SCHEME OF COURSE WORK

Course Details:
Course Title : CHEMICAL ENGINEERING THERMODYNAMICS –II
Course Code : 13CH1110 L T P C :4 1 0 3
Program: : B.Tech
Specialization: : Chemical Engineering
Semester : IV
Prerequisites : CHEMICAL ENGINEERING THERMODYNAMICS –I
Courses to which it is a prerequisite : Advanced Chemical Engineering Thermodynamics

Course Outcomes (COs):

1 Evaluate the heat effects that accompany physical and chemical operations.
2 Apply Raoult’s law and the cubic equations of state to perform vapor liquid equilibrium
calculations.
3 Develop the theoretical formulations for application of thermodynamics to gas mixtures and
liquid solutions and formulate activity – coefficient correlations to predict vapor liquid
equilibrium data
4 Identify phase equilibria in chemical engineering operations.
5 Evaluate the extent of reaction, effect of temperature on equilibrium constant and
equilibrium conversion for single reaction and multiple reactions.

Program Outcomes (POs):

1. Able to apply the knowledge of mathematics, science, engineering fundamentals to solve complex
chemical engineering problems.
2. Attain the capability to identify, formulate and analyse problems related to chemical engineering and
substantiate the conclusions
3. In a position to design solutions for chemical engineering problems and design system components and
processes that meet the specified needs with appropriate consideration to public health and safety.
4. Able to perform analysis and interpretation of data by using research methods such as design of
experiments to synthesize the information and to provide valid conclusions.
5. Able to select and apply appropriate techniques from the available resources and modern chemical
engineering and software tools, and will be able to predict and model complex engineering activities
with an understanding of the practical limitations.
6. Able to carry out their professional practice in chemical engineering by appropriately considering and
weighing the issues related to society and culture and the consequent responsibilities.
7. Able to understand the impact of the professional engineering solutions on environmental safety.
8. Transform into responsible citizens by resorting to professional ethics and norms of the engineering
practice.
9. Able to function effectively in individual capacity as well as a member in diverse teams and in
multidisciplinary streams.
10. Able to communicate fluently on complex engineering activities with the engineering community and
society, and will be able to prepare reports and make presentations effectively.
11. Able to apply knowledge of engineering and management principles while managing projects in
multidisciplinary environments.
12. Engage in independent and life-long learning in their specialized areas of chemical engineering.
 Course Outcome Versus Program Outcomes:
COs PO1 PO2 PO3 PO4 PO5 PO6 PO7 PO8 PO9 PO10 PO11 PO12
CO-1 S S M

CO-2 S S S M M

CO-3 S S M M M M

CO-4 S M S M M

CO-5 S S M M M M

S - Strongly correlated, M - Moderately correlated, Blank - No correlation

Assessment Methods: Assignment / Seminar / Mid-Test / End Exam

Teaching-Learning and Evaluation

Week TOPIC / CONTENTS Course Sample questions TEACHING- Assessment
Outcomes LEARNING Method &
STRATEGY Schedule
1 Sensible Heat Effects, Temperature CO-1 1)Find the Final temperature when  Lecture Mid – Test
a fluid is subjected to heating or  Derivation Assignment
dependence of the heat capacity, cooling  Discussion Quiz
Problems related to heat capacity 2) Estimate the heat required to
including gas mixtures of constant raise the temperature
3)Derive the relation for specific
composition, Evaluation of the heat based on enthalpy
Sensible Heat integral and problems, calculations
2 Latent heats of pure substances and CO-1 Estimate the latent heat of pure  Lecture Mid – Test
substance using various empirical  solving from Assignment
related problems, relations fundamentals Quiz
 Problem solving
3 heat effects of industrial reactions, CO-1 & CO-5 1) Give the procedure to find the  Lecture Mid – Test
heat of an industrial reaction.  Discussion Assignment
Standard heat of reaction, Formation, 2) Estimate the heat of reaction at  Problem solving Quiz
Combustion, Temperature dependence the system temperature, given
of heat of reaction and problems heat of reaction at reference
temperature.
4 Concept of Vapor-Liquid Equilibrium, CO-2 1)Explain isothermal and isobaric  Lecture Mid – Test
VLE with the help of diagrams  Derivation Assignment
Nature of Equilibrium, and Phase Rule 2) Develop expressions to carry  Problem solving Quiz
and Qualitative behavior, Dew point our bubble point and dew point
calculations
and Bubble point calculations using 3)Evaluate BUBL and DEW point
Raoult’s law pressure and temperature –
analytically for a given mixture.
5 Dew point and Bubble point CO-2 1)Using modified Raoult’s law find  Lecture Mid – Test
dew point and bubble point, define  Problem solving Assignment
calculations from Modified Raoult’s K-value  Discussion Quiz
law, VLE from K- Value correlation,  Derivation
flash calculations, 2)Generate isothermal VLE and /or
isobaric VLE for fthe given binary
system

3) Explain the flash operation

along with the relevant equations

6 Dew Point and Bubble point CO-3 1)Brief on Gamma – Phi  Lecture Mid – Test
Formulation  Discussion Assignment
calculations for non-ideal solutions 2) For a given system, give the Quiz
algorithm and flow chart to carry
 (Algorithms and Flow Charts), out DEW point, bubble point
calculations
7 Flash Calculations (Algorithms and CO-2 & CO-3 1)For a given system, give the  Lecture Mid – Test
algorithm and flow chart to carry  Problem solving Assignment
Flow Charts), VLE from vander Waals out DEW point, bubble point approach Quiz
and Redlich Kwong Equations of state. calculations
2) Using cubic Equation of state
make VLE calculation.
8 Fundamental property relation and CO-3 1)Derive Summability relation and  Lecture Mid – Test
Gibbs – Duhem relation.  Derivation Assignment
chemical potential a criterion for 2) Define chemical potential and  Problem solving Quiz
phase equilibrium, Partial Properties, its significance in phase
Summability relation & Gibbs Duhem equilibrium
3) For the given binary system,
equation, Partial properties of binary find the partial molar properties.
solutions and problems
9 Mid-Test 1
10 Ideal gas mixtures & problems, CO-3 & CO-4 1)Develop model equations for  Lecture Mid – Test
ideal gas mixtures  Discussion Assignment
Fugacity and fugacity coefficient of 2)Define and determine fugacity  Problem solving Quiz
Pure Species, Fugacity and fugacity and fugacity coefficient for pure
coefficient of species in solution and species and species in solution
problems,
11 Poynting correction factor for CO3 1)Derive pointing equation  Lecture Mid – Test
2)Determine the fugacity  Discussion Assignment
estimating the fugacity of pure liquid, coefficient with and without  Problem solving Quiz
Generalized Correlations for the experimental data
Fugacity Coefficient
12 Ideal Solution and Excess Properties, CO-2 & CO-3 1)Derive the activity coefficient  Lecture Mid – Test
correlations using various models  Discussion Assignment
Modified Raoult’s Law and VLE 2)Give the procedure to test the  Problem solving Quiz
Estimation from Margules, Van Laar equilibrium data
and Wilson equations, UNIFAC,
UNIQUAC & NRTL Models
(qualitative), Thermo Dynamic
Consistency
13 Equilibrium and stability, Liquid - CO-4 1)Derive the criterion for  Lecture Mid – Test
equilibrium and stability of the  Discussion Assignment
Liquid Equilibrium, (LLE), VLLE system Quiz
2)Brief about various phase
diagrams involved in LLE
3)Explain VLLE qualitatively
14 SLE and SVE, Equilibrium adsorption CO-4 1)Discuss on SLE and SVE  Lecture Mid – Test
2)Explain the equilibrium  Discussion Assignment
of gases and solids (Qualitative adsorption of gases and solids Quiz
treatment only)
15 Reaction Co-ordinate, Criterion for CO-5 1)Find the expressions for mole  Lecture Mid – Test
fractions of reacting species in  Discussion Assignment
Reaction Equilibrium, Relationship terms of reaction co-ordinate  Problem solving Quiz
between ∆Go& K, Effect of 2)Define equilibrium constant for a
Temperature on the Equilibrium reaction and discuss its
dependency on temperature
Constant
16 Gas Phase Reaction, Liquid Phase CO-5 1)Obtain equations for gas phase  Lecture Mid – Test
and liquid phase reactions  Discussion Assignment
Reaction, Equilibrium conversions for showing relation between  Problem solving Quiz
single reactions equilibrium constant and
composition
2) Estimate the conversion for
single phase reactions
17 Multi reaction Equilibria, Phase Rule CO-5 1)Find the expressions for mole  Lecture Mid – Test
fractions of reacting species in  Discussion Assignment
and Duhems theorem for reacting terms of reaction co-ordinate  Problem solving Quiz
systems
18 Mid-Test 2
19/20 END EXAM