91- ADVANCED Sheet

FIITJEE AMINES
Day:42(07.07.2021)

SINGLE ANSWER TYPE:

1. Carboxylic acid react with diazomethane to yield
a) amines b) alcohols c) esters d) amides

2.

Regarding X and Y which of the following statements is/are correct.

I. Both X and Y are aromatic
II. One of them is anti aromatic
III. All the carbon in X and Y are sp2 hybridised.
IV. One of the above species can give addition reaction with Pyrrole and can
Cl

produce N as a major product

a) I, III b) I, III, IV c) III, IV d) II, IV
3. Which of the following is the strongest base?

NH 2 NH 2
CH2NH 2 NHCH 3
CH3

a) b)
c) d)
4.

4) All
N N
3) N
H 2) Me
1)
5. Consider the following reaction and identify X.
O
C N3

Toluene X
NH2
a) NH2 c) d)
N C O N NH

C OH C O
b) NH2
NH2 N N

H H
6. Calcium cyanamide is treated with ethyl chloride to give a product which on acid hydrolysis followed
by heating gives another product (A). Product (A) is treated with excess of CH3I followed by heating
with moist Ag2O gives the product (B). Product(B) on heating strongly gives (C) which is

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FIITJEE AMINES
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a) ethanol b) ethane c) isobutene d) tetra allyl ammonium iodide

7. Which of the following substances represent a colourless substance?
N C6H5
H5C6 N b) c)
N C6H5 NH C6H5 d) Methyl orange
O H5C6 N H5C6 NH
a)
8. Which of the following reactions will give enantiometrically pure product?
O
COOH
HO HO
H+
a)
⎯⎯→ O
HO
OH
O
COOC2H5

b) H C
COOC2H5 ⎯⎯⎯→ H3C
NaBH4
3

O OH
c) ⎯⎯⎯
LiH4
→
Ph O Ph OH
O
NH 2
NH

d) HOOC COOH ⎯⎯
→
COOH

MULTIPLE ANSWER TYPE:

9. What is true about the following reactions sequence?
( C2 H 5 )3 N : + : CCl2 → ( A ) → C2 H 4 + ( B ) ⎯⎯⎯
H O
OH
→ (C ) 2
−

a) CCl2 is acting as nucleophile

b) compound B is ( H 5C2 )2 N CHCl2
c) A to B is effective in polar aprotic solvent
d) compound C is (C2H5)2 – NCHO

10.

Which of the following statements is/are correct for above reaction

a) a mixture of four different amines are formed confirming that a free carbonylnitrene intermediate is formed.
b) a mixture of two amines are formed confirming that rearrangement is strictly intramoelcular
c) If R is chiral, it migrates with retention of configuration
O

d) A free carbonylnitrene H3C C N intermediate is formed and only two amines are formed.

11.

Products A and B are

15 15
a) Ph – CH2 – NH2 b) Ph − CH 2 − N H 2 c) Ph – NH2 d) Ph − N H 2

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FIITJEE AMINES
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12.

Choose the correct statement(s) for the above reaction

a) A behaves as an electrophile to attack benzene ring at o/p position.
b) I to II conversion is highly exothermic
c) B is CuCN
d) NH2 group is a ring activating group for aromatic electrophilic substitution reaction for benzene.
13. Choose the correct statement (s) for the following conversion.
NH2
Br Br Br Br

⎯⎯
A
→ B ⎯⎯
→ C

Br Br

a) A is Electrophile b) C is an monobasic acid

c) one of the biproduct is gas having highest bond order
d) conversion of reactant to B take place at high temperature
14.

15.

16.

NUMERICAL ANSWER TYPE:

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 91- ADVANCED Sheet
FIITJEE AMINES
Day:42(07.07.2021)

17.

18.

19.

20.

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Day:42(07.07.2021)

21.

22.

23. A hydrocarbon ‘P’ having molecular formula C8H10 can form only three monochloroderivative. ‘P’ on oxidation
with KMnO4 yields a compound, which on heating with aq. NH3 yields ‘Q’. ‘Q’ on treatment with NaOH followed
by NaOCl yields a salt which on acidification yields a compound ‘R’ having molecular formula C7H7O2N.
The compound ‘R’ is further treated with (NaNO2 + HCl) and then with base to give dipolar ion ‘S’ which readily
losses two gases to give an intermediate ‘T’ is finally converted into hydrocarbon ‘U’ on dimersiation. Degree of
unsaturation in the hydrocarbon ‘U’ will be

24. The number of Hoffmann’s exhaustive methylation sequences required to get trimethyl amine from

MISCELLANEOUS ANSWER TYPE:

25. Match the following
Column – I Column – II
N
CH3 C3 H7 P) Optically inactive
A) C2 H5
CH3 N D
Q) one chiral atom is present
B) H
D

CH3 C NH 2 R) Aliphatic 10 amine

C) C2H5

NH 2 S) aromatic primary amine

D)
26. Match the following
Column – I Column – II
A) Alanine P) optically active
Q) can be prepared by Gabriel Phthalimide
B) N,N-dimethyl aniline
synthesis
C) Benzyl amine R) releases N2 on reaction with HNO2
D) 2-methyl butylamine S) more basic than aniline
27. Match the following
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FIITJEE AMINES
Day:42(07.07.2021)

List – I List – II
P) Treatment of NaNO2, HCl gives N-Nitroso
A) CH3CH2CH2 NH2
compound
H
Q) Treatment of NaNO2, HCl gives diazonium
chloride
B) CH3 CH2 N CH3
CH3 N CH3
R) Treatment of excess CH3I followed by
CH3 AgOH and heat gives out alkene
C)

NH 2 S) Does not show Hofmann mustard oil reaction

D)

28. Compound A, (C5H11NO) is a neutral compound when this was heated in presence of NaOH, it forms a salt B and
C. This C when reacts with acetyl chloride forms D. (C4H9NO). C also reacts with HNO2 to give yellow oily
solution. This C was also reacting with Hinsberg reagent but insoluble in alkali.

The compound C in the above sequence is

CH 3 − N − CH 3
a) CH 3 − N H − CH 3 b) CH3 – CH2 – NH2 c) CH3 – NH – CH2 – CH3
CH3
d)
29. The compound ‘C’
a) Is less basic than methyl amine & trimethyl amine in aq. Solution
b) Gives carbyl amine reaction
c) Is more basic than methyl amine & trimethyl amine is aq. Solution
d) Can take 3 moles of methyl iodide to form quaternary ammonium salt.

30. Compound A is
O CH3 CH2 C NH CH2 CH3

a) CH3 CH2 CH2 CH2 C NH 2 b) O

CH3
CH3 CH2 CH2 C NH CH3
CH3 CH2 C N
c) O CH3
d) O

ANSWER KEY
1. C 2. C 3. A 4. B 5. D 6. B 7. C 8. D 9. BCD 10. BC
11. BC 12. BCD 13. ABC 14. BC 15. ABCD 16. ABCD 17. 2.50 18. 2.20 19. 4 20. 1
21. 2 22. 2 23. 9 24. 3 25. 26. 27. 28. A 29. C 30. D

25. A – P, Q ; B – P,Q,R ; C – Q, R ; D – P, R
26. A – P, Q, R ; B – S ; C – Q, R, S ; D – P, Q, R, S
27. A – Q, R ; B – P, R; C – S ; D – Q

SOLUTIONS:

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