CONFI

DENTI
AL* ANSWERSET296
2/1

MODULPENGGAL1STPM 201
9
SET2

CHEMI
STRYMARKI
NG SCHEME

SECTI
ONA

NO ANSWER EXPLANATI
ON

1 A Lowerm/er atiowi lldef l

ec t
smor e
2 C Fe2+: no. ofel ec trons=24
s3d44s 2
Predi ctedc onf igurat ioni
s3d54s 1
Actualc onf igur ationi
High ers tabi li
t ywi thh alf-
fill
edd- orbital
s
3+
3 D Cr : no. ofel ec trons=21
Elect ronicc onf igur at on=3d3
i
3+
Al :no. ofel ec tr
ons=1 0
2 2 6
Elect ronicc onf igur at i
on=1 s 2s2p
Cu2+: no. ofel ec trons=27
Elect ronicc onf igur at on=3d9
i
3+
OnlyCr h as3unpai redel ect r
ons
4 B CH3CHOc annotf or mh ydrogenbondsasnoneofi t
sHat omsare
bondedt oas trong lyel ectroneg ativ
eat oms uchasO
5 D Met al sc onduc tel ec tri
cityinbot hsolidandmol t
enorliquid
states ,wh ilei onicc ompoundsonl yconductelect
ric
ityi
nt h
e
mol tens tate
6 A H2O -bent -
s hape( 1 04.
5 º
)
BF3 -t rigonalpl anar( 120º)
NH3 -t rigonalpy rami dal( 1
07º )
BeCl 2 – l
in ear (1 80º)
7 B PV=nRT
n(A)=( 1
01 )(50)
(8.
31 )(400)
=1 .
52mol
n(B)=1 .
94mol
n(C)=1 .
82mol
n(D)=0. 6 9mol
Ther efor e,th ev alueofn( B)ist hehighest
8 D
9 B Thef i
rstor derg r
aphofr atevs[ r
eac t
ant]shouldbet hatofa
straightli
nepas si
ngt hr
oughth eori
ginwithac onstantgradient
1
0 A Ther atewi threspecttoPandQi sfi
rstorderandz eroor der
respec ti
vely.Therefore,t
heg raphof[reactant]vstimef oraz ero
orderg raphwoul dbeas tr
aightli
newi thaneg ati
ves l
ope
1
1 C Cat al
ysth avenoef fectont h
epos iti
onofequi li
bri
umand
increasest herateoft heforwardandbac kwar dreactiontot h
e
sameex tent.Theequi l
ibri
umc onstantandt h
eent halpych angeare
unaf f
ec t
edbyc atal
y s
ts

1
CONFI
DENTI
AL* ANSWERSET296
2/1

1
2 D moldm-3)
A( (moldm-3) =moldm-3
(moldm-3)

moldm-3) -4
B ( =mol dm12
-
3 -
34
(
moldm )(
moldm )

moldm-3)2
C ( =moldm-3
(moldm-3)

moldm-3)
D( (moldm-3)=nouni
t
moldm-3)
( (moldm-3)

1
3 A No. esofH+
ofmol =2x0.
50x59/1000=0.
050mol
-
No.
ofmol
esofOH =0.
50x59/1000 =0.025mol
No.
ofmol
esofexcessH+=0.
050–0.
025 =0.025mol

H+]=0.
[ 025x1
000/1 25moldm-3
00=0.

pH=-
l H+]=-
og[ log(
0.25
)=0.
6

1
4 D Theh i
ghertheKs p, t
hemor es olublethes ubstance.Th ereforethe
sil
verc hlori
dei smor esolublet hansilv
erc hromat e(VI )
Addi ti
onofh ydroch l
ori
cac idandaqueouss odiumc hlor i
de
increasest heconc entr
at i
onofc hl
ori
dei onsint hesol ution,
t h
us
dec reasingthes ol
ubilit
yofs i
lv erchl
oride( commoni onsef fects)
Addi ngaqueousammoni adec reasesthec onc ent
rationofs i
lver
ions, (
commoni onsef f
ec t
s)andi ncr
eas est h
es olubilityofsilv
er
chlorideands il
v erchromat e(
VI )
Addi ti
ont henit
r ateionswillhav enoeffec tont heioni cproductof
theionsi nvolv
ed, andt huswoul dnotleadt opr ecipi
tat ion

1
5 B LetSol
ubi
li
tyofX( 2 =amo
OH) ldm-3

X(
OH)
2 X2+ +2OH-

X2+] OH-]2
Ksp=[ [
-1
1 2
1
.96x1
0 =( a)( 2a)
a =1
.70x1 0-4moldm-3

9. 0-3 =1
86x1 . 0-4
70x1
RMM
RMM =5 8.
0

TOTAL [
15]
MARK

2
 CONFI
DENTI
AL* ANSWERSET296
2/1

Sec
tionB(1
5mar
ks)
Ques
tion
Sug
ges
tedans
wer(
Sec
tionB[
15mar
ks]
) Mar
k
Number

1
6(a)

Cor
rectAxes+Corr
ectshape [
1]
Markallpoi
nts+Alll
abell
ed [
1]

(
b) Th
eph
asedi
agr
ami
ssi
mil
art
oth
atofwat
er. [
1]
Pmelt
satalowert
emperat
urewh
enpr
essur
eisi
ncr
eas
ed [
1]
bec
ausei
tsv
olumedecr
easesasi
tmelt
s. [
1]
(
c)
*Unl
ikemostsubst
ancest
hatmel
tatah
igh
ert
emper
atur
ewh
en
pres
sureisi
ncreased
(
d) Ondiagram(a) [
1]

3
CONFI
DENTI
AL* ANSWERSET296
2/1

Tot
al 6mar
ks

NO1
7 ANSWER MARKS

(
a) Orderwithres pectt oNOi ss
econdorder//2ndorder [
1]
Reason:Fr omex peri
ment3and4,bydoubl i
ng
(
i) t
h ec onc ent
rati
onofNO,th
er ateofr eact
ioni
squadr
upl
es.
Orcal
culati
on:
x y
Rat
e=k[ NO] [ H2]

Fr
omex peri
ment4and3:
x y x y
k(0.
0020)(0.
006
0)/k(0.
001
0)( 0.
0060)=1.20x
10-4/0.
30x
10-4
x 2
2 =2
x =2 [
1]
st
Orderwi t
hr espec ttoH2i sfi
r stor
der //1 order [
1]
Reas on:Fromex periment1and2,bydoubl ingthec onc ent
rat
ionof
H2,
t
her ateofr eacti
oni sdoubled.
Orc alculati
on:
Fromex peri
ment2and1 :
x y x y
k(0.0060)( 0.
0020)/k( 0.006
0) (0.
0010) =3.60x0-4/1
1 .80x
1 0-4
2x =21 [
1]
x =2
2
(
ii) Rat e=k[ NO] [H2] [
1]
2
(
b) Rat
e=k[
NO][H2]

Fromexperi
mentno. 1,
0-4=k( 2
1.
80x1 0.
0060) (0.
001
0) [
1]
0 mol dm6mi
3 -
2
k=5 .
00x1 n-1 (3s
igni
fi
cantf
igur
e) [
1]

(
c) Fr
omtheequat
ion,
Moler
ati
oofNO: H2=1:
1
1 [
1]
[
NO]=0.
006
0x (
0.0020)
2
[
1]
=0. 0moldm-3
005

Tot
al 9marks
Tot
al(
Q16+Q1
7) 1
5
marks

4
CONFI
DENTI
AL* ANSWERSET296
2/1

1
8a) (
i) Ionform/e43=
+
CH3CH2CH2 [
1]
and
+
CH3CHCH3 [
1]

Ionform/e45=
+
CH2CH2OH [
1]
and
+
CH(OH) CH3 [
1]
(
ii) Thealcoholisnot1
-pr
oponol//CH3CH2CH2OH [
1]

becausethemassspec
trumdoesnotc
ont
aint
he
foll
owingpeak,
whi
chisonl
ypossi
blef
or1-
propanol:
+ +
CH3CH2=29,CH2OH =31 [
1]+
[1]

Th er
efor
et h
ealcoholi
s2-pr
opanol
//CH3CH( OH)CH3. [
1]
(
iii
) Th espec
iescausethem/e=61peakis
13 +
CH3CH(OH)CH3 [
1]

1
8(b) (
i)

[
1]
Axis+ener gylevel
[
1]
Lymans eries+Bal mers eri
es
(
ii) Thelinewithth elongestwavelengthi
sgiv
enby [
1]
th
et ransit
ionofn= 3ton=2
(
c) Theel ect
ronicpredi c
tedbyAuf bauPri
nci
ple; [
1]
2 2
2s 2p63s2
3p64s2
Cu: 1
s 3d9

Act
ualelectr
onicc onf
igur
ati
on; [
1]
2 2 6 2 6 1 1 0
Cu:1s 2s 2p 3s 3p 4s3d

5
 CONFI
DENTI
AL* ANSWERSET296
2/1

Thi
sisbec
aus
eful
ly-f
il
led3dor
bit
alsh
asex
tra [
1]
st
abil
it
y.

Tot
almar
ks 1
5mar
ks

Mar
kSc
heme Mar
ks
1
9(a)
(i)Atequi
libri
um,
Rateofforwardreac ti
on=Rat
eofbac
kwar
dreac
tion
Or
2
k1[
H2][I2]=k-1[
HI]

Or
[
1]
=KC
Forar ever si
blereact
ion,acat
aly
stinc
reasestherat
eofbot ht
heforwar
d&r
ever
se [
1]
react
ions. [
1]
k1&k-1increase. [
1]
Ac at
alysth asnoeffectont
heposi
ti
onofequil
ibr
ium&finalc
omposi
ti
on. [
1]
KCremai nsconstant
.

[
1]
(i
i)Sincetheforwardreacti
onisendothermi
c, [
1]
th
einc r
easingintemperatureshi
ftsth
eposi
tionofequi
li
bri
umtot
heri
g h
t. [
1]
ThevalueofKCi nc
reases. [
1]
Thei ncr
eas i
ng intemper atur
e alsoincr
eases therate ofr
eac
tions i
n bot
h [
1]
di
recti
ons.
Si
nceKC= , k1↑ataf
ast
err
atet
hank-1.

(
b)

2HI(g) H2(
g) I2(
g)
Initial
ly(
mol) 1 0 0
ch ange -2x +x +x [
1]
Atequi li
bri
um(mol) 0.78 0.
11 0.1
1
[
1]
*
Fr omHI ,
1-
2x=0.78 Or 2x=0. 22
x=0.
1 1 x=0.11

2 [
1]
=(0.1
1)(0.1
1)/(
0.78)
-
2
=2.0x10 ( 2s
f)* nouni
t

6
 CONFI
DENTI
AL* ANSWERSET296
2/1

i
i. [
1]
2HI(
g) H2(g) I
2(g
)
Ini
tial
ly(
mol) 0 2 1
change 2x -x -
x
Atequili
bri
um(mol
) 2x 2-x 1
-x
[
1]

2
(
2-x
)(1
-x)
/(2x
) =2.
0x0-2
1
739moldm-3
x =0.
[
1]
[
HI]atequi
li
bri
um=2x
=2(
0.739)
=15moldm-3
. (
2sf
)
TOTALMARKS 1
6
MAXIMUM 1
5

7
 CONFI
DENTI
AL* ANSWERSET296
2/1

MarkSc
heme Marks
20.
(a)(i
) Azeot
ropi
cmi x
tureisamixt
ureoftwomisci
bleli
quidsth
ath
asacons
tant [1
]
boi
lingpoint
andthevapourthatexi
stsi
nequil
ibr
ium wi
ththeliqui
dandhast
hesame
compositi
on
asthel
iqui
d.

(
ii)

[
1]
[
1]
Label
ledaxes [
1]
Label
ledcurv
ed
(
mar
kph
asess
houl
dnott
ouc
hcur
ves
)
Sh
owmi
nimumpoi
nts

[
1]

(i
ii
)Wh enami xt
ur eof5 0%pr opan-1-olandtheper centageofwaterisals
o5 0%bymas s [ 1
]
i
s
disti
ll
edbyf rac t
ionaldistill
ation, [
1]+
[1]
theinit
ialboilingpointoc cursatT1andt hevapourt hatexi
stsi
nequili
bri
umh as [1
]
compos i
tionofC. [1
]
Thevapouri sricherinpr opan-1-olthanthes ol
utionwh er
eastheresi
duei sr
icherin [1
]
water.
Theboil
ingpoi ntgraduallyincreas es.
Ifvapourisati
onandc ondens ationprocessesar ec onti
nued,fi
nall
yt h
edis t
il
lat
e
wouldbe [1
]
anazeotropicmi xtur
eof28%wat er,72%propan-1-olandtheresi
dueispurewater.
[1
]

[
1]
(
iii
)Thewh i
tepr eci
pit
atedissol
vesanday ell
owpr ec
ipi
tateisfor
med.
Sil
verchlori
dei sspari
ng l
ysolubl einwat
er:
+ -
Ag Cl(s) Ag (
aq) +Cl(aq
)
+ -
Inthepresenc eofaqueouspot as si
umiodide,
theAg (
aq)i
onswillc
ombi
newi
tht
heI
(
aq)
i
ons
(fr
omKI
)tof
orms
ilv
eri
odi
dewh
ichi
syel
low.

Ag
Cl(s) +
Ag( ) +C
aq
-
l(
aq) [
1]
-
+I

Ag
I(s)

8
 CONFI
DENTI
AL* ANSWERSET296
2/1

Or
Th
isi
sbec
aus
eth
esol
ubi
li
typr
oduc
t(Ksp)ofAg
Iismuc
hlowert
hant
hatofAg
Cl.

TOTALMARKS 1
5