SnO2 Sistema cristalino tetragonal, parámetros de red a = b = 4.7382 c = 3.

1871 Å,a=b:= 90º

Longitud de onda del Ka de Cu = 1.54 Å

a1 a2 a3
a 0 0
a 0 0
0 0 c
Vector G

2θ θ d d^2 Gh Gk Gl
26.2 13.1 3.397289028 11.54157274 0.06981317 0.06981317 0
33.9 16.95 2.641173645 6.975798226 0.104719755 0.034906585 0
36.9 18.45 2.43303646 5.919666417 0.06981317 0.06981317 0
51.9 25.95 1.759651552 3.096373584 0.104719755 0.104719755 0.034906585
65.9 32.95 1.415683327 2.004159283 0.06981317 0.06981317 0.034906585
37 38.5
1 Å,a=b:= 90º g = 90 º

λ 1.54 Theta 1
a 4.7382 Theta 2
c 3.1871 Beta
Tamaño del cristal

d^2
d teorica h k l diferencia d
teórica
2.806317405 1.675206675 2 2 0 0.590971623277596
2.245053924 1.498350401 3 1 0 0.396119721477981
2.806317405 1.675206675 2 2 0 -0.373280944693572
1.110850839 1.053969088 3 3 1 0.648800712548567
2.198830236 1.482845318 2 2 1 -0.783146908937321
 𝒂 ⃗_𝟏=𝒂𝒙 ̂ 𝒂 ⃗_𝟐=𝒂𝒚 ̂ 𝒂 ⃗_𝟑=𝒄𝒛 ̂
37
38.5 𝑽=𝒂^𝟐 𝒄
1.5
0.960202 𝒃 ⃗_𝟐=𝟐𝝅/𝒂 𝒚 ̂
𝒃 ⃗_𝟏=𝟐𝝅/𝒂 𝒙 ̂ 𝒃 ⃗_𝟑=𝟐𝝅/𝒄 𝒛 ̂
2θ θ
0.457276264 0.228638132 𝒅=𝝀/(𝟐 𝒔𝒊𝒏⁡𝜽 )
0.591666616 0.295833308
0.644026494 0.322013247
0.905825882 0.452912941
1.150171977 0.575085989
𝒅_𝒉𝒌𝒍^𝟐=[((𝒉^𝟐+𝒌^𝟐 ))/𝒂^𝟐 +𝒍^𝟐/𝒄^𝟐 ]^(−𝟏)

𝑮_𝒉𝒌𝒍=𝒉𝒃 ⃗_𝟏+𝒌𝒃 
⃗_𝟐+𝒍𝒃 
⃗_𝟑

𝒕=𝟎.𝟗𝟒 𝝀/(𝑩 𝐜𝐨𝐬⁡𝜽 )

𝑩=( 〖𝟐𝜽〗 _𝟐− 〖𝟐𝜽〗 _𝟏)/𝟐

 ⃗_𝟑=𝒄𝒛 ̂

𝒃 ⃗_𝟑=𝟐𝝅/𝒄 𝒛 ̂

/𝒄^𝟐 ]^(−𝟏)
Sn Sistema cristalino tetragonal, parámetros de red a = b = 5.83 Å c = 3.18 Å a =b:= g = 90 º

Longitud de onda del Ka de Cu = 1.54 Å

a1 a2 a3
a 0 0
a 0 0
0 0 c
Vector G

θ d^2
2θ d d^2 Gh Gk Gl
teórica
31 15.5 2.8813227 8.30202052 0.10471976 0.03490659 0 3.39889
44.3 22.15 2.04226335 4.17083958 0.10471976 0.06981317 0 2.61453077
55.2 27.6 1.66200429 2.76225827 0.10471976 0.10471976 0 1.88827222
61.8 30.9 1.49939269 2.24817844 0.10471976 0.10471976 0.03490659 1.59115787
64.5 32.25 1.44298923 2.08221792 0.10471976 0.06981317 0.03490659 2.07742003
 λ 1.54 Theta 1 62
a 5.83 Theta 2 63
c 3.18 Beta 1
Tamaño del cristal 1.386770

d teorica h k l diferencia d 2θ θ
1.84360788 3 1 0 -0.517567297400892 0.54105207 0.27052603
1.61695107 3 2 0 -0.572267421131528 0.77318086 0.38659043
1.37414418 3 3 0 -0.226267927709343 0.96342175 0.48171087
1.26141106 3 3 1 -0.0917651760934504 1.07861348 0.53930674
1.44132579 3 2 1 -0.634430802902459 1.12573737 0.56286868

𝒅_𝒉𝒌𝒍^𝟐=[((
62 63
 𝒂 ⃗_𝟏=−𝒂/𝟐 𝒙 ̂+𝒂/𝟐 𝒚 ̂+𝒄/𝟐 𝒛 ̂

𝒂 ⃗_𝟐=𝒂/𝟐 𝒙 ̂−𝒂/𝟐 𝒚 ̂+𝒄/𝟐 𝒛 ̂

𝒂 ⃗_𝟑=𝒂/𝟐 𝒙 ̂+𝒂/𝟐 𝒚 ̂−𝒄/𝟐 𝒛 ̂

𝑽=(𝒂^𝟐 𝒄)/𝟐

𝒃 ⃗_𝟏=−𝟐𝝅/𝒂 𝒙 ̂−𝟐𝝅/𝒄 𝒛 ̂

𝒃 ⃗_𝟐=𝟐𝝅/𝒂 𝒙 ̂+𝟐𝝅/𝒄 𝒛 ̂

𝒃 ⃗_𝟑=𝟐𝝅/𝒂 𝒙 ̂+𝟐𝝅/𝒄 𝒚 ̂

𝒅=𝝀/(𝟐 𝒔𝒊𝒏⁡𝜽 )

𝒅_𝒉𝒌𝒍^𝟐=[((𝒉^𝟐+𝒌^𝟐 ))/𝒂^𝟐 +𝒍^𝟐/𝒄^𝟐 ]^(−𝟏)

𝑮_𝒉𝒌𝒍=𝒉𝒃 ⃗_𝟏+𝒌𝒃 ⃗_𝟐+𝒍𝒃 ⃗_𝟑
 𝒕=𝟎.𝟗𝟒 𝝀/(𝑩 𝐜𝐨𝐬⁡𝜽 )

𝑩=( 〖𝟐𝜽〗 _𝟐− 〖𝟐𝜽〗 _𝟏)/𝟐