Atomic Structure

ATOMIC STRUCTURE
DPP - 1
JEE [MAIN + ADV.] DIVISION
HINT & SOLUTIONS

SINGLE CORRECT QUESTIONS
1. B
2. C
3. C
4. A
5. B
Mass of a neutron = 1.675 × 10–24 g mass of a proton =1.672 × 10–24
6. A
Carbon is 6 C12 and silicon is 14
Si 28 .
SUBJECTIVE QUESTIONS
23
7. 11, 23, 11, 11 Na
A ,A=N+P
ZX
8. 8, 10, 7
9. 32
NO3– = 7 + 8 × 3 + 1 = 32
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8 Page : 1
ATOMIC STRUCUTRE
DPP - 2
HINT & SOLUTIONS

1. A
Isobars have same mass number.
2. D
Each has 10 electrons.
In C H3 = 6 + 3 – 1 = 8 e
In H3 O+ = 3 + 8 – 1 = 10 e
3. C
4. B
5. B
6. D
7. C
ONE OR MORE OPTIONS MAY BE CORRECT

8. BD
Isotopes have same atomic number but different mass number.
9. BD
Isotones have same number of neutrons.
10 ABCD
Isoelectronic specis have same number of electrons.
11. 40, Calcium
2 (p + n) + 3p = 140  7x = 140  x = 20
 p = e = n = 20  Total number of nucleons = n + p = 40
 Element = Calcium
8 Page : 2
ATOMIC STRUCUTRE
DPP - 3
HINT & SOLUTIONS

1. B
E1  2 6000

E2 1 = 3000 = 2.
2. A
3. A
4. A
5. C
6. 7500 Å.
1
Maximum wave length will correspond to minimum frequency as   , and that is given for red

light in the spectrum.
C 3  10 8 m / s
max. =  = = 750 × 10–9 m.
min . 4  1014 m
 7500 Å.
7. 4
C 3  10 8 m / s
= = = 250 m = 0.25 km.
 1200  10 3 s 1
1 1 km
 = Wave no. = = 0.25 km = 4 wave per km.

8. (a) n =1 ; (b) 2.5 × 106 m–1

4 4 3
(a) R = R0A1/3  R3 = R 0 A
3 3
 V  A  n =1
 7.5 1014
(b) = = = 2.5 × 106 m–1
c 3 108
9. n = 16.
nhc
Use E= , Here n is number of protons.

10. 750 nm
hc 6.6  10 34  3  10 8
Photon absorb = = = 6.6 × 10–19 Joule
300  10 9 300  10 9
hc
One re-emitted photon energy = = 3.96 × 10–19 Joule
500  10 9
other photon have energy = 6.6 × 10–19 – 3.93 × 10–19 = 2.65 × 10–19 Joule.
8 Page : 3
ATOMIC STRUCUTRE
DPP - 4
HINT & SOLUTIONS

1. A
50
Eemitted = × Eabsorbed
100
50
No. of emitted photons × Energy of emitted photon = × No. of absorbed photon × Energy of
100
absorbed photon.
12400 50 12400
 5x × = × 8x × .
5000 100  (Å )
Å) = 4000 Å
COMPREHENSION
2. C
1/ 3
R1  A1 
=  

R2  A2 
1/ 3
1  A1 
 =  

2  A2 
A1 1
 =
A2 8
ratio of atomic mass number.
3. B
4 K Ze 2
r0 =
M0 v 20
4 K Ze 2
 2r0 =
M0 v  2
 r0 v02 = 2 r0 v2
v0
 v =
2
4. C
4 K Z e2
Given R =
M0 v 20
4K Z e2
 R = 2 = 4R
v 
M0  0 
 2 
4R  R
 % error = × 100 = 300 %.
R
8 Page : 4
5. 1.125 × 1022
nhc
Use E=

n  6.64  10 34  3  108

60 × 60 =
620  10 9
n = 1.125 × 1022
6. 25 %
12400
Energy of one photon = = 2 eV = 2 × 96 = 192 KJ mol–1
6200
192  144 48
 % of energy of photon converted to K.E. of A atoms = × 100 = × 100 = 25%
192 192
7. 6.32 × 106 m/s.

4Kze 2
Use R= .
m v  2
8. 1000 m
In one second, wave can travel distance =  ×  = 10 × 2.5 m = 25 m
In 40 seconds, it will travel = 25 × 40 m = 1000 m.
MATCH THE COLUMN

9. [A – q] ; [B – r] ; [C – s] ; [D – p].
Definition
8 Page : 5
ATOMIC STRUCUTRE
DPP - 5
HINT & SOLUTIONS

1. D
Only for Single electron species.
2. B
1  1 1 
 RZ2    ....... (1)
1  nC nA 
1  1 1
 RZ2    ....... (ii)
1 n
 C nB
1  1 1 
 RZ2   
3  nB nA 
1 1 1   1 1
   2 
3 1  2 1 2 3000
3 = 3000 Å.
3. C
12
For r = 0.52 Å ×
1
12
For L2+ r1 = 0.529 ×
3
r r
=3  r1 =
r1 3
4. C
r4 – r3 = 7 × r1
5. A
z
Use Vn = 2.185 × 108   cm/sec.
n
6. D
KZe 2
PE = – .
r
7. C
nh 2h
  n = 4,
2 

 2 2 
P.E. = 2(T.E.) = 2   13 .6  2  = – 6.8 eV..
 4 
8 Page : 6
8. C
50
Eemitted = × Eabsorbed
100
50
No. of emitted photons × Energy of emitted photon = × No. of absorbed photon × Energy of
100
absorbed photon.
12400 50 12400
 5x × = × 8x × .
5000 100  (Å )
Å) = 4000 Å
MATCH THE COLUMN
9. (A – s) ; (B – s) ; (C – p) ; (D – q, r).
(A) En–y  rn /Z
y
 Z2  1  n2 
  13.6 eV     0.529 Å 
 n2  z  Z 
   
y=1
nh
(B) n  nx   nx  x = 1
2
(C) Potential energy = 2 (total energy)
n3
(D) Tn   t=–2  m = – 3.
z2
8 Page : 7
TM
ATOMIC STRUCUTRE
DPP - 6
HINT & SOLUTIONS

1. B
EI Photon + EII Photon
= Esingle Photon
hc
hc 1 + hc  2 =

1 1 1
  =    = 5.25  10 8  7.25  108 = 12.5  10 8 = 8 x 10–10 m = 8 Å
1 2
2. D
Use : E 1 – E 2 / E 2 – E 3
3. B
r1 1 r3 9 r2 1
    
r2 4 r4 16 r4 4
1
So corresponding energy of ratio is E2 – E1 and E4 – E2.
4
4. B
R1 4 n12 n1 2 f1 n32 27
R2
= = 2 , hence
n2
= . So, f = 3 = .
9 n2 3 2 n1 8
5. D
Z3
Electrostatic force of attraction F 
n4
(Fn 3 )He  7 7
23 / 3 4  2 3 KZe 2
 (F ) 2  = =   =    x = –7 F=
n 2 Li 33 / 24 3 2 R2
6. A
Order of energy  Violet > Blue > yellow > red
Order of energy  E2  1 > E5  2 > E6  3 > E4  3
 Violet (2  1), Blue (5  2), yellow (6  3), Red (4  3)
8 Page : 8
7. B
Let the given transition for both the species is n1  n2
1 1
Then Xcm–1 = R × 22  2  2  For He+ ..... (i)
 n1 n 2 
1 1
and (wave no.) Be3+ = R × 42  2  2  For Be3+ ..... (ii)
 n1 n2 
From eq. (i) and (ii) (wave no.) Be3+ = 4x cm–1.
ONE OR MORE OPTIONS MAY BE CORRECT

8. A,B,D
BE for (n = 3) = 1.51 Z2 = 12 eV (given)
 Z2 = 12/1.51
I Excitation potential = 10.2 Z2 = 10.2  (12/1.51) = 81V
II Excitation potential = 12.09 Z2 = 12.09  (12/1.51) = 96eV
Ionisation potential = 13.6 Z2 = 13.6 (12/1.51) = 108 V
BE of (n = 2) = 3.4 Z2 = 3.4 x (12/1.51) = 27eV
8 Page : 9
TM
ATOMIC STRUCUTRE
DPP - 7
HINT & SOLUTIONS

1. B
Paschen series as for Paschan series nC = 3
2. A
In H – Spectrum, visible lines are only observed in Balmer series.
3. D
(E1)H = – 13.6 × (1)2 eV
13.6 eV
RH =
hc
13.6 eV = hc × RH
(E1H) = –13.6 eV = –hcRH
4. B
For lowest frequency, e must be minimum & for absorption it (e) should go from low to high.
8
3
2
5. D
Minimum energy required will be the energy required to excite up to lowest exited state that is
1st excited state
Hence (n = 2)
Energy req. = (E2 – E1) = 13.6 – 3.4 = 10.2eV
6. B
2  1 1
h0 = 13.6  Z  2  2 
 2 3 
2  1 1
h = 13.6  2   2  2 
2 3 
0 1
   = 40
 4
7. A
8. B
2  1 1 2 1 1
  RH  1  2  2   RH  2   2  2
2 3   nL nH 
2 2
 1 2  1 2   2  2 
            
 2   3    nL   nH  
8 Page : 10
On relative compairing
1 2
  nL = 4
2 nL
1 2
& 2  n  nH = 2 × 3 = 6
H
9. C
E3 – E2 = E
1 1 
13.6  Z2     E
4 9
36E
13.6 × Z2 = I.E. =
5
10. D
1 1 
  1 Balmer  R H  Z2   
4 9
5 5R H
 R H  Z2   .
36 36
8 Page : 11
ATOMIC STRUCUTRE
DPP - 8
HINT & SOLUTIONS

1. C
Series limit  Last line of series (nH  )
 1  2 1 1
   RH  1  2   R H   L   912Å

  L 1
  R H
 1  2  1 1  RH 4
   R H  1  2  2     B   4  912Å
   B 2   4 RH
2. A
Shortest ‘’ is always for longest or last line i.e. series limit :
1 1 1
  RH   912Å
 shortest L   L
  R H
3. A
Longest ‘’  1st line
1 2 1 1  3R H
 RH  1 12  22   4
1L  
4
1L  = 1215Å
3R H
4. A
1 1 2 1 1  5R H
  RH  1  22  32   36
  B  1 B
   
1 1 2  1 1  3RH
  R H  1  2  2  
 

B
 2 B 2 4  16
5
 2B   36 
80
 1B  3 108
16
80
(2B) =  6500Å = 4814 Å
108
5. A
1 R 41
 H    B    3664Å
  B 4 RH
8 Page : 12
6. D
n
P - Paschen
3
B - Balmer
2 L - Lyman
1
h = hP + hB + hL   = P + B + L
h = h’B + h’L   = ’B + ’L
h = h’’P + h’’L   = ’’P + ’’L
Above these information suggest that ‘n’ should be greater than ‘3’
Hence ace. to option (D) correct.
7. C
(E2 – E1)H = 10.2 eV
2
E2  E1 Be
3  E2  E1 H  2Be 
= 10.2 × (4)2 = 10.2 × 16
= 163.2 eV
8 Page : 13
ATOMIC STRUCUTRE
DPP - 9
HINT & SOLUTIONS
1. (A)
Z = 2 n1 = 2 n2 = 
 1 1 
 = R (2)2  22   2  = R
 
2. (D)
h1 = 13.6 eV
h 2 = 13.6 × 22 eV
3
h 3 = 13.6 × 22 × eV
4
 h 2 = h1 + h 3
  2 = 1 +  3
3. (D)
(i) Series limit of Lyman series  n =  to n = 1.
(ii) Series limit of Balmer series  n =  to n = 2.
En = 2 to n = 1 = En =  to n = 1 – En =  to n = 2
hC hC hC
=  – 
 1 2
1 1 1 1 2
=  –    =  
 1 2 2 1
4. (D)
Both the photons will not be absorbed by the electron of H-atom as the energy levels are quantised.
12400 12400
Sum of energies of both photons = + = 10 + 6.2 = 16.2 eV > (IE)H
1240 2000
5. (A, B)
(A) Only first four spectral lines belonging to Balmer series in hydrogen spectrum lie in visible
region.
(B) If a light of frequency  falls on a metal surface having work functional h , photoelectric effect
will take place only if   0, since 0 is the minimum frequency required for photoelectric effect.
6. (C)
n n  1
= 15
2
 n = 5  n–2=5  n=7
7. (D)
 1 1  5R
1 = R × 32  2  2  =
 2 3  4
8 Page : 14
32
2 = R × =R
32
5R R
2 – 1 = –R=
4 4
8. (B)
5
4
3 n1 n2 z
  1
2 n3 n 4 z 2
n=1
Clearly 2nd lowest energy is 4  3 transition
hence transition is Li 2+ having same energy is 9  12
9. [A  r, s] ; [B  p, s] ; [C  q, r, s] ; [D  p, q, s].
(A) 6  3 n = 3
3(3  1)
 no. of lines = = 6. All lines are in infrared region
2
(B) 7  3 n = 4
4( 4  1)
 no. of lines = = 10. All lines are in infrared region
2
(C) 5  2 n = 3
3(3  1)
no. of lines = = 6. All lines are in visible region
2
(D) 6  2 n = 4
4( 4  1)
no. of lines = = 10. All lines are in visible region.
2
10. (D)
 1 1
 = RcZ2  2  2 
 n1 n2 
1 1 3Rc
For 2  1 transition in H– atom sample,  = Rc(1)2  2  2  =
1 2  4
 (H)2  1 = (He )4  2 = (Li )6  3
+ 2+
Thus, given photon is not emitted from 8  3 transition in He+ ion sample.
8 Page : 15
ATOMIC STRUCUTRE
DPP - 10
HINT & SOLUTIONS

1. D
Only Spin quantum number (s) is not derived from Schrodinger wave equation.
2. D
3. D
4. B
5. C
number of electrons in subshells = 2 (2l + 1)
6. D
7. A
1
For n = 8 to n = 6, energy difference is minimum and   Energy
8. B
S1 : Photoelectric effect can be explained on the basis of particle nature of electromagnetic radiations.
S2 : n = 2,  = 1  2p-orbital  dumb-bell shaped.
S3 : dxy orbital has its lobes directed at an angle of 45º from X-axis and Y-axis. So, it has zero
probability of finding electrons along X-axis and Y-axis.
9. A
 h 
S1 : Angular momentum = mvr = n    Angular momentum  n.
 2 
S2 : An orbital can only accomodate 2 electrons with opposite spin.
S3 : s-orbital is non-directional in nature, rest all orbitals are directional.
8 Page : 16
ATOMIC STRUCUTRE
DPP - 11
HINT & SOLUTIONS

1. D
n = 4, m = – 3  only possible value of  is 3.
h 2 3h 3h
 Orbital angular momentum =  (  1) = = .
2 2 
2. A
Z = 26  [Ar]4s2 3d6
nn  2 = 24  n=4
In d orbital number of unpaired electron = 4 , but element have charge so 4s electron have to be
removed hence n+ = 2.
3. C
V (Z = 23), [Ar] 4s2 3d3 unpaired electron = 3 ;
Cr (Z = 24), [Ar] 4s1 3d5 unpaired electron = 6
Mn (Z = 25), [Ar] 4s2 3d5 unpaired electron = 5
4. C
For n = 4,   4, for  = 3, m  4
5. D
n
Total spin = 3  =3  n=6
2
i.e. magnetic moment = n(n  2) = 6(6  2) = 48 B.M.
.M.
6. D
25Mn – [Ar] 3d54s2
Given n(n  2) =
15  n=3
Hence to have ‘3’ unpaired electrons Mn must be in ‘+4’ state.
7. D
Magnetic moment = n(n  2)
8. C
Orbital angular momentum of electron
h h h
= (  1)  (  1) = 3   =3
2 2 
 number of orientations = 2  + 1 = 2 × 3 + 1 = 7
9. A
Configuration of the following elements
Cr3+ – [Ar] 3d3 clearly
Mn4+ – [Ar] 3d3 Fe3+ has 5 unpaired electrons and
3+
Fe – [Ar] 3d 5 Cr3+, Mn4+ has 3 unpaired electrons
10. 32
Maximum possible number of electrons in an atom with (n +  = 7) = 7s (2) + 6p (6) + 5d (10) +
4f (14) = 32
8 Page : 17
ATOMIC STRUCUTRE
DPP - 12
HINT & SOLUTIONS

1. C
Definition
2. C
12.3
= .
v
3. C
32
16 S = e– = 16
x +2 = e– = 16
( A = Z+ N)
4. B
(B) has same number of electrons i.e., 18.
[NH3  BH3] = 10 + 8 = 18.
5. (a) 21 (b) 8 (c) 12 (d) 1 (e) 1.

E.C.  1s2,2s2,2p6,3s2,3p6,3d1,4s2
6. (a) Co3+ : 1s2 2s2 2p6 3s2 3p6 3d6  4 unpaired electrons  µ = 4( 4  2) = 24 = 4.9 BM
(b) Number of radial nodes = n –  – 1
Number of radial nodes in 3p orbital = 3 – 1 – 1 = 1
(c) Number of electrons with (m = 0) in Mn2+ (1s2 2s2 2p6 3s2 3p6 3d5) ion = 1s (2) + 2s (2) + 2p (2)
+ 3s (2) + 3p (2) + 3d (1) = 11
(d) Orbital angular momentum for the unpaired electron in V4+ lies in 3d orbital.   = 2
h 6h
 Orbital angular momentum =  (  1) =
2 2
7. Number of unpiared electron are given by

Magnetic moment = [n(n  2)] B.M.
where n is number of unpaired electrons
or 1.73 = [n(n  2)] or 1.73 × 1.73 = n2 + 2n  n=1
Now Vanadium atom must have one unpaired electron and thus its configuration is
4+ : 1s2 , 2s2 2p6, 3s2 3p6 3d1
23V
8 Page : 18

Atomic Structure - DPP-1 To 12 - Sol.

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Atomic Structure - DPP-1 To 12 - Sol.

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HINT & SOLUTIONS

HINT & SOLUTIONS

ONE OR MORE OPTIONS MAY BE CORRECT

HINT & SOLUTIONS

8. (a) n =1 ; (b) 2.5 × 106 m–1

HINT & SOLUTIONS

n  6.64  10 34  3  108

7. 6.32 × 106 m/s.

MATCH THE COLUMN

HINT & SOLUTIONS

MATCH THE COLUMN

HINT & SOLUTIONS

From eq. (i) and (ii) (wave no.) Be3+ = 4x cm–1.

ONE OR MORE OPTIONS MAY BE CORRECT

HINT & SOLUTIONS

HINT & SOLUTIONS

HINT & SOLUTIONS

HINT & SOLUTIONS

HINT & SOLUTIONS

HINT & SOLUTIONS

5. (a) 21 (b) 8 (c) 12 (d) 1 (e) 1.

7. Number of unpiared electron are given by

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