Rajat/chemistry/cbse/EM/PT-2/22.10.

21

1.Which of the following molecules has tetrahedral geometry?

(a) BF3 (b) NH3
(c) PCl3 (d) IF3
2.Predict the correct order among the following:
(a) bond pair - bond pair > lone pair - bond pair
> lone pair - lone pair
(b) lone pair - bond pair > bond pair - bond pair
> lone pair - lone pair
(c) lone pair - lone pair > lone pair - bond pair
> bond pair - bond pair
(d) lone pair - lone pair > bond pair - bond pair
3.The hybridizations of atomic orbitals of nitrogen in NO+, NO2– and NH4+ respectively are
(a) sp, sp3 and sp2 (b) sp2, sp3 and sp
(c) sp, sp2 and sp3 (d) sp2, sp and sp3
4.Hybridisation of CO2 is
(a)sp². ( b)sp³. (c)sp. (d)sp³d
5. No of lone pair in sulphur in SO2 is
A 1. B 2. C 3. D 4.
6.A sp3 hybrid orbital contains
(a) 1/4 s-character (b) 1/2 s-character
(c) 1/3 s-character (d) 2/3 s-character.
7.Bond order of O2 will be
A 1. B 2. C 1.5. D None of these
8. Which of the following pair is expected to have the same bond order?
(i) O2 , N2
(ii) O2+, N2–
(iii) O2– , N2+
(iv) O2–, N2
9.In which of the following substances will the hydrogen bond be strongest?
(i) HCl
(ii) H2O
(iii) HI
(iv) H2S
10.Which of the following is not an example of redox reaction?
(i) CuO + H2 → Cu + H2O
(ii) Fe2O3 + 3CO → 2Fe + 3CO2
(iii) 2K + F2 → 2KF
(iv) BaCl2 + H2SO4 → BaSO4 + 2HCl
11.Oxidation numbers of P in PO4³-
, of S in SO4²- will be
(a) +3, +6
(b) +5, +3
(c) –3, +6
(d) +5, +6
12.The oxidation state of I in H4IO – is
A +5. B +7. C+6. D +3
 Section B
The electronic configurations of three elements, A, B and C are given below.
Answer the questions 14 to 17 on the basis of these configurations.
A 1s2 2s2 2p6
B 1s2 2s2 2p6 3s2 3p3
C 1s2 2s2 2p6 3s2 3p5

14. Stable form of A may be represented by the formula :

(i) A
(ii) A2
(iii) A3
(iv) A4
15. Stable form of C may be represented by the formula :
(i) C
(ii) C2
(iii) C3
(iv) C4
16. The molecular formula of the compound formed from B and C will be
(i) BC
(ii) B2C
(iii) BC2
(iv) BC3
17. The bond between B and C will be
(i) Ionic
(ii) Covalent
(iii) Hydrogen
(iv) Coordinate

Section C
In the following questions a statement of Assertion (A) followed by a statement of
Reason (R) is given. Choose the correct option out of the choices given below each
question.
(i) A and R both are correct, and R is the correct explanation of A.
(ii) A and R both are correct, but R is not the correct explanation of A.
(iii) A is true but R is false.
(iv) A and R both are false.

18.Assertion (A) : Sodium chloride formed by the action of chlorine gas on

sodium metal is a stable compound.
Reason (R) : This is because sodium and chloride ions acquire octet in
sodium chloride formation.
19.Assertion (A) : Though the central atom of both NH3 and H2O molecules aresp3
hybridised, yet H–N–H bond angle is greater than that of H–O–H.
Reason (R) : This is because nitrogen atom has one lone pair and oxygen
atom have two lone pairs.
20.Assertion (A): Among the two O–H bonds in H2O molecule, the energy
required to break the first O–H bond and the other O–H bonds the same.
Reason (R) : This is because the electronic environment around oxygen is the same even
after breakage of one O–H bond.