chemisol ‘Material Safety Data Sheet IDENTIFICATION OF THE SUBSTANCH/ PREPARATION AND COMPA! ‘Telephone Fax Emergency Telephone Number Other Taformation ‘Low Aromatic White Spirit ‘Version 1.7, Effective Date: 30.04.2012 DERTAKING : Low Ardmatic White Spiritilaws + Industrial Solvent. £Q3312, 93327 + Chemisol The, S/F Johngon Bldg. #5 D. Muto St, ‘Tandang Sora, Quezon City Philippi (632) 9385388 + (682) 9383818 1 (632) 9985388 + Shellsol i$ a trademark owned by Shell Trademark Management B.V. and Shell [Brands Ine. and used by affiliates of Royal Dutch Spell ple. 2 HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Symbol Signal Words CHS Hazard Statoments GHS Precautionary Statements Prevention Flammable liquids: Category no, 3 ‘Aspiration hazard: Category no. 1 ‘Acute hazards to the aquatic environment: Category ne. 2 Chronic hazards to the aquatic environment: Category:no. 3 :Danger | :PHYSICAL HAZARDS: 226 Flafsableiguid and vapor. HEALTH HAZARDS: B04: Mabe fatal swallowed and enters airvays. ENVIRONMENTAL HAZARDS: ADI: Tori to aqua i, 412: Hat to aquatic ie with long lasting effets, #P210: Keep away from heav/sparks/open flames/hot sutfaces. ‘Nosinoking 240; Grotnd/bond container and receiving equipment. P241: Uselexplosion-proof eletrical/ventiating lighting equipment, ; 20: Ueonlyronsparkna tos 243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye | | i Chemisol,Material Safety Data Sheet ‘Response Storage Disposal (Other Hazards which do not result in classification ‘Aggravated Medical Condition ‘Low Aromatic White Spirit Version 1.7 | | Eifective Date: 30.04.2012 provetion/fce protectin. P2781 Avoid release (othe environment. 'P303+P361-+P353: IF ON SKIN (or hai): Remaveltake off Timmediately all contaminated clothing. Rise skin with watershower. 370+P378: In case of fire: Use appropriete media for extinction. 3014310: IF SWALLOWED: Immediately cl a POISON CENTRE or doctos/physician. P331; Do NOT induce vomiting, +: P403+P235; Store in a well-ventilated place, Keep ool. P405: Store locked up. + B5OL: Dispose of contents and container to appropriate waste site or reclame in accordance wih local and national regulations. +s Inuse, may form flammuabic/explosive vapour-air mixture, Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Possibility of organ oF organ system damage ftom prolonged cexposute; see Chapler 11 for deals, Target organ(s): Auditory system, Repeated exposure may cause skin dryness or eekcing, Slihtlyitatng vo respeatory system. + Pre-existing medical conditions ofthe following organ(s) or organ system(s) may be aggravated by exposure to this ‘material; Skin, Respiratory system, Auditory system, ‘COMPOSITION’ INFORMATION ON INGREDIENTS ‘Synonyms CAS No. INDEX No. EINECS No. hssieton of component according to GHS : LAWS i 64742-82-1 ! 649-330-002 i 1 265-185-4 i | ‘Chemical Name | Synonyms | CASNo._| Hazard Class (category) | Wavard statement Cone. 13.5-Trimethy seers HE26;HSB5;HA | —0.60- Benzene ‘Aquat Chronie, 3.00 Flam, Liq.2;Acute Tox.,4;Acute ciphers soos) oe Snr es 020 3;Aquatic Acute,2; STOT RE, 2; Tri Flam. Lig., 3;Acute Tox., 4; H226;H332;H3 een 95-6946 | 4349, 2;STOTBE, 3Skinint,2; | 1gH335yHas; | 20° Aquatic|Chronic, 2; A212; : ‘Raiiiional Information THR Chap 16 il ext oF HC Rpt 2 i (Chemisol_GHS_revisionLow Aromatie White Spirit Version L7 Effective Date: 30.04.2012 Material Safety Data Sheet protection/fce protection. P273: Avoid release to the environment Response 2 P3034P361#P383:1F ON SKIN (or bal): Removelake off immediately all contaminated lating. Rinse skin with seaterishower. PS70HP376: Incase of te: Use appropriate media for extintion 30142310: IF SWALLOWED: immediately calls POISON CENTRE or doctorphysican, P331: Do NOT induce vomiting. Storage 4034P235; Store in a well-ventilated place. Keep cool 405: Store locked up. Disposal = PSOL: Dispose oP contents and container to appropriate waste site or reclame in accordance with local and national regulations Other Hazards which do tot result in dassifention = nuse, may form lammubl“explosive vapour-alewibaure. Elcetrstatle charges may be generated ding pumping. i lees dacharge may cause fe. Possibility of organ or organ system damage from prolonged exposure; see Chepter 11 for details. Target organ(): Auditory system. Repeated exposure may cause skin dryness or cracking, Slightly imitating to respiratory system. Aggravated Medical i Condition : Pre-existing medical conditions ofthe following organ(s) or ‘organ system(s) may be aggravated by exposure to this atrial: Skin. Respiratory system. Auditory system, 3, COMPOSITION INFORMATION ON INGREDIENTS Synonyms :LAWS CAS No. 64742-82-1 INDEX No. 649-330-002 ‘ EINECS No. 1265-18544 Classieation of components according to GHS ‘Ghemical Name [ Synonyms | CASNo, | Hazard Class (category) |_| Hazard statement | cone. 13.5Timethyl roser | Flam. Liq, 35107 SE,3; | Haze;Ha3sHa | 0.60- Benzene ‘Aquatic Chron, 1 3.00 Flam, Lig, 2;Acute Tox. Ayheute | HA2SHB3H3 Tox, 5;Skin Corr/erit,2; Eye | 03;H315;H329; Ethylbenzene 10042-4 | yam, 2A; Asp! Tox. USTOTSE, | H304;3H401;H i 3;Aquatic Acute,2; STOT RE, 2; 373; Flam, Liq, 3yAcute Tox, 4) | HA26H3325H3 oe | 95636 | H319,2; STOTSE,3;Skinirit,2; | ag;Haa5uaas; | 200 nae Aquatic/Chronic, 2; “naga; z ‘Kiltional Tnformation 7 Refer Chapter 16 for fl tet of EC Rephraes ww Chemisol_ GHS_revisionMaterial Safety Data Sheet ‘FIRST AD MEASURES Inhalation ‘Skin Contact Bye Contact Ingestion Advice to Physician Low Aromatic White Spirit Version 1.7 Exfeotive Date: 30.04.2012 :Remove to fresh air. Ifrapid recovery docs not occur, transport to the nearest medical fclty fr adduonl treatment : Remove cotfaminatd clothing. ish exposed re wih water and fallow by ‘ashing wit cap iayalable Flush eye wth copious quantifies of water. Ifpensstenitaton occurs, aban medical atention :fevallowed, do aot indice voting transport the nearest media ality foradationaleatmen. I yomiing ocous spontzocously, Kee hed blow hips to prevent aspiration. + Causes central nervous system depression. Dermatitis may result from prolonged ot epetedexposire Potente! fr chemical preumonta. Consider: gastric lavage with protected airway, administration of activated charcoal. Call 8 doctor or poison cont enter for guidance. ‘5 FIRE FIGHTING MEASURES Cleer fire area of ail non-emergency personnel. Specific Hazards Extinguishing Medin Unsuitable Extinguishing Media Protective Equipment for Firefighters Additional Advice Carbon monoxide may’be evolved if incomplete combustion occurs. Will float ‘and can be reignited on surface water. ‘The vapour is heavier than air, spreads along the ground and distant ignition is possible. + Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth ‘may be used for small fires only. Do not discharge extinguishing waters into the aquatic environment. Do not use water in a jet. + Wear full protective clothing and self-contained breathing apparatus. + Keep adjacent containers cool by spraying with water. © ACCIDENTAL RELBASE MEASURES Observe all relevant local'and international regulations. Protective Measures Clean Up Methods + Avoid contact with spilled or released material, For guidance on selection of personal protective equipment see Chapter 8 ofthis Material Safety Data Sheet, For guidance on disposal of spilled material see Chapter 13 of this Material Safety Data Sheet. Shutoff leaks, if possible without personal risks, Remove all possible sources of ignition inthe surrounding area. Use appropriate containment (of product and firefighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches, or rivers by using sand earth, or other appropriate barriers. Attempt to disperse the vapour ‘or to direct its low to a safe location for example by using fog sprays. Take precautionary measures against static discharge, Ensure clectrial continuity by ‘bonding and grounding (earthing) all equipment. + For small liquid spills (<1 drum), transfes by mechanical means to a labeled, sealable container for product recovery or safe disposal. Allow residues to eT ‘Chemisol_GHS_revisionLow Aromatic White Spirit ‘Version 1.7, Effective Date: 30.04.2012 Material Safety Data Sheet Srerorie of Soek up with an appropriate absorbent material and dispose of Gaily. Remove contaminated soil and dispose of safely. For large liquid spill Cie uum. transfer by mechanical means such as vacuum truck ton salvage {ank recovery or safe disposal. Do not flush away residues with water, Relate 28 contaminated waste. Allow residues to evaporate or soak up with an Speropriate absorbent material and dispose of safely. Remove contaminated soll and dispose of safely, Additional Advice + ec chapter 13 for information on disposal. Notify authorities i ny exposure {o the general public orthe environment occurs ors likely to occu Vapour ‘may form an explosive mixture with aie, 7. HANDLING STORAGE General Precautions + Avoid breathing vapours or contact with material. Only use in well ventilated atcas. Wash thoroughly after handling, For guidance on selection of persooal protective equipment see Chapter 8 ofthis Material Safety Data Sheet, Use the i input to risk assessment of local ¢ Bandling + Avoid contact with skin, eyes, and clothing. Extinguish any naked flames. Do yr tmoke, Remove ignition sources, Avoid sparks. The vapour is heavies thon ae brea along the ground and dst inition is posible. Ensure cleseal Continuity by bonding and grounding (earthing) all equipment. Reset tne Pees dating pomping in order to avoid generation of electrostatic dacharge sreralse unt pipe submerzed to twice ts diameter then 7 hear fetes flog, Do NOT use compressed air for filg, discharging oy fanaling opeetions. Handie and open container with care sna welled Gary mtlte workplace in such a way tha the Occupational Expeoee Ieee (OBL) is not exceeded, Do notentpty into drains. Storage "IM be stored ina diked (bunded) well-ventilated area, away from su {gation souoes and other sources of heat. Bulk storage lanle shcold Ge Gerdes. Keco avay ftom aerosol, fammablesoniizing agente oe eee dhe com tte Nanmable products Which ae nt harmful or tonic tee ny the environment. Storage Temperature: Ambient, Product Transfer +R electrical continuity by bonding and grovaing (earthing) all OF electonate fee tee duriog pumping in oxder to avoid generation Gastar atl discharge (<= tnvsec nl fil pipe submerged Ween giantter, ten <= 7 m/sec), Avoid splash filling. Do NOT xe ‘compressed air for filing, discharging, or hendling operations: Elecoestate charges may be sealing dents PUmPInG operations, Electrostatic discharge may Coane tego Rostive displacement pumps are used, these must be ited will ¢ ot-integral Dressure relief valve, Recommended Materials “er Conners, or continernings use ld steel and taints steel. For Unsuitable Materials Container Advice mntainers, 5. EXPOSURE CONTROLS/PERSONAL PROTECTION + —— ® Chemisol GHS revisionMaterial Safety Data Sheet Occupational Exposure Limits In the absence of occupational exposure standards for this product, Low Aromatic White Spirit Version 1.7 Effective Date: 30.04.2012 recommended thatthe following are adopted, Material Source. “Type ppm mgind Notation REP SPA TWA (8h) 30 mg/m ‘Mineral spits | OEL 150-200 Ethylbenzene | ACGI, TWA 160 ppm ‘ACGIH. ‘STEL 125 ppm POEL CEIL PHL 100 ppm: 35 mein Additional Information Materia Ethylbenzene Respiratory Pratection Hand Protection Eye Protection Protective Clothing + Adequate ventilation to control airborne concentrations below the exposure guidelines(iimits, Source Hazard Designation ACGIH Confismed animal carcinogen with uaknown relevance 10 humans, : HFenginecring controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and mecting relevant legislation. Check with’ the respirstory protective equipment suppliers. Where sir-fitering respirators are suitable, select an appropriate combination of mask and filter, Seleete filter suitable for organic gases and vapours [boiling point >65°C (149 °F)] meeting EN141. Where airfiltering respirators are unsuitable (@g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. + Longer term protection: Nitrile rubber gloves incidental contactsplash protection: PVC or neoprene rubber gloves. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands, After using aloves, hands should be washed and dried thoroughly, Application of a non- perfumed moisturizer is recommended. : Chemical splash goggles (Chemical monogoggles). + Chemical resistant gioves/gauntlets, boots, and apron. Skin protection not ‘ordinarily required beyond standard issue work clothes. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance point Typical 162- 192°C /324- 378 °F Melting/Freezing point (ot applicable. Flash point Typical 41- 42°C/ 106- 108 °F (Abel) Explosion /Flammability 107+ 6.5 96 (VY) Limits in air ‘Auto-ignition temperature $296 °C/ 565 °F (ASTM E-659) a ‘Chemisol_GHS_revision| ‘Low Aromatic White Spirit Version 1.7 | fective Date: 30.04.2012 Matera Safety Data Shect | 245 °C/ 473 °F (DIN 51794) Vapour phessure “Typical 370 Pa at 20°C? 68 °F ‘Typical 110 Pa at 0°C/32°F | ‘Typical 1,800 Pa at 50 °C! 522°F Density | ‘Typical 783 ke/ms at 15 *C/ 39°F (ASTM D-40s2) Water solubility = Insoluble Solubility in other solvents ‘Aromatics Miscible | Aliphatics Miscible. swoctanolhwater part 67 coefficient log Pow) Kinematie viscosity ‘Typical 1.08 mm2/s st 25 °C/ 77°F ‘Vapou dosiy fae) : Data not avaleble, CCoefticieht of expansion + Typical 0.0008/*C Dielectrig constant + Typical 2.1 at 20 °C/ 68 °F Refractive index: + Typical 1-434 at 20°C/'68°F (ASTM D-1218) Reaction with water ‘Not applicable. Saturated Vapour 121 gim3 (estimated valves) Concentration (in ac) Volatile organic carbon 285 % (BC/1999/13) content Evaporation rate(nBuAc1) __: 0.16 (ASTM D 3539, nBuAc=1) 80 (DUN 53170, d-eyl ether=1) ‘Surface tension : Typical 26.4 mN/m at 20 °C/ 68 °F (ASTM D-971) ‘Moleculat weight 2140 g/mo} 10. STABILITY AND REACTIVITY ee Stability | + Stable under normal conditions of use. + Avoid heat, sparks, open flames and other ignition sources. + Sttong oxidizing agents, Hazardous Decamposition _: Thermal decomposition is highly dependent on conditions. A complex mixture of Products| sirbome solids liquid aid gases, including carbon monoxide, earbon dioxide and | other organi compounds will be evolved when this material undergoes ' ‘combustion or thermal or oxidative degrad TI. TOXICOLOGICAL INFORMATION Basis for Assessment + Information given is based on product testing, andios similar products, and/or ‘components, Acute Oral Toxicity : Low Toxicity: LDS0 >2000 mg/kg, Rat Aspiration into the lungsiwhen swallowed or vomited may cause chernical ‘pneumonitis which can be fatal Acute Deriual Toxicity Low Toxicity: LDS0 >2000 mg/kg, Rat Acute Inhalation Toxicity Low Toxicity: LCS0 greater than near-saturated vapour concentration. /4 hours, Rat igh concentrations may cause central nervous system depression resulting in headaches, dizziness and nausea; continued inhalation may result in ‘unconsciousness and/or death, ‘Skin Irritation ‘May cause moderate skin irritation (but insufficient to classify). wo Chemisol GHS_revisionLow Aromatic White Spirit ‘Version 1.7 Effective Date: 30.04.2012 Material Safety Data Sheet Prolonged/repested contact may cause deffating of the skin which can ead to derma Bye Irritation Essentially noniritating to eyes. Respiratory Irritation alation of vapours ot mists may eause iitation tothe respiratory system. Sensitization Nota skin sensitizer, Repeated Dase'Toxleity + Aueltony system: prolonged and repeated exposure to high concentrations have ‘resulted in hearing oss in rts. Solvent abuse and noise interaction inthe work ‘environment may cause hearing loss. Central nervous system: repeated ‘exposure affets the nervous system. Kidney: caused kidney effects in male rats which are not considered relevant to humans. Mutagenicity ot expected to bo mutagenic. Carcinogenicity + Limited evidence to be carcinogenic effet. (Ethylbeazene) Reproductive and + Causes foetotoxcity inanimals at doses which ate maternally toxic, Developmental Toxicity + Not expected to impair feity. TE, ECOLOGICAL INFORMATION ‘Acute Toxicity Fish + Harmful: 10 100 mg/l Mobility + Floats on water. Persistence/degradability + Readily biodegradable, Oxidizes rapidly by photo-chemical reactions in air. Bioaccumulation + Has the potential bioaccumulate, 13, DISPOSAL CONSIDERATIONS Materia! Disposal + Recover or reycle if posible. ti the responsibility of the waste generator to determine th toxicity and physical properties ofthe matral genctted to determine the proper waste classification and disposal methods in compliance with applicable regulations, Do not dispose Int ihe environment sn dnins or in watercourses. Waste product should not be allowed o contaminate sll or wate. Container Disposal = Drain container thoroughly. After draining, vent na safe place away from spats and fie, Resides may case an explosion hacar. Do nt puncte cit ce weld uncleaned drums recoverer or ntl reclimer, Local Legislation = Disposal should bein acordanee with aplicabte ene, national, an Toca Jaws and regulations, Local regulons may be more stringent han rogionl Of tational requirements and must be complied with 14, TRANSPORTINFORMATION MDG + UN1300 ‘TURPENTINE SUBSTITUTE 3 Ith 78 ‘Chemisol_GHS_revisionLow Aromatic White Spirit Version 1.7 | Bete Date: 30.04.2012 Mater Stay Data Sect Marine pollutant Yes IATA Country variations may apply) UNNo., 1300 Proper shipping name : Turpentine substitute Class! Division 33 Packing group in 15. REGULATORY INFORMATION 7 ‘The regulatory information is not intended to be comprehensive. Other regulations may apply to this material EC Label Name : LOW AROMATIC WHITE SPIRIT BC Labe/EC Number 265-1854 EC Classification : Flammable, Harmful, Dangerous for the environment. EC Annex i Number + 649-330-00-2 EC Symbols Xn Harmful, | N Dangerous for the environment. BC Risk Phrases : RIO Flammable. i [R6S Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. 51/3 Toxic to aquatic organisms, may cause longc-term adverse effects in the | aquatic environment. BC Safety Phrase $23 Do not breathe vapéour, ‘824 Avoid contact with skin, | ‘S61 Avoid release to the environment, Refer to special instructions/ Safety data | sheets. i '862 If swallowed, do not induce vomiting: seek medical advice immediately ‘and show this container or label. pst | Listed, INV(CN) TSCA | EINECS 265-185-4 KECI(KR) KE-25620 Priority Chemical List (PCL) (DENR Administrative Order No, 98- 58) Benzene Listed. Other Information S4/69/EC (21" ATP). The benzene content of this product is less than 0.1 %. ‘Nota P applies, Classification and labeling as carcinogen (R43) is not required, : 16. OTHER INFORMATION Rephrase(s) R10 Flammable RU Highly flammable. R20 Harmfil by inhalation, wo ‘Chemisol_GHS_ revision‘Low Aromatic White Spirit ‘Version 1.7 Eefective Date: 30.04.2012 Material Safety Data Sheet 36/37/38 MSDS Version Number MSDS Effective Date ‘MSDS Revisions Uses and Restrictions ‘MSDS Distribution Disclaimer Invitaing eyes, respiratory system and skin, Initating o eyes and skin, Irritating to respeatory system. May cause cancer. May cause heritable genetic damage, Toxic: danger of serious damage to healt by prolonged exposure through inhalation, in contact, with skin and ifswalloweed. Toxic to aquatic organisms, may cause long-term adverse effets in the aquatic enviroament. Harmfil: May cause king daunage ifsvallowed. Repeated exposure may cause skin dryness or eracking. Vapours may cause drowsiness and dizziness, iT 30.04.2012 +A vertical bar () in the left margin indicates an amendment ftom the previous = The information in this document should be made available to all who may handle the product. : This information is based on our current knowledge and is intended to desctibe ‘the product for the purposes of health, safety and environmental requirements ‘only. It should not therefore be construed as guaranteeing any specific property of the product. a Chemisol GHS_revision