CHEMI

CALKI
NETI
CS R.
SANTANU

1.
Wri
tet
hef
act
orst
hataf
fectt
her
ateofachemi
cal
react
ion.Def
inespeci
fi
creact
ionr
ate.

2.Wri
tethefactorsthataf
fectt
herat
econst
antofareact
ion.3.
Define:a)
Rat
eofachemi
cal
react
ion.b)Instant
eniousrateofar
eact
ionc)Aver
agerateofareacti
on.

4.
Whati
sor
derofar
eact
ion?Whati
srat
edet
ermi
ningst
ep?

5.
Giv
eexampl
eofai
)zer
oor
derr
eact
ioni
i
)Fi
rstor
derr
eact
ioni
i
i)Fr
act
ional
orderr
eact
ion.

6.
Drawgraphsfora)l
og[R]v
stf
ori
)zer
oii
)f
ir
stand i
i
i)secondor
derr
eact
ion.b)l R0]
og[ /
[
R]foraf
irstor
derr
eacti
on.

7.Est
abli
sht
hei
ntegr
atedr
ateequat
ionf
orr
ateconst
antf
ori
)zer
oor
derandi
i
)fi
rstor
der
react
ion.

8.Whati
shalfli
feperi
od?Showt
hathalfl
if
eofafir
storderr
eact
ioni
sindependentofi
tsi
nit
ial
concent
rat
ion.9.Showthatt
hef
ir
storderr
eact
ionneveroestocompl
eati
on.

10.
Whati
spseudof
ir
stor
derorpseudouni
mol
ecul
arr
eact
on?
Giv
eexampl
e.Whati
tiscal
l
ed
so?

11.Whati
sfr
equencyf
act
or?Whati
sef
fect
ivecol
l
isi
on?Namet
hebar
ri
ersf
orar
eact
iont
o
occur
.

12.
Whati
sact
ivat
ionener
gy?Whati
sact
ivat
edcompl
ex?
Canact
ivat
ionener
gyf
orar
eact
ion
bezer
o?

13.
Whati
scat
aly
st?Whati
stheef
fectofcat
aly
stoni
)r
ateofr
eact
ionandi
i
)act
ivat
ionener
gy?

14.
Wri
tet
hedi
ff
erencesbet
weenor
derandmol
ecul
ari
tyofar
eact
ion.

15.
Whyr
ateofr
eact
ioni
ncr
easeswi
thr
isei
ntemper
atur
e?Whati
sthr
eshol
dener
gy?

16.
Wri
teAr
rheni
ousequat
ionandexpl
aint
het
ermsi
nvol
ved.Whati
stemper
atur
ecoef
fi
cient
?

17.
Defi
nemolecul
ari
tyofar
eact
ion.Whymol
ecul
ari
tyofacompl
exr
eact
ioncannotbe
det
ermi
ned?

18.
Def
iner
atel
aw.Howr
atel
awdi
ff
ersf
rom l
awofmassact
ion?

19.
React
ionhav
ingmol
ecul
ari
tygr
eat
ert
hant
hreei
snotobser
ved.–Expl
ain.

20.
Canacat
aly
sti
nit
iat
eanonspont
aneousr
eact
ion?Expl
ain.

21.
Drawagr
aphbet
weent2v
1/ s[
A]f
ori
)zer
oor
deri
i
)fi
rstor
deri
i
i)secondor
derr
eact
on.

22.NOreact
swit
hO2toproduceNO2:2NO(g)+O2 (g) 2NO2( g)
.Ther
atel
awf
ort
his
2
react
ioni
sRate=k[
NO] [O2]
.Pr
oposeamechani
sm f
orthereact
ion.

23.
Ifi
nAr
rheni
usequat
ion,
T ∞,
whati
sthev
alueofr
ateconst
ant
.
2
24.
Fort
her
eact
ion:
2NO+Br
2 2NOBr
;Rat
e=k[
NO][Br
2]
.Wr
it
ethepr
oposedmechani
sm.
25.Fort
her
eact
ion:
H2+I
2 2HI;
Rat
e=k[
H2]
[I
2]
.Wr
it
ethepr
oposedmechani
sm.

+ALLNCERTI
NTEXTANDEXERCI
SEQUESTI
ONS