Safety Data Sheet

ETEROL 100

Safety Data Sheet dated 1/2/2021, version 2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Mixture identification:
Trade name: ETEROL 100

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Used in detergents.
Additive used in industrial sector.
1.3. Details of the supplier of the safety data sheet
Company:
CISME Italy SRL
Via Giuseppe Marcora 7
20121 Milano
Tel 0030 02 29000402
Fax 0039 02 654946
CISME Italy SRL - Phone 0039 0229000402
Competent person responsible for the safety data sheet:
msds@cismeitaly.com
1.4. Emergency telephone number
CISME Italy SRL - Phone 0039 0229000402

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP)
Danger, Eye Dam. 1, Causes serious eye damage.

Warning, Aquatic Acute 1, Very toxic to aquatic life.

Warning, Aquatic Chronic 2, Very toxic to aquatic life with long lasting effects.

Adverse physicochemical, human health and environmental effects:

No other hazards
2.2. Label elements
Hazard pictograms:

Danger
Hazard statements:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.

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P310 Immediately call a POISON CENTER/doctor/...
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions:
None
Contains
C18 - ALKYLTRIMETHYLAMMONIUM CHLORIDE
C20/22-alkyltrimethyl Ammonium Chloride
Special provisions according to Annex XVII of REACH and subsequent amendments:
None

2.3. Other hazards

vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

SECTION 3: Composition/information on ingredients

3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification:

Name Ident. Number Classification

C18 - CAS: 112-03-8 3.1/4/Oral Acute Tox. 4 H302
ALKYLTRIMETHYLAM EC: 203-929-1
MONIUM CHLORIDE REACH No.: 01-21199705 3.2/1C Skin Corr. 1C H314
59-21-0000 3.3/1 Eye Dam. 1 H318
4.1/A1 Aquatic Acute 1 H400
4.1/C1 Aquatic Chronic 1
H410
C20/22-alkyltrimethyl CAS: 68607-24-9 3.2/2 Skin Irrit. 2 H315
Ammonium Chloride EC: 271-756-9
REACH No.: 01-21194848 3.3/1 Eye Dam. 1 H318
17-22-0000 3.9/2 STOT RE 2 H373
4.1/A1 Aquatic Acute 1 H400
4.1/C2 Aquatic Chronic 2
H411
Propan-2-ol Index 603-117-00-0 2.6/2 Flam. Liq. 2 H225
number:
CAS: 67-63-0 3.8/3 STOT SE 3 H336
EC: 200-661-7 3.3/2 Eye Irrit. 2 H319
REACH No.: 01-21194575
58-25-0000

SECTION 4: First aid measures

4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
Remove contaminated clothing immediatley and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.

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In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of
time, then consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do NOT induce vomiting.
Give nothing to eat or drink.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use
or safety data sheet if possible).
Treatment:
None

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material
residuals in the containers.

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Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Handle the product after consultation with all sections of this SDS.
Store in its original packaging, in a cool, well-ventilated area away from open flames and heat
sources.
Compatible materials: stainless steel, polyethylene, paper.
Avoid store temperature higher than 70 °C.
Do not eat, drink or smoke in storage place.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
ETEROL 100
- OEL Type: TLV- ACGIH - STEL: 492 mg/m3, 200 ppm - Notes: propan-2-ol CAS
67-63-0 BEI - Eye and URT irr, CNS impair
- OEL Type: STEL - STEL: 983 mg/m3, 400 ppm
Propan-2-ol - CAS: 67-63-0
- OEL Type: ACGIH - TWA(8h): 200 ppm - STEL: 400 ppm - Notes: A4, BEI - Eye and
URT irr, CNS impair
DNEL Exposure Limit Values
ETEROL 100
Worker Industry: 0.49 mg/m3 - Exposure: Inhalation - Frequency: Long Term, systemic
effects - Notes: CAS 68607-24-9
Worker Professional: 1.7 mg/kg bw/day - Exposure: Dermal - Frequency: Long Term,
systemic effects - Notes: CAS 68607-24-9
Worker Industry: 888 mg/kg bw/day - Exposure: Dermal - Frequency: Long Term,
systemic effects - Notes: CAS 67-63-0
Worker Professional: 500 mg/m3 - Exposure: Inhalation - Frequency: Long Term,
systemic effects - Notes: CAS 67-63-0
Consumer: 26 mg/kg bw/day - Exposure: Oral - Frequency: Long Term, systemic
effects - Notes: CAS 67-63-0
PNEC Exposure Limit Values
ETEROL 100
Target: Fresh Water - Value: 0.23 ug/Kg - Notes: CAS 122-19-0
Target: Marine water - Value: 0.23 ug/Kg - Notes: CAS 122-19-0
Target: Marine water - Value: 0.013 mg/l - Notes: CAS 68607-24-9
Target: Fresh Water - Value: 0.13 mg/l - Notes: CAS 68607-24-9
Target: Terrestrial compartment - Value: 0.64 mg/l - Notes: CAS 122-19-0
8.2. Exposure controls
Eye protection:
You should wear safety goggles.
Goggles (DIN EN 166)
Protection for skin:
Chemical protection clothing.
Protection for hands:
Protect hands with suitable gloves, the duration of which will depend on the time of use and
use.
Suitable gloves type:

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ETEROL 100
PVC (polyvinyl chloride).
Neoprene.
NBR (nitrile rubber - butyl rubber).
Protect your hands with gloves category ref . Standard EN 374.
Respiratory protection:
The use of protective equipment, such as masks of the type indicated, is necessary in the
absence of technical measures limiting worker exposure.
Not required for normal use.
Maintain adequate ventilation in the working environment, prevent the formation of mists or
vapors.
Thermal Hazards:
Data not available.
Environmental exposure controls:
As the use of adequate technical equipment must always take priority over personal
protective equipment, make sure that workplace is well aired through effective local
aspiration. When choosing protective equipment, ask your chemical substance supplier.
Personal protective equipment must be CE marked, showing that is complies with applicable
standard.
Appropriate engineering controls:
None

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Method: Notes

Appearance and colour: Whitish wax -- --
Odour: Characteristic -- --
Odour threshold: -- --
pH: 3.8 - 4.5 sol. -- --
4%
Melting point / freezing 50 °C -- --
point:
Initial boiling point and N.A. -- --
boiling range:
Flash point: > 125 ° C -- --
Evaporation rate: N.A. -- --
Solid/gas flammability: N.A. -- --
Upper/lower flammability N.A. -- --
or explosive limits:
Vapour pressure: N.A. -- --
Vapour density: N.A. -- --
Relative density: N.A. -- --
Solubility in water: Dispersible. -- --
Solubility in oil: -- --
Partition coefficient N.A. -- --
(n-octanol/water):
Auto-ignition temperature: N.A. -- --
Decomposition > 200 °C -- --
temperature:
Viscosity: N.A. -- --
Explosive properties: -- --
Oxidizing properties: -- --

9.2. Other information

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Properties Value Method: Notes

Miscibility: N.A. -- --
Fat Solubility: N.A. -- --
Conductivity: N.A. -- --
Substance Groups -- --
relevant properties

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable in normal condiction.
10.2. Chemical stability
Stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions
Under normal circumstances no hazardous reactions are foreseeable.
10.4. Conditions to avoid
None in particular. However follow the usual precautions against chemicals.
Avoid the contact with strong oxidants
10.5. Incompatible materials
Avoid the contact with powerful oxidising agents.
10.6. Hazardous decomposition products
In case of overheating and fire, may develop irritating vapors / gases.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological information of the product:
ETEROL 100
Acute toxicity.:
Test: LD50 - Route: skin - Species: Rabbit = 12800 mg/kg - Source: OECD 404 -
Notes: CAS 60-63-0
Test: LD50 - Route: Oral - Species: Rat = 5045 mg/kg - Duration: 4h - Source: OECD
403 - Notes: CAS 60-63-0
Test: LD50 - Route: Oral - Species: Rat = 795 mg/kg bw - Source: OECD 401 - Notes:
CAS 122-19-0
Test: LD50 - Route: Oral - Species: Rat = 3190 mg/kg bw - Source: OECD 401 - Notes:
CAS 68607-24-9
Not classified - Notes: ETEROL 100
Test: LD50 - Route: Oral - Species: Rat = 795 mg/kg bw - Source: OECD 401 - Notes:
CAS 122-19-0
Skin corrosion/irritation.:
Route: Skin Negative - Source: OECD439 - Notes: CAS 122-19-0
Test: Skin Irritant - Route: Skin - Species: Rabbit Positive - Duration: 4h - Notes:
N-Benil trimethyl ammonium chloride CAS 68607-24-9
Serious eye damage/irritation:
Test: Eye Irritant Positive - Source: OECD 492 - Notes: CAS 122-19-0
Route: Skin Serius yes demage - Notes: ETREOL 100
Toxicological information of the main substances found in the product:
N.A.
If not differently specified, the information required in Regulation (EU)2015/830 listed below must be
considered as N.A.:
Acute toxicity.;
Skin corrosion/irritation.;
Serious eye damage/irritation;
Respiratory or skin sensitization.;
Germ cells mutagenicity.;

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Carcinogenicity.;
Reproductive toxicity.;
STOT-single exposure;
STOT-repeated exposure.;
Aspiration hazard..

SECTION 12:Ecological information

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.

ETEROL 100
Aquatic acute toxicity.:
Endpoint: LC50 - Species: Fish = 0.85 mg/l - Duration h: 96 - Notes: CAS 122-19-0
Endpoint: EC50 - Species: Daphnia = 0.016 mg/l - Duration h: 48 - Notes: CAS
122-19-0
Endpoint: LC50 - Species: Fish = 3.5 mg/l - Duration h: 96 - Notes: CAS 68607-24-9
Endpoint: EC50 - Species: Daphnia = 1.39 mg/l - Duration h: 48 - Notes: CAS
68607-24-9
Endpoint: EC50 - Species: Algae = 3.4 mg/l - Duration h: 72 - Notes: CAS 68607-24-9
Endpoint: LC50 - Species: Fish = 9640 mg/l - Duration h: 96 - Notes: CAS 67-63-0
Endpoint: EC50 - Species: Daphnia = 13299 mg/l - Duration h: 48 - Notes: CAS
67-63-0
Aquatic chronic toxicity.:
Endpoint: EC10 - Species: Fish = 0.025 mg/l - Duration h: 504 - Notes: CAS 122-19-0
Endpoint: NOEC - Species: Fish = 0.24 mg/l - Notes: CAS 67-63-0
12.2. Persistence and degradability
ETEROL 100
Biodegradability: Persistent and biodegradable. - Test: N.A. - Duration h: N.A. - %: N.A.
- Notes: CAS 122-19-0
Biodegradability: Easily biodegradable. - Test: OECD 301 - Duration h: 28 d - %: 64 -
Notes: CAS8607-24-9
12.3. Bioaccumulative potential
ETEROL 100
Data not available. - Test: N.A. N.A. - Duration h: N.A. - Notes: N.A.
12.4. Mobility in soil
ETEROL 100
Data not available. - Test: N.A. N.A. - Duration h: N.A. - Notes: N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.

SECTION 14: Transport information

14.1. UN number
ADR-UN number: 3077
IATA-Un number: 3077
IMDG-Un number: 3077
14.2. UN proper shipping name
ADR-Shipping Name: ENVIRONMETALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.(MIXTURE OF QUATERNARY SURFACTANTS)

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IATA-Technical name: ENVIRONMETALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.(MIXTURE OF QUATERNARY SURFACTANTS)
IMDG-Technical name: ENVIRONMETALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.(MIXTURE OF QUATERNARY SURFACTANTS)
14.3. Transport hazard class(es)
ADR-Class: 9
ADR-Label: 9
IATA-Class: 9
IMDG-Class: 9
14.4. Packing group
ADR-Packing Group: III
IATA-Packing group: III
IMDG-Packing group: III
14.5. Environmental hazards
Marine pollutant: Marine pollutant
14.6. Special precautions for user
IATA-Passenger Aircraft: 956
IATA-Cargo Aircraft: 9565
IMDG-Technical name: ENVIRONMETALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.(MIXTURE OF QUATERNARY SURFACTANTS)
IMDG-EMS: F-A,S-F
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
N.A.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 453/2010 (Annex II)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation
(EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product:
Restriction 3
Restriction 40
Restrictions related to the substances contained:
No restriction.
Where applicable, refer to the following regulatory provisions :
Directive 2012/18/EU (Seveso III)
Regulation (EC) nr 648/2004 (detergents).
Dir. 2004/42/EC (VOC directive)

Provisions related to directive EU 2012/18 (Seveso III):

Seveso III category according to Annex 1, part 1
Product belongs to category: E1

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for the mixture.

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SECTION 16: Other information
Full text of phrases referred to in Section 3:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H315 Causes skin irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H225 Highly flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H319 Causes serious eye irritation.

Hazard class and Code Description

hazard category
Flam. Liq. 2 2.6/2 Flammable liquid, Category 2
Acute Tox. 4 3.1/4/Oral Acute toxicity (oral), Category 4
Skin Corr. 1A 3.2/1A Skin corrosion, Category 1A
Skin Corr. 1C 3.2/1C Skin corrosion, Category 1C
Skin Irrit. 2 3.2/2 Skin irritation, Category 2
Eye Dam. 1 3.3/1 Serious eye damage, Category 1
Eye Irrit. 2 3.3/2 Eye irritation, Category 2
STOT SE 3 3.8/3 Specific target organ toxicity - single exposure,
Category 3
STOT RE 2 3.9/2 Specific target organ toxicity - repeated
exposure, Category 2
Aquatic Acute 1 4.1/A1 Acute aquatic hazard, category 1
Aquatic Chronic 1 4.1/C1 Chronic (long term) aquatic hazard, category 1
Aquatic Chronic 2 4.1/C2 Chronic (long term) aquatic hazard, category 2

Paragraphs modified from the previous revision:

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazards identification
SECTION 3: Composition/information on ingredients
SECTION 4: First aid measures
SECTION 6: Accidental release measures
SECTION 8: Exposure controls/personal protection
SECTION 10: Stability and reactivity
SECTION 11: Toxicological information
SECTION 12:Ecological information
SECTION 14: Transport information
SECTION 15: Regulatory information
SECTION 16: Other information

Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) 1272/2008 [CLP]:

Classification according to Regulation (EC) Nr. Classification procedure

1272/2008
Acute Tox. 4, H302 Calculation method
Skin Corr. 1A, H314 On basis of test data (pH)
Eye Dam. 1, H318 On basis of test data (pH)
STOT RE 2, H373 Calculation method

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Aquatic Acute 1, H400 Calculation method
Aquatic Chronic 1, H410 Calculation method

This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.

ADR: European Agreement concerning the International Carriage of

Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWA: Time-weighted average
WGK: German Water Hazard Class.

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