Pan Chemicals S.p.A. Revision nr.

2
Dated 08/09/2017
Printed on 12/02/2018
Panchem 5130 Page n. 12/9
3
4
5
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SECTION 16.
2. Physical
8.
9.
11.
15.Hazards
Exposure
Toxicological
Regulatory
Other information ... /properties
identification
and ...
controls/personal
information
chemical
information >>/...
>>/protection
...>>/ >> ... / >> ... / >>
2.3.Substances
Solubility
SERIOUS
7. Regulation
Other EYE
hazards subject
(EU)DAMAGE to the/ Rotterdam
487/2013 IRRITATION
(IV Atp. CLP) Safety Data Sheet
Convention:of the European Dispersable in waterRegulation
Parliament8.
SULPHURIC ACID (EU) 944/2013 (V Atp. CLP) of the European Parliament
9.Partition
None
Causes
Threshold Regulation coefficient:
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605/2014
Valuedamage (VI Atp. CLP) of the European Not available
Parliament
SECTION
Auto-ignition
On Type
10. basis14.
Regulation
the 6.temperature
Accidental
of(EU) Transport
available Country
2015/1221 data, the release
information
(VII TWA/8h
Atp. CLP)
product measures
does of the Not available
not European
contain STEL/15min
any Parliament
PBT or vPvB in percentage greater than 0,1%.
SECTION
6.1.
14.1.Decomposition
Substances
11.
RESPIRATORY
SECTION
Regulation
Personal
UN number 1.
subjectIdentification
temperature
(EU)
precautions,
3. (EU)
OR to the
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STOT
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Any
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SECTION Hazard
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14.7.
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SECTION
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SECTION EU Product
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INFORMATION mixture:
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EU (German). Directive 2009/161/EU; >2000 mg/kg 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC;
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Vapour
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(II Atp. CLP)ACID of the European Not available
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Substances CORROSION subject /toIRRITATION
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EPY 9.3.0 - SDS 1004.9
 Pan Chemicals S.p.A. Revision nr.2
Dated 08/09/2017
Printed on 12/02/2018
Panchem 5130 Page n. 2 / 9

SECTION 2. Hazards identification ... / >>

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

SECTION 3. Composition/information on ingredients

3.1. Substances

Information not relevant

3.2. Mixtures

Contains:

Identification x = Conc. % Classification 1272/2008 (CLP)

SULPHURIC ACID
CAS 7664-93-9 50 ≤ x < 90 Skin Corr. 1A H314,
Classification note according to Annex VI to the CLP Regulation: B
EC 231-639-5
INDEX 016-020-00-8
DIETHYLTHIOUREA
CAS 105-55-5 2 ≤ x < 10 Acute Tox. 4 H302, Eye Irrit. 2 H319
EC 203-308-5
INDEX

The full wording of hazard (H) phrases is given in section 16 of the sheet.

SECTION 4. First aid measures

4.1. Description of first aid measures
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed
Specific information on symptoms and effects caused by the product are unknown.
For symptoms and effects caused by the contained substances, see section 11.

4.3. Indication of any immediate medical attention and special treatment needed
Information not available

SECTION 5. Firefighting measures

5.1. Extinguishing media
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

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SECTION 6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent
any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of
the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage

7.1. Precautions for safe handling
Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which
people eat. Avoid leakage of the product into the environment.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other
sources of ignition. Keep containers away from any incompatible materials, see section 10 for details.

Storage class TRGS 510 (Germany): 8A

7.3. Specific end use(s)

Information not available

SECTION 8. Exposure controls/personal protection

DIETHYLTHIOUREA
Powder mask P1 (UNI EN 143-140)
Exposure Limit for Dietylthiourea
WME : total = 10 mg/m3 ; breathing = 5 mg/m3 .

8.1. Control parameters

Regulatory References:

DEU Deutschland MAK-und BAT-Werte-Liste 2012

ESP España INSHT - Límites de exposición profesional para agentes químicos en España 2015
FRA France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102
GBR United Kingdom EH40/2005 Workplace exposure limits
ITA Italia Decreto Legislativo 9 Aprile 2008, n.81
NLD Nederland Databank of the social and Economic Concil of Netherlands (SER) Values, AF 2011:18
POL Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 16 grudnia 2011r
PRT Portugal Ministério da Economia e do Emprego Consolida as prescrições mínimas em matéria de protecção
dos trabalhadores contra os riscos para a segurança e a saúde devido à exposição a agentes
químicos no trabalho - Diaro da Republica I 26; 2012-02-06
EU OEL EU Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC;
Directive 91/322/EEC.
TLV-ACGIH ACGIH 2017

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SULPHURIC ACID
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
AGW DEU 0,1 0,1 INHAL
MAK DEU 0,1 0,1 INHAL
VLA ESP 0,05
VLEP FRA 0,05 3 THORA
WEL GBR 0,05 THORA
VLEP ITA 0,05 THORA
OEL NLD 0,05 THORA
NDS POL 1 3
VLE PRT 0,05 THORA
OEL EU 0,05
TLV-ACGIH 0,2

Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.

8.2. Exposure controls

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on
the duration and type of use.
SKIN PROTECTION
Wear category III professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type
B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases
or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing
apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

SECTION 9. Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid
Colour Colourless
Odour Light typical of the product
Odour threshold Not available
pH Acid
Melting point / freezing point Not available
Initial boiling point > 100 °C
Boiling range Not available
Flash point Not available
Evaporation Rate Not available
Flammability of solids and gases Not available
Lower inflammability limit Not available
Upper inflammability limit Not available
Lower explosive limit Not available
Upper explosive limit Not available
Vapour pressure Not available
Vapour density Not available
Relative density Not available
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SECTION 9. Physical and chemical properties ... / >>

Solubility Dispersable in water
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Explosive properties Not available
Oxidising properties Not available
9.2. Other information
pH solution at 10% P/P < pH 5

SECTION 10. Stability and reactivity

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

SULPHURIC ACID
Decomposes at 450°C/842°F.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials

SULPHURIC ACID
Incompatible with: flammable substances,reducing substances,basic substances,metals,organic substances,water.

10.6. Hazardous decomposition products

SULPHURIC ACID
May develop: sulphur oxides.

SECTION 11. Toxicological information

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

DIETHYLTHIOUREA
Dietylthiourea :
LD 50 (mouse) : 316 mg/kg
Cancer-causing cat : 3 (IARC 1999).

11.1. Information on toxicological effects

ACUTE TOXICITY

LC50 (Inhalation - vapours) of the mixture: Not classified (no significant component)
LC50 (Inhalation - mists / powders) of the mixture: Not classified (no significant component)
LD50 (Oral) of the mixture: >2000 mg/kg
LD50 (Dermal) of the mixture: Not classified (no significant component)

SULPHURIC ACID
LD50 (Oral) 2140 mg/kg Rat

DIETHYLTHIOUREA
LD50 (Oral) > 930 mg/kg Mouse

SKIN CORROSION / IRRITATION

Corrosive for the skin

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SECTION 11. Toxicological information ... / >>

SERIOUS EYE DAMAGE / IRRITATION
Causes serious eye damage

RESPIRATORY OR SKIN SENSITISATION

Does not meet the classification criteria for this hazard class

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY
Does not meet the classification criteria for this hazard class

REPRODUCTIVE TOXICITY
Does not meet the classification criteria for this hazard class

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

ASPIRATION HAZARD
Does not meet the classification criteria for this hazard class

SECTION 12. Ecological information

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or
contaminate soil or vegetation.

DIETHYLTHIOUREA
Dietythiourea :
ED 50 (Dafnia) : 193 mg/48 h
Lightly Bio-accumulate
WGK : 2.

12.1. Toxicity
Information not available

12.2. Persistence and degradability

SULPHURIC ACID
Solubility in water 1000 - 10000 mg/l
Degradability: information not available

12.3. Bioaccumulative potential

Information not available

12.4. Mobility in soil

Information not available

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects

Information not available

SECTION 13. Disposal considerations

13.1. Waste treatment methods
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product
should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

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SECTION 14. Transport information

14.1. UN number

ADR / RID, IMDG, IATA: 2796

14.2. UN proper shipping name

ADR / RID: SULPHURIC ACID or BATTERY FLUID, ACID

IMDG: SULPHURIC ACID or BATTERY FLUID, ACID
IATA: SULPHURIC ACID or BATTERY FLUID, ACID

14.3. Transport hazard class(es)

ADR / RID: Class: 8 Label: 8

IMDG: Class: 8 Label: 8

IATA: Class: 8 Label: 8

14.4. Packing group

ADR / RID, IMDG, IATA: II

14.5. Environmental hazards

ADR / RID: NO
IMDG: NO
IATA: NO

14.6. Special precautions for user

ADR / RID: HIN - Kemler: 80 Limited Quantities: 1 L Tunnel restriction code: (E)
Special Provision: -
IMDG: EMS: F-A, S-B Limited Quantities: 1 L
IATA: Cargo: Maximum quantity: 30 L Packaging instructions: 855
Pass.: Maximum quantity: 1 L Packaging instructions: 851
Special Instructions: -

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Information not relevant

SECTION 15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Seveso Category - Directive 2012/18/EC: None

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006
Product
Point 3

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.

Substances subject to authorisarion (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:

None

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SECTION 15. Regulatory information ... / >>

Substances subject to the Rotterdam Convention:
None

Substances subject to the Stockholm Convention:

None

Healthcare controls
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks
related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

WGK 2: Hazard to waters

15.2. Chemical safety assessment

No chemical safety assessment has been processed for the mixture and the substances it contains.

SECTION 16. Other information

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Acute Tox. 4 Acute toxicity, category 4

Skin Corr. 1A Skin corrosion, category 1A
Eye Dam. 1 Serious eye damage, category 1
Eye Irrit. 2 Eye irritation, category 2
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament

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SECTION 16. Other information ... / >>

7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)

- The Merck Index. - 10th Edition

- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

Changes to previous review:

The following sections were modified:
01 / 02 / 03 / 04 / 07 / 08 / 10 / 11 / 12 / 14 / 15.

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