JEEMAI

Topi
c:At
omi
cSt
ruct
ure Ti
me:1.
0Hr
s

I
nst
ruct
ions:

 At
temptal
lquest
ions

 Eachquest
ioncar
ry+4f
orcor
rectand-
1fori
ncor
rectanswer

Sect
ionA:
-

1-Foranelectr
oninahy dr
ogenatom,
thewavefuncti
onψi sproport
ional
exp(r
/a0)
, wher
ea0 is
theBohr’
sradius.Whatist
herat
iooft
heprobabi
li
tydensi
tytheelect
ronatthenucleustothe
probabi
l
itydensit
yata0

a)c b)c2 e2
c)1/ d)0

2-Theor
bit
alangul
armoment
um ofanel
ect
roni
n2s-
orbi
tal
is

a)h/
2∏ b)0 c)h/
2∏
h
d)2
2π

3-When4f
-lev
elofanat
om i
scompl
etel
yfi
l
ledwi
thel
ect
rons,
thenextel
ect
ronwi
l
lent
er

a)5s b)6s c)5d d)5p

4-Photoelectr
icemissionisobser
vedf r
om asurfaceforfr
equenci
esѵ1 andѵ2 oft
hei
nci
dent
radi
ati
on( ѵ1>ѵ2)
.Ifthemaximum K.E.ofthephot
oelect
ronsi
nthetwocasesarei nt
her
ati
o1:k
thenthethreshol
dfrequencyѵisgi
venby

ѵ2-ѵ1 kѵ
1-ѵ2 kѵ2-ѵ1
a) b) c) d)
k-1 k-1 k-
1
ѵ2-ѵ1
k

5-Thenucleusofanatom i
slocat
edatx=y
=z=0.I
fthepr
obabi
li
tyoffi
ndingans-
orbi
tal
-
5
elect
roni
nat i
nyvolumex=a, y=z=0i
s1x10 .Whatist
heprobabi
li
tyoffi
ndi
ngtheelect
roni
n
thesamesizedvolumearoundx=z=0,y=a?

a)1X10-5 b)1X10-5a c)1X10-5xa2 d)1X10-5xa-

1

6-I
fhund’
srul
eisnotf
oll
owed,
magnet
icmomentofFe2+,
Mn+andCral
lhav
ing24el
ect
rons
wil
lbei
norder

a)Fe2+<Mn+<Cr b)Fe2+=Cr<Mn+ c)Fe2+=Mn+<Cr d)Mn+=Cr

<Fe2+

7-Thewav
elengt
hisequal
tot
hedi
stancet
rav
ell
edbyt
heel
ect
roni
nonesecondt
hen

h h
a)λ=h/
v b)λ=h/
m c)λ= d)λ=
p m

8-Theworkf
uncti
onforamet ali
s4eV.Toemitaphot
oel
ect
ronofzer
ovel
oci
tyf
rom t
he
surf
aceofmetal
,thewav
elengthofi
nci
dentl
i
ghtshoul
dbe

a)27000A⁰ b)1700A⁰ c)5900A⁰ d)3100A⁰

9-I
nanatom t
woelect
ronsmovearoundt
henucleusincir
cularor
bit
sofr
adi
iRand4R.The
rat
iooft
het
imetakenbythem t
ocomplet
eonerevolut
ionis

a)1:
4 b)4:1 c)1:
8 d)8:
7

10-Thedist
anceofcl
osestappr
oachofanα-parti
clef
ir
edtowar
dsanucl
euswithmoment um
pisr.Whatwil
lbethedi
stanceofcl
osestappor
achwhenthemomentum ofα-
part
icl
eis2p?

a)2r b)4r c)r

/2 d)r
/4

11-Thenumberofwav
esmadebyaBohrel
ect
roni
nanor
bitofmaxi
mum magnet
icquant
um
number+2

a)3 b)4 c)2 d)1

12-Thewav
efunct
ion(
ψ)of2si
sgi
venby

Atr
=r0,
radi
alnodei
sfor
med.Thus,
for2s,
r0i
nter
msofa0i
s

a)r
0=a0 b)r
0=2a0 c)r
0=a0/
2 d)r
0=4a0

13-Theangul
armomentum ofel
ect
roni
nLi
2+wasf
oundt
obe(
7h/
2∏)
.Thedi
stanceoft
he
el
ectr
onfrom nucl
eusi
s

a)1.
69A b)0.
68A c)2.
82A d)8.
19A

14-Therati
ooft
heener gyoft
heel
ect
roni
ngr
oundst
ateofhy
drogent
otheel
ect
roni
nfi
rst
3+
exci
tedstat
eofBe i s

a)1:
4 b)1:
8 c)1:
16 d)16:
1

15-Maxi
mum v
alue(
n+l
+m)f
orunpai
redel
ect
ronsi
nsecondexci
tedst
ateofchl
ori
neCl
-17i
s

a)28 b)25 c)20 d)None

16-Whenacer tainmetalwasi rr
adi
taedwithli
ghtoff requency3.2x1016Hz.t hephot
o
el
ectronsemit
tedhast wicet heki
neti
cenergyasdi dphotoel
ecronsemit
tedwhenthesame
16
metalwasir
radiatedwi
thlightoffr
equency2.
5x10 Hz.Thet hr
eshol
dfr
equencyoft
hemetal
15
i
s…..10 Hz

a)18 b)20 c)22 d)16

17-I
ftheabov
eradi
alpr
obabi
l
tycur
vei
ndi
cat
es2sandor
bit
al,
thedi
stanebet
weent
hepeak
poi
ntsxandyis

a)2.
07A b)1.
59A c0.
53A
d)2.
12A

18-Whati
sthemaxi
mum numberofel
ect
ronsi
nanat
om t
hatcanhav
ethequant
um number
n=4,ml=+1?

a)4 b)15 c)3 d)6

19-Hydr
ogenli
kei
onhast
hewavel
engt
hdiff
erencebet
weenthefi
rstl
i
nesofbal
merandl
yman
seri
esequal
to33.
4nm.Theat
omicumberofthati
onisequal
to

a)4 b)3 c)2 d)5

20-Theradi
usoftheorbiti
nthehy
drogenat
om i
s0.
8464nm.Thev
eloci
tyofel
ect
roni
nthi
s
3
orbi
t(i
ntheorderof10 m/s)is

a)547 b)637 c)342 d)832

Sect
ionB:
-Int
egerTy
pequest
ion

21-Themax
imum numberofel
ect
ronst
hatcanhav
epr
ii
nci
plequant
um numbern=3andspi
n
quant
um numberms=-
1/2i
s…………….
.

22-Theworkfuncti
onofsomemet al
sisl
ist
edbelow.Thenumberofmetal
swhi
chwi
l
lshow
photoel
ect
ri
ceffectwhenl
ightof300nm wavel
engt
hfall
sonthemetal
is…….

23-I
nwhichquantum l
evel
doest
heel
ect
ronjumpsinHe+i
ont ogr
oundst
atei
fiti
sgi
venan
+
ener
gycorr
espondingt
o99%ofthei
oni
zati
onpotent
ial
ofHe ion?

24-Whatwil
lbethenumberofl
i
nescor
respondi
ngt
oLy
manser
ieswhenanel
ect
roni
sin3rd
exci
tedst
ateofhydr
ogenatom?

25-Fi
ndthequant
um number‘n’
cor
respondingtotheexci
tedst
ateofHe+ionifontr
ansi
ti
ont
o
thegr
oundstat
ethati
onemitstwophotosinsucessi
onwithwavelengt
hs1078.5and30.
4nm.