Version: 1

Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Section 1: Identification of the substance/mixture and the company

1.1 Product identifier
Product name: ROMBEST® GREEN PS 58152

Product form: Mixture

Chemical composition: Mixture of additives and pigments in PS carrier – see Technical Data Sheet
for more information

1.2 Relevant identified uses of the substance /mixture and uses advised against

1.2.1Use of substance /mixture Description of Uses:

Industry sector: Plastic processing industry.
Type of use: Colorant for plastic material processing

1.2.2 Uses advised against

1.3. Details of the supplier of the safety data sheet

ROMCOLOR 2000 SA
1, Salcamului St, Copaceni 077006, Ilfov Romania
Tel. no.: +40/21/3166920;21;22;23;24
Fax no.: +40/21/3166927
Web site: www.romcolor.ro
Email address: service@romcolor.ro

1.4 Emergency phone number

+40/21/3166920;21;22;23;24 ROMCOLOR 2000 SA (Monday to Friday 9:00 a.m-17:00 p.m)
+40/21/318 36 06 National Institute for Public Health (Monday to Friday 8:00 a.m-15:00 p.m)

Section 2: Hazard identification

2.1 Classification of the substance/ mixture

Page 1 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

According to Art. 18, paragraph 3 point a) Regulation of the European Parliament and Council
Regulation (EC) No 1272/2008 (CLP)

- this product is not classified as dangerous mixture

2.2 Label elements

The product is a mixture containing polymers and is subject to derogation from the labeling
requirements in accordance with Article 23 of the Regulation of the European Parliament and Council
Regulation (EC) No 1272/2008 (CLP).
In accordance with the provisions of section 1.3 of Annex I to CLP, mixtures containing polymers and
mixtures containing elastomers do not require labeling in accordance with Annex I, if they do not
pose a threat to human health by inhalation, ingestion or contact with skin or to the aquatic
environment in the form in which they are placed on the market, although they are classified as
hazardous in accordance with Annex I (section 1.3.4.1.). Instead, the supplier shall provide the
information to end users or distributors by means of the safety data sheet (section 1.3.4.2.)

2.3. Other hazards

Other hazards
This mixture does not meet the vPvB criteria of REACH regulation, annex XIII.
• Avoid the formation and spread of dust generated as a result of grinding product (e.g.
milling) and the accumulation of dust.
• Risk of dust explosion when grinding granulated particles of small size or the presence of
fine dust of the product.
• The product may accumulate static electricity, which could cause combustion.
• Dust can cause irritation to the eyes, respiratory system and skin.
• Molten material can cause severe burns.
• During the heating of the material, there can be formed steams and fumes irritating and
harmful to the health (see subsection 10.6).
• Spilled pellets create the risk of slipping on hard surfaces.

Section 3: Composition /Information on ingredients

3.1 Substance: Not applicable

3.2 Mixture
Chemical characterization:

Page 2 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Mixture containing polystyrene, titanium dioxide(main ingredient)

Hazardous component. None to our knowledge.

Section 4: First –aid measures

4.1 Description of first aid measures

• Skin contact
Molten material can cause severe burns. In case of contact of molten polymer with skin do
not abrade the skin-Cool the burn with water, cover the burn and seek medical advice. In case
of skin exposure to product dust, wash with water and soap and rinse thoroughly.
• Eye contact Rinse opened eye for several minutes under running water. Exposure to splashing
of hot product treat the eyes with cold water –seek medical advice.
• Inhalation
In case of exposure to fumes or vapors produced by heated or burned product move
The effected person to fresh air. Seek medical advice if the person continues to feel
unwell.
• Ingestion
In case of swallowing seek medical treatment.

Section 5: Fire - fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Dry powder, water spray or foam (for larger fires )

Unsuitable extinguishing media:

High power water jet

5.2 Special hazards caused by the substance or mixture

In case of fire the following can be released: smoke, Styrene-Monomer, aldehydes and acids
(organic), carbon monoxide and carbon dioxide (CO2).

5.3 Advice for fire fighters

Wear self –contained respiratory device in case of risk of exposure to vapor or fumes.

Section 6: Accidental release measures

Page 3 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

6.1. Personal precautions, protective equipment and emergency procedures

Do not allow bystanders and unauthorized personnel. In the case of releasing large quantities of
product, label area with warning signs. To work related to the elimination of the consequences of
accidental release refer a person trained and equipped with personal protective equipment (see
section 8).

Avoid the scattering of dust in the air (e.g. when cleaning dusty surfaces with compressed air).
Remove sources of ignition, do not smoke and do not use sparking tools (risk of dust explosion).

Ensure adequate ventilation. Do not inhale dust. Avoid direct contact with spilled product and remove
product dust from contaminated clothing. Surfaces contaminated with granulate may be slippery.

6.2. Environmental precautions

Prevent product from entering drains, surface water and groundwater, basements and other
enclosed low-lying spaces.

6.3. Methods and material for containment and cleaning up

Small amounts of spillage should be collected in suitable, closed and labelled containers and be
disposed of. When collecting large quantities, you can use vacuum dust removal equipment. In the
case of pollution of water reservoirs, reduce the released granules by means of protective booms.
The collected product must be placed in a sealable container appropriately labeled, to be disposed of
or recycled.

Section 7: Handling and storage

7.1. Precautions for safe handling

Comply with general hygiene principles and safety regulations for working with.
Avoid contact with skin and eyes. Be sure to avoid contact with the molten product - melted product
can cause severe skin burns and eye damage.
Avoid the formation and spread of product dust and dust accumulation. Be particularly careful while
performing tasks associated with grinding (e.g. milling granules). Dust of the ground /crushed/
product poses a risk of explosion. Comply with the regulations regarding the presence at the
workplace of an explosive atmosphere.
Do not use the product near an open flame, heat or other sources of ignition. Do not expose the
product to direct sunlight. Forbid smoking.
The product may accumulate static electricity (e.g. as a result of friction occurring during mixing and
handling). Take measures to prevent the accumulation of electrostatic discharge (proper grounding,

Page 4 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

bridging). Use non-sparking equipment. Do not breathe dust. Do not inhale fumes and vapors formed
during heating of the product. Provide adequate ventilation, including local exhaust ventilation.
Wear appropriate personal protective equipment (see section 8). Product dirty clothing and shoes
should be removed and cleaned/washed before reuse.
Observe the rules of hygiene. Do not eat, drink or smoke while handling the product, except in places
designed for this; wash hands before breaks and after work.

7.2 Conditions for safe storage including any incompatibilities

Store in roofed, dry, well ventilated places at room temperature and at atmospheric pressure in
original unopened packaging (plastic), or in silo made of appropriate material (aluminium staineless
steel). Avoid dust accumulation by use of filters in pneumatic transport equipment.Avoid static
electricity build up with connection to earth. Store away from heating sourses.Protect the product
from moisture. Keep away from oxidizers and other incopatible substances (Section 10) .

Section 8: Exposure controls/Personal protection

8.1 Control parameters

Data below applies for Titanium Dioxide

Occupational exposure limits

UK. EH40 Workplace Exposure Limits (WELs)

Material Type Value

Form

Titanium dioxide (CAS TWA 4 mg/m3

Respirable
13463-67-7)
10 mg/m3
Inhalable
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Follow standard monitoring procedures.
procedures
Derived no effect levels (DNELs)
Workers
Product Value Assessment factor
Notes
Titanium dioxide (CAS 13463-67-7)
Long-term, Local, Inhalation 10 mg/m3 3

Page 5 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Predicted no effect concentrations (PNECs)

Product Value Assessment factor
Notes
Titanium dioxide (CAS 13463-67-7)
Freshwater 0.184 mg/l
Intermittent releases 0.193 mg/l
Marine water 0.0184 mg/l
Sediment (freshwater) 1000 mg/kg 100
Sediment (marine water) 100 mg/kg 1000
Soil 100 mg/kg 10
STP 100 mg/l 10

8.2 Exposure controls

Appropriate engineering controls
Ventilate as needed to control airborne dust. Provide adequate ventilation. Observe Occupational
Exposure Limits and minimise the risk of inhalation of dust.
Individual protection measures, such as personal protective equipment
General information
Personal protective equipment should be chosen according to the CEN standards and in discussion
with the supplier of the personal protective equipment.
Eye/face protection Wear dust-resistant safety goggles where there is risk of eye contact.
Skin protection
- Hand protection Wear suitable gloves. Suitable gloves can be recommended by the glove supplier.
- Other Wear appropriate clothing to prevent repeated or prolonged skin contact.
Respiratory protection In case of inadequate ventilation or risk of inhalation of dust, use suitable
respiratory equipment with particle filter (type P2). Seek advice from local supervisor.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Hygiene measures. Do not breathe dust. Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.
Environmental exposure controls. Contain spills and prevent releases and observe national
regulations on emissions.

Section 9: Physical and chemical properties

9.1 Information on basic physical & chemical properties

Physical state: solid

Appearance: granule

Page 6 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Color: green
Odor: slightly perceptible
Odor threshold: No measurement data
pH: N/A - insoluble solid
Melting point: No data
Boiling point/range: No data available
Flash point: No data available
Relative evaporation rate (butyl acetate=1): No data available
Flammability (solid, gas): polymer and organic additives are flammable; no component has been
classified as flammable according to the CLP criteria
Upper / lower flammability limit or explosive point: No data available
Vapor pressure: No data available
Relative vapor density at 20oC: No data available
Density [g/cm3]: no measurement data
Solubility: insoluble in water (<0.01 mg/l)
Partition coefficient polypropylene - technically not feasible n-octanol / water: No data available
Self-ignition temperature: No data available
Decomposition temperature: > 300 ° C
Viscosity: N/A - solid
Explosive properties: the risk of dust explosion in the event of fragmentation of the product into
particles of small size
Oxidizing properties: no data available

9.2. Further information

The product may be statically charged. Static electricity may build up during handling of the product.
It is therefore recommended that suitable safety procedures are defined and that production
equipment is fitted with an earth connection.

Section 10: Stability and reactivity

10.1 Reactivity
May be dissolved in solvent: styrene

10.2 Chemical stability

Stable under normal conditions of use

10.3 Possibility of hazardous reactions

No information available

Page 7 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

10.4 Incompatible materials

See 10.1

10.5 Conditions to avoid

Avoid dust generation and accumulation. Avoid static discharge (see chapter 7). Avoid
elevated temperature for prolonged time (see chapter 7). Extreme heat, ignition sources

10.6 Hazardous decomposition products

In case of combustion, the following can be released: smoke, Styrene-Monomer, aldehydes and
acids(organic),carbon monoxide and carbon dioxide (CO2).

Section 11: Toxicological information

11.1 Information on toxicological data
The data below applies for Titanium Dioxide
General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation Dust may irritate respiratory system.
Skin contact Dust may irritate skin.
Eye contact Dust may irritate the eyes.
Ingestion Ingestion may cause irritation and malaise.
Symptoms Dusts or powder may irritate the respiratory tract, skin and eyes. Coughing. Frequent
inhalation of
dust over a long period of time increases the risk of developing lung diseases.
11.1. Information on toxicological effects
Acute toxicity May cause discomfort if swallowed.
Skin corrosion/irritation Dust may irritate skin. Skin irritation occurs on contact with moist or wet
skin.
Serious eye damage/eye irritation Dust may irritate the eyes. Dust in the eyes: Exposed individuals
may experience eye tearing, redness, and discomfort.
Respiratory sensitisation Based on available data, the classification criteria are not met.
Skin sensitisation Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Suspected of causing cancer. IARC has classified TIO2 as 2B Possibly carcinogenic to
humans.
However, the only evidence of carcinogenicity is in rats exposed to very high concentrations. Two
major epidemiology studies among titanium dioxide workers in the US and in EUROPE could not
demonstrate an elevated lung cancer risk.
Boffetta et. al. Mortality among workers employed in the titanium dioxide production industry in
Europe. Cancer Causes Control. 2004 Sep;15(7):697-706.

Page 8 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Fryzek et. al. A cohort mortality study among titanium dioxide manufacturing workers in the
United States. J Occup Environ Med. 2003 Apr;45(4):400-9.
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. IARC Monographs,
Volume 93 (Summary)
IARC Monographs. Overall Evaluation of Carcinogenicity
Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity -single exposure
Based on available data, the classification criteria are not met.
Specific target organ toxicity -repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard Not classified.
Mixture versus substance information Not available.
Other information No other specific acute or chronic health impact noted.

Section 12: Ecological information

Data available for Titanium Dioxide
12.1. Toxicity The product is not expected to be hazardous to the environment.
12.2. Persistence and degradability The degradability of the product has not been stated.
12.3. Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low
water solubility of this product.
Partition coefficient n-octanol/water (log Kow) Not available.
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil The product is insoluble in water and will sediment in water systems.
12.5. Results of PBT and vPvB assessment
Not a PBT or vPvB substance or mixture.
12.6. Other adverse effects Not established.

Section 13: Disposal Considerations

Must be disposed, according to local regulations.
Non contaminated packaging may be recycled. Packaging that may not be clean are to be disposed
of in the same manner as the product.

Section 14: Transport information

Page 9 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

14.1. UN number: Not applicable

14.2. UN proper shipping name: Not applicable

14.3. Transport hazard class(es): Not applicable

14.4. Packing group: Not applicable

14.5. Environmental hazards: Not applicable

14.6. Special precautions for user: Not applicable

14.6. Special precautions for user: Not applicable

Section 15 : Regulatory information

Labelling:
This product is not under obligation of labeling according to Regulation (EC) No. 1272/2008 (CLP),
enclosure I, paragraph 1.3.4.1.: "Mixtures containing polymers are not under obligation of labeling
according to this supplement if they do not pose any danger to human health in case of inhalation,
ingestion or skin contact or the aquatic environment in the form in which they are marketed even
though they are classified as dangerous according to the criteria in this supplement."

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006
concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH),
establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council
Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (in the
corrected version OJ L 136, 29.05.2007 p. 3, with subsequent amendments)

Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of
the European Parliament and of the Council on the Registration, Evaluation, Authorization and
Restriction of Chemicals (REACH) (Text with EEA relevance). OJ L 132/8, 25.05.2015 p. 8.

Section 16: Other information

List of symbols indicating the hazard class and the H-Statements which are provided in Sections 2
and 3 of the SDS and their full meaning:
None

Page 10 of 11
 Version: 1
Date of issue: 15/01/2020

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006

Precautionary statements (CLP):

None
Disclaimer:
The information in this Data Sheet applies only to the products designated herein and produced or
supplied by us .It is based on our experience and on the data available to us at the time of its issue and
is accurate to the best of our knowledge The customer is strongly advised to observe and ensure that
its employees and customers observe all directions contained herein. However, no warranty is made
or implied that the information is accurate or complete and no liability will be accepted whatsoever
arising out of the use of the information or the products designated herein. Where third party products
are used in conjunction with or instead of products produced or supplied, customers should themselves
obtain all necessary technical, health and safety information about such products from the third party.

Page 11 of 11