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Department of Chemical Engineering, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey
Abstract
In this work, the sun drying behaviour of figs was investigated. Drying experiments were conducted for figs (Ficus carica) grown
in Iskenderun-Hatay, Turkey. The constant rate period is absent from the drying curve. The drying process took place in the falling
rate period. The drying data were fitted to the different mathematical models such as Lewis, Henderson and Pabis, Page, Logarith-
mic, Two-term, Two-term exponential, Verma et al. and Wang and Singh models. The performance of these models was investigated
by comparing the determination of coefficient (R2), reduced chi-square (v2) and root mean square error (RMSE) between the
observed and predicted moisture ratios. The results showed that the Verma et al. model was found to satisfactorily describe the
sun drying curve of figs with a R2 of 0.9944, v2 of 0.000483 and RMSE of 0.062857.
2004 Elsevier Ltd. All rights reserved.
0260-8774/$ - see front matter 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jfoodeng.2004.11.003
404 I. Doymaz / Journal of Food Engineering 71 (2005) 403–407
Nomenclature
50 0.14
0.1
42
0.08
38 0.06
0.04
34
0.02
30 0
8.00 10.00 12.00 14.00 16.00 18.00 20.00
0 20 40 60 80 100
Day times Drying time (h)
Fig. 1. Variation of ambient temperature during sun drying of figs on Fig. 3. Drying rate of figs changes with drying time.
a typical day of August 2003 at Iskenderun-Hatay.
2
0.6 v ¼ i¼1 ð1Þ
N z
" #1=2
0.4 1 XN
2
RMSE ¼ ðMRpre;i MRexp;i Þ ð2Þ
N i¼1
0.2
where MRexp,i is the ith experimentally observed mois-
ture ratio, MRpre,i is the ith predicted moisture ratio,
0.0 N is number of observations and z is number of
0 20 40 60 80 100 constants.
Drying time (h) Non-linear regression was used to obtain each
Fig. 2. Experimentally determined and predicted moisture ratios of parameter value of every model. R2, v2 and RMSE val-
figs versus drying time. ues obtained for figs are summarised in Table 3. The
406 I. Doymaz / Journal of Food Engineering 71 (2005) 403–407
Table 2
Mathematical models tested for the moisture ratio values of the figs
Model name Model equation References
Lewis MR = exp(kt) Ayensu (1997)
Henderson and Pabis MR = a exp(kt) Akpinar et al. (2003)
Page MR = exp(ktn) Karathanos and Belessiotis (1999)
Logarithmic MR = a exp(kt) + c Yaldiz et al. (2001)
Two-term model MR = a exp(k0t) + b exp(k1t) Togrul and Pehlivan (2004)
Two-term exponential MR = a exp(kt) + (1 a)exp(kat) Midilli and Kucuk (2003)
Verma et al. MR = a exp(kt) + (1 a)exp(gt) Verma et al. (1985)
Wang and Singh MR = 1 + at + bt2 Wang and Singh (1978)
Table 3
Curve fitting criteria for the various models and parameters for drying of figs
Model name Model constants R2 v2 RMSE
Lewis k: 0.030468 0.9717 0.002119 0.122045
Henderson and Pabis a: 0.925237,k: 0.027830 0.9838 0.001302 0.095712
Page k: 0.064780, y: 0.791604 0.9912 0.000703 0.075107
Logarithmic a: 0.886485, k: 0.032325, 0.9854 0.001270 0.095909
c: 0.053585
Two-term a: 0.837497, b: 0.164923, 0.9944 0.000526 0.063381
k0: 0.024954, k1: 0.314409
Two-term exponential a: 0.140044, k: 0.186061 0.9912 0.000706 0.074918
Verma et al. a: 0.837681, k: 0.024960, 0.9944 0.000483 0.062857
g: 0.312673
Wang and Singh a: 0.025114, b: 0.000182 0.9512 0.003935 0.157139
best model describing the thin-layer drying characteris- Eq. (3) can be further simplified to a straight-line equa-
tics of figs was chosen as the one with the highest R2 tion as (Riva & Peri, 1986):
values and the lowest v2 and RMSE values. In all cases, 2
6 p Deff t
the R2 values for the models were greater than 0.95, indi- MR ¼ ln 2 ð4Þ
p r2
cating a good fit. Generally R2, v2 and RMSE values
were between 0.9512 and 0.9944, 0.000483 and The effective diffusivity was calculated using the
0.003935 and 0.062857 and 0.157139, respectively. As method of slopes. Effective diffusivities are typically
expected, the Two-term and Verma et al. models give determined by plotting experimental drying data in
the highest value of R2. However, the results have shown terms of ln (MR) versus time data (Lomauro, Bakshi,
that the v2 and RMSE values of the Verma et al. model & Labuza, 1985). From Eq. (4), a plot of ln (MR) versus
are lower than the other models (Table 3). According to time gives a straight line with a slope (k2) of:
these results, Verma et al. model was successfully p2 Deff
k2 ¼ ð5Þ
applied to the sun drying of figs. Fig. 2 shows compari- r2
son of experimental and predicted moisture ratio values During drying of fig, the effective diffusivity is found
with the Verma et al. model. 2.47 · 1010 m2/s. This value was lower than the re-
ported diffusivities for figs (Babalis & Belessiotis,
3.2. Determination of effective diffusivity 2004), but within the general range of 1009–1011 m2/s
for food materials (Madamba, Driscoll, & Buckle,
The effective diffusivity of the fig is estimated by using 1996). Table 4 shows the Deff of the present study as well
the simplified mathematical FickÕs second model. Ana-
lytical solution of one-dimensional FickÕs law of diffu- Table 4
sion with constant moisture diffusivity for sphere is Effective diffusivities of figs and other fruits
given as (Crank, 1975): Fruits Effective diffusivity (m2/s) References
2 2 Apricot 10
8.90 · 10 –1.30 · 10 09
Mahmutoglu et al. (1995)
6 X1
1 n p Deff t
MR ¼ 2 exp ð3Þ Grape 7.91 · 1010–2.50 · 1009 Doymaz and Pala (2002)
p n¼1 n2 r2 Mulberry 2.32 · 1010–2.76 · 1009 Maskan and Gogus (1998)
Prune 4.30 · 1010–7.60 · 1010 Sabarez and Price (1999)
where Deff is the effective diffusivity (m2/s) and r is the ra- Fig 7.77 · 1010–2.45 · 1009 Babalis and Belessiotis (2004)
dius of the fig (m). For long drying times (setting n = 1), Fig 2.47 · 1010 Present work
I. Doymaz / Journal of Food Engineering 71 (2005) 403–407 407
as information available in the literature. As a result, IGEME, (2003). Statistical database. Available from
these values are consistent with the present estimated <www.igeme.gov.tr>.
Karathanos, V. T., & Belessiotis, V. G. (1999). Application of a thin-
Deff value for figs. layer equation to drying data of fresh and semi-dried fruits. Journal
of Agricultural Engineering Research, 74, 355–361.
Kostaropoulos, A. E., & Saravacos, G. D. (1995). Microwave pre-
4. Conclusions treatment for sun-dried raisins. Journal of Food Science, 60,
344–347.
Lahsasni, S., Kouhila, M., Mahrouz, M., & Jaouhari, J. J. (2004). Thin
In this study, sun drying of figs was investigated. Dry- layer convective solar drying and mathematical modeling of prickly
ing of figs occurred in the falling rate period; no con- pear peel (Opuntia ficus indica). Energy, 29, 211–224.
stant rate period of drying was observed. To explain Lomauro, C. J., Bakshi, A. S., & Labuza, T. P. (1985). Moisture
the drying behaviour of figs eight thin-layer drying mod- transfer properties of dry and semimoist foods. Journal of Food
els were applied. Among these models, the Verma et al. Science, 50, 397–400.
Madamba, P. S., Driscoll, R. H., & Buckle, K. A. (1996). The thin-
model has shown a better fit to the experimental fig data layer drying characteristics of garlic slices. Journal of Food
than the other models. The resulting model gave values Engineering, 29, 75–97.
of parameters: R2: 0.9945, v2: 0.000483 and RMSE: Mahmutoglu, T., Pala, M., & Unal, M. (1995). Mathematical
0.062857 for samples in the thin-layer sun drying pro- modelling of moisture, volume and temperature changes during
cess. According to the results, the Verma et al. model drying of pretreated apricots. Journal of Food Processing and
Preservation, 19, 467–490.
could adequately describe drying characteristics of fig. Maskan, M., & Gogus, F. (1998). Sorption isotherms and drying
The effective moisture diffusivity value was estimated characteristics of mulberry (Morus alba). Journal of Food Engi-
from FickÕs diffusional model by 2.47 · 1010 m2/s. neering, 37, 437–449.
Midilli, A., & Kucuk, H. (2003). Mathematical modelling of thin layer
drying of pistachio by using solar energy. Energy Conversion and
Management, 44(7), 1111–1122.
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