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Journal of Thermal Analysis and Calorimetry

https://doi.org/10.1007/s10973-018-7565-4(0123456789().,-volV)(0123456789().,-volV)

Applications of nanofluids in porous medium

A critical review

Khalil Khanafer1,2 • Kambiz Vafai3

Received: 8 June 2018 / Accepted: 15 July 2018


Ó Akadémiai Kiadó, Budapest, Hungary 2018

Abstract
This investigation provides a review on the applications of nanofluids in porous media. The transport phenomena in porous
media have been of continuing interest for the past decades. This is due to its wide applications in solar receiver devices,
building thermal insulation, heat exchangers, energy storage units, ceramic processing, and catalytic reactors to name a
few. Furthermore, nanofluids have been also used in porous media due to their superior thermal characteristics. This review
is structured into two parts: The first part focuses on presenting the latest results for the thermal conductivity, viscosity,
specific heat, and the thermal expansion coefficient of nanofluids reported in the literature. The second part of this review is
allocated to the applications of nanofluids in thermal systems filled with porous medium and of different geometries, flow
regimes, boundary conditions, and different types of nanofluids and thermophysical properties. Finally, future studies on
the applications of nanofluids in porous media are recommended in this review.

Keywords Laminar  Nanofluid  Porous medium  Natural and mixed convection  MHD

Introduction Several pertinent physical phenomena were investigated


in the literature when modeling flow, heat, and mass
Transport phenomena in porous media have received transfer in porous media. For example, the effects of non-
considerable attention in the last few decades due to its Darcy on transport phenomena in porous media were
importance in many engineering and industrial applica- analyzed for various geometrical configurations and
tions. Such applications include thermal insulation, packed boundary conditions. Other parameters included porosity
bed heat exchangers, drying technology, catalytic reactors, variation, thermal dispersion, the effects of local thermal
petroleum industries, geothermal systems, and electronic equilibrium between the fluid phase and the solid phase,
cooling [1–6]. Moreover, substantial progresses were also and an anisotropic porous media.
made in using porous medium in biomedical applications Many of the research studies in porous media for the
such as tissue replacement production, drug delivery, past few decades utilized the generalized model. Vafai and
advanced medical imaging, porous scaffolds for tissue Tien [1, 2] presented a comprehensive study of the gen-
engineering, and transport in biological tissues [7–12]. eralized transport model known as the Brinkman–Forch-
heimer-extended Darcy model. The effects of presence of
the solid walls and inertial forces on the temporal variation
& Kambiz Vafai of the mass transfer in porous media were also studied in
vafai@engr.ucr.edu detail by Vafai and Tien [2]. Some important issues of
1
transport phenomena in porous media were also discussed
Mechanical Engineering Department, Australian College of
Kuwait, 13060 Safat, Kuwait
in book chapters by Nield and Bejan [13], Vafai [4, 5],
2
Hadim and Vafai [6], and Vafai and Hadim [7]. Models for
Advanced Manufacturing Lab (AML), School of
Engineering, University of Guelph, Guelph, ON, Canada
multiphase transport in porous media were analyzed and
3
presented thoroughly by Vafai and Sozen [14, 15] and
Mechanical Engineering Department, University of
Sozen and Vafai [16, 17]. In these investigations, a detailed
California, Riverside, CA 92521, USA

123
K. Khanafer, K. Vafai

analysis of different multiphase models including the phase theoretically [28–39]. Although different investigations
change process was presented and discussed. reported that nanofluids exhibited larger heat transfer
A comprehensive analysis of variations within transport enhancement compared with conventional heat transfer
models for flow and heat transfer in porous media was fluids, contradictory results on the thermal properties of
presented by Alazmi and Vafai [18]. Four major classifi- nanofluids were cited by Khanafer and Vafai [28]. Kha-
cations in modeling the transport phenomena through nafer and Vafai [28] provided a comprehensive review on
porous media were discussed. These categories were con- the variations within the thermophysical properties of
stant porosity, variable porosity, thermal dispersion, and nanofluids. They showed in their investigation that the
local thermal non-equilibrium. Further, the same authors experimental results for the effective viscosity and thermal
[19] analyzed various types of interfacial conditions conductivity of nanofluids reported by many researchers in
between a porous medium and a fluid layer. The effects of the literature were in disagreement. Table 1 illustrates a
the pertinent parameters such as Darcy number, Reynolds comparison of the experimental thermal conductivity
number, porosity, inertia parameter, and slip coefficients on augmentations of nanofluids reported in the literature.
the fluid flow and heat transfer in the neighborhood of the Moreover, new correlations for the viscosity and thermal
interface region were analyzed by Alazmi and Vafai [19]. conductivity of nanofluids were developed using the pub-
Determination of the correct thermal boundary conditions lished experimental results as given in Table 2.
for the solid and fluid phases within a porous medium was Therefore, the objective of this review is to summarize
also an important topic [20]. Different turbulent models for the latest development of the applications of nanofluids in
transport phenomena through porous media were also porous media. In particular, it will cover applications of
analyzed thoroughly in the literature by Vafai et al. [21]. nanofluids in natural, mixed convection heat transfer, and
Porous media theory was also used substantially in MHD effect in porous medium.
modeling biomedical applications. For example, Khanafer
and Vafai [22] conducted a review study summarizing Natural convection in porous medium
various studies associated with the applications of porous
media in drug delivery and magnetic resonance imaging. In Natural convection heat transfer is considered critical in
another study, Khaled and Vafai [23] analyzed different many engineering and industrial applications such as geo-
biomedical areas that utilized porous media theory in the physics, solar energy, thermal insulation in buildings,
diffusion process in brain tissues, blood flow in tumors, and electronic cooling, and nuclear energy. Khanafer et al. [26]
bioheat transfer in tissues. A numerical investigation based were the first who studied numerically the buoyancy-driven
on fluid–structure interaction analysis was investigated by heat transfer enhancement of nanofluids in a square cavity.
Al-Amiri [24] to determine the effect of pulsatile turbulent They showed that the addition of nanoparticles signifi-
flow and heating protocol on temperature and heat flux cantly increased the heat transfer activities inside the cavity
variations in blood vessel and tumor tissues under hyper- for various values of Grashof number. In addition, they
thermia treatment. The arterial wall was modeled in their showed that the heat transfer rate increased with an
study using the volume-averaged porous media equations. increase in the nanoparticles volume fraction. Although
many numerical and experimental studies of natural con-
vection flow and heat transfer of nanofluids in enclosures
Nanofluids applications in porous media were conducted in the literature, only few studies consid-
ered porous medium filled with a nanofluid.
Nanofluids, developed by adding nanoparticles (10–50 nm) Bourantas et al. [50] studied numerically natural con-
to traditional fluids [25], were used extensively recently in vection of a nanofluid in a square cavity filled with a
energy and biomedical applications. Nanofluids showed the porous medium as shown in Fig. 1a. The Darcy–Brinkman
potential to substantially increase heat transfer properties in and the energy transport equations were solved for various
a variety of areas such as industrial cooling applications, volume fractions and different types of nanoparticles.
nuclear reactors, transportation industry, micro-electrome- Numerical results of streamlines, temperature profile, and
chanical systems (MEMS), electronics and instrumenta- Nusselt number were obtained in that study for a wide
tion, and biomedical applications (nano-drug delivery, range of dimensionless parameters (Rayleigh number
cancer therapeutics, cryopreservation) [26, 27]. Potential between 105 and 107 and Darcy number between 10-5 and
enhancement in thermal conductivity of the fluid can lead 10-3). The average Nusselt number was found unaffected
into higher energy efficiency and lower operating costs. by the presence or the absence of a porous medium at low
A large number of studies published in the literature and Rayleigh number (Ra = 103). However, the average Nus-
related to heat transfer enhancement using nanofluids were selt number was found to increase with an increase in the
investigated by the authors both experimentally and volume fraction of nanoparticles for various Rayleigh

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Applications of nanofluids in porous medium

Table 1 Comparison of the


Reference Base fluid Particle dp/nm /p/% Thermal conductivity enhancement
experimental thermal
conductivity of nanofluids [39] Water Al2O3 38.4 4 9% (21 °C), 16% (36 °C), 24% (51 °C)
enhancements of metallic and
non-metallic nanofluids [39] Water CuO 28.6 4 14% (21 °C), 26% (36 °C), 36% (51 °C)
reported in the literature [40] Water Al2O3 131 4 24% (51 °C)
(Khanafer and Vafai [28]) [41] Water Al2O3 13 4.3 32.4% (31.8 °C)
[41] Water Al2O3 13 4.3 29.6% (46.8 °C)
[41] Water Al2O3 13 4.3 26.2% (66.8 °C)
[41] Water SiO2 12 2.3 1.1% (31.8 °C)
[41] Water SiO2 12 2.3 1% (46.8 °C)
[42] Water CuO 23.6 3.4 12%
[42] EG CuO 23.6 4 23%
[42] Water Al2O3 38.4 4.3 11%
[42] EG Al2O3 38.4 5 19%
[43] Water CuO 23 9.7 34%
[43] EG CuO 23 14.8 54%
[43] Water Al2O3 28 5.5 16%
[43] EG Al2O3 28 5 24.5%
[44] Water Al2O3 11 1 14.8% (70 °C)
[44] Water Al2O3 47 1 10.2% (70 °C)
[44] Water Al2O3 150 1 4.8% (60 °C)
[44] Water Al2O3 47 4 28.8% (70 °C)
[44] Water Al2O3 47 1 3% (21 °C)
[45] Water CuO 29 6 36% (28.9 °C)
[45] Water CuO 29 6 50% (31.3 °C)
[45] Water Al2O3 36 6 28.2%
[45] Water Al2O3 47 6 26.1%
[46] Water Al2O3 20 5 15%
[47] Water Al2O3 11 5 8%
[47] Water Al2O3 20 5 7%
[47] Water Al2O3 40 5 10%
[48] Water Cu 100 7.5 78%
[49] Water Au 10–20 0.03 21%
[49] Water Ag 60–80 0.001 17%
EG Ethylene glycol

numbers for a cavity filled with a porous medium. Fig- study to model nanofluid. Their results illustrated that the
ure 1b illustrates that Cu and Ag nanoparticles exhibited average Nusselt and Sherwood numbers increased with an
the largest average Nusselt number values due to their increase in the buoyancy ratio parameter, thermophoresis
highest thermal conductivity values. However, TiO2 parameter, and phase deviation and decreased with an
showed the smallest value of the thermal conductivity, increase in Lewis number, Brownian motion parameter,
which leads to a low average Nusselt number. and amplitude ratio. Figure 2b illustrates that an increase in
Sheremet and Pop [51] investigated numerically laminar Lewis number from 10 to 1000 resulted in an insignificant
natural convection of a water-based nanofluid in a 2D decrease in the average Nusselt number. The same authors
square cavity filled with porous medium. Sinusoidal tem- [53] studied natural convection of a nanofluid in a cavity
perature distributions were imposed on both vertical walls, filled with a porous medium using Buongiorno’s model
and adiabatic conditions were assumed for the upper and [52]. The nanofluid model in their study included Brownian
lower walls (Fig. 2a). The flow activities in the cavity were diffusion and thermophoresis effects. It was found in that
assumed very small so that advective and Forchheimer study that the local Nusselt number at the solid porous
quadratic terms were ignored in the momentum equation. increased with an increase in Rayleigh number, buoyancy
Moreover, Buongiorno’s model [52] was used in their ratio parameter. Moreover, it was found that the average

123
K. Khanafer, K. Vafai

Table 2 Summary of the correlations synthesized and developed by Khanafer and Vafai [28] based on the reported experimental data
Physical properties Room temperature Temperature dependent

Density qeff ¼ ð1  /p Þqf þ /p qp Al2O3–water


qeff ¼ 1001:064 þ 2738:6191/p  0:2095T
0  /p  0:04; 5  Tð CÞ  40
Specific heat ð1/p Þqf cf þ/p qp cp N/A
ceff ¼ qeff

Thermal expansion ð1/p ÞðqbÞf þ/p ðqbÞp Al2O3–water


beff ¼ qeff  
coefficient 4:7211
beff ¼ ð1  /p Þbf þ /p bp beff ¼  0:479/p þ 9:3158  103 T   103
T2
0  /p  0:04; 10 C  T  40  C
Viscosity N/A Al2O3–water
28:837
leff ¼ 0:4491 þ þ 0:574/p  0:1634/2p
T
/2p /p
þ 23:053 2 þ 0:0132/3p  2354:735 3
T T
/2p /3p
þ 23::498 2  3:0185 2
dp dp
1%  /p  9%; 20  Tð CÞ  70; 13 nm  dp  131 nm
Thermal conductivity Al2O3–water and CuO–water Al2O3–water
keff  0:2246  
¼ 1:0 þ 1:0112/p þ 2:4375/p keff 1 leff ðTÞ 0:0235
kf    ¼ 0:9843 þ 0:398/0:7383
p
47 kp kf dp ðnmÞ lf ðTÞ
dp ðnmÞ  0:0248/p 0:613
/p /2p /p
 3:9517 þ 34:034 3 þ 32:509 2
T T T
0  /p  10%; 11 nm  d  150 nm; 20  C  T  70  C

Fig. 1 a Geometry and L


boundary conditions for a 7.5
square cavity filled with a Tc Ag
porous medium. b Average 7 Al2O3
Nusselt number for several Cu
types of nanoparticles and for TiO2
6.5
various volume fractions g
(Bourantas et al. [50]) Tc Tc
6
Nuave

y
5.5

x b 5

4.5

d 4
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2
q″
ϕ

(a) (b)

Nusselt number decreased with an increase in the ther- equilibrium in the porous medium were also assumed in
mophoresis parameter, Lewis number, and dimensionless their investigation. The authors considered in their model
thickness of the heat-conducting solid walls. the effects of Brownian motion and thermophoresis. The
Nield and Kuznetsov [54] analyzed analytically the similarity solution was obtained by the authors and found
Cheng–Minkowycz problem for natural convective to depend on Lewis number, buoyancy ratio number, and
boundary-layer flow of a nanofluid in a porous medium. the thermophoresis number. The same authors [55] studied
The Oberbeck–Boussinesq approximation was utilized in analytically the onset of natural convection of a nanofluid
that study, and the homogeneity and local thermal in a horizontal porous layer medium. The effects of

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Applications of nanofluids in porous medium

Nul
y 4.85
∂T/ ∂y = 0 4.8
∂C/ ∂y = 0 Le = 10
4.75
L Le = 1000
⎩ 4.7
T( y ) = Tc + Ar sin⎧
2π y
Jp = 0 g +ϕ ⎧ 4.65
⎩ L
4.6
⎩ 4.55
2π y
T( y ) = Tc + Al sin⎧ ⎧ Jp = 0
⎩ L 4.5
x
4.45
0 L
∂T/ ∂y = 0, 4.4
∂C/ ∂y = 0 0.05 0.01 0.15 0.2 0.25 τ

(a) (b)

Fig. 2 a Physical model and coordinate system, b variation of the average Nusselt number at left vertical wall with the Lewis number and
dimensionless time (Sheremet and Pop [51])

Fig. 3 a Physical model of y


convection in a trapezoidal C
porous cavity together with the D
Ag
coordinate system, b variation 11 Cu
of the average Nusselt number TiO2
L
interfaces with u for different Tc 10
(a) nanoparticles (Alsabery Nanofluid
Th Porous layer
et al. [56]) layer 9
ϕ
Nu
g
w 8

7
B
6
β

A L X 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2
φ
(a) (b)

Brownian motion and thermophoresis were studied. Their using the local thermal non-equilibrium (LTNE) model.
results showed that oscillatory instability was found pos- The authors used Buongiorno’s model for nanofluid and
sible in the case of a bottom-heavy nanoparticle incorporated the effects of thermophoresis and Brownian
distribution. motion. Their results showed that the average Nusselt
The problem of Darcian natural convection of a nano- number was found to increase with an increase in Rayleigh
fluid in a trapezoidal cavity partially filled with porous number, Darcy number, and the thermal conductivity
medium was studied numerically by Alsabery et al. [56] ratios. Sheremet et al. [58] investigated numerically natural
using finite difference method. The left inclined wall was convection inside a porous wavy cavity filled with a
maintained at a constant hot temperature and the right nanofluid under the effect of thermal dispersion using the
inclined wall was maintained at a constant cold tempera- Forchheimer–Buongiorno approach (Fig. 4a). The left
ture, while the horizontal walls were assumed insulated. It surface of the cavity was a wavy isothermal wall, while the
was shown that convection heat transfer increased signifi- rest of the walls were assumed straight isothermal walls.
cantly by the addition of silver–water nanofluid (Fig. 3b) All boundaries were assumed to be impermeable to the
and the heat transfer rate was affected by the inclination base fluid and nanoparticles. The effects of Rayleigh
angle of the cavity variation. number, undulation number, thermal dispersion parameter,
Natural convection heat transfer in a cavity filled with and flow inertia parameter on the average Nusselt number,
three layers of solid, porous medium, and free fluid, streamlines, isotherms, and isoconcentrations were pre-
respectively, was investigated numerically by sented (Fig. 4b). Their results revealed that the heat
Tahmasebi et al. [57]. The porous and free fluid layers were transfer enhancement was associated with Rayleigh num-
filled with a nanofluid, and the porous layer was modeled ber, undulation number, and dispersion parameter.

123
K. Khanafer, K. Vafai

Tc Jp = 0
H

g ψ θ ϕ
y

Tc 0.8

Jp = 0 Tc
Jp = 0 0.6

0.4

X 0.2

Th Jp = 0
0 D
0

(a) (b)
Fig. 4 a Physical model and coordinate system, b streamlines w, isotherms h, and isoconcentrations u for j = 2.0, Ds = 0.1, c = 100, and
Ra = 50 (Sheremet et al. [58])

u
g

0.55
Nr=0.5,Nb=0.3,Nt=0.1,Le=10
0.50
v
r
Vw 0.45
– θ' (ξ,0)

Tw, Cw
0.40

T∞, C∞ 0.35 n=0,8,0,9,1,0,1,1,1,2


γ

0.30

0.25
0.0 0.2 0.4 0.6 0.8 1.0
y ξ

(a) (b)
Fig. 5 a Flow model and physical coordinate system, b effect of n on the local Nusselt number (Rashad et al. [59])

Moreover, uniform distribution of nanoparticles was found parameter increased, the local Sherwood number increased,
to occur with an increase in Rayleigh number and a while the local Nusselt number decreased.
decrease in the number of undulations.
Free convection boundary layer of a non-Newtonian MHD convection of nanofluids in porous medium
fluid in a permeable vertical cone embedded in a porous
medium saturated with a nanofluid was studied by Magnetohydrodynamic (MHD) effect has received a lot of
Rashad et al. [59] (Fig. 5). The authors incorporated the attention by many authors in recent years due to its wide
effects of Brownian motion and thermophoresis in their applications in the cooling process of a nuclear reactor,
study. It was found that both the local Nusselt and Sher- power generator, control of chemical waste and pollutants
wood numbers increased with an increase in the viscosity dissemination, and metallurgical applications [60]. For
index (Fig. 5b). However, as the buoyancy ratio increased, example, Sheikholeslami et al. [60] studied numerically
both the local Nusselt and Sherwood numbers decreased. In free convection heat transfer in a cavity filled with CuO–
addition, it was found that as the Brownian motion water nanofluids in the presence of magnetic field. The left
side of their model was sinusoidal wall and subjected to a

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Applications of nanofluids in porous medium

Fig. 6 a Geometry and the 7


boundary conditions, b variation a = 0.1
of average Nusselt number a = 0.2
6 a = 0.3
along the wall with constant
heat flux for different values of

⎩⎩
⎧⎧ – π/2
amplitude of the sinusoidal wall Tc
5
‘‘a’’ and Hartmann number (Ha)
at Ra = 104, Pr = 6.2 and

⎩ H
y

Nuave
2H
q″

= 1 – α⎧1 + sin⎧ π
u = 0.04 (Sheikholeslami et al. 4
[60])


3

B
γ

H
x
2
y S

x 1
0 20 40 60 80 100
H Ha

(a) (b)

constant heat flux as depicted in Fig. 6a. Their results Prasad et al. [62] conducted a numerical study on MHD
showed that the average Nusselt number increased with an natural convection heat transfer of nanofluid over a vertical
increase in nanoparticles volume fraction, dimensionless porous plate with variable heat flux. Two different types of
amplitude of the sinusoidal wall, and Rayleigh number, water-based nanofluids containing copper (Cu) and silver
while it decreased with an increase in Hartmann number. (Ag) were considered in their investigation. It was found
Javaherdeh et al. [61] conducted a numerical investi- that Cu–water nanofluid showed the greatest wall friction
gation of 2D steady laminar natural convection flow with performance compared with Ag–water nanofluid. More-
heat and mass transfer past a moving vertical plate in a over, the increase in the values of heat source parameter
porous medium subjected to a transverse magnetic field was found to decrease the fluid temperature for both Cu–
using Darcy model. Results were presented in that study for water and Ag–water nanofluid.
various pertinent parameters such as Grashof number, Malik and Nayak [63] analyzed numerically heat
porosity number, magnetic field number, and exponents in transfer and entropy generation of a MHD nanofluid flow
the power law variation of the surface temperature and inside an enclosure filled with porous medium (Fig. 7).
concentration, m and n. Their results showed that Grashof Time-dependent heat sources were applied along the short
number had a significant effect on the flow velocity due to sides of their model. The results of their investigation were
the augmentation in the buoyancy force. Furthermore, the presented for a wide range of pertinent parameters such as
increases in the temperature and concentration rates Grashof number (104–106), Hartmann number (1–50),
improved heat and mass transfer rates on the surface. Darcy number (0.001–1.0), and volume fraction of

y*
Streamlines Isotherms Energy flux
TH (1 – asin(2π t*/ω ))

Porous domain
L L/3 B0 g L/3
Gr = 106

Tc

Hot portion Cold portion


L/3
Adiabatic wall

L x#

(a) (b)
Fig. 7 a Geometry and boundary conditions, b streamline, isotherm, and energy flux vector plots at Ha = 50, Da = 0.001 with u = 0.0 (solid
lines) and u = 0.2 (dashed lines) for Gr = 106 and L/3 (Malik and Nayak [63])

123
K. Khanafer, K. Vafai

Fig. 8 Streamlines (W),


isotherms for the nanofluid (hnf)
and the solid (hs) at Ra = 500, 8 0.95 0.95
Ha = 0, u = 0.04, and e = 0.3 7 0.9 0.85
6 0.85 0.75
(Sheikholeslami and Rokni 5 0.8 0.7
[64]) 4 0.75 0.65
3 0.7 0.6

Nhs = 10
2 0.65 0.55
1 0.6 0.5
0.55 0.45
0.5 0.4
0.45 0.35
0.4 0.3
0.35 0.25
0.3 0.2
0.25 0.15
0.2 0.1
0.15 0.05
0.1
0.05

A Tc

Nanofluid

g Th
y
o ζ
x Ha = 0 Ha = 40
B
rin
γ
rout
porous media

(a) (b)

Fig. 9 a, b Effect of nanoparticle volume fraction on isotherms (left) and streamlines (right) contours for u = 0 (—) and u = 0.04 (-)
(Ra = 105, Da = 100, N = 5) (Sheikholeslamia et al. [66])

nanoparticles (0.0–0.2) at a Prandtl number of 6.2. The MHD CuO–water nanofluid flow and heat transfer in a
flow in the porous medium was modeled using Darcy– semi-annulus filled with porous medium and subjected to
Brinkman model. Their results revealed that higher heat constant heat flux were studied numerically by Sheik-
transfer and entropy generation were found for higher holeslamia and Shehzad [65]. Koo–Kleinstreuer–Li corre-
values of Grashof number. Based on their results, the lation and Darcy model were utilized in that investigation.
maximum heat transfer was achieved when Da = 0.001 The effect of inner cylinder radius, volume fraction of CuO
and u = 0.2 for Gr = 106 and Ha = 50 (Fig. 7b). nanoparticles, and Hartmann and Rayleigh numbers was
Sheikholeslami and Rokni [64] analyzed numerically investigated by the authors. Results illustrated that the heat
flow and heat transfer of a nanofluid in a cavity filled with transfer augmentation decreased with an increase in
porous medium and considering the effects of Brownian buoyancy forces. Further, the influence of adding CuO
motion and the magnetic field. Thermal non-equilibrium nanoparticles improved with an increase in Lorentz forces.
model and Boussinesq–Darcy law for fluid flow inside the Sheikholeslamia et al. [66] analyzed numerically the effect
cavity were utilized in that study for CuO–water nanofluid of radiation and convection of a nanofluid inside a porous
flow. Various pertinent parameters were considered in their medium using non-Darcy model. The effects of Hartmann
investigation such as solid–nanofluid interface heat transfer number, volume fraction of nanoparticles, radiation
parameter (Nhs), Hartmann number (Ha), porosity (e), and parameter, Darcy number, number of undulations, and
Rayleigh number (Ra) (Fig. 8). Their results illustrated that Rayleigh number on flow and heat transfer within the
the heat transfer rate decreased with an increase in Nhs, but porous medium were investigated in that study. The results
it augmented with an increase in Rayleigh number. Further, of that study demonstrated that Nusselt number increased
the porosity of the porous medium exhibited an inverse with increasing the permeability of porous media. More-
correlation with the temperature gradient. over, the fluid motion was found to increase with an
increase in the volume fraction of nanoparticles (Fig. 9b).

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Applications of nanofluids in porous medium

7.2

6.8

6.6
B0
6.4

NuAve
6 2 5

A a c TWall C 6.2
3 0 1

6 2 5 7 4 8
6
3 0 1
OUT
7 4 8
5.8
φ = 0%
IN 6 2 5
5.6 φ = 3%
Tin 3 0 1 φ = 3%
2
φ
6 5
uin (fully developed) = 7%
3
0
1
7 4 8
5.4
Y B TWall b d D
X 7 4 8 0 5 10 15
Ha
(a) (b)

Fig. 10 a Geometry of the problem with the structure of porous medium, channel aspect ratio is AC/AB = 4, b average Nusselt number for
different volume fractions of nanoparticle and Hartmann number (Servati et al. [70])

Forced and mixed convection of nanofluids vertical walls of their geometry were kept at a constant
in porous medium temperature. The mathematical formulation of the problem
was based on the Brinkman–Boussinesq approximation and
The analysis of forced convective flow and heat transfer in using a two-phase nanofluid model. The effects of various
a geometry filled with a porous medium received a great significant parameters, such as Reynolds number, Lewis
attention by many authors due to its importance in many number, the buoyancy ratio number, the thermophoresis to
applications such as heat exchangers, electronic cooling, Brownian motion ratio number, Darcy number, and Gra-
and heat pipes [67–69]. Using lattice Boltzmann method, shof number, on the velocity, temperature, and nanoparti-
Servati et al. [70] studied the effects of magnetic field on cles’ concentration profiles were investigated in their study.
force convection flow of Al2O3–water nanofluid in a The maximum values of the dimensionless temperature
channel partially filled with porous media (Fig. 10a). The were found for Al2O3 and TiO2 nanoparticles.
effect of various volume fractions of nanoparticles (u = 0, A numerical study of MHD mixed convection flow and
3, 5 and 7%) and different Hartman numbers (Ha = 0, 5, 10 heat transfer of Cu–water nanofluid in a square cavity filled
and 15) on the heat transfer rate was thoroughly explored with a Darcian porous medium was carried out by
and discussed in that study. Their results showed that the Sivasankaran et al. [73]. The top and bottom walls of the
average temperature, velocity at the outlet of the channel as cavity were assumed insulated, while the right vertical wall
well as the average Nusselt number increased with an was kept at a constant lower temperature than the left
increase in the volume fraction of nanoparticles. In addi- vertical wall. Further, both left and right walls of the cavity
tion, increasing the volume fraction of nanoparticles u were moving with a constant speed Vo, where the effect of
from 0 to 7% resulted in nearly 20% enhancement in partial slip was imposed on these walls. It was assumed in
Nusselt number, while increasing Ha from 0 to 15 resulted that study that both the fluid and nanoparticles phases were
in only 6% enhancement (Fig. 10b). in thermal equilibrium. The results of that study illustrated
Begum et al. [71] investigated numerically mixed con- that the average Nusselt number decreased first and then
vection flow and heat transfer of nanofluids in an enclosure increased with an increase in the volume fraction of
filled with a porous medium and driven by a mid-moving nanoparticles when both walls were moving in opposite
heated wall. The vertical walls of the model were subjected direction (Fig. 11b). However, the average Nusselt number
to a sinusoidal heating boundary condition, while the was found to decrease when both walls moved in the same
horizontal walls were assumed thermally insulated. It was direction (upward) as depicted in Fig. 11c.
noticed from their results that the effect of mid-moving MHD mixed convection flow and heat transfer of a
wall was found to play a key role in enhancing the heat gold–kerosene oil nanofluid in a vertical channel filled with
transfer rate of the enclosure. Trimbitas and Grosan [72] a porous medium was analyzed numerically by Aman et al.
presented an analytical study of laminar mixed convection [74] (Fig. 12). Four other types of nanoparticles (silver,
heat transfer of a nanofluid in a long channel filled with a copper, alumina, and magnetite) were also considered in
porous medium and considering heat generation effect. The that study for comparison. The porous medium was

123
K. Khanafer, K. Vafai

y, v

±v0 v0 5.5
2.1
λr=−λi=1 λr=−λi=1
Ri=0.01 5.0 Ri=0.01
adiabatic
2.0 Ri=0.1 Ri=0.1
Ri=1.0 4.5 Ri=1.0
Ri=10.0 Ri=10.0
g 1.9 Ri=100
Ri=100 4.0

Num
Num
1.8 3.5
Th Tc
3.0
1.7
B0 2.5
1.6
2.0

Φ 1.5 1.5
x,u 0.00 0.05 0.10 0.15 0.20 0.00 0.05 0.10 0.15 0.20
adiabatic φ φ

(a) (b) (c)


Fig. 11 Sketch of the geometry and coordinate system of the cavity (Sivasankaran et al. [73])

x channel. Ramzan et al. [75] studied numerically mixed


u(0,t) = 0 u(d,t) = 0 convective viscoelastic nanofluid flow past a porous media
T(0,t) = T0 T(d,t) = Tw with Soret–Dufour effects. The results of that investigation
y
showed that the flow velocity increased with an increase in
mixed convective and viscoelastic parameters but it
Kerosene oil Cylindrical shape
based nanofluid gold nanoparticles
decreased with an increase in the values of the porosity
parameter. Also, it was observed from the presented results
that Dufour number had an opposite influence on the
C(0,t) = C0 C(d,t) = Cw temperature and concentration profiles.
Mittal et al. [76] studied numerically mixed convection
flow and heat transfer of a nanofluid in a lid-driven cavity
y=0 d y=d
filled with a porous medium using Brinkman-extended
Fig. 12 Poiseuille flow of nanofluid with gold nanoparticles (Aman Darcy model (Fig. 13a). The effects of Grashof number,
et al. [74]) Darcy number, and nanoparticles volume fraction on the
streamlines and the isotherms were studied in that inves-
approximated in that study using Darcy model. Their tigation. The numerical results showed that the addition of
results showed that gold nanoparticles were found to have nanoparticles augmented the heat transfer coefficient
the highest rate of heat transfer followed by alumina and (Fig. 13b). It was also noticed from the results that the
magnetite. Further, porosity and magnetic field were found average Nusselt number increased with an increase in the
to have an inverse effect on velocity distribution inside the

V Adiabatic wall 3.5


3

Porous medium 3
2.5
Gr = 100, Da = 0.1
2.5 Gr = 10000, Da = 0.1
Tc Th
Nu avg

Nu avg

Gr = 100, Da = 0.01
2 Gr = 10000, Da = 0.01
2

1.5
1.5

Adiabatic wall V 1 1
0 0.02 0.04 0.06 0.08 0.1 0 0.02 0.04 0.06 0.08 0.1
Volume fraction Volume fraction
(a) (b)

Fig. 13 a Schematic diagram of the flow configuration, b effect of average Nusselt number on solid volume fractions at Ri = 100 (Mittal et al.
[76])

123
Applications of nanofluids in porous medium

0.04 the most significant parameters accountable for different


Al2O3
results of velocity and temperature. Ethylene glycol was
Fe3O4
TiO2
found in that study the best base fluid compared to water
0.03 due to its higher viscosity and thermal conductivity. The
Cu
Ag results presented in this investigation revealed that the
u(y,t)

cylinder shape of Al2O3 nanofluid exhibited the highest


0.02
velocity followed by Fe3O4, TiO2, Cu, and silver nanoflu-
ids (Fig. 14). Srinivasachary and Kumar [78] studied the
effect of thermal stratification on mixed convection of a
0.01
nanofluid along an inclined wavy surface embedded in a
porous medium. The effects of various pertinent parame-
ters such as thermal stratification, Brownian motion, ther-
0.2 0.4 0.6 0.8 mophoresis, amplitude of the wavy surface, and angle of
y
inclination of the wavy surface on the velocity, tempera-
Fig. 14 Velocity profile of different nanoparticles in EG-based ture, and nanoparticles volume fraction for both aiding and
nanofluid when Gr = 0.1, N = 0.1, u = 0.04, k = 1, M = 1, t = 5, opposing flows were studied and displayed graphically.
K = 2, x = 0.2 (Aaiza et al. [77])
The results of that investigation demonstrated that an
increase in the thermal stratification parameter reduced
Darcy number for a constant nanoparticles volume fraction
velocity, temperature, local heat, and nanoparticle mass
at a Grashof number of 104 (Fig. 13b).
transfer rates for aiding flow, whereas the velocity, local
Unsteady MHD mixed convection flow and heat transfer
heat, and mass transfer rates increased and the temperature
of a nanofluid inside a channel filled with porous medium
and nanoparticle volume fraction decreased in the case of
was investigated by Aaiza et al. [77]. The channel with
opposing flow (Fig. 15).
non-uniform walls temperature was taken in a vertical
Sheremet et al. [79] studied numerically double-diffu-
direction under the influence of a transverse magnetic field.
sive mixed convection flow and heat transfer of a nanofluid
Four various shapes of nanoparticles of equal volume
in an open cavity filled with a porous medium using
fraction were used in the base fluids, ethylene glycol (EG)
mathematical nanofluid model proposed by Buongiorno
(C2H6O2) and water (H2O). It was noticed from the results
(Fig. 16a). The effect of Rayleigh number, Reynolds
of that study that viscosity and thermal conductivity were

1.0 1.0
1.5
Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6,
Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6, Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6,
Le = 5.0, ξ = 0.1 0.8 0.8
1.4 Le = 5.0, ξ = 0.1 Le = 5.0, ξ = 0.1

1.3 0.6
0.6
Aiding flow
f′

1.2 0.4
θ

Δ = 1.0, ST = 0, 0.5, 1.0, 1.5 Aiding flow


Δ = 1.0, ST = 0, 0.5, 1.0, 1.5 0.4 Aiding flow
Δ = 1.0, ST = 0, 0.5, 1.0, 1.5
1.1 0.2
0.2
1.0
0.0
0.0
0 1 2 3 4 5 6 0 1 2 3 4 5 6 0 1 2 3
η η η
1.0 1.0

1.00 Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6, Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6,
0.8 Le = 5.0, ξ = 0.1 0.8 Le = 5.0, ξ = 0.1

0.95
Opposing flow 0.6
0.6
0.90 Δ = –0.5, ST = 0, 0.5, 1.0, 1.5
Opposing flow Opposing flow
s
f′

0.4 Δ = –0.5, ST = 0, 0.5, 1.0, 1.5 Δ = –0.5, ST = 0, 0.5, 1.0, 1.5


0.85 0.4
Nr = 0.3, Nt = 0.1, Nb = 0.5, a = 0.1, A = π /6,
0.2
0.80 Le = 5.0, ξ = 0.1 0.2

0.75 0.0
0.0
0 1 2 3 4 5 6 0 1 2 3 4 5 6 0 1 2 3
η η η

(a) (b) (c)

Fig. 15 Variation of a velocity, b temperature, c nanoparticle volume fraction profiles with thermal stratification parameter (ST) for aiding and
opposing flows (Srinivasachary and Kumar [78])

123
K. Khanafer, K. Vafai

Nu Sh
L – 0.5 – 2.5

g – 1.5 – 7.5

– 2.5 – 12.5

Th, Ch
uin – 3.5
Le = 1.0 – 17.5
Le = 10.0
Tin, Cin, ϕ in x
– 4.5 – 22.5
0 L 0 20 40 60 80 Re 0 20 40 60 80 Re

(a) (b) (c)

Fig. 16 a Physical model and coordinate system, b variation of the average Nusselt number, c variation of Sherwood number at right vertical
wall with different Reynolds and Lewis numbers for Ra = 50, Ld = Ln = 1.0, Nr = Nc = Nb = Nt = Nd = 0.1 (Sheremet et al. [79])

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