Professional Documents
Culture Documents
Submitted to:
Professor Hasan M Abdullah, PhD.
Water Resource Management
Course-ES-505
Heavy metals from industrial processes accumulate in nearby lakes and rivers.
These are toxic to marine life such as fish and shellfish, and subsequently to the
humans who eat them. Heavy metals can slow development; result in birth defects
and some are carcinogenic.
Industrial waste often contains many toxic compounds that damage the health of
aquatic animals and those who eat them. Some of the toxins in industrial waste
may only have a mild effect whereas other can be fatal. They can cause immune
suppression, reproductive failure or acute poisoning.
Sector Pollutant
Iron and steel BOD, COD, oil, metals, acids, phenols, and
cyanide
Textiles and leather BOD, solids, sulfates and chromium
Pulp and paper BOD, COD, solids, Chlorinated organic
compounds
Petrochemicals and BOD, COD, mineral oils, phenols, and chromium
refineries
Chemicals COD, organic chemicals, heavy metals, SS, and
cyanide
Non-ferrous metals Fluorine and SS
Microelectronics COD and organic chemicals
Mining SS, metals, acids and salts
Water Pollutants by the Industrial Sector
The metal-working industries discharge chromium, nickel, zinc, cadmium, lead, iron
and titanium compounds, among them the electroplating industry is an important
pollution distributor. Photo processing shops produce silver, dry cleaning and car
repair shops generate solvent waste, and printing plants release inks and dyes. The
pulp and paper industry relies heavily on chlorine-based substances, and as a result,
pulp and paper mill effluents contain chloride organics and dioxins, as well as
suspended solids and organic wastes. The petrochemical industry discharges a lot of
phenols and mineral oils. Also waste-water from food processing plants is high in
suspended solids and organic material. Like the various characteristics of industrial
waste-water, the treatment of industrial waste-water must be designed specifically
for the particular type of effluent produced.
The waste-water produced by the pharmaceutical industry has a very bad quality
for waste-water treatment. Usually the concentration of COD is around 5000 –
15000 mg/L, the concentration of BOD5 is relative low, and the ratio of BOD5
/COD is lower than 30% which means the waste-water has a poor
biodegradability. Such waste-water has bad color and high (or low) pH value,
and it needs a strong pretreatment method, followed by a biological treatment
process with a long reaction time.
Waste-water produced by tannery plants
A tannery is one of the most water intensive plants, and its production process
consists of several steps. The quality of water depends only to a slight degree on
the type of hides and the mechanical and chemical methods used in tanning. In a
tannery with chrome and bark tanning, the waste-water resulting from the different
processes are as follows:
In fact the waste-water flow is very uneven. The peak flow can be 250% of the
hourly average flow rate.
ii. Eutrophication:
Eutrophication is an increase in chemicals nutrients, typically compounds containing
nitrogen or phosphorus, in an ecosystem. It can result in an increase in the
ecosystems primary productivity (excessive plant growth and decay), and further
effects including lack of oxygen and severe reductions in water quality, fish and
other animal populations.
When the nutrient content of water undergoes changes, it can disturb the delicate
balance of the ecosystem. For example, when the nutrient content of water
increases, which is known as eutrophication, it can promote algal bloom. Algal
bloom can deplete the oxygen content of water. Though algae produce oxygen in
the daytime with the help of photosynthesis, at night, they use the oxygen
dissolved in water. Algal bloom is often followed by the death of a large quantity
algae, which are decomposed by bacteria by using oxygen. Thus, the entire process
of algal bloom, and the consequent bacterial decomposition of algae deplete the
amount of dissolved oxygen in water. Sometimes, this process can reduce the
oxygen content of water to such an extent that it can no longer support aquatic life.
Such hypoxic areas of ocean, where marine life cannot survive are known as dead
zones.
iii. Increased the Murkiness of Water
Industrial waste-water can increase the murkiness of water. This in turn, can
prevent sunlight from reaching the bottom of the water bodies. As a result, bottom-
dwelling plants can fail to photosynthesize. Excessive murkiness of water can also
block the gills of fish, and thus, make it difficult for them to take up dissolved
oxygen from the surrounding water.
Action Plan
Any action plan to reduce industrial pollution will need to be tailored toward
specific pollutants to work well and not pose undue risks on either the economy or
the environment. A slightly generalized plan based on the different kinds of
solutions available can be proposed for the different pollutants:
Industrial Pollution: A European Solution:
European nations are rapidly undergoing industrial development which is also
taking toll on their environment and climate in the form of industrial pollution. A
successful process of controlling industrial pollution is going on in those countries,
which is called ‘LIFE’. LIFE (“L’Instrument Financier pour l’Environment”/the
financing instrument for the Environment) is an EU program coordinated by the
Environment Directorate-General (LIFE Unit).
LIFE provides industrial innovators with support that may be decisive, in particular
within small and medium-sized industries, in demonstrating the feasibility of
promising technologies and ensuring dissemination of positive results. Several LIFE
projects in various sectors have already contributed to improving manufacturing
processes and others are in progress. This brochure highlights examples of the role
which LIFE plays in stimulating clean technologies. This role will be further
strengthened through the LIFE-Environment projects selected in 2003. There are
twice as many projects focusing on such technologies and on reducing the
greenhouse effect as in 2002, representing more than 16% of the total. Action at
source, and in particular at production sites, is an essential condition for the success
of endeavors to reduce the environmental impact of economic activities. Priority
should be given to choosing innovative techniques that are geared to prevention. It
is also important not to consider problems separately but from an overall
environmental point of view: air, water, soil, natural resources, etc. This two-
pronged approach, both innovative and integrated, is characteristic of LIFE projects.
Many of them contribute to the development of clean technologies in a wide range
of industrial sectors.
Several Countries got benefited using LIFE to control pollution:
In Belgium (p. 12), a research centre has been successful in preventing the
use of sulphuric acid in the manufacture of semiconductors and reducing de
ionized water consumption by 90%.
In Spain (p. 13), a manufacturer of margarine has met the challenge of
excluding from its production process all chemical treatment, waste disposal
and pollutant emissions.
In Italy (p. 14), a textile SME has reduced ink surpluses by 100% and waste
water by 60% by developing digital fabric printing techniques at industrial level.
In Austria (p. 15), one of the world’s leading diode manufacturers have
drastically reduced the level of molybdenum in residual water discharged into
the Danube and has transferred the process used to a Hungarian site.
In Germany (p. 16), an SME has introduced, with major benefits to the
environment and worker health, a dry sawing technique for metal tubes and
profiles which is likely to be recognized as BAT.
In France (p. 18), a plant of a major pharmaceutical concern has considerably
improved its management of water resources by developing a set of new
techniques applicable to many other sectors.
In the Netherlands (p. 20), a major manufacturer of shock absorbers and a
company specializing in industrial coatings have designed a varnish which
contains hardly any volatile solvents, thereby putting an end to a conflict with
the local population.
Industrial water treatment
Before raw sewage can be safely released back into the water, it needs to be
treated correctly in a water treatment plant. In a water treatment plant, sewage
goes through a number of chambers and chemical processes to reduce the amount
and toxicity of the waste.
The sewage first goes through a primary phase. This is where some of the
suspended, solid particles and inorganic material is removed by the use of filters.
The secondary phase of the treatment involves the reduction of organic, this is
done with the use of biological filters and processes that naturally degrade the
organic waste material.
The final stage of treatment is the tertiary phase; this stage must be done before
the water can be reused. Almost all solid particles are removed from the water and
chemical additives are supplied to get rid of any left-over impurities.
Septic tanks and sewage treatment
Septic tanks treat sewage at the place where it is located, rather than transporting
the waste through a treatment plant or sewage system. Septic tanks are usually
used to treat sewage from an individual building.
Untreated sewage from a property flows into the septic tank and the solids are
separated from the liquid.
Solid material is separated depending on their density. Heavier particles settle at
the bottom of the tank whereas lighter particles, such as soap scum, will form a
layer at the top of the tank.
Biological processes are used to help degrade the solid materials.
There are many laws that protect the world’s oceans, rivers and lakes from
unnecessary water pollution. Each continent and country may differ in which laws
they enforce but they aim to have the same overall positive influence.
In Europe, there have been a number laws enforced to protect the surrounding
ocean from marine dumping.
In 1989, the dumping of industrial waste was terminated in all countries in North-
Western Europe, apart from the UK. Dumping was terminated in the UK in 1993.
Recommendations:
1. More efficient production can both reduce industrialists’ costs and reduce the
costs to the nation, local community and environment in terms of pollution.
2. Change the composition of the product to reduce the amount of waste resulting
from the product’s use.
3. It should be made mandatory by promulgating laws to use pollution control
devices in Industries.
4. Due to the difficultly in tracking toxic compounds and their fate, combined with
the need to use complex and costly treatment methods to remove them from
waste-water, it is advisable and cost effective to consider the implementation of
cleaner production methods in industries (such as the replacement of toxic
recalcitrant compounds with others that are less harmful or not harmful at all)
and, also to raise awareness of society to reduce the use of such types of
compounds.
5. Industrial waste-water, especially from chemical and pharmaceutical production,
often contains substances that need to be treated before being discharged into
a biological treatment plant and subsequent water bodies. Generally, this can
be done close to the site of production itself, in selected waste-water streams
before reaching a central treatment plant. Each of the approaches used has
certain advantages and disadvantages. Furthermore, various waste-water
treatment processes exist, but selection of the best technically and
commercially viable solution is always a challenge.
6. Steps should be taken to treat the waste products from industries properly, i.e.
chemical waste management should be taken seriously and it should be
handled in a way that their hazardous quality might be reduced.
7. Production modernization will also help in this regard. The production facilities
should be checked from time to time to detect any discrepancies if present.
8. Good experience and success story of other countries should be shared and
learned to practice as remedy of water pollution by the Industries.
End