SUBJECT: CHEMISTRY SUNDAY TEST: 26 JUNE square inside the circle.

What is the side length of

PART – A (SOLVE ANY 15) the innermost square?
a a a a
1. As shown in the figure, a chord AB of circle of (1) π 2 (2) 2 (3) 2 2 (4) 2
√ √ √
unit radius subtends an angle of 900 at the center, o.
The area of the shaded region is 7. The area of the triangle formed by joining the
points (2017, 2017), (2027, 2027) and (2037,
2017) is:
(1) 2017 (2) 100
(3) 100√10 (4) 100√20
1 1 1
(1) 2 (𝜋 − 2) (2) 4 (𝜋 − 2) 8. Three semi-circles are drawn inside a big circle
1
(3) 2 (𝜋 − 2)
1
(4) 4 (𝜋 −
1
) as shown in the figure. If the radius of the two
2 identical smaller semi-circles is ¼ th of that of the
big circle and the radius of the bigger semicircle is
2. Statements: No watch is cycle. No cycle is twice that of the small semi-circle, what proportion
Motorbike. Some auto are motorbike
of the big circle's area is shaded?
Conclusion:
I. No Motorbike is watch
II. No motor bike is cycle
III. Some cycles are watches
IV. All Motorbikes are watches
(1) None follows (2) Only I follows (1)
11
(2)
12
(3)
13
(4)
13
12 16 16 14
(3) Only I and III follow (4) None of
these 9. A rectangular photo frame of size 30 cm × 40 cm
has a photograph mounted at the centre leaving a 5
3. Equilateral triangles are drawn one inside the cm border all around. The area of the border is?
other as shown. What is the ratio of the two shaded (1) 600 cm2 (2) 350 cm2
areas? (3) 400 cm 2 (4) 700 cm2

10. In a given circle, O is the centre, LPAO=40o,

LPBQ=30o and the outer angle LAOB=2200

(1) 2: 1 (2) √3 : 4
(3) 4: 1 ` (4) 8: 1
4. D is a point on AC in the following triangle such
that ∠𝐴𝐷𝐵 = ∠ 𝐴𝐵𝐶. Then BD (in cm) is:

Then LAQB is
(1) 700 (2) 800
(3) 60 0 (4) 1100
11. Find the area of the given shape.
(1) 8 (2) 6
(3) 3 (4) 4
5. OA, OB and OC are radii of the quarter circle
shown in the figure. AB is also equal to the radius.

(1) 270 cm2 (2) 282 cm2

(3) 285 cm2 (4) 290 cm2

What is angle OCB?

(1) 600 (2) 750 (3) 550 (4) 650

6. Consider a square of side a. Fit the largest

possible circle inside it and the largest possible
12. Find the area of the shaded region. (4)

17. Statements: Some messages are whatsapp. All

Hikes are whatsapp. All whatsapp are facebook.
Conclusion:
I. Some facebook are messages
II. II. All hikes are facebook
(1) 242 cm2 (2) 208 cm2 III. Some messages are hikes
(3) 450 cm2 (4) 289 cm2 IV. IV. Some message are facebook
(1) All follow (2) Only I, II and III follow
13. AB is a diameter of a circle, centre O. (3) Only I, II and IV follow (4) Only III and IV follow
C is a point on the circumference of the circle, such
that ∠CAB = 2 × ∠CBA. What is the size of ∠CBA? 18. In a town of 500 people, 285 speak Hindi and
212 speak Marathi and 127 speak English, 20 speak
Hindi and English not Marathi and 29 speak Hindi
and Marathi not English and 35 speak English and
Marathi not Hindi, remaining 50 speak none of
these languages. Then how many speak only one of
these three languages ?
(1) 321 (2) 371
(1) 30° (2) 40° (3) 45° (4) 60° (3) 312 (4) None of these

14. ABCD is a cyclic quadrilateral drawn inside a
circle center O. ∠ABC = 108°. What is the size of
∠ADC?
19. Represents students in Science, represents
students in Arts, represents students in
Commerce and represents students in Law, then
from the following figure find how many students
of commerce are also students of Science or Arts or
Law ?

(1) 72° (2) 82° (3) 90° (4) 108°

15. The semicircle of area 1250 π centimetres is (1 ) 4 (2) 2 (3) 3 (4) 5

inscribed inside a rectangle. The diameter of the
semicircle coincides with the length of the 20. In a group of 44 players, 26 play hockey, 24 play
rectangle. Find the area of the rectangle. football and 24 play cricket. Eight of them play both
(1) 5000 cm2 (2) 2500 cm2 hockey and football, 12 play both football and
(3) 2250 cm 2 (4) 1250 cm2 cricket, and 5 play all the three games. How many
play both hockey and cricket?
16. In the following if the smalllest circle represents (1) 10 (2) 15 (3) None (4) 7
candidates clearing GSET exam, bigger circle
represents candidates clearing only Paper –I of the PART B : SOLID STATE
GSET exam and the biggest circle represents the 21. The total number of elements of symmetry in a
candidates who failed in the GSET exam, then cubic crystal is
choose the diagram which correctly represents (1) 9 (2) 23 (3) 11 (4) None of these
these relationships.
(1) 22. The volume occupied by an atom in a simple
cubic unit cell is-
4𝜋𝑎 3 𝜋𝑎 3 √(3𝜋)
(2) (1) 𝑎3 (b) 3
(c) 6
(d) 8

23. Which of the following is not a property of

crystalline solids?
(3) (1) Isotropic (2) Sharp melting point
(3) Definite geometry
(4) High intermolecular forces
24. The number of Bravias lattices in a cubic crystal (2) Different in all directions
is (3) cannot be measured (4) always zero
(1) 14 (2) 3 (3) 1 (4) 4
36. What should be the greatest length of a rod
25. In the spinel structure, oxides ions are cubical- that can be placed inside a cube whose edge length
closest packed whereas 1/8th of tetrahedral voids is 𝑎 ?
are occupied by A2+ cation and 1/2 of octahedral (1) 𝑎 (2) 2𝑎 (3) √2𝑎 (4) √3𝑎
voids are occupied by B 3+ cations. The general
formula of the compound having spinel structure is 37. In diamond, carbon atom occupies FCC lattice
: points as well as alternate tetrahedral voids. If edge
(1) A2 B2 O4 (2) AB2 O4 length of the unit cell is 356 pm, then radius of
(3) A2 B4 O2 (d) A4 B2 O2 carbon atom is
(a) 77.07 pm (b) 154.14 pm
26. The distance between an octahedral and (c) 251.7 pm (d) 89 pm
tetrahedral void in fcc lattice would be :
(1) √3𝑎 (2)
√3𝑎 38. In face centred cubic (fcc) crystal lattice, edge
2 length is 400 pm. Find the diameter of greatest
√3𝑎 √7𝑎
(3) 4
(4) 4
sphere which can be fit into the interstitial void
without distortion of lattice.
27. In a crystal AB, which of the following crystal (1) 100 pm (2) 200 pm
systems will have parameters, a  b  c and     (3) 87.2 pm (4) 117.2 pm
  90?
(1) Cubic (2) orthorhombic 39. Crystal A diffracts from (1 1 1) and (2 0 0)
(3) Monoclinic (4) Triclinic planes but not from (1 1 0) plane, while the crystal
B diffracts from (1 1 0) and (2 0 0 ) planes but not
28. Solid CO2 is an example of from the (1 1 1) plane. From the above, we may
(1) Ionic solid (2) Covalent solid conclude that
(3) Metallic solid (4) Molecular solid (1) A has fcc lattice while B has bcc lattice
(2) A has bcc lattice while B has fcc lattice
29. How many hexagonal faces are present in an (3) A and B both have fcc lattice
truncated octahedron shape ? (4) A and B both have bcc lattice
(a) 2 (b) 6 (c) 8 (d) 12
40. Metallic silver crystallizes in face-centred-cubic
30. Ratio of the nearest distance between the atom lattice structure with a unit cell of length 40 nm.
to edge length in a body centred cubic crystal is The first order diffraction angle of X-ray beam from
(1) √3: 2 (2) 1: √3 (2,1,0) plane of silver is 30°. The wavelength of X-
ray used is close to:
(3) 2: √3 (4) 1: √2
(1) 11 nm (2) 18 nm
(3) 25 nm (4) 32 nm
31. The number of corners, edges and triangular
faces are present in a tetrahedron shape is :
41. The distance between two successive (110)
(1) 4, 4 and 4 (2) 4, 6 and 4
planes in a simple cubic lattice with lattice
(3) 4, 6 and 6 (4) 6, 4 and 6
parameter ‘a’ is:
12. If Ca crystallizes in fcc lattice, then calculate
the total number of voids in 0.5 mol Ca ? (1) √2 𝑎 (2) √3 𝑎
(1) 6NA (2) NA (3) 2√2 𝑎 (4) 𝑎/√2
(3) 1.5 NA (4) 2.25 NA
42. A metallic element exists as a cubic lattice. Each
33. Iodine molecules are hold in the crystals lattice edge of the unit cell is 2.88 Å. The density of the
by metal is 7.20 g cm−3. Number of unit cells in 100 g
(1) London forces (2) Dipole-Dipole interactions of the metal will be
(3) Covalent bonds (4) Columbic forces (1) 6.022 × 1023 (2) 2.78 ×1023
(3) 5.82 ×10 23
(4) 2.88 × 1010
34. Which of the following is an amorphous solid ?
(1) Graphite (2) Quartz glass 43. An element crystallizes both in fcc and bcc
(3) chrome alum (4) Silicon carbide lattices. If the density of the element in the two
forms is the same, the ratio of unit cell length of fcc
35. Which of the following is true about the value of to that of bcc lattice is
1 1
refractive index of quartz glass ? 1
1 3 1
1 3
(1) same in all directions (1) 2 3 (2) (2) (3) 4 3 (4) (4)
44. If an element (at. mass = 50) crystallises in fcc 52. A compound AX BY has a cubic structure with A
lattice, with a = 0.50 nm. What is the density of unit atoms occupying all the corners of the cube as well
cell if it contains 0.25% Schottky defects [Use 𝑁𝐴 = as all the face center positions. The B atoms occupy
6.022 × 1023] four tetrahedral voids. The values of x and y
(1) 2.0 g/cc (2) 2.66 g/cc respectively, are
(3) 3.06 g/cc (d) None of these (1) 4, 4 (2) 4, 8 (3) 8, 4 (4) 4, 2

45. The arrangement of X − ions around A+ ion in 53. The interplanar spacing of (110) planes in a
solid AX is given in the figure (not drawn to scale). cubic cell with lattice parameter a = 4.243 Å is :
If the radius of X − is 250 pm, the radius of A+ is (1) 3Å (2) 6Å (3) 7.35 Å (4) 2.45Å

54. The packing fraction of a simple cubic lattice is

close to
(1) 0.94 (2) 0.76 (3) 0.52 (4) 0.45

(1) 104 pm (2) 125 pm 55. The coordinates for the atoms in body centred
(3) 183 pm (d) 57 pm cubic unit cell are
(1) (0, 0, 0) & (½, 0, 0) (2) (0, 0, 0) & (½, ½, ½)
46. The packing efficiency of a two-dimensional (3) (0, 0, 0) & (0, ½, 0) (4) (0, 0, 0) & (0, 0, ½)
square unit cell shown below is
56. In a AB unit cell (Rock salt type) assuming A+
forming fcc :
(1) The nearest neighbour of A+ is 6B − ion
(2) The nearest neighbour of B − is 6A+ ion
(3) The second neighbour of A+ is 12 A+
(4) All of the above
(1) 39.27% (2) 68.02%
(3) 74.05% (4) 78.54% 57. Packing fraction of an identical solid sphere is
74% in :
47. The structure of obtained when all the (1) simple cubic structure (2) Ecc structure
tetrahedral holes are occupied in a fcc structure, it (3) hcp structure (4) bcc structure
of the type
(1) NaCl (2) CsCl (3) CaF2 (4) ZnS 58. When NaCl is doped with 10−5mole % of SrCl2,
what is the no. of cationic vacancies ?
48. The packing efficiency for the following cubic (a) 10−5 NA (b) 10−7 NA
structures varies a follows: diamond (D), simple (c) 2 × 10 NA
−7
(d) None of these
cube (SCC) face centered cube (FCC) and body
centered cube (BCC) 59. In a cubic crystal the plane (100) is equally
(1) D > FCC > BCC > SCC inclined to the planes:
(2) FCC > BCC > SCC > D (1) (010) and (011) (2) (010) and (110)
(3) BCC > FCC > SCC > D (3) (001) and (101) (4) (110) and (011)
(4) D > SCC > BCC > FCC
60. In face centred cubic (fcc) crystal lattice, edge
49. Which of the following expression is correct in length is a. Find the 2nd next nearest distance
case of a sodium chloride unit cell (edge length, a) ? between two atoms ?
a
(1) rc + ra = a (2) rc + ra = 𝑎 √3𝑎 3
2 (a) 𝑎 (b) (c) (d) √2 𝑎
√2 2
(c) rc + ra = 2a (4) rc + ra = √2a

50. First three nearest neighbour distances for

body centered cubic lattice are respectively :
𝑎
(1) √2𝑎 , 𝑎 , √3𝑎 (2) 2 , 𝑎 , √3𝑎
√
√3𝑎 √3𝑎
(c) 2
, 𝑎 , √2𝑎 (d) 2
, 𝑎 , √3𝑎

51. Metallic gold crystallizes in fcc structure with

unit cell dimension of 4.00 Å. The atomic radius of
gold is :
(1) 0.866 Å (2) 1.414 Å
(4) 1.732 Å (4) 2.000 Å