Subject: Chemistry Class :11th 1. Avogadro’s law and its applications. 2. Law of multiple proportions. 3. Determination of empirical and molecular formula (numerical). 4. Mole concept, atomic and molecular mass. 5. Molarity, normality & mole fraction. 6. Relationship between ∆H and ∆U. 7. Heat capacity Cp and Cv. 8. Hess’s law of constant heat summation. 9. Spontaneity of a chemical reaction and concept of entropy. 10. Second law of thermodynamic. 11. Law of equilibrium and equilibrium constant. 12. Le-Chatlier’s principle: effect of change in conc., temperature and pressure on equilibrium. 13. Various concepts of acids and bases. 14. PH scale, buffer solutions and common ion effect. 15. Solubility of sparingly soluble salts and solubility product constant. 16. Ionization enthalpy, electronegativity, atomic radius, electron gain enthalpy and their periodic variation. 17. VSEPR theory and shapes of molecules. 18. Octet rule and its draw backs. 19. Hybridization and its types. 20. Molecular orbital theory. MOT diagrams, electronic configuration, bond order and magnetic behavoiur of following molecules: O2, F2, N2, O22-, O2-. 21. Hydrogen bonding, London dispersion force. 22. Surface tension and viscosity. 23. Kinetic theory of gases (postulates only). 24. Daltons law of partial pressures, ideal gas equation. 25. Extensive and intensive properties. 26. State functions, types of thermodynamic processes: Isothermal process, adiabatic process, reversible and irreversible processes. 27. First law of thermodynamics: internal energy and enthalpy. 28. Frequency, wavelength, relationship. Numerical on 𝑪 = 𝝊𝝀 29. Dual nature of electromagnetic radiations. 30. de-Broglie’s particle wave relationship. 31. Heisenberg’s uncertainty principle. 2|Page
32. Quantum numbers.
33. Shapes of atomic orbitals. 34. Pauli’s Exclusion principle. Hund’s rule of max. multiplicity. 35. Electronic configuration (Cr and Cu). 36. Balancing of a redox reaction by oxidation no. method and ion electron method. 37. Identification of oxidizing and reducing agents. 38. Determination of oxidation no. (e.g. KMnO 4, K2Cr2O7 , H2S2O8 etc.). 39. Conformations of ethane, nomenclature of organic compounds. 40. Cis-trans isomerism in alkenes. 41. Inductive effect, electromeric effect, hyerconjugation and resonance. 42. Reaction intermediates: carbocations, carbanions, free radicals & carbenes. 43. Substitution reactions, nucleophilic substitution reactions. 44. Addition reactions and elimination reactions. 45. Markownikov’s rule and sytzeff’s rule. 46. Ozonolysis of alkenes. 47. Aromatic and non-aromatic compounds, Huckle rule. 48. Electrphilic aromatic substitution reactions. 49. Chromatography. 50. Green house effect and ozone depletion. 51. Smog, acid rains and air pollution. 52. Diagonal relationship 53. Solvay process. 54. Structure and properties of di borane 55. Cement, Silicates, Silicones, Zeolites, Boric Acid its preparation and structure. 56. Boron halides and their order of acidity.