Pan Chemicals S.p.A. Revision nr.

2
Dated 19/10/2015
Printed on 04/07/2017
Pancover S 4730 Page n. 12/7
3
4
5
6
7 0

SECTION 16.
2. Physical
6.
9.
12.
15.Hazards
Accidental
Ecological
Regulatory
Other information. ... properties.
identification.
and
release
information.
information.
chemical / ...
>>...
measures. /...>>
// >>
>>... / >>... / >>

-Upper
2.3.
6.2.
12.3. The
Other Merck
Substancesinflammability
Environmental Index.precautions.
subject
Bioaccumulative
hazards. to- 10th
limit.Editionreporting pursuant to (EC)
exportation
potential. Safety data sheet
Not available.
Reg. 649/2012:
-The
Information
Lower
Handling
None. product
explosive
Chemical
not
mustavailable.
limit.
notSafety
penetrate into the sewer system Notoravailable.
come into contact with surface water or ground water.
-On
Upper
INRS
theexplosive
-basis
FicheofToxicologique
available
limit. data,
(toxicological
the product sheet)
does not Not
contain
available.
any PBT or vPvB in percentage greater than 0,1%.
Substances
SECTION
-Vapour
6.3.
12.4. Patty
Methods
Mobility subject
1.
-pressure.
Industrial
and
in soil. to the Rotterdam
Identification
Hygiene
material forand Convention:
of theand
Toxicology
containment substance/mixture
Not available.
cleaning up. and of the company/undertaking.
None.
-Confine
Information
Vapour
N.I. Sax density
using
- Dangerous
not available.
earth or properties
inert material.
of Industrial
Collect
Materials-7,
as Not
muchavailable.
1989
material
Edition
as possible and eliminate the rest using jets of water. Contaminated material
SECTION
1.1.-should
Product
Relative
ECHA be 3.
website
density. Composition/information
identifier.of in compliance with the provisions
disposed on ingredients.
1,300-1,400
set forth in point 13.
Kg/l
Substances
Solubility
12.5. Results subject
of PBT toand
the vPvB
Stockholm Convention:
assessment. soluble
3.1. Substances.
6.4.None.
Product
Partition
Reference name.
coefficient:
to othern-octanol/water
sections. Pancover
Not S 4730
available.
Any
Auto-ignition
Note
On the
information
for basis
users:
Informationcontrols.temperature.
of available
on personal
not relevant. data,
protection
the product
and does
disposal
not Not
contain
is given
available.
any
in sections
PBT or 8vPvB
and in13.percentage greater than 0,1%.
1.2.Healthcare
TheRelevant
Decomposition identified
information temperature.uses of
contained in the
thesubstance or mixture
present sheet are and uses
Not available.
based advised
on our own against.
knowledge on the date of the last version. Users must verify the
Workers
suitability
Viscosity
12.6. exposed to this chemical
and thoroughness
Other adverse effects. of provided agent must not
information Notundergo
according
available.healthspecific
to each checks,useprovided that available risk-assessment data prove that the risks
of the product.
3.2. Mixtures.
SECTION 7.workers'
Handling and storage.
related
Intended
This
Explosive touse.
documentthe
properties
must not health and safety
be regarded as are modest Not
a guarantee and
Wire that
on any the 98/24/EC
surface
available. treatment
specific directive
product beforeisdrawing.
property. respected.
Information
7.1.The
Oxidising
Contains:
Precautions ofnot
use propertiesthisavailable.
for product is not subject to our direct
safe handling. Notcontrol;
available.
therefore, users must, under their own responsibility, comply with the current health
15.2.
1.3.andChemical
Details
safety oflawssafety
the assessment.
supplier
and of the safety
regulations. data sheet.
9.2. Other
Before information.
handling the product,The producer
consult all is
therelieved
other from any liability
sections of this arising from
material improper
safety datauses.
sheet. Avoid leakage of the product into the
Provide
Information
environment. appointed
Identification. not Do available.
staff
not eat,with
drinkadequate
Conc. or%.smoke training
during on how
use. to use
Classification chemical
1272/2008 products.
(CLP).
SECTION
No
Name.chemical13. safety Disposal
assessmentconsiderations.
has been processedPan for the mixture and
Chemicals the substances it contains.
S.p.A.
Borax pentahydrate
Full address.
Changes to previous review: via Leopardi, 24
13.1.
7.2. CAS.
Conditions
SECTION 12179-04-3
Waste treatment forStability
safemethods. 30 - and
storage, 50including any Repr. 1B H360FD
incompatibilities.
District
The and 10.Country. reactivity. 24060 Rogno (BG)
EC.following
SECTION
Keep
Reuse, thewhen 16.
productsections
215-540-4 Other were
in clearly
possible. modified:
information.
labelled
Product containers.
residues Keepbe
should containers
considered away from any
special incompatible
hazardous materials,
waste. see section
The hazard level of10 for details.
waste containing this product
01 / 02 / 04 / 06 / 07 / 08 / 09 / 10 / 11 / 12 / 14. Italia - Italy
should
10.1.INDEX. be evaluated
Reactivity. 005-011-02-9 according to applicable regulations.
Tel.of the +39 - 035977488
7.3.Text
SODIUM ofare
Disposal
There
Specifichazard
must
no (H)
CARBONATE
end indications
particular
be performed
use(s). risks of mentioned
through
reaction in section
anwith
authorised 2-3
other substances
waste sheet:
management
in normal firm,
conditions
in compliance
of use. with national and local regulations.
Fax. +39 - 035977288
Information
CONTAMINATED
CAS. not available.
497-19-8 PACKAGING 0-2 Eye Irrit. 2 H319
e-mail
Repr. address
1B of the competent person. toxicity, category 1B
Reproductive
Contaminated
10.2.EC.
Chemical packaging must
207-838-8
stability. be recovered or disposed of in compliance with national waste management regulations.
responsible
Eye Irrit. for 2 the Safety Data Eye Sheet. category 2 vago@panchemical.com
irritation,
The product
INDEX. is stable in normal conditions of use and storage.
011-005-00-2
SECTIONH360FD 8. Exposure Maycontrols/personal
damage fertility. Suspected protection.
of damaging the unborn child.
SECTION
Product
Note:
10.3. Upper
Possibility 14.
H319distribution
limit Transport
by: Causes
is not included
of hazardous information.
serious eye irritation.
into the range.
reactions.
Pan Chemicals
8.1. Control parameters.
The
NoUN
14.1. fullnumber.
wording
hazardous of hazard
reactions are(H) phrases is in
foreseeable given
normalin section 16 ofofthe
conditions usesheet.
and storage.
1.4. Emergency telephone number.
10.4. During
Not Conditions riskto
theinquiries
applicable. avoid.
assessment process, it is essential
SECTION
LEGEND:
For urgent 4. First referaid to. measures. PANtoCHEMICALS
take into consideration
+39 - 035977488the ACGIH occupational exposure levels for inert particulate not
None in particular. However
(PNOCthe usual precautions used for chemical products should be respected.
-otherwise
ADR: European classifiedAgreement respirable
concerning fraction:
the carriage 3 mg/m3;
of DangerousPNOC inhalable
goods by Road fraction: 10 mg/m3). For values above these limits, use a P type
4.1.-filter,
14.2. UNwhose
Description
CAS proper
NUMBER: class (1, 2aid
shipping
of first
Chemical orname.
3)Abstract
must beService
measures. chosenNumber according to the outcome of risk assessment.
SECTION
10.5.
-Not
Incompatible
CE50:specifically 2. Hazards
Effective necessary.
concentration identification.
materials.Observance
(requiredoftogood induce industrial
a 50% hygiene
effect) is recommended.
Information
8.2.-Not applicable.
Exposure not available.
controls.
CE NUMBER: Identifier
2.1. Classification of the substance or mixture. in ESIS (European archive of existing substances)
4.2.- CLP:
Most EC important
Regulation symptoms
1272/2008 and effects, both acute and delayed.
10.6.
As
14.3. No Hazardous
episodes
the use
Transport of
ofdecomposition
damage
adequate
hazard to Level
health
class(es). products.
technical ascribable
equipment to themustproductalways
havetake
beenpriority
reported. over personal protective equipment, make sure that the workplace is
-TheDNEL: Derived
product No Effect
Information
well aired notisavailable.
through
classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments
effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable
-andEmS: Emergency Schedule
supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and
standards.
4.3.-Not GHS: applicable.
Indication Globally of any immediate
Harmonized medical
System attention and
of classification andspecial treatment
labeling of chemicalsneeded.
subsequent amendments.
Any
Provide
-Information
SECTION IATA DGR:an emergency
additional
not
11. available.
International
information
shower
Toxicological Air with face
Transport
concerning
and eye wash
information.
Association
the
station. Goods Regulation
Dangerous
risks for health and/or the environment are given in sections 11 and 12 of this sheet.
14.4.-HAND Packing
IC50: PROTECTION
group. Concentration 50%
Immobilization
11.1. InIMDG:
the
-Hazard case
Information of prolonged contact
on toxicological
International Maritime Codewith thedangerous
effects.
for product, protectgoods the hands with penetration-resistant work gloves (see standard EN 374).
SECTION
-Not
In
Work the
IMO: applicable.
absence
glove 5.material
International
Firefighting
classification and
of experimental
Maritime
indication:
must be measures.
data
chosen
Organization for the product itself,
according to thehealth
use hazards
process are andevaluated according
the products that to the form.
may properties
Latexof gloves
the substances
may causeit sensitivity
Reproductive toxicity, category 1B H360FD May damage fertility. Suspected of damaging the unborn
5.1.-contains,
reactions.
INDEX
Extinguishing using the
NUMBER: criteria
Identifier
media. specified
in Annex in VI
theofapplicable
CLP regulation for classification.
child.
14.5.-It
SKINisEnvironmental
LC50:
SUITABLEtherefore
PROTECTION
Lethal necessary
hazards.
Concentration
EXTINGUISHING to take 50% into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
EQUIPMENT
-toxicological
Wear
TheLD50: category
Lethal
extinguishing effects
dose of
50%exposure
I equipment
professional to the
should beproduct.
long-sleeved overalls and kind:
of the conventional safety footwear
carbon (seefoam,
dioxide, Directive 89/686/EEC
powder and water and standard EN ISO 20344). Wash body
spray.
2.2. Label elements.
Not
with applicable.
soap
-UNSUITABLE
OEL: and water
Occupational after
Exposureremoving
EXTINGUISHING EQUIPMENT Level protective clothing.
-This
EYE
None
Hazard
product
PBT:PROTECTION
inPersistent hasbioaccumulative
particular.
labelling
a teratogenic and
pursuant to EC Regulation
effect on as
toxic human
REACH
1272/2008
beings: damages fertility and has toxic effects on fetus development. There is sufficient
Regulation
(CLP) and subsequent amendments and supplements.
14.6.-evidence
Wear Special
PEC: toprecautions
airtight
Predicted make
protective us goggles
believe
for user.
environmental that standard
(see the substance
Concentration EN 166). contained in the product is likely to affect the embryo-fetal development and the fetus
development.
RESPIRATORY
5.2.-Hazard
PEL:
Special Predicted
hazards PROTECTION
exposure
arising level from the substance or mixture.
pictograms:
Not theapplicable.
If PNEC:
-HAZARDS operator
Predicted
CAUSEDis exposed
noBY effect to concentration
a carcinogenic
EXPOSURE IN THE or EVENT
mutagenic OF agent,
FIRE wear a type FFP3 facemask, (see standard EN 149).
-Respiratory
Do REACH:
not breatheECprotection
Regulation
combustiondevices
1907/2006 must beThe
products. used if theis combustible
product technical measuresand, when adopted
the powderare not suitable into
is released for restricting the worker's
the air in sufficient exposure toand
concentrations the
14.7. SODIUM
threshold
-in Transport
RID: CARBONATE
values
Regulation in considered.
bulk according
concerning The
the protection
to Annex
international IIprovided
of by
MARPOL73/78
transport masks
of is
and
dangerous in any
the
goodscase
IBC by limited.
Code.
train
the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid product
LD50
-from
TLV:the (Oral).
ENVIRONMENTAL
Threshold
container, LimitEXPOSURE
whenValueit reaches 4090
high mg/kg
CONTROLS. Rat
temperatures or through contact with sources of ignition.
LD50
-Information
The (Dermal).
TLVemissions
CEILING: not relevant.
generated by that
Concentration 117
shouldmg/kg
manufacturing not Mouse
processes,
be exceeded including
during anythosetime of generated
occupational by exposure.
ventilation equipment, should be checked to ensure
5.3.-LC50
compliance
TWA
Advice (Inhalation).
forwith
STEL: environmental
Short-term
firefighters. exposure 2,3
limitmg/l/2h Rat
standards.
-GENERAL
TWA: Time-weighted
INFORMATION average exposure limit
SECTION
-Signal
VOC: Volatile
15.organic
RegulatoryCompounds
information.
Use
SECTION jets of
words: water to
9.Persistent
12. Physicalcool
Ecological the containers
Danger
and to preventproperties.
information.
chemical product decomposition and the development of substances potentially hazardous for health.
-Always
vPvB: Very and very Bioaccumulative
wear full fire prevention gear. Collect extinguishing as for REACH water Regulationto prevent it from draining into the sewer system. Dispose of contaminated
-UseWGK:
water
9.1.Hazard
15.1. this
used
Information
Safety, Water
product
for
health
statements:hazard
on basic classes
according
extinction and
and environmental (German).
to
the good
remains
physical and chemical working
of the practices.
fire according
regulations/legislation Avoid
to
properties. specific littering.for
applicable Inform the competent
regulations.
the substance authorities, should the product reach waterways or
or mixture.
Appearance
contaminate
SPECIAL
H360FDPROTECTIVE
soil or vegetation.
EQUIPMENT
May damageFOR fertility.
FIRE-FIGHTERS
Suspected
Crystal of
Powder
damaging the unborn child.
GENERAL
Seveso fireBIBLIOGRAPHY
Colour category.
Normal fighting clothing i.e. 2fireto kit
Restricted professional
(BS EN beige469),
users. gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
1. Regulation (EU)
Odour
self-contained open1907/2006 (REACH)
circuit positive of the
pressure European
LightParliament
compressed typical
air of the apparatus
breathing product (BS EN 137).
2. Regulation
Restrictions
Odour
Precautionary
12.1. threshold.
Toxicity. (EC)
relating 1272/2008
to the product
statements: (CLP) of the European
or contained substancesParliament
Not pursuant to Annex XVII to EC Regulation 1907/2006.
available.
3. Regulation
Contained
P201
Information
pH. not (EU) 790/2009
substance.
available. (I Atp.
Obtain CLP) of
special the European
instructions Parliament
before
9,5 use.
SECTION
4. P202
Melting point6./(EU)
Regulation
Point. Accidental
2015/830
freezing 30ofnot
Do
point. release
the European
handle measures.
Borax
until Parliament
pentahydrate
all
> safety
500precautions
°C. have been read and understood.
5.
12.2. Regulation
P280
Initial boiling
Persistence (EU)
point.
and286/2011 Wear
(II Atp.
degradability. protective
CLP) ofgloves
the European
/ clothing
Not Parliament
and eye / face protection.
available.
6.1.Substances
Personal
P308+P313 precautions,
in Candidate Listprotective
IF exposed
(Art. 59 equipment
or concerned:
REACH). andGetemergency
medical procedures.
advice / attention.
6. Regulation
Boiling range. (EU) 618/2012 (III Atp. CLP) of the European Parliament
Not available.
Use breathing
Borax pentahydrateequipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in
7. Regulation
Flash
SODIUMpoint. (EU) 487/2013 (IV Atp. CLP) of the European
CARBONATE Parliament
Not available.
emergency procedures.
Contains: (EU) 944/2013 Borax pentahydrate
8. Regulation
Solubility
Evaporationin water.
Rate (V Atp. CLP) of the European
Not
mg/l Parliament
available.
1000 - 10000
Substances
9. Regulationsubject
(EU) to authorisarion
605/2014 (VI (Annex XIVofREACH).
Biodegradability:
Flammability of solids
Information not Atp.
and gases CLP)
available. the European Parliament
Not available.
None.
10. Regulation
Lower (EU) 2015/1221
inflammability limit. (VII Atp. CLP) of the Not
European Parliament
available.

EPY 9.1.7 - SDS 1003

 Pan Chemicals S.p.A. Revision nr.2
Dated 19/10/2015
Printed on 04/07/2017
Pancover S 4730 Page n. 2 / 7

SECTION 2. Hazards identification. ... / >>

2.3. Other hazards.

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

SECTION 3. Composition/information on ingredients.

3.1. Substances.

Information not relevant.

3.2. Mixtures.

Contains:

Identification. Conc. %. Classification 1272/2008 (CLP).

Borax pentahydrate
CAS. 12179-04-3 30 - 50 Repr. 1B H360FD
EC. 215-540-4
INDEX. 005-011-02-9
SODIUM CARBONATE
CAS. 497-19-8 0-2 Eye Irrit. 2 H319
EC. 207-838-8
INDEX. 011-005-00-2

Note: Upper limit is not included into the range.

The full wording of hazard (H) phrases is given in section 16 of the sheet.

SECTION 4. First aid measures.

4.1. Description of first aid measures.
Not specifically necessary. Observance of good industrial hygiene is recommended.

4.2. Most important symptoms and effects, both acute and delayed.
No episodes of damage to health ascribable to the product have been reported.

4.3. Indication of any immediate medical attention and special treatment needed.
Information not available.

SECTION 5. Firefighting measures.

5.1. Extinguishing media.
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture.

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products. The product is combustible and, when the powder is released into the air in sufficient concentrations and
in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid product
from the container, when it reaches high temperatures or through contact with sources of ignition.

5.3. Advice for firefighters.

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated
water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

SECTION 6. Accidental release measures.

6.1. Personal precautions, protective equipment and emergency procedures.
Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in
emergency procedures.

EPY 9.1.7 - SDS 1003

 Pan Chemicals S.p.A. Revision nr.2
Dated 19/10/2015
Printed on 04/07/2017
Pancover S 4730 Page n. 3 / 7

SECTION 6. Accidental release measures. ... / >>

6.2. Environmental precautions.
The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up.

Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material
should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections.

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage.

7.1. Precautions for safe handling.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the
environment. Do not eat, drink or smoke during use.

7.2. Conditions for safe storage, including any incompatibilities.

Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s).

Information not available.

SECTION 8. Exposure controls/personal protection.

8.1. Control parameters.

During the risk assessment process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate not
otherwise classified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type
filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment.

8.2. Exposure controls.

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is
well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable
standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374).
Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity
reactions.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the operator is exposed to a carcinogenic or mutagenic agent, wear a type FFP3 facemask, (see standard EN 149).
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
ENVIRONMENTAL EXPOSURE CONTROLS.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

SECTION 9. Physical and chemical properties.

9.1. Information on basic physical and chemical properties.
Appearance Crystal Powder
Colour beige
Odour Light typical of the product
Odour threshold. Not available.
pH. 9,5
Melting point / freezing point. > 500 °C.
Initial boiling point. Not available.
Boiling range. Not available.
Flash point. Not available.
Evaporation Rate Not available.
Flammability of solids and gases Not available.
Lower inflammability limit. Not available.

EPY 9.1.7 - SDS 1003

 Pan Chemicals S.p.A. Revision nr.2
Dated 19/10/2015
Printed on 04/07/2017
Pancover S 4730 Page n. 4 / 7

SECTION 9. Physical and chemical properties. ... / >>

Upper inflammability limit. Not available.
Lower explosive limit. Not available.
Upper explosive limit. Not available.
Vapour pressure. Not available.
Vapour density Not available.
Relative density. 1,300-1,400 Kg/l
Solubility soluble
Partition coefficient: n-octanol/water Not available.
Auto-ignition temperature. Not available.
Decomposition temperature. Not available.
Viscosity Not available.
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information.
Information not available.

SECTION 10. Stability and reactivity.

10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability.

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions.

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid.

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials.

Information not available.

10.6. Hazardous decomposition products.

Information not available.

SECTION 11. Toxicological information.

11.1. Information on toxicological effects.
In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

This product has a teratogenic effect on human beings: damages fertility and has toxic effects on fetus development. There is sufficient
evidence to make us believe that the substance contained in the product is likely to affect the embryo-fetal development and the fetus
development.

SODIUM CARBONATE
LD50 (Oral). 4090 mg/kg Rat
LD50 (Dermal). 117 mg/kg Mouse
LC50 (Inhalation). 2,3 mg/l/2h Rat

SECTION 12. Ecological information.

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or
contaminate soil or vegetation.

12.1. Toxicity.
Information not available.

12.2. Persistence and degradability.

SODIUM CARBONATE
Solubility in water. mg/l 1000 - 10000
Biodegradability: Information not available.

EPY 9.1.7 - SDS 1003

 Pan Chemicals S.p.A. Revision nr.2
Dated 19/10/2015
Printed on 04/07/2017
Pancover S 4730 Page n. 5 / 7

SECTION 12. Ecological information. ... / >>

12.3. Bioaccumulative potential.
Information not available.

12.4. Mobility in soil.

Information not available.

12.5. Results of PBT and vPvB assessment.

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects.

Information not available.

SECTION 13. Disposal considerations.

13.1. Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product
should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information.

14.1. UN number.

Not applicable.

14.2. UN proper shipping name.

Not applicable.

14.3. Transport hazard class(es).

Not applicable.

14.4. Packing group.

Not applicable.

14.5. Environmental hazards.

Not applicable.

14.6. Special precautions for user.

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code.

Information not relevant.

SECTION 15. Regulatory information.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.

Seveso category. 2

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Contained substance.
Point. 30 Borax pentahydrate

Substances in Candidate List (Art. 59 REACH).

Borax pentahydrate

Substances subject to authorisarion (Annex XIV REACH).

None.

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SECTION 15. Regulatory information. ... / >>

Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:
None.

Substances subject to the Rotterdam Convention:

None.

Substances subject to the Stockholm Convention:

None.

Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks
related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

15.2. Chemical safety assessment.

No chemical safety assessment has been processed for the mixture and the substances it contains.

SECTION 16. Other information.

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Repr. 1B Reproductive toxicity, category 1B

Eye Irrit. 2 Eye irritation, category 2
H360FD May damage fertility. Suspected of damaging the unborn child.
H319 Causes serious eye irritation.

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament

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SECTION 16. Other information. ... / >>

- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

Changes to previous review:

The following sections were modified:
01 / 02 / 04 / 06 / 07 / 08 / 09 / 10 / 11 / 12 / 14.

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