Chemistry – Electro Chemistry ICON – C2 – Part - II

ELECTRO CHEMISTRY
ELECTROLYSIS
CLASS WORKSHEET
LEVEL – I
1. Key: (3)
Solution: During electrolysis the cations move towards negative electrode (cathode) and anions move
towards positive electrode (anode).
2. Key: (1)
Solution: Anode is the oxidizing electrode which accept electrons, Cathode is the reducing electrode
which supplies electrons.
3. Key: (2)
Solution: The ions move randomly.
4. Key: (4)
Solution: OH having lower discharge potential than SO24ion
5. Key: (1)
Solution: An anode Cl  lose electron to form Cl2 .
2Cl   Cl2 g   2e .

6. Key: (4)
Solution: At anode oxidation takes place.
7. Key: (2)
Solution: At cathode H ions left, at anode SO 24ions left
H   SO 24   H 2SO 4 .
8. Key: (4)
Solution: At cathode Na  ions and at anode OH ions left Na   OH  NaOH solution turns into base.
So pH increases
9. Key: (2)
Solution: Anions migrate towards
Anode and Undergoes oxidation.
10. Key: (4)
Solution: Always reduction takes place at cathode
During electrolysis 2H   2e  H 2
11. Key: (4)
Solution: Anode reaction.
12. Key: (2)
Solution: At cathode H  discharged because H  having less discharge potential than Na  .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
13. Key: (2)
Solution: H having less discharge potential than K  . OH  having less discharge potential than NO3 .
Discharge potential order for cations:
Li   K   Na   Ca 2  Mg 2  Al 3  Mn 2  Zn 2 
Cr 3  Fe2  H   Cu 2  Ag   Hg 2  Pt 2  Au 3
Discharge potential order for anions:
F   PO 4 3  SO 4 2  NO3  OH   Cl   Br   I  .
14. Key: (4)
Solution: When the same quantity of electricity of passed through different electrolytes, the masses of
different ions liberated at the electrodes are directly proportional to their chemical equivalents
(equivalent weight)
W1 E1 Z E
 or 1  1
W2 E 2 Z2 E 2
15. Key: (2)
Solution: Charge of 1 mole of electrons
 6.023  10 23 e   6.023  10 23  1.602  10 19 C
 96, 500 C
16. Key: (1)
Solution: Hydrogen having less equivalent weight for a given weight it contains more number of ions
other.
17. Key: (2)
Solution: According faraday second law amount of substance deposit at respective electrode are in the
ratio of their chemical equivalents. Cuprous having more equivalent weight than cupric
18. Key: (2)
Solution: Cryolite decomposition Na 3AlF6  Al 3  6F
At cathode  Al 3  3e   Al   2  2mol of Al
At anode  2F  F2  2e   3  3mol of F2
Molar ratio of Al and Flourine is 2 : 3
19. Key: (3)
Solution: 2Cl   Cl2  2e
2F  2  35.5
1F  35.5
0.1F  35.5  0.1  3.55g
20. Key: (3)
Solution: Cu 2  2e  Cu
1e  6.023 1023
2e  are required to deposit one Cu atom
2  6.023 10 23 molecules required to deposit 63.5gm of Cu  12.0 / 46 1023

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Chemistry – Electro Chemistry ICON – C2 – Part - II
21. Key: (1)
E
Solution: e 
96500
E  e  96500
 0.0006735  96500
 65
22. Key: (3)
1
Solution: H 2O  H 2  O2
2
1 mole of H 2O decomposed and producing
22.4 mol of H 2 and11.2 molof O2 produced
23. Key: (3)
Solution: Ag   1e  Ag Cu 2  2e   Cu
1F  96500C  108g 2F  63.5g
108
1C  2(96500C)  63.5g
F
108 63.5 63.5
Ratio  :  108 : 31.75 1C 
F 2F 2F
24. Key: (1)
Solution: Ag   1e  Ag 1F  108gms
2
Ni  2e  Ni 2F  59  1F  29.5 gms
52
Cr 3  3e  Cr 3F  52  1F=  17.3 gms .
3
25. Key: (4)
Solution: i = 1 amper
t = 10 sec
q = it = 10×1 amper sec
Coulumb
 10 1 sec
sec
 10C
Charge of e  1.6 1019 C
10e
10C  19
 6.25 1019
1.6 10
26. Key : (4)
Solution: Charge on one ion N3  3 1.6 1019
One gm of ion  6.023 1023
Charge of N3 gm of ion
 3  6.023 1023 1.6 1019
 2.89 105

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Chemistry – Electro Chemistry ICON – C2 – Part - II
27. Key : (1)
Solution: i  9.65amp t ?
3
10 milli moles of Al  27 10 3 g
Al 3  3F  Al
3F  27g
1mole  27g
1milli mole  27 103 g
E
Z
F
27
Z
3.F
m  Zit
m 27 103
t 
Zi  27 
  9.65 
 3F 
 30sec
28. Key : (1)
weight of k E.wt of k
Solution: 
weight of Al E wt of Al
39
19.5
  1
W of Al 27
3
19.5  9
 W of Al   4.5gm
39

LEVEL – II
1. Key: (2)
Solution: 2Cl   Cl2  2e
71 gms  2N0e
2N 0
0.355 gms   0.355
71
 0.01N 0

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Chemistry – Electro Chemistry ICON – C2 – Part - II
2. Key: (2)
Solution: Ag   1e  Ag 1mole  108gm for 1 mole Ag
1
Cu 2  2e  Cu 2mole  63.5gms for mole Cu
2
1mole  31.75 gm
27
Al 3  3e  Al 3 mole e  27 for 1 mole Al 
3
1 1
Ag : Cu : Al  1: :  6 : 3: 2 .
2 3
3. Key: (1)
Solution: 2H 2 O  4H   O 2  4e 
i  2 ampere
t = 965sec
q = it = 2  965=1930 coulumbs
4 mole e   1mole O 2  22.4Lt
4  96500 Coulumbs  22.4Lt
22.4 11.2
1930 coulumbs   2  965   0.112Lt.
4  96500 100
4. Key: (1)
Solution: i  0.965 amphere
t  1sec
q  it  0.965Coulumbs
N0e   96500C
xe  0.965
x  1105 N 0e
5. Key: (1,2)
Solution: NaClO3  NaClO4
ClO 4  2H   2e   ClO 3  H 2 O
245
Number of equivalents of NaClO 4   4  4F
61.25
4 100
No. of Faradays =  6.67F
60
 6.43×105 C .
6. Key: (1)
Solution: Aq NaCl electrolysis gives H 2 and Cl2 and NaOH.
2e   2H 2 O  2OH   H 2 (Reduction – Cathode)
2Cl   Cl2  2e (Oxidation – Anode).

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Chemistry – Electro Chemistry ICON – C2 – Part - II
7. Key: (4)
Solution: 2Cl   Cl2  2e 
M  1000 gms (or )1158
t?
355
Z  Electro chemical equation
1
I = 25 amphere
35.5
M = Z it  1000 gms   25  t
1
Utilised current
Current efficiency 
Passage current
Passage current × Current efficiency
Utilised current =
100
25  62
  15.5ampere
100
E it
Feraday 1st law W 
96,500
35.5 15.5  t
1000 
96500
t  1.754  105 sec
t  48.7 hours
8. Key: (3)
Solution: During electrolysis 1000 gm Cl2 formed. 35.5 gram Cl  = 40 gms NaOH.
40
1Kg Cl    1000
35.5
 1126.7gms NaOH
Weight 1
M 
Gram V
1126.7 1
M   1.4
40 20lt
9. Key: (3)
No.of moles of AgNO3
Solution: M 
Volme(lt )
nAgNO3
1  0.2 mole AgNO3
0.2 lt
0.2 mole AgNO3  0.2mole Ag 
1
 108(or) 0.2 108
5
21.6
 21.6   10.8gm
2

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Chemistry – Electro Chemistry ICON – C2 – Part - II
From the given sum
1 Zit
mole of Ag means 10.8 gms Silver M 
2 96500
I = 1 ampere
108 1
10.8 
96500
t  9650 sec  160 min
10. Key: (2)
Solution: Charge carried by 1 mole of e   1F
Deposition order of  H     Na    OH    SO 4 2

11. Key: (3)

Solution: 0.05F ____1.6g
1F _______ x
x  32g
A.wt
Eq.wt 
V
 A.wt  32  2  64g
12. Key: (3)
Solution: 2H 2O  2H   2OH
1
A : 2OH   O2  H 2O  2O 
2
 
C : 2H  2e  H 2
3
2 moles of H 2O ____ moles of gases  O2 ,H 2 
2
3
  22.4
2
 33.6 ltrs
13. Key: (2)
Solution: 6  1023 e s ____1F ____ Eq.wt  x 
6  1022 e  ____________1.9g
6 1023
x 1.9  19
6 1022
A.wt 59
Eq.wt   O.No   3
V(or)O.No 19

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Chemistry – Electro Chemistry ICON – C2 – Part - II
14. Key: (3)
Solution: 2H 2O  2H 2  O 2
2 moles of H2O  3moles of gases
x ___ 2
2 4
x   2  moles of H 2 O
3 3
15. Key: (4)
Solution: 12g ___1F ___ 60
1g ____ x
1
x F
12
9g ____1F
10g ____ x
10 600
x F  66.67 Rs
9 9
16. Key: (4)
E
Solution: M  Q
96500
Q  1F  96500C
197
Eq.Wt of Au 
3
197 197
M  96500 
3(96500) 3
1
 g.atom .
3
17. Key: (4)
E
Solution: M  Q
96500
Here M = 3.175 = deposited at cathode.
Which is equal to the mass of ‘Cu’ dissolved at anode
3.175 1
n   0.05 moles .
63.5 20
18. Key: (2)
Solution: A B C
E1 : E 2 : E 3  m1 : m 2 : m3
At Wt1 At Wt 2 At Wt 3
: :  m1 : m2 : m3
V1 V2 V3
7 27 48
: :  2.1: 2.7 : 7.2
V1 V2 V3

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Chemistry – Electro Chemistry ICON – C2 – Part - II
7 V2 2.1
:  .........(1)
V1 27 2.7
V2 3

V1 1
27 V3 2.7
 
V2 48 7.2
V2  3
V3  2
V1 : V2 : V3  1: 3 : 2 .
19. Key: (2)
Solution: Time  6hr  6  60  60  21600
E  3.7 59
m  21600  21600  3.7
96500 2(96500)
M  6.6  3.7  24.42
Wt 1
M 
GMW 0.5
24.42 1
M   0.89
5.9 0.5
0.89M  2M .
20. Key: (2)
Solution: Current passed  3.7 amp  90%utiliged 
90
Current utilised  3.7 
100
 3.33amp
32.5  3.33  230
m
96500
 0.26 g of Zn
Before electrolysis
W 1000
0.16  
161 300
W  7.75g ZnSO4
161g ZnSO4 ____ 65g of Zn
7.75g ZnsO4 ____ x
7.75
x  65  3.13g of Zn
161
Mass of Zn 2 after electrolysis  3.13  0.26
 2.89
2.89 1000
M   0.15 M
65 300

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Chemistry – Electro Chemistry ICON – C2 – Part - II
21. Key: (1)
Solution: 2H 2 O  2H   2OH 
K 2SO 4  2K   SO 4 2
1
A : 2OH   H 2 O  O2  2e
2
 
C : 2H  2e  H 2
3
2F ____ moles of gases  33.6 ltrs
2
x ____________________1.68 ltrs
1.68 3.36
x 2   0.1F
33.6 33.6
MnO 4  Oe   Mn 2
1mole of MnO 4 ____ 5F
x ________________ 0.1F
0.1
x 1  0.02 moles of MnO 4
5

LEVEL – III
1. Key: (4)
E
Solution: m  Q
96500
9
4.5  Q
96500
96500
Q  48250C
2
11.2C
V of H 2   482500  5.6C
96500
2. Key: (3)
E
Solution: m  it
96500
8
m  8 1.5  60  60
96500
m  3.5
3.5
no. of mole =  0.1119
32
 0.112

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Chemistry – Electro Chemistry ICON – C2 – Part - II
3. Key: (4)
W
Solution: d 
V
V  0.25mm  (0.321106 )
 0.08 106
 8 104
W  d  V  7.2  8 104
 57.6 104
E
m  i  60
96500
52
57.6  10 4   i  60
6  96500
576 104  96500
i
52 10
 10.689.2 104
 10.689 107
4. Key: (3)
5.6 1.2  7  50
Solution: VO2 
96500
 0.029 ltrs
 29 ml
11.2 1.2  4  60
VH2 
96.500
0.05849ltrs
 58.49 ml
1
1mole of Cu  mole of O 2  11.2ltrs ]
2
63.5 g _________11.2ltrs
0.4 g __________ x
0.4
x  11.200
63.5
 70.5 ml
Total of VO2  29  70.5  99.5mlof O2
5. Key: (4)
Solution: In AgNO3  Ag deposit at cathode O2 E value at anode.
HNO3 can form pH  (decreases).
In LiCl  H 2 deposit at cathode, Cl2 E volue at anode.
LiOH can form pH  increases.

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Chemistry – Electro Chemistry ICON – C2 – Part - II
6. Key: (3)
Solution: 1 mole of electrons can transfer – 1 equivalent
10 3 moles (6 1020 ) of electrons can transfer - 103 equivalent = 0.001.
7. Key: (2)
Solution: In AgNO3  Ag deposit at cathode O2 Evolve at anode.
HNO3 can form pH  (decreases).
In LiCl  H2 deposit at cathode, Cl2 Evolve at anode.
LiOH  pH  increases.
8. Key: (1)
Solution: 1 coulomb can be defined as the amount of charge passed when 1 ampere of current passed
for 1 second.
9. Key: (1,3)
Solution: Anode: Cu  Cu 2  2e
Cathode: Cu 2  2e  Cu
10. Key: (1, 4)
Solution: Charge of an electron - ?
1F  1mole e
1F mole  charge of electron
  Charge of e 
1N A mole
96500
 .
1N A
11. Key: (1, 4)
Solution: Non spontaneous process requires energy G is positive for electrolytic decomposition as it
is endothermic.
12. Key: (2, 4)
Solution: Cathode : 2H   2e  H 2

Anode :2Cl   Cl2  2e

13. Key: (4)
Solution: Ag 2SO 4  2Ag   SO 4 2
2H 2 O  2H   2OH 
1
A : 2OH   H 2 O  O 2  2e
2
 
B : 2Ag  2e  2Ag
WO2 WAg

FO2 FAg
1.6 WAg
  WAg  21.6g
8 FAg

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Chemistry – Electro Chemistry ICON – C2 – Part - II
14. Key: (1, 2, 3, 4)
Solution: In any cell oxidation takes place at anode and reduction takes place of cathode.
15. Key: (3, 4)
Solution: 1Faraday possess
Al 3  3e  Al
1mole A1
IF 
3
1Faraday posses
Na   1e  Na
1F  1mole Na
1:3  3 .
AlF3 fused NaF fused posses through 1 faraday equal volumes released.
16. Key: (4)
Solution: CuSO 4 ( aq )  Cu 2  ( aq )  SO 4 2 ( aq )
Initially CuSO 4 ( aq ) appears as blue. Finally
Anode : 2H 2 O  O 2  4e   4H 
Cathode : Cu 2  2e  W
Remaining ions H  ,SO 4 2 combined to form H 2SO4 (Sulphuric acid). It is colour less solution.
17. Key: (2)
Solution: The passage of current liberates H 2 and Cl2 at anode the solution is NaCl (aq ) using Pt
electrodes option (2)
18. Key: (2)
Solution: Anode: 2H 2 O  O 2  4e   4H  .
H 2 O  O 2  2e   4H 
i  1A t  16 min 5sec  965sec
2F  1moleO2 9  it  96K
965C  x mole O 2 .
19. Key: (4)
Solution: 1mole charge - 106.4 gms
10800C  2.977 gms

96500  charge  106.4gms

Charge 96500×2.977=10800×106.4
1149120
Charge 
96500  2.977
11.9079
  3.99  4.
2.977

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Chemistry – Electro Chemistry ICON – C2 – Part - II
20. Key: (4)
Solution: Given metal weight = electro chemical equivalent weight
M=Z t = 0.25 sec
M = Z it
I = 1 l it
It = 1  i  0.25  1
1 100
i  i4.
0.25 25
21. Key: (8)
1
Solution: H 2O  O 2  2e   2OH 
2
2H 2 O  O 2  4e  4OH 
molecular weight of O2
Equivalent weight of O2 
Valence
32
 8.
4
22. Key: (1)
OH 
Solution: Mn 3O4   MnO24
8
6
3
8
 6
3
 8  18  8 
 3 6    3    10
 3  3 
For1mole  10
For 2 mole = 20
=2×10=2×10 x
x  1.
23. Key: (3)
Solution:
6F
[Fe2 (C2O4 )3 ]   6CO 2

3 2
6F  1mole
18F  3mole
x  3mole .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
24. Key: (4)
Solution: i  3ampere
t  1hr  1 60  60 sec
3  60  60C  2.977 gms
n  96500  106.4 gms
3  60  60  106.4
n  96500 
2.977
3  60  60 106.4
n
2.977  96500
n  4.
25. Key: (1)
electrolysis 1 1
Solution: 2HCOOK   2CO 2  2KOH  H 2  H 2
2 2
Total 1 mole H 2 .
26. Key: (1)
1
Solution: 1F  remove 1 mole Cl to Cl2
2
 102 
102 F  remove102 mole Cl  to   Cl2
 2 
n
[H  ]  [4  ] 
v
102 mole

100
1000
102 1000
  102  10
100
 101
pH   log[H  ]
 pH  1
27. Key: (2)
1
Solution: 1F  4 mole O2
1
1F   22.4lt of O2
4
2
2F   22.4lt of O 2
4
VO 2  11.2lt
5.6X  11.2 lt
5.6 × X  5.6  2
x  2.

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Chemistry – Electro Chemistry ICON – C2 – Part - II
28. Key: (3)
Solution: q  it
i  2 ampere
t  5 hr  5  60  60sec
=18000 ampere sec  18×103C
2×18×103C  22.2 gms
ch arg e  96500C  177 gms
Charge  96500  22.2 gm  18 103 C 177 gms
18 103 C  177 gms  2
Charge =
96500  22.2gms
3186 103  2

965  22.2 10 2
3186 1032  2

2142300
 1.48  2  3 .
29. Key: A-q,r; B-q,r; C-q,r; D-p,s
Solution:
Dilute solution of HCl:
Cathode: 2H   4e  2H 2 H 2 evolved at cathode
Anode: 2H 2 O  O2 +4e  4H  O 2 evolved as anode.
Dilute Solution of NaCl:
NaCl  Na   Cl 
Anode :2H 2 O  O 2 +2e   4H 
Cathode : 2 H   2e   H 2
Because of dilute solution.
Concentration of solution of NaCl:
Anode : 2Cl   Cl2  2e  (Cl2 liberated)
Cathode :2H   2e  H 2 ( H 2 liberated)
Fairly concentrate solution of AgNO3
Anode : 2H 2 O  O 2  2e   4H 
Cathode :Ag   1e  Ag .
30. Key: A-r; B-s; C-p,q; D-r
Solution: Anode : 2H 2 O  O 2  4e  4H 
Cathode : Ag   e   Ag
Ar.
Electronegative gas O2 liberated at anode.
Anode: Anode : Cu  Cu 2  2e
Cathode : Cu 2  2e  W

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Chemistry – Electro Chemistry ICON – C2 – Part - II
B  S.
Anode : 2HSO 4  H 2S2 O8  2e 
Cathode: 2H   2e   H 2
O O

H O S O O S O H

O O at anode
Peroxy
H 2 at anode
C  p, q
Anode: 2Cl  Cl2  2e 
Cathode: 2Na   2e  2Na
Electronegative gas.
DR.

PRACTICE WORKSHEET
LEVEL – I
1. Key: (2)
Solution: Electrolytic cell converts electrical energy into chemical energy. A substance can be
decoposed.
2. Key: (1)
Solution: Electrons enter the solution through negative electrode.
3. Key: (3)
Solution: During electrolysis, reduction (electronation) takes place at cathode and oxidation (de-
electronation) takes place at anode .
4. Key: (4)
Solution: Oxidation takes place at anode nickel lose electrons.
Ni  Ni 2  2e .
5. Key: (3)
Solution: At Cathode aluminium gain three electrons to become neutral and also takes place reduction.
Al 3  3e   Al .
6. Key: (1)
Solution: At anode oxidation takes place chromium oxides.
7. Key: (1)
Solution: At cathode Na  ions left, and at anode OH ions left. Solution turns into base so pH increases.
Na   OH   NaOH .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
8. Key: (2)
Solution: H having less discharge potential than Na 
Decreasing order of discharge potentials for various cations.
Li   K   Na   Ca 2  Mg 2  Al 3  Mn 2  Zn 2 
Cr 3  Fe2  H   Cu 2  Ag   Hg 2  Pt 2  Au 3
Order of deposition of cation.
Au 3  Pt 2  Hg 2  Ag   Cu 2  H   Fe 2 
Cr 3  Zn 2  Mn 2  Al 3  Mg 2  Ca 2  Na   K   Li  .
9. Key: (2)
Solution: At cathode Na formed. It dissolves in mercury and forms sodium amalgam.
10. Key: (1)
Solution: H having less discharge potential than Na  .
11. Key: (2)
Solution: At anode OH discharged at cathode Ag  discharged. H and NO3 remains in solution and
forms HNO3
.
12. Key: (1)
Solution: Metal which is having more reduction potential that metal reduces first.
13. Key: (2)
Solution: The mass of the substance(m) deposited or liberated at any electrode is directly proportional
to the quantity of electricity or charge (Q) passed.
Mathematical equation is m  Q .
m is the mass in grams.
Q is measured in coulombs (C) and (e) is the proportionality constant in g/C.
14. Key: (3)
Solution: When the same quantity of electricity of passed through different electrolytes, the masses of
different ions liberated at the electrodes are directly proportional to their chemical equivalents
(equivalent weight)
W1 E1 Z E
 or 1  1
W2 E 2 Z2 E 2
15. Key: (3)
Solution: Gram equivalent weight and gram atomic weight are same for silver.
Ag atomic weight 108 and also silver loss one electron forms Ag 1 .
Weight of silver
Equivalent weight of silver 
Gram Equivalent Weight
108

1
 108 .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
16. Key: (4)
Solution: The mass of the substance (m) deposited or liberated at any electrode is directly proportional
to the quantity of electricity or charge (Q) passed.
Mathematical equation is m  Q .
m  ect q  ct
m  e  q q  1coulomb or 96500 F
When the same quantity of electricity of passed through different electrolytes, the masses of
different ions liberated at the electrodes are directly proportional to their chemical equivalents
(equivalent weight)
W1 E1 Z E
 or 1  1 .
W2 E 2 Z2 E 2
Normal hydrogen electro N.H.E or S.H.E is represented as Pt, H 2  atm  / H  1M  .
17. Key: (2)
Solution: One Faraday of charge is the magnitude of the charge of one mole of electrons.
At anode oxidation is takes place.
At cathode reduction is takes place.
One faraday equal to 1 coulomb:
6.02 1023
F
6.24  1018
F  9.65 104 c / mol .
18. Key: (1)
Solution: Cu 2  2e  Cu
2 Faradays will deposit  1gm atom of Cu  63.5gm .

19. Key: (2)

EQ 9Q
Solution: M   5.4 
F 96500
5.4  96500
Q  57900C
9
20. Key: (2)
Solution: m  e  q
E
e
96500
E  y  96500 .
21. Key: (4)
Eit
Solution: m 
96500
m  96500
i
E t
0.1 96500
  965amp
110

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Chemistry – Electro Chemistry ICON – C2 – Part - II
22. Key: (4)
Eq.V
Solution: V  it
96500
11.2  103
112 ml  1 t
96500
112  96500
t 1  965sec
112 102
23. Key: (3)
Solution: Equivalent weight of Al
13.5
  96500
9
13.5
 F
9
 1.5 F
24. Key: (2)
16
 1 1
Ei t 2 8
Solution: m   
96500 96500 96500
25. Key: (3)
Solution: Change in oxidation state is 5
Eletricity  5  96500
 4.8  105 e
26. Key: (1)
Solution: Mn3O4
MnO  Mn 2 O3  MnO 24

2 2( 3) Mn 6
3Mn  3Mn
(+2+6)  3(+6)
+8  +18
10e
10 moles of electrons involved.
= 10F.
27. Key: (4)
AW
(Ferrus)
M1 E1 2
Solution:  
M2 E2 A 2 W2
(Ferric)
3
M1 3
 .
M2 2

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Chemistry – Electro Chemistry ICON – C2 – Part - II
28. Key: (1)
ECt
Solution: M 
96500
M  96500 0.1 96500
C 
Et 1 9650
 1amp
29. Key: (2)
 1 
Solution: At anode Cl  Cl2  e
2
ECl2  35.5
E  I  t 35.5  2  30  60
WCl2  
96500 96500
 1.32 gm

LEVEL – II
1. Key: (4)
E
Solution: m  Q
96500
9
4.5  Q
96500
96500
Q  48250C
2
11.2C
V of H 2   482500  5.6 L
96500
2. Key: (4)
Solution: Deposition order of H   Li 1  OH   SO 42 .
3. Key: (2)
Solution: In electrolytic cell anode is  ve , cathode is  ve .
4. Key: (3)
Solution: 1g eq. of Sodium formed when IF of current is used.
If 1F of current is used 1/3 moles of ‘Al’ conform.
5. Key: (1,3,4)
Solution: Order of deposition H   Na   Ag 
OH   NO3  SO4 2 .
6. Key: (2,4)
Solution: During electrolysis of water it gets ionised into H  and OH  .
7. Key: (3)
Solution: Deposition order of H  Cu 2
SO 4 2  OH  .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
8. Key: (1)
63.5
Solution: m   10  9650
2  96500
 31.25
0.75mole
Conc. of CuSO 4   0.75
1Lit
1 mole = 2L
N = 2 moles
31.5 = 2.5ml
Remin in =1.5 moles.
9. Key: (4)
Solution: Conc. of [Cu 2 ]  conc of H  deposited.
0.5 mole/Lit = [H ] deposited.
pH   log 0.5
  log 5 101
 1  log 5
 1  0.7
 0.3
10. Key: (1)
2O 2 CO 2
Solution: CH 4    H 2O
64 g 44 s
8
MO 2   10  9650
96500
 8g.
O2
 Wt of CO 2
8g
8  44
x
64 g
5.5g .
11. Key: (3)
Solution: m  E a
 31.75  2  68.5
W 1000
m 
GMW V
0.05 100
n  0.005
1000
12. Key: (2)
Solution: He amount of substance deposited is directly proportional to the charge.
13. Key: (4)
Solution: During electrolysis the ratio of H 2 and O 2 liberated by volume is 2 : 1.

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Chemistry – Electro Chemistry ICON – C2 – Part - II
14. Key: (1)
Solution: 1mole of NaCIO 4 ___ 2F
0.5 ______ x
x  0.5  2  1F
15. Key: (1)
Solution: Thickness (t)  0.1
Volume  l  b  t Area  l  b
 100  0.1  10  10
 10  100
m
d   m  d v
v
 10.8  10
V
m  EQ
108  108  Q
Q  1F
16. Key: (2)
Solution: V  250 ml n  N 1
n
N  1000
v
1  250
n  0.25equivalents  0.25 F
1000
 0.25  96500
 24125 coulombs
17. Key: (3)
Solution: 1g H 2 _____ 8g O2
10 g H 2 ______ 80g O2
 20 Rs
80g O2 ____ 20 Rs
10 g O 2 _____ x
 2.50 Rs
18. Key: (1)
Solution:  mH 2 1 :  mH 2 2  1:1 .
19. Key: (4)
Solution: m H 2  m O 2  2 :16  1: 8
VH 2 : VO 2  22.4 :11.2  2 :1
m H2  x mO2 VH 2  y VO 2
m H2  8 mO2 VH 2  2VO2
x  8 y2

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Chemistry – Electro Chemistry ICON – C2 – Part - II
y 2 1
   0.25
x 8 4
20. Key: (2)
1
Solution: H 2O  H 2  O 2
2
1mole  2 F
d  0.99g/ml
1ml  0.99 g
100 ml  99g
18g ____ 2F
99 ____ x
99
x   2  11F
18
21. Key: (2)
CH3  CH 3  2CO2 2NaOH  H 2
Solution: 2CH 3COONa  2H 2O  
a c
2 moles of E  2F
2F ____ 4 moles of gases
2  96500 ____ 4
0.965  60  60 ___ x
x  72 103 moles
PV  nRT
1 V  72 103  0.0821 298
V  1.762 Hrg
22. Key: (1)
1
Solution: 96500c _____ moles Ni 2  Ni
2
1 60 ____ x
x  0.0008 moles
0.1M Ni  NO3  2  1mole Ni  M _____10/ltre
No. of moles Ni 2 remaining  1  0.0003
 0.9978moles
n 0.9997
Final Concentration  
v 10
 0.09997
 0.1M

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Chemistry – Electro Chemistry ICON – C2 – Part - II
LEVEL – III
1. Key: (4)
Solution: 2F ____ 2  96500 ____ 3 moles of gases
80
0.5  96.45  60  ____ x
100
x  0.03598
740
 V  0.03598  0.0821 300
760
V  0.91L
2. Key: (1,2,4)
Solution: It is based on preferential discharge of ions at respective electrodes.
3. Key: (1)
Solution: 11.2ltrs of H 2 ___ 2.6 ltrs of O2 ___ x lost
5.6ltrs of O2 ____ x
11.2 ltrs of O2 ____ x
?  2x
4. Key: (2)
12 6
1mole K 2 Cr2 O7  2Cr 3

Solution:
 6  96500  0.4
 2.4  96500 C
5. Key: (3)
Solution: 4F __ 4  96500 ___195g
C  5  60  60___0.195
C=21.44 amp
6. Key: (1, 4)
Solution: Electrolysis aq. LiCl.
2Cl   Cl 2  2 e  at anode  .

7. Key: (1,2,3,4)
Solution: All are correct statements as per discharge potential order
8. Key: (1,3,4)
Solution: Deposition order of
K  H
Na   H
SO 42  OH  .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
9. Key: (3)
Solution: 1F _____ 96500coloumb _____100 g
96.5_______x
x  0.108g
 108g
10. Key: (4)
CH3  CH 3  2CO2 2NaOH  H 2
Solution: 2CH 3 COONa  H 2O  
a c
11. Key: (1)
Solution: Electrolysis of aq. CuSO4 the solution is acidic so pH  7
12. Key: (1)
0.06 1
Solution: E  log  0.02 V
3 10
13. Key: (4)
0.06  Zn 2 
Solution: E  E log  2 
2 Cu 
1
E   Cu 2 
 Zn 2  

14. Key: (2)

Solution: I = 1 ampere t = 5hr = 5  60  60 sec  18000 sec
q  it  2 18000  26000C
36000C  22.2gms of tin
n  96500C  118.7gms of tin
118.7  36000
n  1.99  2
96500  22.2
n  2.
Oxidation number = 2.
15. Key: (6)
6F
Solution: C 6 H 5 NO 2  6H   C6 H 5  NH 2  2H 2 O .
16. Key: (2)
Solution: 2Cl   Cl2  2e
2F  1mole Cl2
4F  2mole Cl2 .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
17. Key: (3)
Solution: q = it I = 3.20A t = 40 min
q  3.2  40  60sec  7680C
7680C  3.05gms In
Charge n ×96500  114.81
114.81 7680
n  2.99
96500  3.05
n  3.
18. Key: (9)
Solution: E  W  VQ
i =1ampere t = 90sec
q  it  90C
J
W  90C 100V V=
C
J
 90C 100
C
 9  103 J
W  9KJ
19. Key: (5)
Solution:

MnO4 
5e
or
 Mn 2
5F

7 2
20. Key: (2)
Solution: 2F passes through acidified H2O
Cathose  2H   2e  H 2 (22.4lt )
Anode  40H   O 2  2H 2 O  4e 
1
2OH   O 2  2H 2O  2e
2
22.4
 11.2lt
2
2F
H 2SO 4
 33.6lt .

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Chemistry – Electro Chemistry ICON – C2 – Part - II
21. Key: A-r; B-s; C-p; D-q
Solution:
A) MnO 4 Mn 2
5F
7 2
5  96500  482500C
A–r
Cr2 O72   2Cr 3

2Cr  7(2)  2 Cr 6 
3e
Cr 3

2Cr  12 2Cr 6 
6e
Cr 3
6F  6  96500  579000C
B–s
2 e
Sn 4  Sn 2
2F  2  96500  193000
C–p
3e
Al 3   Al
3F  3  96500  289500
D – q.

Page 28