VII Encontro Brasileiro de Espectroscopia Raman

VII EnBraER
05 a 08/12/2022, São Pedro – SP

Vibrational and magnetic properties of iron tungstate

(Fe2WO6) at low temperature
Raí F. Jucá (PG),1,*, Antônio J. R. de Castro (PQ),2 João M. Soares (PQ),3 José A. S. da Silva (PG),4 Francisco
G. S. Oliveira (PQ),5 Igor F. Vasconcelos (PQ),5 and Gilberto D. Saraiva (PQ),1.
1Faculdade de Educação Ciências e Letras do Sertão Central, FECLESC, Quixadá-CE; 2Universidade Federal do Ceará, Quixadá-
CE; 3Departamento de Física, Universidade do Estado do Rio Grande do Norte, Mossoró-RN; 4Departamento de Física,
Universidade Federal do Ceará, Fortaleza-CE; Pós-graduação em Engenharia e Ciências de Materiais, Centro de Tecnologia,
Universidade Federal do Ceara, Fortaleza-CE,

Palavras Chave: Fe2WO6, Raman spectroscopy, FTIR, magnetic properties, tungstate and Mossbauer.

Highlights
Synthesis of the iron tungstate Fe2WO6 and analysis by X-Ray diffraction (XRD);
Investigation of the magnetic properties of iron tungstate Fe2WO6 at low temperatures;
The magnetization versus applied field (MxH) curve and the electron paramagnetic resonance (EPR) spectroscopy.

Resumo/Abstract
In this research study, we report the synthesis of iron tungstate (Fe2WO6) through the solid-state reaction method. The
characterizations of Fe2WO6 was made using X-ray diffraction techniques; Raman and Fourier transform infrared
spectroscopy (FT-IR), vibrating sample magnetometer (VSM) and Mossbauer spectroscopy. The temperature
dependence Raman spectroscopy and vibrating sample magnetometer were measurements in a temperature range
of 300-10K. At room temperature, the crystal structure of Fe2WO6 was identified as having orthorhombic symmetry
structure and Pbcn space group (𝐷2ℎ 14), with one formula per unit cell (Z = 1). The magnetization versus applied field

(MxH) and the Mossbauer spectrum of Fe2WO6 at room temperature was discussed. The slight Raman spectral
changes occurring in the vibrations of the lattice modes and in the region of the internal modes. In addition, it was also
possible to observe changes in the (MxH) curve at low temperature.

Agradecimentos/Acknowledgments
The authors, acknowledges the support from the FUNCAP/CAPES/CNPq.