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To cite this article: Mohammad Mahbubul Hassan & Samuel James Leighs (2016): Quick-
Dryability of Various Quick-Drying Polyester and Wool Fabrics Assessed by a Novel Method,
Drying Technology, DOI: 10.1080/07373937.2016.1195405
Download by: [Library Services City University London] Date: 03 July 2016, At: 22:54
Quick-Dryability of Various Quick-drying Polyester and Wool Fabrics Assessed by
a Novel Method
Abstract
Modern consumers of textiles are conscious about sustainability of the garments they are
dryability of a fabric. Some of the test methods cited in the literature to measure the
quick-dryability use a method where a small quantity of water is placed on a dry fabric
sample and the time taken for the water to evaporate is measured. These methods are not
suitable for measuring the dryability of a washed fabric as in these test methods the
dryability depends solely on the wicking property of that fabric. In the work presented
here, we are proposing a new test method to measure the real dryability of textile fabrics.
When examined by this proposed method, it was found that some of the commercially
available so-called quick-drying polyester fabrics showed poor dryability. The surface of
examined fabrics was characterised by measuring contact angle and also by ATR-FTIR,
which reveals the reasons behind their poor dryability. This proposed method could be
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KEYWORDS: quick-drying; test method; textile fabrics; contact angle; FTIR
INTRODUCTION
Drying involves the removal of relatively small amounts of water that remain in the
depends of the thickness, structure such as size and shape of pores of the fabric and also
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the chemical interaction between the water molecules and the surface of that fabric [1–3].
If the fabric is hydrophilic, then during wetting of the fabric it will absorb more water and
also retain more water during hydro-extraction than a hydrophobic fabric. In the process
of drying, heat is necessary to evaporate water or moisture from the fibre in a fabric and a
flow of air is needed to carry away the evaporated water/moisture. There are two basic
mechanisms involved in the drying process of textiles: the migration of moisture from the
interior of an individual fibre in the fibre assembly of a fabric to the outer surface of the
fibre, and the evaporation of the moisture from the surface to the surrounding
environment. The rate of drying is determined by the moisture content of the particular
fibre, the drying temperature, the relative humidity and the velocity of the air in contact
Fourt et al. found that if various types of fabrics contain the same quantity of water, all
fabrics dry at the same rate if the drying conditions are same [4]. However, they found
that the time of drying depends upon the amount of water originally held in the fabric,
which is dependent on the molecular characteristics of that fabric and depending on that
factor, some fabric dry faster than the others. Some natural fabrics such as jute and wool
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have high moisture contents and therefore during washing they absorb a large quantity of
water and after squeezing or hydro-extraction they retain comparatively more water than
a hydrophobic fabric. On the other hand, some hydrophobic synthetic fibres made from
polyester and polypropylene fibres absorb very little water during washing and therefore
dry quickly.
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Wet clothes are uncomfortable next to our body skin due to the lower thermal insulation
of wet clothes and the evaporative cooling that occurs while being worn. Therefore it is
necessary to dry the clothes before wearing. Comfort is one of the decision making
factors that affect the buying behaviour of consumers. Clothing is known as the second
skin and therefore clothing intended for next-to-skin applications shouldn’t feel wet. If
the clothing worn becomes wet, it should dry very quickly otherwise it would be
popular. Synthetic fibres (mainly polyester) are the dominant fibres used in this kind of
apparel as they dry rapidly as well as managing quick moisture transfer. The moisture
content of polyester is only 0.4% whereas the moisture content of wool is 15 to 25%,
Traditionally household clothing are dried outside in the air under sun, with the drying
rate enhanced by the velocity of the air flow (wind) along with the intensity of solar
irradiation, i.e. drying very much depends on the weather conditions. Because of
increasing lack of space and sufficient sunshine, in some countries in the urban areas,
clothes are usually machine dried at home or at a commercial laundry by using electric
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driers. If the fabric has poor dryability, it will take longer than usual to dry in the drying
machine, which will eventually increase the energy demand and carbon footprint.
According to the Textile Rental Service Association (TRSA) of America, a laundry uses
1.80 kWh/kg of energy for garment washing and drying; of which 65% is for drying
[5,6]. If the energy consumed in drying could be reduced by 10% at a laundry facility this
would result in total energy reduction of 1309,651 kWh and savings of $57,257 annually
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(assuming a facility handling 11.35 million kilograms/year at 1.76 kWh/kilogram and the
considered "dry" and can be moved to other processing steps such as ironing or folding
[6]. Thus the reduction of water absorption of textiles can significantly shorten their
treatment are commercially available. In reality they may absorb more water and may
take longer to dry than a traditional polyester fabric. Therefore there is no guarantee that
these fabrics after washing will dry faster than other normal fabrics and reduce energy
bills related to drying. The following test methods are used to measure the quick-
dryability of a fabric:
Drying Textiles
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(ii) AATCC Test Method 200-2013, Drying Rate of Textiles at their Absorbent
(iii) AATCC Test Method 201-2013, Drying Rate of Fabrics: Heated Plate Method
(iv) JIS L 1096-2010: Testing Methods for Woven and Knitted Fabrics
The quick-drying textiles are used next-to-body and the human body temperature is 37
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°C. Therefore all of these test methods (except the TTRI method) measure dryability of
fabrics at that temperature. In the TTRI method, developed by the Taiwan Textile
Research Institute, a predetermined size of fabric is cut from a fabric conditioned for 48
hours at 20±2 °C and 65% relative humidity (RH). The fabric sample is placed flat on the
weighing pan of a digital balance, 0.2 ml water is placed at the middle of the sample by a
micropipette from 1 cm above the centre of the fabric and the weight loss is monitored
over time at 20±2 °C and 65% RH. The AATCC Test Method 201-2013 is similar to the
TTRI method except the fabric is placed on a plate heated at 37 °C. JIS method is also
similar to the TTRI method except different volume of water is placed on a fabric. The
AATCC Method 200 is quite different from the other mentioned methods. In this method,
predetermined temperature is passed through the fabric and the temperature of the air is
maintained. The drying rate is measured by gravimetric method under the continuous
All of these above methods favour strongly wicking textiles and do not represent
assessment of real quick-dryability as the fabric samples are not completely wet in these
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methods. They use very small quantity of water and because of high wicking property of
the fabric the water spread and dries quickly. It could be argued that the terminology used
for these tests should be changed to ‘assessment of moisture management’ rather than
the real quick-dryability that will show the benefit in energy saving in drying of textiles.
In this article, we are reporting a novel test method for the measurement of real quick-
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dryability of textile fabrics and compared the results with the quick-dryability assessed by
the TTRI method. The surface of various fabrics was characterised by attenuated total
angle measurement.
Materials
Fabric made with various types of fibres, blends and various constructions were procured
from various sources. The wool fabric used in this work, is an untreated wool fabric, i.e.
no shrink-resist treatment was applied. Sandozin MRN, a non-ionic wetting agent, was
specimen was cut from the fabric and it was conditioned at the above standard conditions
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for 48 hours. The fabric was placed on a pan of a 4-decimal point microbalance with the
face of the fabric upward and the dry weight of the fabric (Wf) was recorded in grams.
0.2 ml water was then placed at the middle of the sample by a micropipette from 1 cm
above the centre of the fabric, and immediately the wet weight (Wo) was recorded. The
change of the weight of the fabric (Wi) at the ith minute (i=10, 20, 30, etc. minutes) was
‘Remained Water Ratio (RWR)’ was calculated by the formula to express the change of
water remaining in the specimen by specified time, to draw the evaporation curve from
Assessment was done according to the method described above. At least three tests were
carried out for each type of fabric and the average was reported here.
The assessment of quick-dryability was carried out at 37±1 °C and 50±2% relative
New Zealand). A battery-powered, four digit microbalance was placed inside the cabinet.
Five fabric samples of 1.748 g were cut from each type of fabric. The samples were
conditioned at 37±1 °C and 50±2% relative humidity for 24 hours and their dry weight
was measured (Wf). Each sample was then placed into a 200 ml solution of distilled water
containing 5 drops of Sandozin MRN (wetting agent) for five minutes. The sample was
then removed, immediately weighed, and placed into a 50 ml centrifuge tube. The tube
had a metal sieve placed in the bottom to prevent the samples from contacting the
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extracted excess liquid collected at the bottom. The centrifuge was set to 2000 rpm for 30
s. The sample was immediately transferred to the Contherm Cabinet and the weight was
recorded (Wi). The oven dry weight (Wf) was measured separately by drying the fabric at
105±2 °C until constant weight was observed. The change of weight (Wo) of the samples
was then recorded at 10 minute intervals, until the weight was equal to the dry weight of
the fabric. The water remaining in the fabric sample (%) was calculated according the
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following equation:
For each fabric type, five measurements were conducted and the average is reported here.
The moisture regain of the control and the various treated wool fabrics was assessed
according to ISO Test Method 6741-1987 at 20±2°C and 65±2% relative humidity. An
untreated wool fabric was used to assess the reliability and robustness of this proposed
test method. Five samples were cut and the quick-dryability for each sample was
measured.
The surface of various fabrics was characterised by ATR-FT-IR and also by contact
angle measurements. A Perkin Elmer Fourier transform infrared (FTIR; Model System
zinc−selenium crystal was used for infrared studies to characterise the surface of various
fabrics. For each sample 64 scans were carried out and the averages are reported here.
KSV CAM 200 Contact Angle Measurement Apparatus (made by KSV Instruments,
Finland) was used to measure the contact angle. The contact angle calculation was
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performed by applying the spherical approximation of the drop by curve fitting based on
the Young-Laplace equation using the software (KSV CAM 200) supplied with the
equipment. For each sample, the contact angle was measured at 10 places and the average
contact angle was reported. For each sample, the first measurement was taken
immediately after placing the drop of water and then measurements were taken at 1 s
intervals for all samples up to 4 s except for sample ‘Sam1’ for which contact angle was
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measured at 20 s intervals up to 80 s.
We are proposing a novel test method to assess the quick-dryability of various textile
fabrics. To check the reliability of the proposed quick-drying test method, five samples
were cut from a 2/2 twill wool fabric and their quick-dryability was measured in terms of
the water remaining in the fabric as a function of time. Statistical analysis of the results
obtained was carried out. Standard deviation (SD) and coefficient of variation (CV) of the
results obtained for five samples cut from the same fabric are shown in Table 2. The
quick-dryability of these wool fabrics samples is shown in Fig. 1. It is evident that very
shows that the maximum CV observed was less than 4%, which indicates that that the
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Fig. 2 shows the quantity of water absorbed by samples cut from the same control fabric
and also water remaining in the fabric after hydro-extraction at 2000 rpm. The fabric
samples soaked in surfactant solution only absorbed a small quantity of water, of which
some portions were removed during hydro-extraction process. It is evident that the
quantity of water absorbed by various samples cut from the same control fabric was
consistent from sample to sample and the CV of the samples was only 1.8%. Similarly,
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the quantity of water remaining in the fabric after hydro-extraction for various samples
was also consistent (CV was only 1.6%). It is evident that water absorbed and water
remaining in the fabric samples after hydro-extraction are reproducible as the CV% was
very small. The achieved results indicate that the water absorbed, water remained in
fabric samples after the hydro-extraction and the assessed quick-dryability were
polyester, wool fabric and blends were measured by the TTRI method as shown in Fig. 3.
It is evident that untreated wool fabric examined here showed very poor quick-dryability
and was the worst of all the types of fabrics investigated. It is not surprising as untreated
wool fabric used in this experiment had high surface hydrophobicity and poor wicking
properties. Therefore water droplet was not spread on the surface of fabric rather
remained as a droplet and therefore took long time to evaporate. On the other hand, in the
case of quick-drying polyester fabrics, the placed water immediately spread to large
surface of the fabric and evaporated quite quickly. Samples Sam7 (quick-drying polyester
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3) and Sam8 (quick-drying polyester 4) showed the best quick-dryability. Samples Sam4
and Sam5, made of Coolmax® blended with ordinary polyester fibre at various
percentages, also showed quick-dryability nearer to that of the samples Sam7 and Sam8.
Samples Sam2 and Sam3 showed slightly poor results compared to Sam4 and Sam5.
Sample Sam9 (quick-drying polyester 2) showed quite poor quick-dryability, which was
in between sample Sam8 and the wool fabric. The third poorest quick-dryability was
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shown by the thin plain-woven quick-drying polyester blended with ordinary polyester. It
is quite interesting that quick-dryability improved in the blended fabric with an increase
in share of the quick-drying polyester 1. It is quite interesting that of the fabric samples
investigated, sample Sam8 made with quick-drying polyester 4 was the heaviest but
showed the best quick-dryability. On the other hand sample Sam5 was the thinnest of the
fabrics studied, but was the third worst (only better than wool fabric and Sam6).
Fig. 4 shows the quick-dryability measured of the same fabrics used in the measurement
of quick-dryability by TTRI method by our proposed method. It can be seen that the
quick-dryability measured by our method showed a different trend compared to the trend
shown for the TTRI method. Sam8 showed the best quick-dryability when it was
measured by the TTRI method but in our method, sample Sam6 showed the best and
Sam8 and Sam9 showed the worst quick-dryability. Wool fibre is one of the most
15%. However, it has an 18-methylecosanoic acid layer attached to the fibre surface by
thioester linkages that provide high surface hydrophobicity [7]. On the other hand,
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ordinary polyester fibre has one the lowest moisture regains. It is commonly perceived
that wool dries very slowly although the results achieved here show that wool fibre could
be dried faster than some of the quick-drying polyester fibres. To understand the quick-
dryability mechanism, it is necessary to study how fibre types affect their water
The chemical structure and surface properties of a polymeric fibre affects water
absorption capacity and also its water retention capacity after hydro-extraction; the
weaving structures also have an effect. Fig. 5 shows the quantity of water absorbed by
wool and various quick-drying polyester fabrics after soaking them in a surfactant
containing water for 10 minutes. It can be seen that samples Sam2 and Sam3 absorbed
the least quantity of water and it was only 1.45 g/g; both of the fabrics are made of 50%
wool and 50% Coolmax® fibre. Of the Coolmax®/ordinary polyester mixed fabrics,
water absorption capacity decreased with a decrease in the percentage of Coolmax® fibre
in the blended fabric. The fabric containing 57% Coolmax® fibre showed the highest
water absorption capacity and the lowest by the blended fabric containing 52%
Coolmax® fibre. Of the Supertex® quick-drying polyester fabrics, sample Sam8 showed
the highest water absorption and Sam9 showed the lowest water absorption. The amount
of water absorbed by wool fabric was similar to the amount absorbed by sample Sam5.
The water retention after hydro-extraction followed the same trend observed for water
absorption. Of all the samples investigated, Sam6 showed the lowest water absorption
and also retention after hydro-extraction. On the other hand, sample Sam9 showed the
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highest water absorption and also water retention after hydro-extraction. It can be seen
that fabric thickness has an effect on water absorption and post-hydro-extraction water
retention capacity as in samples Sam7-9, they were increased with an increase in g/m2 of
the fabric.
Table 3 shows dynamic surface contact angle of wool, various quick-drying polyester
fabrics and their blends with wool. It is evident that wool fabrics are quite hydrophobic as
it showed the highest contact angle of the fabrics investigated. Quick-drying polyesters
are so hydrophilic that for some of them it was difficult to measure the contact angle as
the water droplet spread within less than a second after placing them on the fabric. The
surface of wool fabric was so hydrophobic that even after 80 s the contact angle didn’t
diminish. Wool fibre/Coolmax® blend fabrics (Sam2 and Sam3) showed some surface
hydrophobicity but for both of them contact angle became 0 within 4 s. All
was not possible to measure their contact angle. On the other hand, Supertex® quick-
ATR-FTIR Spectroscopy
Supertex® quick-drying polyester fabrics. The spectrum of Sam1 (untreated wool) shows
the absorbency peak at 1627 cm−1 which can be assigned to the elastic vibration peak of
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the C=O (amide I) and the peak at 1506 cm−1 is labelled as the C–N stretching and N–H
in-plane bending vibrations (amide II) [8]. The spectrum of untreated wool (Sam1) also
shows a broad peak at 3100−3400 cm−1, which could be attributed to hydroxyl groups,
and a weak band at 1223 cm-1, which related to C–N and C–H stretching vibrations
(amide III) [9,10]. Sample Sam2 (wool/Coolmax® blend) shows a weak hydroxyl band at
3100−3400 cm-1 which is coming from the wool fabric as it is a 50/50 blend of
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Coolmax® and wool fibres. It is quite interesting that the spectra of the quick-drying
polyester fabrics show no hydroxyl group peak at 3100−3400 cm-1 although they show
super-hydrophilicity. They may have other hydrophilic groups that are conferring their
hydrophilicity. The spectra of all of the quick-drying polyester fabrics look similar and
they have peaks at 722, 970, 1016, 1093, 1238, 1338, 1407, 1506, 1710, and 2960 cm-1.
The weak band at 2960 cm-1 could be attributed to the stretching vibrations symmetrical
and unsymmetrical vibrations of C-H [11]. The bands at 1016, 1510 and 1710 cm-1 are
related to the stretching vibrations of sulfonic acid, -C=C aromatic and carboxylic acid
various quick-drying polyesters are due the presence of hydrophilic carboxyl and
CONCLUSIONS
fabrics. The quick-dryability measurement was repeated five times and the standard
deviation of the quick-drying results were within an acceptable range. We measured the
quick-dryability of several quick-drying polyester and wool fabrics using this new
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method. Because of high moisture regain, wool fabrics usually dry quite slowly.
However, it was found that some of the commercially available so-called quick-drying
polyester fabric showed the best quick-dryability when assessed by the TRRI developed
test method, but when examined by our proposed method, it performed the worst in terms
of quick-dryability and was even poorer than the wool fabric. Fabrics made from
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Coolmax® polyester fibre blended with wool or ordinary polyester performed well in
both of the test methods investigated. When measured by our proposed test method, it
was found that the quick-dryability rate decreased with an increase in Coolmax® fibre in
the blend fabrics. The more the fabric is hydrophilic the more it absorbs water and takes
longer to dry. This proposed method could be used in industry to compare the quick-
ACKNOWLEDGEMENTS
This research was funded by the Ministry of Business Innovation and Employment
(MBIE) of the New Zealand Government thorough Grant C10X0824. Stewart Collie
REFERENCES
1. Fangueiro, R.; Filgueiras, A.; Soutinho, F.; Meidi, X. Wicking behaviour and
drying capability of functional knitted fabrics. Text. Res. J. 2010, 80, 1522-1530.
15
2. Chen, D.; Tan, L.; Liu, H.; Tang, F.; Hu, J.; Li, Y. Fabrication of fast-absorbing
and quick-drying wool fabrics with good washing durability. ChemSusChem 2010, 3,
1031-1035.
measurements of moisture absorption and quick dry fabrics. Fiber. Textil. East. Eur.
4. Fourt, L.; Sookne, A. M.; Frishman, D.; Harris, M. The rate of drying of fabrics.
www.eecabusines.govt.nz/eib/case-studies/documents/cls-07.pdf.
10. Wang, K.; Li, R.; Ma, J. H.; Jian, Y. K.; Che, J. N. Extracting keratin from wool
16
11. Gupta, B.; Hilborn, J.; Hollenstein, C. H.; Plummer, C. J. G.; Houriet, R.;
17
Table 1 Specifications of fabrics used
woven
Coolmax®
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Coolmax ®
polyester woven
polyester woven
polyester
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Table 2 Reliability of the developed test method assessed by measuring the quick-
Drying time (min) Water remaining in the fabric (%) Mean SD CV(%)
19
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120
110
0
0
0.413 0.39
0
0.40
20
0.42
0
0.39
0
0.40
0
0
0.01 3.13
Table 3 Dynamic surface contact angle of wool and various quick-drying polyester
fabrics
Sam
1
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Sam
Sam
Sam
4
0 0 0 0
Sam
5
0 0 0 0
Sam
Sam
7
0
Sam
8
0
21
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*
9
Sam
22
For Sam1 measurements were taken at 20 s intervals
Figure 1. Quick-dryability of wool fabrics samples cut from the same fabric.
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23
Figure 2. Variation in water absorbed by the fabric samples after wetting them in water
and the water remaining in the fabric after the hydro-extraction for the control fabric. The
CV for the water absorbed and water remaining in the fabric after hydro-extraction was
24
Figure 3. Quick-dryability of fabrics made with various types of fibers measured by the
TTRI method.
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25
Figure 4. Quick-dryability of fabrics made with various types of fibers by our proposed
method.
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26
Figure 5. Water remaining in the fabric after hydro-extraction for the same weight of
27
Figure 6. ATR-FTIR spectra of surface of wool and various quick-drying polyester
fabrics.
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28