Quality Control Lab, Diffusion Engineers Ltd.

Nagpur

Measurement of Uncertainity- % Carbon (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % C
1 0.671
2 0.684
3 0.676
4 0.670
5 0.676
6 0.668
7 0.644
8 0.665
Average (X) 0.669
SD 0.012
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0042
Std Relative uncertainity(Ux/X) 0.0062

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.000288684
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.88684E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.014
Std Deviation in CRM (Ux) 0.001
Relative std Uncertainity(Ux/X) 7.14E-02

Spreadsheet for Carbon Uncertaintity values

Std Std Relative

Uncertainity( Uncertainity

S No Discription Values(X) Ux) (Ux/X) SQ Sum SQRT √ˉ

No 1 Mean value 0.669 0.0042 0.0062 3.87E-05 0.0052 0.072
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.014 1.0E-03 7.1E-02 5.10E-03

Combine Standard Uncertainity(Uc) 0.0483

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.097

Results:-
Carbon Value= 0.669 @± 0.097
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Silicon (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 09/03/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Si
1 1.07
2 1.08
3 1.09
4 1.07
5 1.11
6 1.07
7 1.08
8 1.05
Average (X) 1.08
SD 0.02
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0062
Std Relative uncertainity(Ux/X) 0.0058

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/ 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.14
Std Deviation in CRM (Ux) 0.01
Relative std Uncertainity(Ux/ 7.14E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 1.078 0.0062 0.0058 3.31E-05 0.0052 0.072
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.14 1.0E-02 7.1E-02 5.10E-03

Combine Standard Uncertainity(Uc) 0.0777

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.155

Results:-
Silicon Value= 1.078 @± 0.155
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Mn (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Mn
1 0.577
2 0.579
3 0.582
4 0.581
5 0.571
6 0.587
7 0.592
8 0.582
Average (X) 0.581
SD 0.006
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0022
Std Relative uncertainity(Ux/X) 0.0038

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/ 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.51
Std Deviation in CRM (Ux) 0.01
Relative std Uncertainity(Ux/ 1.96E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.581 0.0022 0.0038 1.47E-05 0.0005 0.021
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.51 1.0E-02 2.0E-02 3.84E-04

Combine Standard Uncertainity(Uc) 0.0125

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.025

Results:-
% Mn Value= 0.581 @± 0.025
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % P (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % P
1 0.0079
2 0.0074
3 0.0081
4 0.0074
5 0.0075
6 0.0079
7 0.0077
8 0.0086
Average (X) 0.0078
SD 0.0004
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0001
Std Relative uncertainity(Ux/X) 0.0185

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/ 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.003
Std Deviation in CRM (Ux) 0.001
Relative std Uncertainity(Ux/ 3.33E-01

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.008 0.0001 0.0185 3.42E-04 0.1115 0.334
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.003 1.0E-03 3.3E-01 1.11E-01

Combine Standard Uncertainity(Uc) 0.0026

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.005

Results:-
% P Value= 0.008 @± 0.005
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % S (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % S
1 0.0061
2 0.0054
3 0.0067
4 0.0060
5 0.0057
6 0.0068
7 0.0061
8 0.0068
Average (X) 0.0062
SD 0.0005
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0002
Std Relative uncertainity(Ux/X) 0.0299

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.028
Std Deviation in CRM (Ux) 0.001
Relative std Uncertainity(Ux/X) 3.57E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.006 0.0002 0.0299 8.92E-04 0.0022 0.047
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.028 1.0E-03 3.6E-02 1.28E-03

Combine Standard Uncertainity(Uc) 0.0003

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.001

Results:-
% S Value= 0.0062 @± 0.001
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Cr (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Cr
1 26.12
2 26.09
3 26.11
4 26.11
5 26.09
6 26.08
7 26.02
8 26.12
Average (X) 26.09
SD 0.0328
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0116
Std Relative uncertainity(Ux/X) 0.0004

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 25.39
Std Deviation in CRM (Ux) 0.06
Relative std Uncertainity(Ux/X) 2.36E-03

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 26.093 0.0116 0.0004 1.98E-07 0.0001 0.008
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 25.39 6.0E-02 2.4E-03 5.58E-06

Combine Standard Uncertainity(Uc) 0.2164

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.433

Results:-
% Cr Value= 26.09 @± 0.433
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Mo (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Mo
1 0.0078
2 0.0069
3 0.0062
4 0.0059
5 0.0050
6 0.0061
7 0.0058
8 0.0062
Average (X) 0.0062
SD 0.0008
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0003
Std Relative uncertainity(Ux/X) 0.0466

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 4.17
Std Deviation in CRM (Ux) 0.04
Relative std Uncertainity(Ux/X) 9.59E-03

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.006 0.0003 0.0466 2.17E-03 0.0023 0.048
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 4.17 4.0E-02 9.6E-03 9.20E-05

Combine Standard Uncertainity(Uc) 0.0003

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.001

Results:-
% Mo Value= 0.0062 @± 0.001
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Ni (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Ni
1 20.46
2 20.41
3 20.51
4 20.43
5 20.45
6 20.47
7 20.47
8 20.25
Average (X) 20.43
SD 0.0790
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0279
Std Relative uncertainity(Ux/X) 0.0014

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 20.5
Std Deviation in CRM (Ux) 0.05
Relative std Uncertainity(Ux/X) 2.44E-03

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 20.431 0.0279 0.0014 1.87E-06 0.0001 0.008
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 20.5 5.0E-02 2.4E-03 5.95E-06

Combine Standard Uncertainity(Uc) 0.1720

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.344

Results:-
% Ni Value= 20.43 @± 0.344
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Ti (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Ti
1 0.0849
2 0.0854
3 0.0869
4 0.0827
5 0.0776
6 0.0831
7 0.0854
8 0.0803
Average (X) 0.0833
SD 0.0031
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0011
Std Relative uncertainity(Ux/X) 0.0131

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.87
Std Deviation in CRM (Ux) 0.02
Relative std Uncertainity(Ux/X) 2.30E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.083 0.0011 0.0131 1.70E-04 0.0008 0.028
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.87 2.0E-02 2.3E-02 5.28E-04

Combine Standard Uncertainity(Uc) 0.0023

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.005

Results:-
% Ti Value= 0.0833 @± 0.005
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Cu (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 09/03/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Cu
1 3.85
2 3.86
3 3.86
4 3.84
5 3.85
6 3.87
7 3.85
8 3.85
Average (X) 3.85
SD 0.01
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0032
Std Relative uncertainity(Ux/X) 0.0008

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.0524
Std Deviation in CRM (Ux) 0.0019
Relative std Uncertainity(Ux/X) 3.63E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 3.854 0.0032 0.0008 7.06E-07 0.0014 0.037
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.0524 1.9E-03 3.6E-02 1.31E-03

Combine Standard Uncertainity(Uc) 0.143

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.286

Results:-
% Cu Value= 3.85 @± 0.286
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % W (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % W
1
2
3
4
5
6
7
8
Average (X) #DIV/0!
SD #DIV/0!
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) #DIV/0!
Std Relative uncertainity(Ux/X) #DIV/0!

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.0364
Std Deviation in CRM (Ux) 0.0016
Relative std Uncertainity(Ux/X) 4.40E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.0364 1.6E-03 4.4E-02 1.93E-03

Combine Standard Uncertainity(Uc) #DIV/0!

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= #DIV/0!

Results:-
% V value= #DIV/0! @± #DIV/0!
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Co (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Co
1 0.0138
2 0.0136
3 0.0140
4 0.0138
5 0.0137
6 0.0136
7 0.0143
8 0.0139
Average (X) 0.0138
SD 0.0002
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0001
Std Relative uncertainity(Ux/X) 0.0059

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 0.338
Std Deviation in CRM (Ux) 0.006
Relative std Uncertainity(Ux/X) 1.78E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.014 0.0001 0.0059 3.53E-05 0.0004 0.020
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 0.338 6.0E-03 1.8E-02 3.15E-04

Combine Standard Uncertainity(Uc) 0.000

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.0006

Results:-
% Co value= 0.014 @± 0.001
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Nb (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Nb
1 0.0053
2 0.0050
3 0.0052
4 0.0047
5 0.0051
6 0.0051
7 0.0054
8 0.0051
Average (X) 0.0051
SD 0.0002
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0001
Std Relative uncertainity(Ux/X) 0.0145

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 2.17
Std Deviation in CRM (Ux) 0.04
Relative std Uncertainity(Ux/X) 1.84E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.005 0.0001 0.0145 2.11E-04 0.0006 0.025
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 2.17 4.0E-02 1.8E-02 3.40E-04

Combine Standard Uncertainity(Uc) 0.0001

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.0003

Results:-
% Nb value= 0.0051 @± 0.0003
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Fe (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Fe
1 39.20
2 39.16
3 39.29
4 39.25
5 38.90
6 39.16
7 39.03
8 39.07
Average (X) 39.13
SD 0.127
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0450
Std Relative uncertainity(Ux/X) 0.0011

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 1.5
Std Deviation in CRM (Ux) 0.02
Relative std Uncertainity(Ux/X) 1.33E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 39.133 0.0450 0.0011 1.32E-06 0.0002 0.016
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 1.5 2.0E-02 1.3E-02 1.78E-04

Combine Standard Uncertainity(Uc) 0.6089

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 1.22

Results:-
% Fe value= 39.13 @± 1.22
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Al (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Al
1 0.0355
2 0.0358
3 0.0352
4 0.0357
5 0.0389
6 0.0348
7 0.0363
8 0.0350
Average (X) 0.0359
SD 0.0013
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0005
Std Relative uncertainity(Ux/X) 0.0128

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 5.97
Std Deviation in CRM (Ux) 0.07
Relative std Uncertainity(Ux/X) 1.17E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.036 0.0005 0.0128 1.65E-04 0.0004 0.019
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 5.97 7.0E-02 1.2E-02 1.37E-04

Combine Standard Uncertainity(Uc) 0.0007

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.0014

Results:-
% Al value= 0.0359 @± 0.0014
Review and Approved by
Quality Manager
 Quality Control Lab, Diffusion Engineers Ltd. Nagpur

Measurement of Uncertainity- % Al (Nickel Alloys)

Test Method- ASTM E 3047:2016 Date- 23/01/2021
Uncertainity component & Quantification
Contribution Factor For Uncertainty Measurement
PART-A
No.1 Uncertainity due to Repeatability

PART-B
No.2 Uncertainity due to Temperature
No.3 Uncertainity due to Argon gas purity
No.4 Uncertainity due to CRM.
Uncertainity Values Part-A
No.1
Uncertainity due to Repeatability

S.No Values % Al
1 0.0355
2 0.0358
3 0.0352
4 0.0357
5 0.0389
6 0.0348
7 0.0363
8 0.0350
Average (X) 0.0359
SD 0.0013
Distribution Normal
Sq. Root of 8 2.828
Std Uncertaintity (Ux) 0.0005
Std Relative uncertainity(Ux/X) 0.0128

Uncertainity Values Part-B

No.2 No 3
Uncertaintity due to Temperature Uncertaintity due to Argon gas purity
Uncertaintity at 20⁰C 0.55 at k=1.96 Purity (X) 99.9995
√3 1.732 Std uncertaintity (Ux) 0.00028868
Temperature at (X) 20 Relative std Uncertainity(Ux/X) 2.89E-06
Std Uncertainity(Ux) 0.15878
Releative std Uncertainity(Ux/X) 0.00794 No 4
Uncertaintity due to CRM
Certified Calue of CRM 5.97
Std Deviation in CRM (Ux) 0.07
Relative std Uncertainity(Ux/X) 1.17E-02

Spreadsheet for Carbon Uncertaintity values

Std Std
Relative
Uncertainit
Uncertaini
S No Discription Values(X) y(Ux) ty (Ux/X) SQ Sum SQRT √ˉ
No 1 Mean value 0.036 0.0005 0.0128 1.65E-04 0.0004 0.019
No 2 Due to Temperature 20 0.15878 0.00794 6.30E-05
No 3 Due to Argon gas Purity 99.9995 0.0003 2.9E-06 8.33E-12
No 4 Due to CRM 5.97 7.0E-02 1.2E-02 1.37E-04

Combine Standard Uncertainity(Uc) 0.0007

Coverage Factor @ 95% Confidence level K= 2

Expanded Uncertainity (U)= 0.0014

Results:-
% Al value= 0.0359 @± 0.0014
Review and Approved by
Quality Manager