ALLEN® Solid State 1

SOLID STATE 7. ,d f}vaxh ;kSfxd esa rRo A ds ijek.kq hcp

1. ,d dk; dsfUær ?kuh; lajpuk esa ,d ijek.kq dh lajpuk cukrs gS rFkk rRo M hcp lajpuk dh

leUo; la[;k gS _______. v"VQydh; fjfDr;ksa dk Hkkx 2/3 ?ksjrs gS rks

f}vaxh ;kSfxd dk lw=k gS %
[eku yhft, fd tkyd ijek.kqvksa ls gh cuk gS]
(1) M2A3 (2) M4A3 (3) M4A (4) MA3
2. dkWij dh ,dd lsy Qyd dsfUnzr ?ku ftldh
8. ,d dBksj inkFkZ mPp rki ij xyrk gS vkSj nksuksa
fdukjk yEckbZ 3.596 Å ls laxr gS vkSj tkyd ds
izR;sd fcUnq ij dkWij dk ,d ijek.kq gS] dkWij Bksl rFkk xfyr voLFkkvksa esa fo|qr jks/kd gSA ;g

dh ijdfyr ?kuRo kg/m3 esa gS _______ Bksl eq[; :i ls ftlds ln 'k gSa] og gS%
[dkWij dh eksyj lagfr : 63.54 g ; vkoksxknzks (1) vk;fud Bksl (2) vkf.od Bksl

la[;k = 6.022 × 1023] (3) /kkfRod Bksl (4) lgla;ksth Bksl

3. ,d tkyd esa izfrtkyd LFkku esa v"VQydh; 9. ghjs esa C ijek.kqvksa dh f=kfofe; lajpuk
fjfDr;ksa dh la[;k gS_____A(fudVre iw.kk±d rd) lgla;kstu vkcU/k ls fojfpr gksrh gSA ghjs dh
4. ,d fuf'pr rRo bdkbZ lsy ds bcc tkyd esa lajpuk esa Qyd dsfUnzr ?kuh; tkyd gksrk gS]
fØLVyhdr gksrk gS ftldh fdukjk yEckbZ 27 Å ftlds 50% prq"Qydh; fjfDr LFkku Hkh dkcZu
gSA ogh rRo leku voLFkk esa ;fn fcc tkyd esa
ijek.kqvksa ls Hkjs gksrs gSaA dkcZu ijek.kqvksa dh
fØLVyhdr gks tk, rks bdkbZ lsy dh fdukjk
la[;k izfr ,dd lsy __________gSA
yEckbZ Å esa ________gksxhA ¼fudVre iw.kk±d esa)
10. ,d dkWij ladqy CCP tkyd esa fØLVfyr gksrk
[eku yhft, fd izR;sd tkyd fcUnq ij ,d
gS ftldh dksf"Bdk ds dksj dh yEckbZ 0.4518 nm
ijek.kq gS]
dk Kku X-fdj.k foorZu ds v/;;u ls gksrk gSA
[eku yhft, % 3 = 1.73, 2 = 1.41]
;fn dkWij ladqy dk ?kuRo 7.62 g cm–3 gks] rks
5. Ga (ijek.kq æO;eku 70 u) ,d "kV~dks.kh; can
dkWij ladqy dh eksyj æO;eku ______ g mol–1
ladqyu lajpuk esa fØLVyhdr gksrk gSA 0.581 g
gSA (fudVre iw.kkZad esa)
Ga esa fjfDrvksa dh dqy la[;k gS _______
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[fn;k gS : NA = 6.022 × 1023 mol–1]

× 1021 ¼fudVre iw.kk±d esa½
11. ,d inkFkZ dh ,dd lsy ds iSjkehVj gSa
[fn;k gS % NA = 6.023 × 1023]
a = 2.5, b = 3.0, c = 4.0, a = 90°, b = 120°,
6. SrBr2 ds 10–5 eksy izfr'kr ls KBr dks Mksi fd;k
g = 90°A inkFkZ ds fy, fØLVy ra=k gS :
x;k gS KBr fØLVy ds 1g esa /kukRed fjfDrvksa dh
(1) "kV~dks.kh;
la[;k gS _____1014A (fudVre iw.kk±d rd)
[vkf.od lagfr;ka : K : 39.1 u, Br : 79.9 u, (2) fo"keyack{k

NA = 6.023 × 1023] (3) ,durk{k

(4) f=kurk{k

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2 Solid State ALLEN®
12. lgh dFkuksa dk p;u dhft,A 14. uhps nks dFku fn, gSaA
(A) fØLVyh; Bklksa esa nh?kZ ijklh O;oLFkk gksrh dFku I : Ýsady
s nks"k fjfDrrk rFkk vUrjkdk'kh nks"k gSA

gSA dFku II : Ýsadsy nks"k] F-dsUnzks dh mifLFkfr ds

(B) fØLVyh; Bksl lenSf'kd gksrs gSaA
(C) vfØLVyh; Bkslksa dks dHkh&dHkh vkHkklh Bksl
Hkh dgrs gSaA
(D) vfØLVyh; Bksl rki ds ,d fuf'pr ijkl
ij uje gks tkrs gSaA
(E) vfØLVyh; Bkslksa dh fuf'pr xyu Å"ek gksrh
gSaA
uhps fn, fodYiksa esa ls lokZf/kd mfpr mÙkj
pqfu, %
dkj.k] vk;fud Bkslksa esa jax mRiUu djrk gSA
mijksDr dFkuksa ds lanHkZ esa uhps fn, fodYiksa eas
ls lgh mÙkj pqfu,A
(1) dFku I vlR; gS ijUrq dFku II lR; gSA
(2) nksuksa dFku I rFkk dFku II lR; gSA
(3) dFku I lR; gS ijUrq dFku II vlR; gSA
(4) nksuksa dFku I rFkk dFku II vlR; gSA
15. lwph–I dh enksa dk feyku lwph–II ls feyku
dhft,A
lwph–I lwph–II

(1) dsoy (A), (B), (E) (2) dsoy (B), (D) (xq.k/keZ) (mnkgj.k)

(a) izfrpqEcdRo (i) MnO

(3) dsoy (C), (D) (4) dsoy (A), (C), (D)
13. uhps nks dFku fn, gSaA ,d vfHkdFku A gS vkSj
nwljk dkj.k R gSA
vfHkdFku A : dk¡p dh iSuh /kkj] dks xyukad rd
xeZ djus ij] fpduh gks tkrh gSA
dkj.k R : xyus ij dk¡p dh ';kurk ?kV tkrh gSA
uhps fn, x;s fodYiksa esa ls lokZf/kd mfpr mÙkj
(b) QsjhpqEcdRo (ii) O2
(c) vuqpqEcdRo (iii) NaCl
(d) izfryksg pqEcdRo (iv) Fe3O4
fuEufyf[kr fodYiksa esa ls lgh mÙkj pqfu,A
(1) (a)–(ii), (b)–(i), (c)–(iii), (d)–(iv)
(2) (a)–(i), (b)–(iii), (c)–(iv), (d)–(ii)
(3) (a)–(iii), (b)–(iv), (c)–(ii), (d)–(i)
(4) (a)–(iv), (b)–(ii), (c)–(i), (d)–(iii)
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pqfu, % Official Ans. by NTA (3)

(1) A lR; gS ijUrq R vlR; gSA 16. ,d ;kSfxd] ftlesa _.kk;u ?kuh; fufoM ladqfyr

(2) A rFkk R nksuksa lR; gS ijUrq R lgh O;k[;k O;oLFkk esa gS vkSj lHkh v"VQydh; LFky /kuk;u
ls v/;kflr gS] ds fy, ewykuqikrh lw=k AxB gSA x
ugha gS A dhA
dk eku gS_________A ¼fudVre iw.kk±d esa½
(3) A vlR; gS ijUrq R lR; gSA

(4) A rFkk R nksuksa lR; gS vkSj R lgh O;k[;k gS

A dhA

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 ALLEN® Solid State 3
SOLUTION 6. Official Ans. by NTA (5)

1. Official Ans. by NTA (8) 10 -5

Sol. 1 mole KBr (= 119 gm) have moles SrBr2
100
Sol. 8
–7
and hence, 10 moles cation vacancy
2. Official Ans. by NTA (9076) 2+
(as 1 Sr will result 1 cation vacancy)
Sol. FCC,
\ Required number of cation vacancies
Z´M 4 ´ 63.54
d= =
NA ´ a 3
1000 ´ 6.022 ´ 10 23 ´ (3.596 ´ 10 -10 ) 3 10 -7 ´ 6.023 ´ 1023
= = 5.06 ´1014 ; 5 ´1014
= 9076 kg/m3 119
3. Official Ans by NTA (1) 7. Official Ans. by NTA (2)

Sol. If number of lattice points are N. Sol. M 2 A6

12 ´
3
then effective octahedral voids = N
M8A6
So, octahedral voids / lattice site = 1
4. Official Ans. by NTA (33) M4A3

Sol. For BCC 3 a = 4r 8. Official Ans. by NTA (4)

Sol. Covalent or network solid have very high
3
so r= ´ 27 melting point and they are insulators in their
4
solid and molten form.
for FCC a = 2 2 r
9. Official Ans. by NTA (8)
3 Sol. Carbon atoms occupy FCC lattice points as well
= 2´ 2´ ´ 27
4 as half of the tetrahedral voids
3 therefore number of carbon atoms atoms per
= ´ 27
2 unit cell = 8
= 33 10. Official Ans. by NTA (106)
5. Official Ans. by NTA (15) M
4´
Sol. HCP structure : Per atom, there will be one æ gm ö NA
Sol. dç ÷= 3
octahedral void (OV) and two tetrahedral è cc ø (a cm)

voids (TV). 4 ´ M / 6.022 ´ 10 23

7.62 = Þ M = 105.8 g / mol
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Therefore total three voids per atom are present (0.4518 ´ 10 -7 cm)3

in HCP structure. 11. Official Ans. by NTA (3)

® therefore total no of atoms of Ga will be- Sol. a ¹ b ¹ c and a = g = 90º ¹ b
Mass 0.581g are parameters of monoclinic unit cell.
= ´ NA = ´ 6.023 ´ 1023
Molar Mass 70g / mol 12. Official Ans. by NTA (4)
® Now, total Number of voids = 3 × total no. Sol. (A) Crystalline solids have definite arrangement
of atoms of constituent particles and have long range order.
0.581 21 (C), (D) Different constituent particles of an
= 3´ ´ 6.023 ´ 10 23 = 14.99 × 10
70 amorphous solid have different bond strengths
; 15 ´ 10 21
and soften over a range of temperatures.

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4 Solid State ALLEN®
13. Official Ans. by NTA (2)
Sol. Hence given statement (A) is not correct
But statement (B) is correct
14. Official Ans. by NTA (3)
Sol. Theory based.
15. Official Ans. by NTA (3)
16. Official Ans. by NTA (1)
Sol. Anions froms CCP or FCC (A–) = 4 A– per unit
cell
Cations occupy all octahedral voids (B+) = 4 B+
per unit cell
cell formula ® A4B4
Empirical formula ® AB

® (x = 1)

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