CHE 134 HW 15A Name:)_______________________________________________________________________________ 1. What is the formula for the hydronium and the hydroxide ions?

2.

In the reaction H2CO3 + H2O

HCO3 + H3O+, the Brnsted acids are?

3.

Identify the conjugate pairs of each reaction. a) HCO3 + HPO42 H2CO3 + PO43

b)

H2PO4 + HSO4

H3PO4 + SO42

c)

CO32 + HSO4

HCO3 + SO42

d)

CO32 + HSO4

HCO3 + SO42

e)

CO32 + H2PO4

HCO3 + HPO42

4.

What is the pH of an aqueous solution that contains 2.7 v 1020 H3O+ ions per liter of solution?

5.

The OH concentration in a 1.0 v 10 3 M Ba(OH)2 solution is

6.

What is the H+ ion concentration in a 4.8 v 10 2 M KOH solution?

CHE 134 HW 15A 7. Calculate the H+ ion concentration in a 8.8 v 10 4 M Ca(OH)2 solution.

8.

A 0.10 M HF solution is 8.4% ionized. Calculate the H+ ion concentration.

9.

Consider the weak acid CH3COOH (acetic acid). If a 0.048 M CH3COOH solution is 5.2% ionized, determine the [H3O+] concentration at equilibrium.

10.

Calculate the pH of a carbonated beverage in which the hydrogen ion concentration is 3.4 v 10 4 M.

11.

Determine the pH of a KOH solution made by mixing 0.251 g KOH with enough water to make 1.00 v 102 mL of solution.

12.

Calculate the pH of a 0.10 M HCN solution that is 0.0070% ionized.

13.

Calculate the pH of 2.6 v 10 2 M KOH.

14.

Calculate the hydrogen ion concentration in a solution of fruit juice having a pH of 4.25.

CHE 134 HW 15A 15. Calculate the hydrogen ion concentration in a solution having a pH of 4.60.

16.

Diet cola drinks have a pH of about 3.0, while milk has a pH of about 7.0. How many times greater is the H3O+ concentration in diet cola than in milk?

17.

The pH of coffee is approximately 5.0. How many times greater is the [H+] in coffee than in neutral water?

18.

Acid strength decreases in the series HI > HSO4 > HF > HCN. Which of these anions is the weakest base?

19.

Arrange the acids HBr, H2Se, and H3As in order of increasing acid strength.

20.

Which one of these net ionic equations represents the reaction of a strong acid with a strong base? A) B) C) D) H+(aq) + OH (aq) p H2O(aq) H+(aq) + CH3NH2(aq) p CH3NH3+(aq) OH (aq) + HCN(aq) p H2O(aq) + CN (aq) HCN(aq) + CH3NH2(aq) p CH3NH3+(aq) + CN (aq)

21.

Predict the direction in which the equilibrium will lie for the reaction H2CO3 + F HCO3 + HF. Ka1[ H2CO3] = 4.2 v 10 7; Ka[HF] = 7.1 v 10 4

22.

Predict the direction in which the equilibrium will lie for the reaction C6H5COO + HF C6H5COOH + F Ka[C6H5COOH] = 6.5 v 10 5; Ka[HF] = 7.1 v 10 4