SECTION -D NEET Booster Questions In the given reaction a cl sa “ + CHOH—“—» 2el —CI will be replaced by OCH, at carbon a2 (2) 3 @) 4 (4) Any of these In the given reaction () CHM cH—cH— cH, PE, (p NA noni! ° (Pyis (1) CH= oa - CH,OH cH, (2) CH GA ~~ CH.- CH, OH OH | @) CH,-C-CH, I CH, (4) CH,— CH=CH, In the given reaction cH,—cH, —4 > (a) + (6) Product (A) and (B) will be (1) C,H,-OH and CH,-CH,-! (2) C,H,-1 and C,H,OH @) CH.-I and CH) (4) CgHg-OH and C,H, The order of reactivity of the following alcohols towards HC! is CH, CH, F VT Fo | OH OH " Y Ph on OH i N (1) > ivenet (2) >>> 1 @) Ve>ilateat (4) >> lov10. "1 Decreasing order of boiling points amongst the 12. following follows the order (A) Butanol-1 (8) Butanol-2 (©) 2-methyt2-propanol (1) A>B>C (2) B>A>C 13. (3) C>A>B (4) C>B>A Acidic strength is maximum for (1) o-amino phenol 14 (2) m-amino phenol 3) p-amino phenol (4) All have equal K, 46. Phenol can be distinguished from alcohol (1) Tollens reagent (2) Schiff's base 3) Neutral FeCl, (4) Fehting solution Intermediate formed when phenol reacts with 16. chloroform in the presence of base is (1) sccl, 2) ®coi, (3) CCl, (4) CHCl, Which one of the following alcohols will give E1 reaction most readily? (1) CH,— CH,— OH (2) CH,—CH,—CH,— OH CH, | (3) CH,—C—CH,— CI | 1H, — CH,OH cH, cH, (4) CH, — e CH,OH CH, 17. The reaction of L\ with RMgX followed by hydrolysis will produce (1) RCH,CH,OH (2) RCH(OH)CH, 3) RCHOHR (4) RCH,CH,R Order of reactivity of HX towards ROH is (1) HI>HBr> HCI (2) HCI > HBr > HI (3) HBr>HCl> HI (4) HBr > HI > HCI The end product of the reaction is Ethyl amine Ny gp PS: , g_Nb (1) Ethyl amide (2) Ethyl amine (3) Acetamide (4) Methyl amine Glycerol reacts with KHSO, to produce (1) Trinitro glycerine (3) Glyceraldehyde (2) Acrolein (4) Formic acid HBr reacts fastest with (1) 2-methyl propan-2-0l (2) Propan-2-ol (8) Propanol (4) 2-methyl propan-1-ol Phenol reacts with CCI, in excess of NaOH will produce (1) Picric acid 3) Salicylic acid (2) Salicylaldehyde (4) Benzoic acid Increasing rate of reaction in a base catalyzed hydrolysis reaction is Me. 0. Me HO. Me Me Me Me H (A) (8) HO OH Et 0. et H H et et (C) (D) (1) (C) < (B) < (A) < (D) (2) (B) < (A) < (D) < (C) (D) < (A) < (B) < (C) (4) (0) < (C) < (8) < (A) 1H Hin, (py ii 7 (Major) Which of the following statements is correct for the formation of above product? (1) The reaction proceeds through formation of carbocation (2) The major product is benzene (3) The major product is an aromatic compound (4) All of these18. 19. 20. a 22, 23, In Victor Meyer's test, red colour is given by a) Au @) -on (8) “on (4) >-0n on 24, ia (100, NaOH , (yy CHHC-O-C-CH, py OH Product (B) is 9 1 O-C-Me OH CHO (a) ‘OMe COOH (3) @) i C-0CH, The treatment of methanol with ethylmagnesium iodide liberates a gas at STP. The gas is (1) CH, (2) CH,CH, (3) CH,OH (4) CH,-CH-OH I CH, +HI AI 373K Pp ‘07 (excess) 26. Product P of the reaction (1 (a) we \ @) Chou Cyclopentene is best prepared from cyclopentanol @ Cu (4) No reaction by using a (1) Conc. H,PO, (2) Cone. HCVZnCl, (3) Cone. HBr (4) Cone. HI 11. Hydroboration 2. Oxidation Oo Pis ‘COOH 25. (2) OH (1) 2-methylcyclohexan-1-o1 (2) 2-methyleyciohexane-2-o1 (3) 1-methylcyclohex-1-o1 (4) 1-methylcyclohexen-1-ol The acidic strength of methoxyphenols are in order (1) Para > Ortho > Meta > Phenol (2) Para > Ortho > Phenol > Meta (3) Meta > Phenol > Ortho > Para (4) Meta > Phenol > Para > Ortho oO CH; @) cHy- ba Which of the following option is incorrect? (1) Sodium may be used to dry diethyl ether and not ethanol (2) Anhydrous CaCl, cannot be used for drying ethanol containing traces of water 3) Williamson synthesis is not superior method for preparation of ether (4) An ether fire is not extinguished by water t-butyl alcohol and phenol can be distinguished by (1) Lucas test (2) Neutral FeCl, test (3) Both (1) & (2) (4) Sodium bicarbonate test28, 29, 30. ONa 34. Aly chlorite [x A250 5, | What is the name of enclosed reaction and major product P? OH (1) Fries rearrangement; CH: CH = GH; OH CH, - CH=CH, (2) Claisen rearrangement; Ou (3) Ciaisen rearrangement; @. CH, - CH=CH, OH (4) Fries rearrangement; CH, - CH=CH, O-H NaNOp+HpS04 Product P may be On OH a) @) N=O No, (3) (4) Both (1) & (3) 33. N-OH O-H 43H, Nx oy Rea P Product ¥ is (1) 2 44. O ® a © Which of the following option is true for below conversion? | Reaction(1) Reaction (2), Reaction 3) oO NaOH: 623 K. Hol Do soo am A HaoH: OK (1) Reaction (1) is called Dow's process (2) B is phenol and formed via activated nucleophilic substitution (3) B is sodium salt of salicyclic acid (4) C is acetyl salicyclic acid Or Identify x. oe ‘OH OH CH, (BH THE HO, OF x (1) @) x CH, @) OH OH CH, (4) CH,- CH- CH= CH, CH, Here X and Y are (1) B,HJH,O,JOH- and PCCICH,Cl, (2) H,O/H" and Cro, (3) BH, and PCC (4) PCCICH,Cl, and B,H,/H,0,JOH- x, o bay? CHs— CH— CH,CHO cH, The reagent(s) used for the determination of number of hydroxyl groups is/are (1) (CH,CO),)0 (2) CH,Coc! (3) CH,COOC,H, (4) Both (1) and (2)36. 36. 37. cH, BH. H,s0, CH.GH-CH-CH, iyo7on* tao" 7 cH, What is Y? (1) CH-CH-CH,-CH,-O-CH,-CH,-CH-CH, CH, CH, @) CHeCH-CH=CH, CH, (3) CH,-CH-CH-O-CH-CH-CH, moet CH, CH, CH, CH, ie () CH-F-O-F-CH, GH, CH, O +H,SO, (fuming) —+x BAO oy What is Y? OH $0,H a) O (2) O ONa -O «0 (Mg CH,=CH—CH,—Br ~Dcno® Aca, B Ho" |= c Product (C) is o@ ‘0 I | @ Ng CH,—CH—CH,—CH;—OH (3) | OH OH HO, (4) I J HO” 39. Ethylene oxide when treated with Grignard reagent yields (1) Primary alcoho! (2) Secondary alcohol (8) Tertiary alcohol (4) Cyclopropy! alcohol What is 8? wonton (ii) HO" Magi dry ether. (ea) 8 HS. _sn+ Crime, 82x SatHel,y z 22. n. what is A? NO, 2) O OH (4) O NaNO, + HCl 05°C NH, ° a 0CH.OH 4. +H80, otk What is the major product A? CH, CH, oof CH, ) CO ® Oj re 42. a +CH,-CH,-CH,-OH + ag What is the major product B? CH;-CH,-CH, (1) (2) CH GHC Br Br Hy CHs f Br (3) Hy CH, i (4) Br 43. Which of the following is the correct increasing order of boiling point of following compounds? CH.-CH-CH;-OH CH,-H-CH, CH,-O-CH,CH, OH 1 " a (1) Weta 2) (3) 1 i> Hv (2) Wvrt>n>t @) Iv>tl>tat (4) I> Iv>>t HO" ® CH,- C= CHT wy enymee : Hu GH, = “@HO,0H Product ® and @) can be distinguished by (1) Sodium metal Q) Neutral FeCl, @) Lucas reagent (4) Esterification reaction a cH, -¢- on 82 @ He CH, Mager oO nse ‘The end product (©) of the reaction is ‘0 - C(CHs)s a) (CH,), — C — CH. @ tee ‘oO “© OH Br, Br (4) Br47. 48, 49, 51 Consider the following reaction 2n dust crc! Y —Znduat_, x__crc___, Phenol ‘Aniyarous AIC, ‘Alkaline KMnO, —Abealing KO, O/H Zz The product Z is (1) Benzene (3) Benzaldehyde OH OH OH | CH,-CH-CH, + Hl ——> X (excess) (2) Toluene (4) Benzoic acid Whatis X? tort | |e _d | (1) CH,-CH-CH, (2) CH,=CH-CH, (3) CHy-CH=CH, 4) CHy-TH-CH, 1 IH + HY SES x Bay (rea) CH,OH What is Y? oH Br (3) (4) CH,Br CH,Br Which of the following will not give positive test with neutral FeCl? (1) Nitrophenol (2) Phenol (3) Allyl alcohol (4) o-cresol In Dow's process haloarene is converted to phenol with fused NaOH. The most reactive compound is cl H. H 1 y H al D. D (2) D D D cl T, T 3) ® 5. T T (4) All are equally reactive ‘Among the following four compounds a. Phenol b. Methyl phenol cc. Meta nitrophenol 4. Para nitrophenol The acidity order is (1) d>c>a>b (2) c>d>a>b (Q) a>d>c>b (4) b>a>cod H ‘C—0H socl, Fyrare® Product (major) The product is a CH, daa . © (3) Mixture of (1) & (2) (4) No reaction CH, Jit ons gS raj Product (C) is CH; CH,55. 56. 57. 58. Reaction of t-butyl bromide with sodium methoxide produces (1) Sodium tbutoxide (2) t-butyl methyl ether (3) Isobutane (4) Isobutylene 59, L Ho A one ?B oH ZN, 4, HMO 4 ou cH, Bis (1) (CH),CHO (2) CH,-C=CH-CH, bu, (3) (CH,),CHCOCH, (®) CH.G— CH, —cH.cH, ° Ethyl chloride is converted into diethyl ether by (1) Perkin's reaction (2) Grignard reaction 3) Wurtz synthesis (4) Williamson's synthesis cH,—CH—CH, VW Pol, l a age ac 0” “CH,OH be Product (C) is Product © is (1) Alkyl iodide (2) Vinyl chloride (3) Vinyl iodide (4) Allyl chloride oH SoH BES amaion Ais 7 Ht SoH Br (1) (2) oH oH Br. SOH Br. Br @ 4) 8 Br