve mebKÙee 16 mes 18 lekeâ oerIe& GòejerÙe ØeMve nQ~
ØelÙeskeâ ØeMve 5 DebkeâeW keâe nw~ ØelÙeskeâ ØeMve keâe Gòej ueieYeie 70

MeyoeW ceW oerefpeS~

(vii) ØeMve-he$e ceW mece«e ™he mes keâesF& efJekeâuhe veneR nw~ leLeeefhe 5

DebkeâeW Jeeues leerveeW ØeMveeW ceW Deebleefjkeâ ÛeÙeve Øeoeve efkeâÙee ieÙee nw~
Ssmes ØeMveeW ceW mes Deehe keâes kesâJeue Skeâ ner ØeMve keâjvee nw~
General Instructions :

(i) All questions are compulsory.

(ii) Marks for each question are indicated

against it.
3029/ (Set : C) P. T. O.
 (4) 3029/ (Set : C)
(iii) Question Number 1 consists of twelve (i-xii)
multiple choice/one word type questions
carrying 1 mark each. Write correct answer
in your answer-book.
(iv) Question Numbers 2 to 10 are very short
answer type questions of 2 marks each.
Answer these in about 30 words each.
(v) Question Numbers 11 to 15 are short
answer type questions of 3 marks each.
Answer these in about 40 words each.
(vi) Question Numbers 16 to 18 are long answer
type questions of 5 marks each. Answer
these in about 70 words each.
(vii) There is no over all choice. However, internal
choice is given in all long answer type
questions of 5 marks each. You have to
attempt only one of the given choice in such
questions.

1. (i) DevegÛegcyekeâlee keâe yeÌ{lee ›eâce nesiee : 1

(A) Cu 2+ , Co 2+ , Mn 2+ , Ni 2+

(B) Co 2+ , Cu 2+ , Mn 2+ , Ni 2+

(C) Cu 2+ , Ni 2+ , Co 2+ , Mn 2+

(D) Mn 2+ , Co 2+ Ni 2+ , Cu 2+

3029/ (Set : C)
 (5) 3029/ (Set : C)
Increasing order of Paramagnetism is :

(A) Cu 2+ , Co 2+ , Mn 2+ , Ni 2+

(B) Co 2+ , Cu 2+ , Mn 2+ , Ni 2+

(C) Cu 2+ , Ni 2+ , Co 2+ , Mn 2+

(D) Mn 2+ , Co 2+ Ni 2+ , Cu 2+

CH2–CHOH–CH3
(ii) keâe IUPAC veece efueefKeS~ 1

CH2–CHOH–CH3
Write IUPAC name of

(iii) Oeeleg keâeyeexefveueeW ceW heeÙee peelee nw : 1

(A) M −C σ DeeyebOe
(B) M − C π DeeyebOe
(C) M − C σ Je M − C π DeeyebOe
(D) FveceW mes keâesF& veneR
Which is present in Metal carbonyls ?
(A) M − C σ bond
(B) M − C π bond
(C) M − C σ and M − C π bond
(D) None of these

3029/ (Set : C) P. T. O.
 (6) 3029/ (Set : C)
(iv) efJešeefceve B12 meeÙeveeskeâesyeeuesefceve ceWs keâewve-meer Oeeleg nw ? 1

(A) Fe (B) Co

(C) Mg (D) Pt

Which metal is present in vitamin B12

Cyanocobalamin ?

(A) Fe (B) Co

(C) Mg (D) Pt

(v) yÙetšsve-2, 3-[eFDeeve keâer mebjÛevee efueefKeS~ 1

Give the structure of Butane-2, 3-dione.

(vi) heesšwefMeÙece hesâjermeeÙeveeF[ keâe met$e nw : 1

(A) K 2 [Fe (CN )6 ] (B) K [Fe (CN )6 ]

(C) K 4 [Fe (CN )6 ] (D) K 3 [Fe (CN ) 6 ]

Potassium ferricyanide is :
(A) K 2 [Fe (CN )6 ] (B) K [Fe (CN )6 ]

(C) K 4 [Fe (CN )6 ] (D) K 3 [Fe (CN ) 6 ]

(vii) efvecveefueefKele ceW mes Øeekeâ=eflekeâ yenguekeâ nw : 1

(A) šsheäuee@ve (B) hee@efueLeerve

(C) veeFuee@ve-6 (D) mšeÛe&
3029/ (Set : C)
 (7) 3029/ (Set : C)
Which of the following is naturally
occurring polymer ?

(A) Teflon (B) Polythene

(C) Nylon-6 (D) Starch

(viii) ceeušesme keâs peue DeheIešve mes Øeehle ceesveesmewkesâjeF[eW kesâ veece
yeleeFS~ 1

Give the names of monosaccharides

obtained when Maltose is hydrolyzed.
(ix) yewkeâsueeFš efvecveefueefKele ceW mes efkeâmekeâe yenguekeâ nQ ? 1

(A) heâervee@ue-heâe@cexefu[neF[
(B) heâervee@ue-heâeefce&keâ Decue
(C) yesv]peesFkeâ Decue-heâe@cexefu[neF[
(D) Lewefuekeâ Decue-heâervee@ue
Bakelite is a polymer of :
(A) Phenol-formaldehyde
(B) Phenol-formic acid
(C) Benzoic acid-formaldehyde
(D) Phthalic acid-phenol
(x) efvecveefueefKele ceW mes efkeâmekeâe efÉOegÇJe DeeIetCe& meJee&efOekeâ nesiee ? 1

(A) CH 2Cl 2 (B) CHCl3

(C) CCl 4 (D) CO2

3029/ (Set : C) P. T. O.
 (8) 3029/ (Set : C)
Which has maximum dipolemoment ?
(A) CH 2Cl 2 (B) CHCl3

(C) CCl 4 (D) CO2

NHCH3
(xi) keâe pkb ceeve CH 3NH 2 mes nesiee : 1

(A) DeefOekeâ (B) keâce

(C) yejeyej (D) FveceW mes keâesF& veneR
NHCH3
The pkb value of as compare
to CH 3NH 2 is :

(A) More (B) Less

(C) Equal (D) None of these

CH3

UV Light
(xii) + Cl 2 → X, Glheeo X nQ : 1

(A) C6H 5Cl (B) C6H 5CH 2Cl

(C) C6H 5CHO (D) CHCl3

3029/ (Set : C)
 (9) 3029/ (Set : C)

CH3
UV Light
+ Cl 2 → X , Product X is :

(A) C6H 5Cl (B) C6H 5CH 2Cl

(C) C6H 5CHO (D) CHCl3

2. meb›eâceCe lelJe mebkegâue Ùeewefiekeâesb keâer jÛevee keâjles nQ ? cegKÙe keâejCe

efueefKeS~ 2

The transition metals form a large number of

complex compounds. Give main reasons.

3. [Fe (H 2O )6 ]3+ Je [Fe (C2O4 )3 ]3− mebkegâueeW ceW keâewve DeefOekeâ

mLeeÙeer nw Deewj keäÙeeW ? 2

[
Among Fe (H 2O )6 ]3+ [
and Fe (C2O4 )3 ]3− complex

which is more stable and why ?

EXCESS
4. CH 3OC 2H 5 + HI   → A + B

Glheeo A Je B keâer mebjÛevee efueefKeS~ 2

EXCESS
CH 3OC2H 5 + HI   → A + B

Give structures of A and B products.

3029/ (Set : C) P. T. O.
 ( 10 ) 3029/ (Set : C)

5. [Cr (NH 3 )5 Cl ] Cl 2 mebkegâue keâe IUPAC veece GhemenmebÙeespeve

mebKÙee DeekeämeerkeâjCe DeJemLee Je ÛegcyekeâerÙe DeeIetCe& yeleeFS~ 2
Give IUPAC name, coordination number,
oxidation state and magnetic moment of
complex [Cr (NH 3 )5 Cl ] Cl 2 .

6. Øeeshesveesve Je Øeeshesvewue ceW efJeYeso keâjves kesâ efueS Skeâ jemeeÙeefvekeâ hejer#eCe
oerefpeS~ 2
Give a chemical test to distinguish between
propanone and propanal.

7. DNA Je RNA ceW oes mebjÛeveelcekeâ Deblej efueefKeS~ 2

Give two differences between DNA and RNA.

8. C6H 5COOH Je CH 3CH 2COOH DecueeW ceW keâewve Øeyeue Decue

nw Deewj keäÙeeW ? 2
Among C6H 5COOH and CH 3CH 2COOH which is
a stronger acid and why ?

9. Øeesšerve kesâ meboYe& ceW efvecveefueefKele keâer heefjYee<ee efueefKeS : 2

(i) heshšeF[ yevOelee

(ii) [ervesÛegjsMeve (efJekeâ=eflekeâjCe)

3029/ (Set : C)
 ( 11 ) 3029/ (Set : C)
Define the following terms in relation to
proteins :

(i) Peptide linkage

(ii) Denaturation

10. ef›eâmšue #es$e efmeæevle kesâ DeeOeej hej mebkegâueeW kesâ jbieeW keâer JÙeeKÙee efkeâme
Øekeâej keâer peeleer nw ? 2

How does crystal field theory explain the colour

of complexes.

11. Ssmee keäÙeeW nw efkeâ meeceevÙelee uewvLesveeF[eW keâer Dehes#ee SsefkeäšveeF[eW keâer
GheÛeÙeve DeJemLeeDeeW keâe heefjmej DeefOekeâ nw ? 3

Why do actinides, in general, exhibit a greater

range of oxidation states than the lanthanides.

12. efvecve keâe JeCe&ve keâjW : 3

(a) Jegšd]&pe-efheâefšie DeefYeef›eâÙee

(b) mesv[cesÙej DeefYeef›eâÙee
Describe the following :

(a) Wurtz Fittig reaction

(b) Sandmeyers reaction

3029/ (Set : C) P. T. O.
 ( 12 ) 3029/ (Set : C)
13. leehemegIešddÙe Je leeheo=Ì{ yenguekeâeW ceW efJeYesokeâj Skeâ-Skeâ GoenjCe meefnle
mecePeeFS~ 3

Distinguish between thermoplastic and

thermosetting polymers by taking one example
of each.

14. meb›eâceCe Oeeleg Deewj Gvekesâ Ùeewefiekeâ meeOeejCeleÙee DeÛÚs GlØesjkeâ keâe keâeÙe&
keâjles nbw~ JÙeeKÙee keâerefpeS~ 3

Transition metals and their compounds are

generally found to be good catalysts. Explain.

15. efvecveefueefKele DeefYeef›eâÙee meceerkeâjCeeW keâes hetCe& keâerefpeS : 3

+ −
(i) C 6H 5 N 2 Cl + KI −−→

H H
(ii) C = C + Br2 CCl→
4
H H

Cl

Anhyd. AlCl 3
(iii) + CH 3COCl →

Complete the following reaction equations :

+ −
(i) C 6H 5 N 2 Cl + KI −−→

3029/ (Set : C)
 ( 13 ) 3029/ (Set : C)
H H
(ii) C = C + Br2 CCl→
4
H H

Cl

Anhyd . AlCl 3
(iii) + CH 3COCl →

16. (a) efvecveefueefKele keâe ™heeblej kewâmes keâjWies ? 3

(i) heâervee@ue keâe yesv]peerve ceW

(ii) Heâervee@ue keâe yesv]peesefkeäJeveesve ceW
(iii) Øeesheerve keâe Øeeshewve-2-Deeue ceW
(b) yesefv]peue Ssukeâesne@ue Je heâervee@ue ceW kewâmes Devlej keâjWies ? 2

(a) How would you convert the following :

(i) Phenol to Benzene
(ii) Phenol to Benzoquinone
(iii) Propene to propan-2-ol

(b) How will you distinguish between benzyl

alcohol & phenol.
DeLeJee
OR
(a) efvecve DeefYeef›eâÙee hetCe& keâerefpeS : 2

HI KCN
CH 3OH → A → B REDUCTION→ C
[H ]
HNO 2
D

3029/ (Set : C) P. T. O.
 ( 14 ) 3029/ (Set : C)
(b) SLee@keämeerSLesve peue ceW IegueveMeerue nw~ mecePeeFS~ 2

(c) F&Lej kesâ efJejÛeve kesâ efueS HI Je HBr ceW mes keâewve GheÙegkeäle nw ? 1

(a) Complete the following reaction :

HI KCN
CH 3OH → A → B REDUCTION→ C
[H ]
HNO 2
D

(b) How do you account for the miscibility of

Ethoxyethane in water ?

(c) Among HI & HBr which is a better reagent

for cleavage of ether ?

17. efvecve keâe JeCe&ve keâerefpeS :

(a) keâeefye&ueSsceerve DeefYeef›eâÙee 2 21

(b) Ùegiceve DeefYeef›eâÙee 2 21

Describe the following :

(a) Carbylamine reaction
(b) Coupling reaction

3029/ (Set : C)
 ( 15 ) 3029/ (Set : C)
DeLeJee
OR

(a) efvecveefueefKele DeJeueeskeâveeW kesâ keâejCe efueefKeÙes :

(i) Ssefveueerve øeâer[sue-›eâeheäšdme DeefYeef›eâÙee veneR keâjleer nw~ 1 21
(ii) Ssefveueerve kesâ efueÙes pkb keâe ceeve cesefLeueSsceerve kesâ ceeve
mes DeefOekeâ neslee nw~ 1 21

(b) cesefLeueSsceerve Deewj [eFcesefLeueSsceerve ceW Deblej keâjves kesâ efueÙe Skeâ
jemeeÙeefvekeâ hejer#eCe efueefKeS~ 2

(a) Account for the following observations :

(i) Aniline does not undergo Friedel Crafts
reaction.
(ii) pkb for aniline is more than that for
methylamine.
(b) Give a chemical test to distinguish between
Methylamine and Dimethylamine.

18. (a) keäÙee neslee nw peye : 2

(i) heâecexefu[neF[ keâer meevõ KOH mes DeefYeef›eâÙee keâjves hej

(ii) yesv]peesÙeue keäueesjeF[ keâer neF[^espeve kesâ meeLe
Pd-BaSO4 keâer GheefmLeefle ceW
(b) efvecveefueefKele DecueeW keâer Decuelee keâer leguevee keâjW : 3

(i) C 6H 5COOH
(ii) HCOOH
(iii) CH 3COOH

3029/ (Set : C) P. T. O.
 ( 16 ) 3029/ (Set : C)
(a) What happens when :
(i) Formaldehydde is treated with conc.
KOH solution.
(ii) Benzoyl chloride treated with hydrogen
in presence of Pd-BaSO4.
(b) Compare the acidic strength of the
following :
(i) C 6H 5COOH
(ii) HCOOH
(iii) CH 3COOH
DeLeJee
OR
efvecveefueefKele veeceeW keâer DeefYeef›eâÙeeDeeW keâer GoenjCe meefnle JÙeeKÙee
efueefKeS : 5
(i) mšerhesâve DeefYeef›eâÙee
(ii) F&še[& DeefYeef›eâÙee
Explain the following reactions with a example :
(i) Stephen reaction
(ii) Etard reaction

S
3029/ (Set : C)