Disha 15 Mock Tests For NTA JEE Main 2022

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Mock Test-1 A-1 A-121

Table of Contents
Past JEE Advanced Numerical Value/Integer B-1–B-44

Type Questions (with Solutions)
Optional NVQs
Optional Numeric Value Questions (NVQs) Mock Test-1 C-1
Optional NVQs Solutions of Mock Test 1–15 C-16–C-32
How to Use this Book Effectively?

• While attempting a Mock Test the student has to attempt 25 Questions in each of the 3 sections.
• First 20 MCQs (Part I) in each section are compulsory. Physics – Q 1 to 20; Chemistry – Q26 to 45;
Mathematics – Q51 to 70;
• Further 5 Numeric Value Questions (NVQs given in Part II) out of 10 have to be attempted in each
section.
• The book provides 5 NVQs in each of the Part II of the 3 sections of the Mock Tests whereas the
Optional NVQs are provided at the end of the book.
For Example:
Mock Test 1
Subject Part I MCQs Part II NVQs Part II Optional NVQs
In respective Mock Test At the end of Book
Physics Q 1 - 20 Q 21 - 25 Q OP21 - 25
Chemistry Q 26 - 45 Q 46 - 50 Q OP46 - 50
Maths Q 51 - 70 Q 71 - 75 Q OP71 - 75
• OMR/Response Sheet has been provided at the end of each Mock Test and solutions are provided
at the end of the Book.
• In case of Optional Questions, the student should mark OP if he/she attempts any question from
the later set of Optional Questions.
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1
OPTIONAL NUMERICAL VALUE QUESTIONS (NVQS)
PHYSICS PART - II OC48. The heat of neutralization of strong base and strong acid
r r r r is 57.0 kJ. The heat released when 0.5 mole of HNO3 is
OP21. If for two vectors A and B, sum ( A + B) is added to 0.20 mole of NaOH solution in kJ is ______ .
r r
perpendicular to the difference ( A – B). The ratio of OC49. Among NH3, HNO3, NaN3 and Mg3N2 the number of
their magnitude is ______. molecules having nitrogen in negative oxidation state
OP22. The potential energy of a 1 kg particle free to move is _______ .
æ x 4 x2 ö OC50. Rate of a reaction can be expressed by following rate
along the x-axis is given by V ( x) = ç - ÷ J. expression
è 4 2ø Rate = k[A]2 [B], if concentration of A is increased by 3
times, and concentration of B is increased by 2 times,
The total mechanical energy of the particle is 2 J. Then,
how many times rate of reaction increases?
the maximum speed (in m/s) is ______.
OP23. In a meter bridge experiment null point is obtained at 20 MATHEMATICS PART - II
cm. from one end of the wire when resistance X is
balanced against another resistance Y. If X < Y, then -1 3p
OM71. If cos p + cos -1 1 - p + cos -1 1 - q = then
where will be the new position (in cm) of the null point 4
from the same end, if one decides to balance a resistance the value of q is equal to_________.
of 4 X against Y
OP24. A wheel of radius 0.4 m can rotate freely about its axis é1 2 3ù é x ù
as shown in the figure. A string is wrapped over its rim ê úê ú
OM72. If [1 x 1] ê0 5 1 ú ê 1 ú = O, then x = ________.
and a mass of 4 kg is hung. An angular acceleration of 8
êë0 3 2ûú êë -2ûú
rad s–2 is produced in it due to the torque. Then, moment
of inertia (in kg–m2) of the wheel is (g = 10 ms–2) OM73. The total number of local maxima and local minima of
ïì( 2 + x ) , -3 < x £ -1
3
the function f ( x )= í
23
ïî x , -1 < x < 2
is________.
OM74. A coin is tossed until a head appears or until the coin
4 kg has been tossed five times. If a head does not occur on
the first two tosses, then the probability that the coin
OP25. A TV tower has a height of 100m. By how much the height will be tossed 5 times is___________.
(in m) of tower be increased to triple its coverage range? OM75. A survey of 500 television viewers produced the
CHEMISTRY PART - II following information, 285 watch football, 195 watch
hockey, 115 watch basket-ball, 45 watch football and
OC46. Experimentally it was found that a metal oxide has formula basket ball, 70 watch football and hockey, 50 watch
M 0.98 O . Metal M, is present as M2+ and M3+ in its hockey and basket ball, 50 do not watch any of the
oxide. Fraction of the metal which exists as M3+ would three games. The number of viewers, who watch exactly
be_____________. one of the three games are_________.
OC47. What is the amount of chlorine evolved when 2 amperes
of current is passed for 30 minutes in an aqueous
solution of NaCl ?
C-2 Mock Test
2
PHYSICS PART - II OC47. The sum of number of electrons of bond pair and lone
pair of electrons in oleum is _______ .
OP21. A constant torque of 2000 N-m turns a wheel of moment
OC48. Given that heat of neutralization of strong acid and
of inertia 200 kg-m2 about an axis passing through its
strong base is – 57.1 kJ. The heat produced when 0.25
centre. Its angular velocity after 2 second is ____ rad/s.
mole of HCl is neutralized with 0.25 mole of NaOH in
OP22. The period of revolution of planet A around the sun is 8 aqueous solution is _______ .
times that of B. The distance of A from the sun is how
OC49. Calculate the total pressure in a 10.0 L cylinder which
many times greater than that of B from the sun? contains 0.4 g helium, 1.6 g oxygen and 1.4 g nitrogen at
OP23. When sound is produced in an aeroplane moving with 27 °C.
a velocity of 200 m/s horizontally its echo is heard after OC50. What will be the mass of oxygen liberated by
10 5 seconds. If velocity of sound in air is 300 m/s-1 decomposition of 200 mL hydrogen peroxide solution
the elevation of aircraft is _____ m. with a strength of 34 g per litre?
OP24. Two small spherical balls each carrying a charge MATHEMATICS PART - II
Q = 10mC (10 micro-coulomb) are suspended by two
insulating threads of equal lengths 1m each, from a point (cos x - 1) (cos x - e x )
OM71. The integer n for which lim is
fixed in the ceiling. It is found that in equilibrium threads x ®0 xn
are separated by an angle 60° between them, as shown a finite non-zero number is_________.
in the figure. What is the tension (in N) in the threads. OM72. Two lines are drawn through (3, 4), each of which makes
1 9 2 angle of 45° with the line x – y = 2, then area of the
(Given: 4pe = 9 ´ 10 Nm / C ) triangle formed by these lines is__________.
( 0)
OM73. The number of points at which the function
f(x) = |x – 0.5| + |x – 1| + tan x does not have a derivative in
60º the interval (0, 2), is_________.
OM74. If sum of two numbers is 6, the minimum value of the
sum of their reciprocals is____________.
Q Q OM75. Let the straight line x = b divide the area enclosed by

y = (1 - x ) , y = 0
2
and x= 0 into two parts
OP25. If a source is transmitting electromagnetic wave of
R1 ( 0 £ x £ b ) and R2 ( b £ x £ 1) such that
frequency 8.2 × 106 Hz. then wavelength (in m) of the
electromagnetic waves transmitted from the source will 1
R1 - R2 = . Then, b equals________.
be 4
CHEMISTRY PART - II
OC46. Uncertaintyin the position of an electron (mass = 9.1 × 10–31 kg)
moving with a velocity 300 ms–1, accurate upto 0.001% in
terms of x × 10–2m will be (h = 6.63 × 10–34 Js)
Mock Test C-3
3
OC48. Coagulation value of the electrolytes AlCl3 and NaCl
PHYSICS PART - II
for As2S3 sol are 0.093 and 52 respectively. How many
abc times AlCl3 has greater coagulating power than NaCl ?
OP21. The relation gives the value of P as P = . Find OC49. The measurement of the electron position is associated
7d
the percentage error in P if the percentage error in a, b, with an uncertainty in momentum, which is equal to
c and d are 2%, 2%, 2% and 4% respectively. 1×10–18 g cm s–1. The uncertainty in electron velocity in
terms of x × 10 cm/sec is _______ .
OP22. The vectors A and B are such that (mass of an electron is 9 × 10– 28 g)
OC50. A first order reaction is half completed in 45 minutes.
| A + B |=| A - B |
How long does it need 99.9% of the reaction to be
The angle between the two vectors is _____ . completed (in min.)
OP23. A lead bullet strikes against a steel plate with a velocity MATHEMATICS PART - II
200 ms–1. If the impact is perfectly inelastic and the heat OM71. If m and n are the order and degree of the differential
produced is equally shared between the bullet and the equation
target, then the rise in temperature of the bullet is ____ °C 3
(specific heat capacity of lead = 125 Jkg–1 K–1) æ d2y ö
5 ç 2÷
OP24. A parallel plate capacitor with air between the plates æ d2y ö ç dx ÷ 3
è ø + d y = x 2 - 1 , then value of
has a capacitance of 9 pF. The separation between its ç 2 ÷ +4
ç dx ÷ æ d 3 y ö dx 3
è ø
plates is 'd'. The space between the plates is now filled ç 3÷
ç dx ÷
with two dielectrics. One of the dielectrics has dielectric è ø
constant k1 = 3 and thickness d/3 while the other one m + n is_________.
has dielectric constant k 2 = 6 and thickness 2d/3. r r r
OM72. If a = (1, – 1, 2), b = (– 2, 3, 5), c = (2, – 2, 4) and iˆ is
Capacitance of the capacitor is now _____ pF.
the unit vector in the x-direction, then
OP25. If i1 = 3 sin wt, i2 = 4 cos wt, and i3 = i0 sin (wt + 53°), find r r r
the value of i0. (a – 2b + 3c ) iˆ = _______.
OM73. The value of f(0) so that the function
i1 i2
1 - cos(1 - cos x)
f (x) = is continuous everywhere
i3 x4
is________.
OM74. For all complex numbers z1, z2 satisfying |z1|=12 and
CHEMISTRY PART - II | z2 – 3 – 4i | = 5, the minimum value of |z1 – z2| is_______.
OC46. On passing a current of 1.0 ampere for 16 min and 5 sec
4q(tan q - sin q)
through one litre solution of CuCl2, all copper of the OM75. lim is_________.
solution was deposited at cathode. The strength of CuCl2 q®0 (1 - cos 2q) 2
solution was _______ . (Molar mass of Cu= 63.5;
Faraday constant = 96,500 C mol–1)
OC47. The amount of urea to be dissolved in 500 c.c. of water
(K = 1.86 °C mol–1) to produce a depression of 0.186 °C
in the freezing point is _______ .
C-4 Mock Test
4
PHYSICS PART - II OC48. Considering H2O as a weak field ligand, the number of
OP21. The period of oscillation of a simple pendulum is given unpaired electrons in [Mn(H 2O) 6 ]2+ will be______.
l (At. no. of Mn = 25)
by T = 2p where l is about 100 cm and is known to
g OC49. The heat of neutralization of HCl by NaOH is –55.9 kJ mol–
1. The energy of dissociation of HCN is :
have 1 mm accuracy. The period is about 2s. The time of
100 oscillations is measured by a stop watch of least (HCN + OH - ® CN - + H 2O; DH = -12.1 kJ)
count 0.1s The percentage error in g is _____ %. OC50. The osmotic pressure (at 27 °C) of an aqueous solution
OP22. A particle moves along a straight line such that its (200 mL) containing 6 g of a protein is 2 × 10–3 atm. If
displacement at any time t is given by R = 0.080 L atm mol–1K–1, the molecular weight of protein
S = 6t3 – 18t2 + 2 metres in terms of x × 105 is _______
The velocity when the acceleration is zero is ____ m/s. MATHEMATICS PART - II
OP23. A glass flask is filled up to a mark with 50 cc of mercury at
18°C. If the flask and contents are heated to 38°C, how OM71. The probability of India winning a test match against
much mercury (in cc) will be above the mark (a for glass 1
Westindies is assuming independence from match
is 9 × 10–6/°C and coefficient of real expansion of mercury 2
is 180 × 10–6/°C) to match the probability that in a 5 match series India's
OP24. A fish looking up through the water sees the outside second win occurs at the third test, is__________.
world contained in a circular horizon. If the refractive
OM72. From a point P (l, l , l), perpendiculars PQ and PR are
4 drawn respectively on the lines y = x, z = 1 and
index of water is and the fish is 12 cm below the
3 y = - x, z = -1. If P is such that ÐQPR is a right angle,
surface, the radius of this circle in cm is _____.
OP25. In optical communication system operating at 1200 nm, then the possible value (s) of | l | is (are)__________.
only 2% of the source frequency is available for TV æ 1 -1 1 ö æ 4 2 2ö
transmission having a bandwidth of 5 MHz. The number ç ÷ ç ÷
OM73. Let A = ç 2 1 -3 ÷ and 10 B = ç -5 0 a ÷ . If B is
of TV channels that can be transmitted is _____million. ç1 1 1 ÷ ç 1 -2 3 ÷
è ø è ø
CHEMISTRY PART - II the inverse of matrix A, then a is______.
OC46. An electrolytic cell contains a solution of Ag2SO4 and 2Z1 Z - Z2
have platinum electrodes. A current is passed until OM74. If is a purely imaginary number, then 1 is
3Z 2 Z1 + Z 2
1.6 g of O2 has been liberated at anode. The amount of
silver deposited at cathode would be _______ . equal to_________.
OM75. The letters of the word COCHIN are permutated and all
OC47. The graph between log æç x ö÷ and log p is a straight line the permutations are arranged in an alphabetical order
èmø as in an English dictionary. The number of words that
appear before the word COCHIN is__________.
at an angle 45° with intercept on y-axis at 0.3010.
Calculate the amount of gas adsorbed in gram per gram
of the adsorbent when the pressure is 0.2 atm.
Mock Test C-5
5
PHYSICS PART - II OC49. In sun's atmosphere, how many of the following form
are stable?
OP21. Two trains A and B each of length 400 m are moving on
Ortho-H, Para-H, Molecular-H
two parallel tracks in the same direction (with A ahead
OC50. In the hexagonal close packed structure of a metallic
of B) with same speed 72km/h. The driver of B decides
lattice, the number of nearest neighbours of a metallic
to overtake A and accelerates by 1m/s2. If after 50s. B
atom is _______ .
just brushes past A, calculate the original distance
(in m) between A and B. MATHEMATICS PART - II
OP22. If in a circular coil A of radius R, current I is flowing and
in another coil B of radius 2R a current 2I is flowing, OM71. If the scalar projection of the vectors xiˆ – ˆj + kˆ on the
then the ratio of the magnetic fields BA and BB, produced 1
by them at their centre will be _____. vector 2iˆ – ˆj + 5kˆ is , then value of | x | is equal
30
OP23. A projectile is thrown in the upward direction making to_______.
an angle of 60° with the horizontal direction with a
OM72. If cos–1x + cos–1 y + cos–1 z = p then x2 + y2 + z2 + 2xyz
velocity of 147 ms–1. Then the time after which its =________.
inclination with the horizontal is 45°, is _____ s.
OP24. A bar magnet has coercivity 4 × 103 Am–1. It is desired é1 -1ù éa 1 ù
to demagnetise it by inserting it inside a solenoid 12 cm OM73. If A = ê 2 -1ú , B = ê b -1ú and (A + B)2 = A2 + B2,
ë û ë û
long and having 60 turns. The current that should be then the values of a + b is_______.
sent through the solenoid is _____ A.
10 + x æ 200x ö
OP25. An isolated and charged spherical soap bubble has a OM74. Ifef (x) = , x Î (–10,10) and f (x) = kf ç ÷,
radius r and the pressure inside is atmospheric. If T is 10 – x è 100 + x 2 ø
the surface tension of soap solution, then charge on then k =_______.
drop is X pr 2rTe 0 then find the value of X. OM75. The number of integers satisfying the equation
CHEMISTRY PART - II 4 - x2 4 - x2
|x|+ = x+ is__________.
OC46. 6 × 1020 molecules of CO2 are removed from 220 x x
milligram of CO2. What are the remaining moles of CO2.
OC47. If enthalpies of methane and ethane are respectively
320 and 560 calories, then the bond energy of C — C
bond is _______ .
OC48. FeS2 + O2 ® Fe2O3 + SO2
In the above equation the number of electrons lost by
one molecule of FeS2 are –
C-6 Mock Test
6
PHYSICS PART - II O
OP21. The period of oscillation of a simple pendulum is given ||
NaOH
CH3 - CH = O + CH3 - C - CH 3 ¾¾¾¾ ®
l OC49. The volume of oxygen liberated from 0.68 g of H2O2 is
by T = 2 p where l is about 100 cm and is known to
g _______ .
have 1 mm accuracy. The period is about 2s. The time of
OC50. If 0.5 mol of BaCl2 is mixed with 0.2 mole of Na3PO4,
100 oscillations is measured by a stop watch of least
find the maximum amount of Ba3(PO4)2 that can be
count 0.1s. The percentage error in g is _____ %.
OP22. The figure shows a meter-bridge circuit, X = 12W and formed.
R = 18W. The jockey J is at the null point. If R is made MATHEMATICS PART - II
8W, through the jockey J have to be moved by 4 × A cm
to obtain null point again then find the value of A. OM71. Let the equation of the plane containing line
+ – x - y - z - 4 = 0, x + y + 2 z - 4 = 0 and parallel to the
line of intersection of the planes 2 x + 3 y + z = 1 = 0 and
X R
x + 3 y + 2 z = 2 be x + Ay + Bz + C = 0. Then the
value of A + B + C - 4 is_________.
OM72. For a point P in the plane, let d1 ( p) and d2 ( p) be the
A J B
distance of the point P from the lines x - y = 0 and x + y =
0 respectively. What is the area of the region R consisting
OP23. A gun of mass 10 kg fires 4 bullets per second. The of all points plying in the first quadrant of the plane and
mass of each bullet is 20 g and the velocity of the bullet satisfying 2 £ d1 ( P ) + d 2 ( P) £ 4, _________.
when it leaves the gun is 300 ms–1. The force required 2 2 2
OM73. If a + b + c = – 2 and
to hold the gun while firing is _____ N.
OP24. An air bubble in a glass slab (m = 1.5) is 5 cm deep when
viewed from one face and 2 cm deep when viewed from 1 + a2 x (1 + b 2 ) x (1 + c 2 ) x
2
the opposite face. The thickness of the slab is ____ cm. f (x) = (1 + a ) x 1 + b2 x (1 + c 2 ) x ,
OP25. A small disc of radius 2 cm is cut from a disc of radius 6
cm. If the distance between their centres is 3.2 cm, what (1 + a 2 ) x (1 + b 2 ) x 1 + c2 x
is the shift (in cm) in the centre of mass of the disc?
then f (x) is a polynomial of degree_________.
CHEMISTRY PART - II
OM74. 3 + i x2y and x2 + y + 4i are complex conjugate numbers,
OC46. In the first order reaction, the concentration of the
reactant is reduced to 25% in one hour. The half life then x2 + y2 =________.
period of the reaction is _______ . OM75. The following data give the distribution of heights of
OC47. How many isomeric naphthylamines are expected in the students :
following reaction ? Height
160 150 152 161 156 154 155
(in cm)
Br
NaNH , NH Number of
¾¾¾¾
2 ¾¾
3®
12 8 4 4 3 3 7
– 33°C s tudents
OC48. How many cross aldol products (without counting The median of the distribution is______.
stereoisomers) are produced in the following reaction?
Mock Test C-7
7
PHYSICS PART - II OC48. Cl – O bond order in perchlorate ion is _____.
OP21. The position vector of a particle is given as OC49. The solubility of AgCl in 0.2 M NaCl solution in terms
r of x × 10 M is _____.
r = (t 2 - 4t + 6)iˆ + (t 2 )ˆj . The time after which the
(Ksp of AgCl = 1.20 × 10–10)
velocity vector and acceleration vector become
perpendicular to each other is equal to _____ s. OC50. One mole of N2H4 loses 10 moles of electrons to form a
OP22. As per Bohr Model, the minimum energy (in eV) required new compound, Y. Assuming that all nitrogen appear in
to remove an electron from the ground state of doubly the new compound, what is the oxidation state of
ionized Li atom (Z = 3) is _____ eV. nitrogen in Y (there is no change in the oxidation state
OP23. A monkey of mass 20 kg is holding a vertical rope. The of hydrogen )?
rope will not break when a mass of 25 kg is suspended
from it but will break if the mass exceeds 25 kg. What is MATHEMATICS PART - II
the maximum acceleration (in m/s2) with which the
OM71. A coin is tossed n times. The probability of getting
monkey can climb up along the rope (g = 10 m/s2).
head at least once is greater than 0.8, then the least
OP24. The potential energy of a particle of mass m is given by
value of n is_______.
ìE 0 ; 0 £ x £ 1
U(x) = í OM72. If one of the diameters of the circle x2 + y2 – 2x – 6y + 6 = 0
î 0; x >1 is a chord to the circle with centre (2, 1), then the radius
l1 and l2 are the de-Broglie wavelengths of the particle, of the circle is_______.
when 0 £ x £ 1 and x > 1 respectively. If the total energy OM73. The area of the region, bounded by the curves
l1 y = sin -1 x + x (1 - x ) and y = sin -1 x - x (1 - x ) in the
of particle is 2E0, then ratio will be_______.
l2 first quadrant, is_______.
OP25. A 2 kg block slides on a horizontal floor with a speed of
4m/s. It strikes a uncompressed spring, and compresses 40
OM74. If the combined mean of two groups is and if the
it till the block is motionless. The kinetic friction force is 3
15N and spring constant is 10,000 N/m. The spring mean of one group with 10 observations is 15, then
the mean of the other group with 8 observations is
compresses by ____ cm. equal to_______
CHEMISTRY PART - II OM75. The value of a for which the function
1 p
OC46. 6.8 g H2O2 present in 100 mL of its solution. What is f ( x ) = a sin x + sin 3 x has an extremum at x =
the molarity of solution? 3 3
OC47. The ionization enthalpy of hydrogen atom is________.
is 1.312 × 106 J mol–1. The energy required to excite
the electron in the atom from n = 1 to n = 2 in terms of
x × 105 J/mol is _____.
C-8 Mock Test
8
PHYSICS PART - II OC48. The half-life of 2 samples are 0.1 and 0.4 seconds. Their
OP21. Two stones are projected from the same point with same respective concentration are 200 and 50 respectively.
speed making angles (45° + q) and (45° – q) with the What is the order of the reaction
OC49. The energy of an electron in the 3rd orbit of an atom is –
horizontal respectively. If q £ 45° , then the horizontal E. The energy of an electron in the first orbit will be x ×
ranges of the two stones are in the ratio of ____. E. What will be the value of x.
OP22. The force between two charges 0.06 m apart is 5 N. If OC50. If 500 mL of gas A at 400 torr and 666.6 ml of B at 600 torr
each charge is moved towards the other by 0.01 m, then are placed in a 3 litre flask, the pressure of the system
the force between them will become ____ N. will be ______ .
OP23. A fly wheel of moment of inertial 3 × 102 kg m2 is rotating
with uniform angular speed of 4.6 rad s–1. If a torque of MATHEMATICS PART - II
6.9 × 102 Nm retards the wheel, then the time in which
the wheel comes to rest is ____ s. OM71. The area bounded by the straight lines x = 0, x = 2 and
OP24. The primary and secondary coil of a transformer have a b
50 and 1500 turns respectively. If the magnetic flux f the curves y = 2 x , y = 2 x - x 2 is - then value
log 2 c
linked with the primary coil is given by f = f0 + 4t, where of a + b + c is_______.
f is in webers, t is time in seconds and f0 is a constant, r r r
the output voltage across the secondary coil is ____ OM72. If a = 3, b = 4 and the angle between ar and b be
volt. r r
OP25. A body weighs 72 N on the surface of the earth. What is 120°, then 4a + 3b is equal to_______.
the gravitational force (in N) on it due to earth at a OM73. If X follows a binomial distribution with parameters
height equal to half the radius of the earth from the
surface? 1
n = 100 and p = , then P(X = r) is maximum when r is
3
CHEMISTRY PART - II equal to_________.
OC46. On mixing 3 g of non - volatile solute in 200 mL of water, OM74. If a and b are the roots of 2x2 + 7x + c = 0 and
its boiling point (100 °C) becomes 100.52°C. If Kb for 7
water is 0.6 K/m then molecular wt. of solute is ______ . | a2 - b2 | = then c is equal to_______.
4
OC47. An electric current is passed through silver nitrate OM75. The value of |l|, for which the circle x2 + y2 + 2lx + 6y +
solution using silver electrodes. 10.79 g of silver was 1 = 0 intersects the circle x2 + y2 + 4x +2y = 0
found to be deposited on the cathode if the same amount orthogonally, is_______.
of electricity is passed through copper sulphate solution
using copper electrodes, the weight of copper deposited
on the cathodes is ______ .
Mock Test C-9
9
PHYSICS PART - II (Given : ionization energy of H=2.18 ×10–18J atom–1and
OP21. Two full turns of the circular scale of a screw gauge h = 6.625 × 10–34 J s )
cover a distance of 1mm on its main scale. The total OC48. In transforming 0.01 mole of PbS to PbSO4 the volume
number of divisions on the circular scale is 50. Further, of '10 volume' H2O2 required will be ______ .
it is found that the screw gauge has a zero error of OC49. KCl crystallises in the same type of lattice as does NaCl.
(– 0.03) mm. While measuring the diameter of a thin Given that r + / r - = 0.55 and r + / r - = 0.74.
Na Cl K Cl
wire, a student notes the main scale reading of 3 mm Calculate the ratio of the edge length of the unit cell for
and the number of circular scale divisions in line with KCl to that of NaCl.
the main scale as 35. The diameter of the wire is OC50. A weak electrolyte having the limiting equivalent
____ mm. conductance of 400 S cm2 g. equivalent–1 at 298 K is 2%
OP22. A capacitor with capacitance 5mF is charged to 5mC. If ionized in its 0.1N solution. The resistance of this
the plates are pulled apart to reduce the capacitance to solution (in ohms) in an electrolytic cell of cell constant
2mF, how much work (in J) is done? 0.4 cm–1 at this temperature is _______ .
OP23. When a ball is released from rest in a very long column
MATHEMATICS PART - II
of viscous liquid, its downward acceleration is ‘a’ (just
after release). Its acceleration when it has acquired two OM71. The line passing through the points (5, 1, a) and (3, b, 1)
third of the maximum velocity is a/X. Find the value æ 17 –13ö
crosses the yz-plane at the point çè 0, , ÷ . Then a + b
of X. 2 2 ø
OP24. The moment of inertia of a uniform semicircular wire of is ________.
mass m and radius r, about an axis passing through its 1 w w2
centre of mass and perpendicular to its plane is
OM72. If w is the cube root of unity, then w w2 1
æ kö
mr 2 ç1 - ÷ then find the value of k. 2
è p2 ø w 1 w
OP25. Three sound waves of equal amplitudes have =________.
frequencies (f –1), f, (f + 1). They superpose to give OM73. If odds against solving a question by three students are
beats. The number of beafs produced per second will 2 : 1, 5 : 2 and 5 : 3 respectively, then probability that the
be ____. question is solved only by one student is _______.
OM74. The interior angles of a polygon are in A.P. If the smallest
CHEMISTRY PART - II angle be 120° and the common difference be 5°, then
OC46. If NA is Avogadro’s number then number of valence the number of sides of the polygon is _______.
electrons in 4.2g of nitride ions (N3–) is x × NA. What OM75. The number of integer values of m, for which the
x-coordinate of the point of intersection of the lines
will be the value of x.
3x + 4y = 9 and y = mx + 1 is also an integer, is_____.
OC47. The frequency of radiation emitted when the electron
falls from n = 4 to n = 1 in a hydrogen atom in terms of x
× 1015 s–1 – 10 will be ______ .
C-10 Mock Test
10
PHYSICS PART - II are – 1.18 V and 1.51 V respectively. What is the redox
OP21. The speed of a projectile at its maximum height is potential for the reaction Mn 3+ + 3e – ¾¾ ® Mn ?
3 OC48. Haemoglobin contains 0.334% of iron by weight. The
times its initial speed. If the range of the projectile molecular weight of haemoglobin is approximately
2
67200. The number of iron atoms (at. wt. of Fe is 56)
is ‘P’ times the maximum height attained by it. P is ____.
present in one molecule of haemoglobin are
OP22. An oscillator is producing FM waves of frequency 2
kHz with a variation of 10 kHz. What is the modulating OC49. If NaCl is doped with 10– 4 mol % of SrCl2, the number of
index? cation vacancies will be x × 1016. x will be ______ .
OP23. A solid cylinder rolls down an inclined plane of height 3 (NA = 6.02 × 1023 mol–1)
m and reaches the bottom of plane with angular velocity OC50. Formation of polyethylene from calcium carbide takes
place as follows
of 2 2 rad.s–1. The radius of cylinder must be ___ cm.
(Take g = 10 ms–2) CaC 2 + 2H 2 O ¾
¾® Ca (OH ) 2 + C 2 H 2
OP24. The pulleys and strings shown in the figure are smooth C2 H2 + H2 ¾
¾® C 2 H 4
and of negligible mass. For the system to remain in
equilibrium. The angle q should be _____. nC 2 H 4 ¾
¾® ( - CH 2 - CH 2 - ) n
The amount of polyethylene obtained from 64.1 kg of
CaC2 is ______.
q
OM71. A coin is tossed successively three times. The
2m
probability of getting exactly one head or 2 heads,
is________.
m m OM72. An edge of a variable cube is increasing at the rate 10 cm/
OP25. The flux linked with a coil at any instant 't' is given by sec. How fast the volume of the cube will increase when
the edge is 5 cm long in term of cm3/sec?
f = 10t 2 - 50t + 250 r r r
OM73. If a1 , a2 & a3 be non-coplanar vectors and
The induced emf at t = 3s is _____ V. r r r r
( x + y - 3) a1 + (2 x - y + 2) a2 +(2 x + y + l ) a3 = 0
CHEMISTRY PART - II holds for some x and y then |l| is __________.
OM74. If the lines 3y + 4x = 1, y = x + 5 and 5y + bx = 3 are
OC46. What is the de-Broglie wavelength associated with the
concurrent, then value of b is equal to______.
hydrogen electron in its third orbit is x × 10–10. The
value of x will be ______. 1 + 2 + 3 +¼ n
OM75. The value of lim is equal to : _______.
OC47. The standard redox potentials for the reactions n®¥ n 2 + 100
Mn 2+ + 2e – ¾¾ ® Mn 2+
® Mn and Mn 3+ + e – ¾¾
Mock Test C-11
11
PHYSICS PART - II OC49. The packing efficiency of the two-dimensional square
OP21. A cricketer can throw a ball to a maximum horizontal unit cell shown below is :
distance of 100 m. With the same effort. he throws the
ball vertically upwards. The maximum height attained
by the ball is _____ m.
OP22. Eight drops of mercury of equal radius and possessing
equal charge combine to form a big drop. The
capacitance of bigger drop as compared to each small
drop is _____ times. L
OP23. A horizontal force of 10 N is necessary to just hold a OC50. 25 mL of 3.0 M HNO3 are mixed with 75 mL of 4.0 M
block stationary against a wall. The coefficient of friction HNO3. If the volumes are additive, the molarity of the
between the block and the wall is 0.2. The weight of the final mixture would be
block is ____ N. MATHEMATICS PART - II
OM71. I f
r r r r
10N
ˆ ˆ ˆ ˆ
F1 = iˆ - ˆj + k , F2 = -iˆ + 2 ˆj - k, F3 = ˆj - k, A = 4iˆ - 3 ˆj – 2k
ur
OP24. The resistance of a bulb filmanet is 100W at a temperature and B = 6iˆ + ˆj – 3k , then the scalar product of
of 100°C. If its temperature coefficient be 0.005 per °C, its uur uur uur uuur
F1 + F2 + F3 and AB will be________.
resistance will become 200 W at a temperature of ____ °C.
OP25. A ladder rests against a frictionless vertical wall, with OM72. If the straight lines
its upper end 6 m above the ground and the lower end 4 x –1 y – 2 z – 3 x – 2 y – 3 z –1
= = and = = intersect
m away from the wall. The weight of the ladder is 500 N k 2 3 3 k 2
and its C. G at 1/3rd distance from the lower end. Wall's at a point, then the integer |k| is equal to ________.
reaction will be ____ N. 1
OM73. The area bounded by y –1 = |x|, y = 0 and |x| = will
CHEMISTRY PART - II 2
be __________.
OC46. How many moles of KI are required to produce 0.4 moles OM74. If z 2 + z + 1 = 0 , where z is complex number, then the value
of K2HgI4 ? æ 1ö
2
æ 2 1ö
2
æ 3 1ö
2 2
of çè z + ÷ø + çè z + 2 ÷ø + çè z + 3 ÷ø + ....... + æç z6 + 1ö
÷
OC47. The first and second dissociation constants of an acid z z z è z6 ø
H2 A are 1.0 × 10–5 and 5.0 × 10–10 respectively. The is_____.
overall dissociation constant of the acid in terms of x × x - sin x
10–10 will be OM75. If f (x) = , then lim f (x) is______.
x + cos 2 x x ®¥
OC48. In haemoglobin the iron is in the following oxidation
state:
C-12 Mock Test
12
PHYSICS PART - II OC48. What weight of hydrated oxalic acid should be added
OP21. If the velocity of a body is 50ms–1and the units of for complete neutralisation of 100 mL of 0.2N NaOH
solution
length and time are changed in kilometer and hour
OC49. Calculate number of molecules of Grignard reagent
respectively, the numerical value of the velocity is ____.
consumed by 1 molecule of following compound.
OP22. A thin rectangular magnet suspended freely has a
period of oscillation equal to T. Now it is broken into
H
two equal halves (each having half of the original length)
and one piece is made to oscillate freely in the same
T' O
field. If its period of oscillation is T ' , the ratio is
T O O
____. O
OP23. A particle moves in x-y plane under the action of force
HO NO 2
F and p at a given time t px = 2 cos q, py = 2sinq.
Then the angle q between F and p at a given time t OC50. How many geometrical isomers are possible for the
is ____ °. given compound ?
OP24. Interference fringes were produced using white light in
a double slit arrangement. When a mica sheet of uniform
thickness of refractive index 1.6 (relative to air) is placed
in the path of light from one of the slits, the central
fringe moves through some distance. This distance is
equal to the width of 30 interference bands if light of
wavelength 4800 Å is used. The thickness (in µm) of MATHEMATICS PART - II
mica is ____.
OM71. Two aeroplanes I and II bomb a target in succession.
OP25. A block of mass 1 kg is pushed up a surface inclined to The probabilities of I and II scoring a hit correctly are
horizontal at an angle of 30° by a force of 10 N parallel to 0.3 and 0.2, respectively. The second plane will bomb
the inclined surface as shown in the figure. only if the first misses the target. The probability that
1 kg N the target is hit by the second plane is________.
10
y z y z
OM72. Twolines L1 : x = 5, = and L2 : x = a , =
3 - a -2 -1 2 - a
30° are coplanar. Then sum values of a is ______.
The coefficient of friction between block and the incline
is 0.1. If the block is pushed up by 10 m along the incline, 4 éë x 2 ùû
then the work against gravity is ____ J. (Take g =10 m s–2) OM73. The value of the integral ò3 é x2 - 14 x + 49 ù + é x 2 ù dx ,
ë û ë û
CHEMISTRY PART - II where [.] denotes the greatest integer function, is_____.
OC46. The de Broglie wavelength of an electron in the ground OM74. The number of integral terms in the expansion of
state of hydrogen atom is : ( 3 + 8 5)256 is _________.
[K.E. = 13.6 eV; 1eV = 1.602 ´ 10 -19 J] OM75. The value of 112 + 122 + 132 + ……+ 202 is ________.
OC47. Decomposition of X exhibits a rate constant of 0.05 µg/
year. How many years are required for the decomposition
of 5 µg of X into 2.5 µg?
Mock Test C-13
13
PHYSICS PART - II OC48. The number of pp – dp bonds present in XeO3 molecules,
is ______.
V
OP21. If the resistance R = , where V = 100 ± 5 volt and OC49. At what temperature, the rate of effusion of N2 would
I
be 1.625 times that of SO2 at 50 °C
I = 10 ± 0.2 ampere. What is the total error (in %) in R? OC50. When same amount of zinc is treated separately with
OP22. A voltmeter of resistance 280W reads the voltage across excess of sulphuric acid and excess of sodium hydroxide
the terminals of an old dry cell to be 1.40V, while a solution the sum of ratio of volumes of hydrogen
potentiometer reads its voltage equal to 1.55V. To draw evolved is _______.
maximum power from the battery, the load resistance
must have the value _____ W.
OP23. A block rests on a rough inclined plane making an angle OM71. If the mean and variance of a binomial variate X are 2
of 30° with the horizontal. The coefficient of static and 1 respectively, then the probability that X takes a
friction between the block and the plane is 0.8. If the value greater than 1, is_______.
frictional force on the block is 10 N, the mass of the OM72. If g (1) = g ( 2 ) , then
block (in kg) is _____. (take g = 10 m/s 2)
2
OP24. Two concentric coils each of radius equal to 2 p cm are
ò éë f { g ( x )} ùû f '{ g ( x )} g ' ( x ) dx is equal
-1
placed at right angles to each other. 3 ampere and 4

1
ampere are the currents flowing in each coil respectively.
to________.
The magnetic induction in Weber / m 2 at the centre of
OM73. Let P be a point in the first octant, whose image Q in the
the coils will be _______. (m 0 = 4p ´ 10 -7 Wb / A.m ) plane x + y = 3 (that is, the line segment PQ is
OP25. A metal ball of mass 2 kg moving with a velocity of 36
perpendicular to the plane x + y = 3 and the mid-point
km/h has a head on collision with a stationary ball of
mass 3 kg. If after the collision, the two balls move of PQ lies the plane x + y = 3 ) lies on the z-axis. Let the
together, the loss in kinetic energy due to collision is distance of P from the x-axis be 5. If R is the image of P
____J. in the xy-plane, then the lenght of PR is________.
3 z
OC46. Two different electrolytic cells filled with molten OM74. Number of solutions of the equation, z 3 + = 0,
z
Cu(NO3) 2 and molten Al(NO3)3, respectively are
connected in series. When electricity is passed 2.7g, Al where z is a complex number and | z |= 3 is________.
is deposited on the electrode. Calculate the weight of cosec x
Cu deposited on the cathode. ì 1 + tan x ü
OM75. lim í ý is equal to________.
x® 0 î 1 + sin x þ
OC47. Calculate the weight of oxalic acid required to neutralise
100 ml of 1 normal NaOH
C-14 Mock Test
14
PHYSICS PART - II temperature is increased by one-third of absolute
OP21. A bullet is fired from a gun. The force on the bullet is temperature, then final volume of the gas will be
given by F = 600 – 2 × 105 t OC49. The half-life for radioactive decay of C–14 is 5730 years.
Where, F is in newton and t in second. The force on the An archaeological artifact containing wood had only
bullet becomes zero as soon as it leaves the barrel. What 80% of the C–14 found in a living tree. The age of the
is the average impulse (in N-s) imparted to the bullet? sample is ______.
OP22. In an amplitude modulated wave for audio frequency of OC50. Calculate the volume of 3% solution of sodium carbonate
500 cycle/second, the appropriate carrier frquency will necessary to neutralise a litre of 0.1 N sulphuric acid
be ____ cycles/s. MATHEMATICS PART - II
OP23. A disc of mass 2 kg and radius 0.2 m is rotating with
1
angular velocity 30 rad/s. What is angular velocity 1
(in rad/s) if a mass of 0.25 kg is put on periphery of the ò
OM71. The value of I = x x -
2
dx is______.
disc ? 0
OP24. A conducting disc of radius R rotates about its axis r r r
OM72. If a = 3, b = 4 and the angle between ar and b be
with an angular velocity w. Then the potential difference
r r
m ew 2 R 2 240°, then 4a + 3b is equal to_________.
between the centre of the disc and its edge is
Ae OM73. The tangent and the normal drawn to the curve
(no magnetic field is present). Find the value of A.
y = x 2 - x + 4 at P(1, 4) cut the x-axis at A and B
OP25. A body floats in water with 40% of its volume outside
water. When the same body floats in oil, 60% of its respectively. If the length of the subtangent drawn to
the curve at P is equal to the length of the subnormal,
volume remains outside oil. The relative density of the then the area of the triangle PAB in sq. units
oils is _____. is_________.
CHEMISTRY PART - II æp ö æp ö
OM74. If tan ç + q ÷ + tan ç – q ÷ = p sec 2q then the value
OC46. A 600 W mercury lamp emits monochromatic radiation è 4 ø è 4 ø
of wavelength 331.3 nm. How many photons are emitted of p is equal to_________.
from the lamp per second is x × 1020. x will be OM75. The line joining A(b cos a, b sin a) and B(a cos b, a sin
(h = 6.6260 × 10–34 Js velocity of light = 3 × 108 ms–1) b), where a ¹ b, is produced to the point M(x, y) so that
OC47. The sum of number of pp – dp bonds present in XeO3 a +b a +b
AM : MB = b : a. Then x cos + y sin is
and XeO4 molecules, is ______. 2 2
OC48. At 0 °C and one atm pressure, a gas occupies 100 cc. If equal to_________.
the pressure is increased to one and a half times and
Mock Test C-15
15
PHYSICS PART - II OC49. The frequency of radiation emitted when the electron falls
from n = 4 to n = 1 in a hydrogen atom is x × 1015 s–1 will be.
OP21. If the radius of curvature of the path of two particles of
(Given ionization energy of H = 2.18 × 10–18 J atom–1
same masses are in the ratio 1 : 2, then in order to have and h = 6.625 × 10–34 Js)
constant centripetal acceleration, their velocity, should OC50. If 0.50 mol of CaCl2 is mixed with 0.20 mol of Na3PO4,
be in the ratio of _____. the maximum number of moles of Ca3(PO4)2 which can
OP22. A refrigerator is to maintain eatables kept inside at 7°C. be formed, is _______.
The coefficient of performance of refrigerator if room
temperature is 38°C is _____.
OM71. A biased coin with probability p, 0 < p < 1, of heads to
OP23. A capillary tube of radius r is immersed vertically in a
tossed until a head appears for the first time. If the
liquid such that liquid rises in it to height h (less than probability that the number of tosses required is even
the length of the tube). Mass of liquid in the capillary 2
tube is m. If radius of the capillary tube is increased by is , then p = ______.
5
50%, then mass of liquid that will rise in the tube, is
____ times. OM72. The plane denoted by P1 : 4 x + 7 x + 4 z + 81 = 0 is
OP24. 1/2 mole of helium is contained in a container at STP. rotated through a right angle about its line of intersection
How much heat energy is needed to double the pressure with the plane P2 : 5x + 3 y + 10 z = 25. If the plane in its
of the gas, (volume is constant). Heat capacity of gas is new position be denoted by P, and the distance of this
3 j g–1 K–1. plane from the origin is d, then the value of [d/2] (where
OP25. Velocity of sound waves in air is 330 m/s. For a particular [k] represents greatest integer less then or equal to k)
sound wave in air, a path difference of 40 cm is equivalent is _________.
to phase difference of 1.6 p. The frequency of this wave 8
_____ Hz. OM73. The value of
ò x - 5 dx is________.
æ 2 2 ö
OC46. HCl is added to MnO2, PbO2 and BaO. How many would OM74. lim ç x + 8x + 3 - x + 4x + 3 ÷ = _______.
x ®¥ è ø
not give H2O2? OM75. A batsman scores runs in 10 innings 38, 70, 48, 34, 42,
OC47. The g-form of iron has fcc structure (edge length 386 55, 63, 46, 54,44, then the mean deviation about median
pm) and b-form has bcc structure (edge length 290 pm). is_________.
The ratio of density of g-form and b-from is ______.
OC48. Dry air was passed successively through a solution of
5 g of a solute in 80 g of water and then through pure
water. The loss in weight of solution was 2.50 g and
that of pure solvent 0.04 g. What is the molecular weight
of the solute
C-16 Mock Test
SOLUTIONS
OC48. (11.4) Given
MOCK TEST 1
NaOH + HNO3 ® NaNO3 + H 2 O
PHYSICS PART - II 1 mol 1 mol DH = 57.0 kJ
0.2 mol 0.5 mol DH = ?
r r r r Given heat of neutralisation of strong acid by strong base = 57.0 kJ
OP21. (1) ( A + B) is perpendicular to ( A – B ) . Thus
Q 0.2 mole NaOH is limiting reagent.
r r r r r r r r \ Heat of neutralization = 0.2 × 57 = 11.4 kJ
( A + B) × ( A – B) = 0 or A2 + B × A – A × B – B 2 = 0 OC49. (3) Calculating the oxidation state of nitrogen in given molecules;
Because of commutative property of dot product Oxidation state of N in NH3 is x + 3 × (+ 1) = 0 or x = – 3
r r r r 2 2
A × B = B × A \ A – B = 0 or A = B Oxidation state of N in NaNO3 is 1 + x + 3 × (– 2) = 0 or x = + 5
Thus the ratio of magnitudes A/B = 1 1
Oxidation state of N in NaN3 is + 1 + 3x = 0 or x = –
OP22. (1.06) Velocity is maximum when K.E. is maximum 3
dV Oxidation state of N in Mg3N2 is 3 × 2 + 2x = 0 or x = –3
For minimum P.E., = 0 Þ x 3 - x = 0 Þ x = ±1 Thus 3 molecules (i.e. NH3, NaN3 and Mg3N2) have nitrogen
dx in negative oxidation state.
1 1 1 OC50. (18) Reaction Rate r1 = k [A]2 [B]
Þ Min. P.E. = - = - J Now increase conc. of A by three times and conc. of B by two
4 2 4 times. Then new rate
K.E.(max.) + P.E.(min.) = 2 (Given)
r2 = k [3A]2 [2B]
1 9
\ K.E.(max.) = 2 + = r1 k[A]2 [B] 1 1 1
4 4 = = ´ =
1 2 r2 k[3A]2 [2B] 32 2 18
K.E.max . =mvmax .
2 r2 = 18 × r1
1 9 3 Hence rate increases by 18 times.
2
Þ ´ 1 ´ vmax . = Þ vmax. =
2 4 2 MATHEMATICS PART - II
R1 l1 OM71. (0.5)
=
OP23. (50)
R2 l 2 where l2 = 100 – l1 é1 2 3 ù é x ù
X 20 OM72. (1.25) [1 x 1] êê0 5 1 úú êê 1 úú = O
In the first case =
Y 80 êë0 3 2 úû êë -2 úû
4X l
In the second case = Þ l = 50 cm éxù
Y 100 - l Þ [1 2 + 5 x + 3 3 + x + 2 ] ê 1 ú = O
OP24. (2) Given, r = 0.4 m, a = 8 rad s–2 ê ú
m = 4 kg, I = ? êë -2úû
Torque, t = Ia = mgr Þ 4 × 10 × 0.4 = I × 8
16 5
ÞI= = 2 kg–m2. Þ x + (2 + 5x + 3) + (–2)(3 + x + 2) = 0 Þ x = .
8 4
OP25. (800) h = 100m, d µ h ìï( 2 + x )3 , - 3 < x £ -1
To triple coverage range, d is to be increased to 3d OM73. (2) f ( x ) = í
23
Þ h' = 9h = 900m ïî x , -1 < x < 2
Increase in height = h' – h = 800m
ì 3 ( 2 + x ) 2 ; - 3 < x £ -1
CHEMISTRY PART - II ï
Þ f ¢( x) = í 2
OC46. (4.08) Let the fraction of metal which exists as M3+ be x. ï x ;
-1 3
-1 < x < 2
Then the fraction of metal as M2+ = (0.98 – x) î3
\ 3x + 2 (0.98 – x) = 2 For -3 < x £ -1 , f ' ( x ) > 0 .
x + 1.96 = 2
x = 0.04 But -1 < x < 0 , f ' ( x ) < 0
0.04 So, we have one local max. at x = –1
\ % of = M3+ ´100 = 4.08%
0.98 Further for 0 < x < 2 , f ' ( x ) > 0
OC47. (1.32) Equivalent wt. of chlorine (E Cl2 ) = 35.5 \ also, we have one local minima.
ECl2 ´ I ´ t 35.5 ´ 2 ´ 30 ´ 60 1 1 1
WCl2 = = = 1.32 g OM74. (0.25) P (tail in 3rd) . P (tail in 4th) = . =
96500 96500 2 2 4
Mock Test C-17
OM75. (325) CHEMISTRY PART - II

F
f b H
a OC46. (1.92) Given m = 9.1 × 10–31kg
g
e d h = 6.6 × 10–34Js
c
B 300 ´ 0.001
Dv = = 0.003ms–1
100
a + e + f + g = 285, b + d + f + g = 195 From Heisenberg's uncertainity principle
c + d + e + g = 115, e + g = 45, f + g = 70, d + g = 50
6.62 ´ 10 -34
a + b + c + d + e + f + g = 500 – 50 = 450 Dx = -31
= 1.92 ´ 10-2 m
We obtain a + f = 240, b + d = 125, c + e = 65 4 ´ 3.14 ´ 0.003 ´ 9.1´ 10
OC47. (28) Number of electrons of bond pair = 14
a + e = 215, b + f = 145; b + c + d = 165
Number of electrons of bone pair = 14
a + c + e = 255; a + b + f = 335 Total no. of electrons of bond pair and bone pair = 28
Solving we get OC48. (14.275) Conc. of HCl = 0.25 mole
b = 95, c = 40, a = 190 , d = 30, e = 25, f = 50 and g = 20 Conc. of NaOH = 0.25 mole
Heat of neutralization of strong acid by strong base = – 57.1 kJ
Desired quantity = a + b + c = 325
HCl + NaOH ¾ ¾® NaCl + H2O – 57.1kJ
MOCK TEST 2 1 mole of HCl neutralize 1 mole of NaOH, heat evolved = 57.1 kJ
\ 0.25 mole of HCl neutralize 0.25 mole of NaOH
PHYSICS PART - II \ Heat evolved = 57.1 × 0.25 = 14.275 kJ
OC49. (0.49) Given T = 27°C = 27 + 273 = 300 K
OP21. (20) t = 2000 N – m, I = 200 Kg-m2 V = 10.0 L
Mass of He = 0.4 g
Ia = 2000 [Q t = Ia ] Mass of oxygen = 1.6 g
Mass of nitrogen = 1.4 g
2000 nHe = 0.4/4 = 0.1
a= = 10 rad/sec2
200 nO = 1.6/32 = 0.05
2
w = w0 + at = 0 + 2 × 10 = 20 rad/s
OP22. (2) Let TA and TB be time period of A and B about sun. nN = 1.4/28 = 0.05
2
TA = 8TB n total = nHe + nO + nN = 0.1 + 0.05 + 0.05 = 0.2
2 2
TA n RT 0.2 ´ 0.082 ´ 300
=8 ...(1) P= = = 0.492 atm
TB V 10
According to Kepler's law T2 µ r3 OC50. (3.2) Strength of the solution = 34 g/L
3 1 L of the solution contains 34 g of H2O2
TA (rA )3 ær ö r
=
3
Þ ç A
çr ÷÷ = 8 Þ A = 2 34
TB (rB ) rB 200 mL of the solution contains × 200 = 6.8 g of H2O2
è B ø 1000
OP23. (2500) 2H 2O 2 ® 2H 2 O + O 2
OP24. (1.8) In the following figure, in equilibrium 2´34g 32g
Fe = T sin30º, r = 1 m 68 g of H2O2 gives 32 g of O2
32
6.8 g of H2O2 gives = × 6.8 = 3.2 g of O2
30º 30º
68
1m 1m MATHEMATICS PART - II
T T cos 30º (cos x - 1) (cos x - e x )

30º OM71. (3) lim
+10 µC Fe x ®0 xn
T sin30º +10 µC
r
mg é 2x ù
ê 2sin 2 ìï (e x - 1) 1 - cos x üïú
ê í + ýú
Q2 1 2
ê 4.x / 4 îï x x þïú
Þ 9 ´ 109 . =T´
r 2 2 = lim ë û
x ®¥ n -3
x
(. 10 ´10-6 )
2
9 1 It will provide us a finite limit only when n – 3 = 0 Þ n = 3
Þ 9 ´10 =T´ Þ T = 1.8 N
2 2 m ± tan a
1
OM72. (4.5) The equation of lines are y – y1 = ( x - x1 )
1 m m tan a
C 3 ´ 108
OP25. (36.5) l = = = 36.5 m Given the equation of line x – y = 2 for which m = 1. Also given
v 8.2 ´ 106 a = 45° and the point (3, 4)
C-18 Mock Test
1 ± tan 45° MOCK TEST 3

Þ y–4= ( x - 3)
1 m tan 45°
PHYSICS PART - II
1±1
Þ y–4= ( x - 3) Þ y = 4 or x = 3 DP é 1 D a 1 D b 1 D c Dd ù
1m1 OP21. (7) = ±ê + + +
P ë2 a 2 b 2 c d úû
Hence, the lines which make the triangle are
x – y = 2, x = 3 and y = 4. DP é1 1 1 ù
Þ ´ 100 = ± ê ´ 2% + ´ 2% + 2% + 4% ú
The intersection points of these lines are (6, 4), (3, 1) and (3, 4) P ë2 2 2 û
1 9
[6(- 3) + 3(0) + 3(3)] = . = ± [1% + 1% + 1% + 4%] = ±7%
area of the triangle =
2 2 ur uur r r ur uur
OM73. (3) Function f(x) = | x – 0.5| + | x – 1| + tan x does not have a OP22. (90) | A + B |2 = | A |2 + | B |2 + 2A . B
p = A 2 + B2 + 2AB cos q
derivative at the points x = 0.5, 1, Î (0, 2). r r r uur ur uur
2 | A - B |2 = | A |2 + | B |2 - 2 A . B = A 2 + B 2 - 2AB cos q
OM74. (0.67) Let two numbers are a and b.
So, A2 + B2 + 2AB cosq = A2 + B2 – 2AB cos q
\ a+b = 6 ..... (i) 4AB cos q = 0 Þ cos q = 0 \ q = 90º
1 1 1 1 So, angle between A & B is 90º.
Let S = + = + [using (i)]
a b a 6-a 1æ1 2ö
OP23. (80) ms DT = ç mv ÷
6-a+a 6 2è 2 ø
Þ S= Þ S=
2
6a - a 6a - a2 v 2 (200)2 4 ´ 104
DT = = = = 80°C.
4 s 4 ´ 125 4 ´ 125
dS (6 a - a 2 ) ´ 0 - 6 ´ (6 - 2 a) -36 + 12a
= = OP24. (40.5)
da (6a - a 2 )2 (6 a - a 2 ) 2
k1 = 3
dS 12 a - 36 A air A k2 = 6
For minimum value, =0 Þ =0
da (6a - a 2 ) 2
d
but 6 a - a 2 ¹ 0 d/3 2d/3
\ 12a - 36 = 0 Þ a = 3 e0 A 1 1 1 d1 d2
Cair = = 9, = + = +
\ b=3 [by (i)] d Cmed C1 C2 k1e0 A k 2 e 0 A
1 1 2 k1k 2 e 0 A
Þ S= + = Þ Cmed =
3 3 3 k1d 2 + k1d1
OM75. (0.5) Given curves are y = (1 - x ) , x = 0 , y = 0 ,
2
3 ´ 6 ´ e0 A 18
= = ´ 9 = 40.5 pF .
Y 3 ´ 2d / 3 + 6 ´ d / 3 4
OP25. (5) From Kirchoff’s current law,
R2 i3 = i1 + i 2 = 3sin wt + 4sin (wt + 90°)
x=b Þ i3 = i0 sin (wt + f)
R1® where i0 = 32 + 42 + 2(3)(4) cos 90°
X
0 1 4sin 90° 4
and tan f = =
3 + 4 cos90° 3
\ i3 = 5 sin (wt + 53°)
3 b
b
( x - 1) ( b - 1)3 + 1 CHEMISTRY PART - II
ò ( x - 1) dx =
2
R1 = =
3 3 W Q
0
0 OC46. (0.01) By Faraday's Ist Law of electrolysis, =
E 96500
3 1 (where Q = it = charge of ion )
( x - 1) ( b - 1)
1 3
We know that no. of gram equivalent
ò ( x - 1)
2
And, R2 = dx = =-
3 3 W it 1 ´ 965 1
b
b = = = =
E 96500 96500 100
1 2( b - 1) 3 1 1 (where i= 1 A, t = 16×60+5 = 965 sec.)
Þ R1 - R2 = Þ + =
4 3 3 4 Since, we know that
1
1 1
Þ ( b - 1) = - Þ b = .
3
Normality = No. of gram equivalent 100 = 0.01 N
8 2 =
Volume (in litre) 1
OC47. (3)
Mock Test C-19
OC48. (560)
Coagulation power of AlCl3 MOCK TEST 4
Coagulation power of NaCl
PHYSICS PART - II
Coagulation value of NaCl 52
= = = 559.139 » 560 4p 2 l
Coagulation value of AlCl3 0.093 OP21. (0.2) T = 2 p l / g Þ T 2 = 4 p 2 l / g Þ g =
T2
OC49. (1) Dp = mDv
Substituting the given values of Dx and m, we get 1mm 0.1
Here % error in l = ´ 100 = ´ 100 = 0.1%
1×10–18 g cm s–1 = 9×10–28 g × Dv 100cm 100
1´ 10 -18 and % error in T =
0.1
or Dv = = 1.1 × 109 cm s–1 ; 1×109 cm s–1 ´ 100 = 0.05%
9 ´ 10-28 2 ´ 100
\ % error in g = % error in l + 2(% error in T)
0.693 2.303 a
OC50. (448) k = min -1 = log = 0.1 + 2× 0.05 = 0.2 %
45 t99.9% a - 0.999a OP22. (–9)
OP23. (0.153) Due to volume expansion of both mercury and flask, the
2.303 ´ 45 change in volume of mercury relative to flask is given by
t99.9% = log103 = 448 min
0.693 DV = V0 [g L - g g ]Dq = V [g m - 3ag ]Dq
MATHEMATICS PART - II = 50 [180 × 10–6 – 3 × 9 × 10–6] (38 – 18) = 0.153 cc
1 3
d3y OP24. (13.63) sin qc = =
OM71. (5) The highest order (m) of the given equation is = 3 and m 4
dx 3
2 3 3 R Þ 36
æ d3y ö or tan qc = = = R= cm
degree (n) of the given equation is ç 3 ÷ = 2 . 16 - 9 7 12 7
è dx ø
Therefore m = 3 and n = 2 . R
r r r
OM72. (11) a = (1, – 1, 2), b = (–2, 3, 5), c = (2, – 2, 4)
r
So, a = (1, – 1, 2) º iˆ - ˆj + 2kˆ; b̂ = (–2, 3, 5) º –2iˆ + 3 ˆj + 5kˆ
qc qc
r 12 cm
and c = (2, –2, 4) º 2iˆ – 2 ˆj + 4kˆ
r r
r
Þ a – 2b + 3c = (iˆ – ˆj + 2kˆ) – 2(–2kˆ + 3 ˆj + 5kˆ)
+3(2iˆ – 2 ˆj + 4kˆ) c
r r OP25. (1) Optical source frequency v =
= 11iˆ –13 ˆj + 4kˆ and (a – 2b + 3c). iˆ = 11. l
é 2 æ x öù 3 ´108 ms –1
ê 2sin ç 2 ÷ ú Þ v= = 2.5 ´1014 Hz
2sin 2 ê è øú
1 - cos(1 - cos x)
1200 ´10 –9 m
OM73. (0.125) lim = lim ë 2 û Bandwidth of channel (2% of the source frequency)
x ®0 4 ® 4 = 5 × 1012 Hz
x x 0 x
2
æ æ x ö öæ æ x öö æxö Total bandwidth
2sin 2 ç sin 2 ç ÷ ÷ç sin 2 ç ÷ ÷ sin 4 ç ÷ Number of channels =
è è 2 ø øè è 2 øø è 2ø = 1 = 1 Bandwidth needed per channel
= lim = 2 lim
4
x ®0 æ æ x öö
2 x ®0 æ x ö
4 23 8 5 ´ 1012 Hz
x 4 ç sin 2 ç ÷ ÷ ç ÷ 2 = = 106 = 1 million.
è è 2 øø è2ø 16
5 ´ 10 Hz
OM74. (2) We know that, | z1 - z2 | ³ || z1 | - | z 2 || ...(i)
CHEMISTRY PART - II
Here | z1 | = 12 and | z2 – 3 – 4i | = 5
but | z2 – (3 + 4i) |³ | | z2 | – | 3 + 4i | | OC46. (21.6) At cathode : Ag+ + e– ® Ag
Þ 5 ³ | z2 | -5 Þ | z2 | £ 10 1
At anode : 2OH– ® H2O + O2 + 2e–
Also from (i) | z1 – z2 | will have least value when | z2 | has greatest 2
value i.e. 10 1
\ | z1 – z2 | ³12 – 10 = 2. Thus min. value of | z1– z2 | is 2. 108 ´ 32
EAg = = 108; EO2 = 2 =8
4q(tan q - sin q) 4q sin q(1 - cos q) 1 2
lim
OM75. (0.5) q® = lim
2
0 (1 - cos 2q) q®0 4 sin 4 q cos q WAg WO2 1.6×108
= ; WAg = = 21.6 g.
æ q ö 2sin q / 2
2
2sin 2 q / 2 1 E Ag E O2 8
= lim ç ÷ = lim · OC47. (0.4) Intercept = log k
q® 0 è sin q ø sin 2 q cos q q® 0 (2sin( q / 2)cos( q / 2)) 2 cos q
k = anti log (0.3010) = 1.99 » 2
1 1 1 x x
= lim = = kp Þ = 2 ´ 0.2 = 0.4 atm
2
q® 0 2 cos (q / 2).cos q 2 m m
C-20 Mock Test
OC48. (5) Since H2O is a weak ligand, it will not cause pairing of
electrons in the metal ion Mn 2+. Thus electronic configuration Z1 - Z 2 2 - 3iˆ (2) 2 + (3) 2 1 2 Z -Z
of the metal (Mn 2+) in the complex will be Þ = = =1
Z1 + Z 2 2 + 3iˆ 2 2 Þ Z +Z
2+ (2) + (3) 1 2
25 Mn :1s 2 2s 2 2 p 6 3s 2 3 p6 3d 5
OM75. (96) According to dictionary,
i.e. 5 unpaired electrons.
CC HNO ¾¾
® 4!
OC49. (43.8) NaOH + HCl ¾¾ ® NaCl + H2O, DH = – 55.9 kJ
CH CINO ¾¾® 4!
Actually, heat of neutralization of a strong acid by a strong
base means heat of formation of water. CI CHNO ¾¾
® 4!
Thus, H + + OH - ® H 2 O; DH = -55.9 kJ CN CHIO ¾¾
® 4!
CO CHIN ¾¾
® it self
or H 2 O ® H + + OH - ; DH = 55.9 kJ ..(i) 144444244444 3
Given, HCN + OH - ® CN - + H 2 O; DH = -12.1kJ Q Total ways = 4 × 4! = 96
…(ii)
Adding equations (i) and (ii), we get MOCK TEST 5
+ -
HCN ® H + CN ; DH = 55.9 - 12.1 kJ = 43.8 kJ PHYSICS PART - II
OC50. (3.6) Using the relation,
5
w.R.T 6 ´ 0.080 ´ 300 OP21. (1250) For train A, u A = 72km / h = 72 ´ m / s = 20m / s
M = , we get M = = 3.6 × 105 18
pV 2 ´ 10 -3 ´ 0.2
5
MATHEMATICS PART - II For train B, uB = 72km / h = 72 ´ m / s = 20m / s
18
OM71. (0.25) Since, India's second win occurs at the third test. \ uBA = uB - u A = 20m / s - 20m / s = 0m / s
Therefore, the sample space is = [LWW, WLW]
where, L = losing the test aBA = aB - a A = 1m / s 2 - 0m / s 2 = 1m / s 2
W = winning the test. t = 50 s
\ P (India's win occur at the 3rd test)
1 1 2
= P (LWW) + P (WLW) = P (L) P (W) P (W) + P (W) P (L) P (W) SBA = uBAt + aBAt 2 = 0 ´ 60 + ´1´ ( 50) = 1250m.
(Q prob. from match to match is independent). 2 2
OP22. (1) We know that the magnetic field produced by a current
æ 1 1 1ö æ 1 1 1 ö
= ç ´ ´ ÷ + ç ´ ´ ÷ (given) m0 I
è
2 2 2ø è 2 2 2ø carrying circular coil of radius r at its centre is B = ´ 2p
4p r
1 1 2 1
= + = = m0 I
8 8 8 4 Here B A = ´ 2p
x y z -1 4p R
OM72. (1) L1 : = = = r , Q ( r , r , 1)
1 1 0 m0 2I BA
and BB = ´ 2p Þ =1
x y z +1 4p 2 R BB
L2 : = = = s, Q(s, - s, -1, )
1 -1 0 OP23. (5.49) u = 147 m/s, q = 60°
uuur
PQ = ( l - r )iˆ + (l - r ) ˆj + (l - 1)kˆ Vertically, v sin f = u sin q - gt
uuur
and l - r + l - r = 0, as PQ is ^ to L1 Þ 2l = 2r Þ l = r Þ 9.8t = u sin 60° - v sin 45°
uuur
PR = (l - s)iˆ + (l + s) ˆj + (l + 1)kˆ u 3 v
uuur uuur = - ... (i)
and l - s - l - s = 0 Þ s = 0 Since PQ ^ PR , 2 2
so ( l - r )( l - s ) + ( l - r )( l + s) + ( l - 1)( l + 1) = 0 u cos q = v cos f
Horizontally,
Þ ( l - 1)( l + 1) = 0 (Q1 = r ) Þ l = -1,1 Þ u cos 60° = v cos 45°
For l = 1, the point P and Q are concides u
or v = ... (ii)
Hence, the value of | l |= | -1 |= 1. 2
OM73. (5)
1
2Z1 \ t= ( 3 - 1)147 = 5.49 sec
OM74. (1) =i (given) 2(9.8)
3Z 2 OP24. (8) The bar magnet has coercivity 4 × 103 Am–1, i.e., it requires
a magnetic intensity H = 4 × 103 Am–1 to get demagnetised.
Z1 3 Let i be the current carried by solenoid having n number of
= i (By componendo and dividendo)
Z2 2 turns per metre length, then by definition H = ni. Here H = 4
× 103 amp turn metre–1
Z1 - Z 2 3iˆ - 2
Þ = N 60
Z1 + Z 2 3iˆ + 2 n= = = 500 turn metre–1
l 0.12
Mock Test C-21
H 4 ´ 103 Þ xy - 1 - x 2 1 - y 2 = - z Þ xy + z = 1 - x 2 1 - y 2
Þi= = = 8.0A
n 500 Squaring both sides, we get
OP25. (8) Inside pressure must be

4T greater than outside pres- x 2 y 2 + z 2 + 2 xyz = (1 - x 2 )(1 - y 2 ) = 1 - x 2 - y 2 + x 2 y 2
r 2 2 2
sure in bubble. Þ x + y + z + 2 xyz = 1
This excess pressure is provided by charge on bubble. OM73. (5)
4T s 2 4T Q2 f (x) 10 + x æ 10 + x ö
= é Q ù OM74. (0.5) e = , x Î (–10,10) Þ f (x) = log ç ÷
= ; ê s= ú 10 – x
r 2e 0 r 2 4
16p r ´ 2e 0 ë 4 pr 2 û è 10 – x ø
é 200x ù
æ 200x ö ê10 + ú
Q = 8pr 2rTe 0 Þ fç = log ê 100 + x 2 ú
2÷ 200x
è 100 + x ø ê10 – ú
CHEMISTRY PART - II
ëê 100 + x 2 ûú
220 ´ 10 -3 é10(10 + x)2 ù
OC46. (0.004) Mole of 220 mg of CO2 = æ 10 + x ö
44 = log ê 2ú
= 2log ç ÷ = 2f (x)
= 5 × 10–3 moles; ëê10(10 – x) ûú è 10 – x ø
6 ´ 1020 1 æ 200x ö 1
= 10–3 moles \ f (x) = f ç Þ k = = 0.5.
2 è 100 + x 2 ÷ø
Moles of CO2 removed are = 23
6 ´ 10 2
Remaining moles of CO2 = [5 × 10–3 – 10–3]
4 - x2 4 - x2
= 4 × 10–3 moles = 0.004 moles OM75. (4) | x | + = x+
OC47. (80) Given enthalpy of CH4 = 320 calories x x
enthalpy of C2H6 = 560 calories As | a | + | b | = | a + b |Þ ab ³ 0
® C( g ) + 4H( g ) ; DH = 320 cal

CH 4 ( g ) ¾¾ æ 4 - x2 ö
\ xç
ç ÷÷ ³ 0, x ¹ 0 Þ x2 – 4 £ 0 Þ x Î [– 2, 2] – {0}
4DHC - H = 320 calories è x ø
320 Number of integral values = 4.
\ DH C - H = = 80 calories
4
MOCK TEST 6
C 2 H 6 ( g ) ¾¾
® 2C( g ) + 6H( g ); DH = 560 cal
PHYSICS PART - II
\ 6DH C - H + DH C -C = 560 calories
\ DH C -C = 560 - 6DH C - H OP21. (0.2) T = 2 p l / g Þ T 2 = 4 p 2 l / g Þ g =
4p 2 l
= 560 – 6 × 80 = 560 – 480 = 80 calories T2
OC48. (11) Fe2+
is converting into Fe3+ and sulphur is changing
from –1 oxidation state to +4 oxidation state. Here % error in l =
1mm 0.1
´ 100 = ´ 100 = 0.1%
There are two S– and one Fe2+ in FeS2. Thus total no. of 100cm 100
electrons lost in the given reaction are 11.
0.1
OC49. (0) At sun's atomosphere temperature is very high so all forms and % error in T = ´ 100 = 0.05%
are unstable. 2 ´ 100
OC50. (12) Co-ordination number in hcp and ccp arrangement is 12. \ % error in g = % error in l + 2(% error in T)
= 0.1 + 2× 0.05 = 0.2 %
l1 X 12
OP22. (5) If l1 = length from one end then = =
OM71. (2.5) Projection of xiˆ – ˆj + kˆ on 2iˆ – ˆj + 5kˆ 1 - l1 R 18
( xiˆ – ˆj + kˆ) × (2iˆ – ˆj + 5kˆ) 2 x + 1 + 5 12
= = l1 = m = 40cm.
4 + 1 + 25 30 30
and l'1 = length from one end in second case
2x + 6 1 -5 5 l1¢ X 12
Given = Þ 2x + 6 = 1 Þ x = = . = =
30 30 2 2 1 - l1¢ R ¢ 8
-1
OM72. (1) It is given that cos x + cos -1 y + cos -1 z = p 12
l1¢ = m = 60cm. So shift = 20 cm
-1 -1 -1 20
Þ cos x + cos y = p - cos z
OP23. (24) Rate of change of momentum of the bullet in forward
-1 2 2 -1 direction = Force required to hold the gun.
Þ cos [ xy - 1 - x 1 - y ] = cos (- z )
-1 -1 F = nmv = 4 ´ 20 ´ 10 –3 ´ 300 = 24 N
[Since cos ( - z ) = p - cos z]
C-22 Mock Test
Re al depth (R1 ) MATHEMATICS PART - II

OP24. (10.5) 1.5 =
Apparent depth (5 cm) OM71. (15) A plane containing the line of intersection of the given planes is
\ R1 = 1.5 × 5 = 7.5 cm x - y - z - 4 + l( x + y + 2 z - 4) = 0
i.e., (l + 1) x + (l - 1) y + (2l - 1) z - 4( l + 1) = 0 ...(i)
R1 5 cm
vector normal to it
r
air bubble V = (l + 1)$i + (l - 1) $j + (2l - 1)k$
R2 Now the vector along the line of intersection of the planes
2 cm 2 x + 3 y + z - 1 = 0 and x + 3 y + 2 z - 2 = 0 is given by
R2 $i $j k$
For opposite face, 1.5 = Þ R2 = 3.0 cm r
2 n = 2 3 1 = 3(i$ - $j + k$ )
\ Thickness of the slab = R1 + R2 = 7.5 + 3 = 10.5 cm
1 3 2
OP25. (0.4) r
CHEMISTRY PART - II As n is parallel to the plane (i) therefore
r ur
n × V = 0 Þ (l + 1) - (l - 1) + (2l - 1) = 0
2.303 100 2.303 100
OC46. (0.5) k = log = log -1
1 hr 25 t 50 2 + 2l - 1 = 0 Þ l =
2
1 1 1 Hence the required plane is
\ log 4 = log 2 \ 2 log 2 = log 2; t = h = 0.5 h x 3y
t t 2 - - 2z - 2 = 0 Þ x - 3 y - 4 z - 4 = 0
Br 2 2
OC47. (2) Hence A + B + C = -4 = 15.
y=x
NaNH 2 / NH3 OM72. (6) 2 2 x<y
¾¾ ¾ ¾ ¾¾®
– 33° C
NH 2 x y
NH 2 2
NH
¾¾¾
2® +
2 2 2
OH O Let P(h, k ) be any point in the plane.
| ||
OC48. (2) CH 3 - CH - CH 2 - C - CH3 + Given, 2 £ d1 (ρ) + d2 (ρ) £ 4
OH h-k h+k
| Þ 2£ + £ 4 Þ 2 2 £ h - k + h + k £ 4 2,
CH 3 - C - CH 2 - CHO 2 2
|
CH 3 In first quadrant if h ³ k ,
Two products are formed. Þ2 2 £ x- y+ x+ y £ 4 2 Þ 2£ x£2 2

OC49. (224) We know that Similarly in first quadrant when k > h, 2 £ y £ 2 2
2H2O2 –—® 2H2O + O2
2 × 34g 22400 mL \ required area = (2 2) 2 - ( 2) 2 = 6.
2 × 34 g = 68 g of H2O2
1 + (a 2 + b 2 + c 2 + 2) x (1 + b2 ) x (1 + c 2 ) x
68 g of H2O2 = 22400 mL O2 at STP
OM73. (2) f (x) = 1 + (a 2 + b 2 + c 2 + 2) x 1 + b2 x (1 + c 2 ) x
22400 ´ 0.68
\ 0.68 g of H2O2 = = 224 mL. 1 + (a 2 + b 2 + c 2 + 2) x (1 + b 2 ) x 1 + c2 x
68
OC50. (0.1) 3 BaCl2 + 2 Na3PO4 ® 6 NaCl + Ba3(PO4)2 Applying, C1 ® C1 + C 2 + C3
Molar ratio 3 2 6 1
Initial moles 0.5 0.2 0 0
1 (1 + b 2 ) x (1 + c 2 ) x
Limiting reagent is Na3PO4 hence it would be consumed, and
= 1 1 + b2 x (1 + c 2 ) x (\ a 2 + b 2 + c 2 + 2 = 0)
the yield would be decided by it initial moles.
2 2
1 (1 + b ) x 1+ c x
2 moles of Na3PO4 give 1 mole of Ba3 (PO4)2 ,
\ 0.2 moles of Na3PO4 would give 0.1 mole of Ba3(PO4)2
Mock Test C-23
CHEMISTRY PART - II
0 x -1 0
OC46. (2) Q Weight of H2O2 in 100 mL of H2O2 solution = 6.8 g
0 1- x x -1 Q Weight of H2O2 in 1000 mL of its solution = 6.8×10 = 68 g
Þ f(x) =
1 (1 + b2 ) x 1 + c 2 x 68
Molecular weight of H2O2 = 34. Then, Molarity = =2M
34
Applying R1 ® R1 - R 2 , R 2 ® R 2 - R 3 OC47. (9.84) (DE), The energy required to excite an electron in
f (x) = (x – 1)2 . Hence, degree = 2. atom of hydrogen from n = 1 to n = 2 is DE (difference in
OM74. (5) 3 + i x2y and x2 + y + 4i are conjugate energy E2 and E1)
Values of E2 and E1 are,
then x2y = – 4 and x2 + y = 3 Þ x2 = 4, y = – 1 Þ x2 + y2 = 5
OM75. (155) Arranging the data in ascending order of magnitude, we obtain -1.312 ´ 106 ´ (1) 2
E2 = = –3.28 × 105 J mol–1
Height (2) 2
15 0 152 154 1 55 156 160 161
(in cm) E1 = – 1.312 × 106 J mol–1
Number of \ DE = E2 – E1 = [–3.28 × 105]– [–1.312 × 106 ] J mol–1
8 4 3 7 3 12 4
students = (–3.28 × 105 + 13.12 × 105) J mol–1 = 9.84 × 105 J mol–1
–
OC48. (1.75) O
Cumulative
—
8 12 15 22 25 37 41
frequency O — Cl — O
—
Here, the total number of items is 41, i.e., an odd number. O
41 + 1
Hence, the median is th i.e., 21st item. Perchlorate ion (ClO-4 ) have the following possible
2 resonating structures:
From cumulative frequency table, we find that the median, i.e.
21st item is 155. O O
(All items from 16th to 22nd are equal, each 155).
—
—
—
O — Cl — O ¬¾
® O — Cl — O ¬¾
®
MOCK TEST 7
—
—
O O
PHYSICS PART - II O O
—
—
—
–
dy O — Cl — O ¬¾
® O—
— Cl — O
OP21. (1) v = = (2t - 4)iˆ + (2t ) ˆj
—
—
dt O O
–
dv Cl – O bond order = 7/4 = 1.75
a= = 2iˆ + 2 ˆj
dt OC49. (6) Let solubility of AgCl = s mol/L
For a and v to be perpendicular Ag + + Cl-
AgCl
a.v = 0 before dissociation s 0 0
Þ (2iˆ + 2 ˆj ) × [(2t - 4)iˆ + (2t ) ˆj ] after dissociation 0 s s
Þ 4 t – 8 + 4 t = 0 Þ t = 1s ® Na + + Cl-
NaCl ¾¾
OP22. (122.4) E = –Z2 × 13.6 eV = – 9 × 13.6 eV = –122.4 eV Number of Cl– = 0.2
So ionisation energy = + 122.4 eV.
OP23. (2.5) Tension in the string = m(g + a) = Breaking force Total [Cl - ] = x + 0.2
Þ 20(g + a) = 25 × g Þ a = g/4 = 2.5 m/s2
Ksp (AgCl) = [Ag + ][Cl - ] = (s) (s + 0.2) = x 2 + 0.2 x
h
OP24. (1.41) K.E. = 2E0 – E0 = E0 (for 0 £ x £ 1) Þ l1 = \ Ksp ; 0.2 s (Q s 2 << 1)
2mE0
h l
\ 1.2 ´ 10 -10 = 0.2s \ x = 6 ´ 10 -10 M
K.E. = 2E0 (for x > 1) Þ l2 = Þ 1 = 2. -4 +4
4mE 0 l2 loss of 10e -
OC50. (3) N 2 H 4 ¾¾¾¾¾® Y;
OP25. (5.5) Let the block compress the spring by x before stopping.
kinetic energy of the block = (P.E of compressed spring) + Since, O.N. of ‘H’ remains same. So, in new compound Y, (all
work done against friction. nitrogen retained) N will observe loss of 10e–. Hence, O.N.of
1 1 N changes from –2 to +3.
´ 2 ´ (4)2 = ´ 10,000 ´ x 2 + 15 ´ x
2 2 MATHEMATICS PART - II
10,000 x2 + 30x – 32 = 0
OM71. (3) Let X be the number of heads getting. X follows binomial
Þ 5000 x 2 + 15 x - 16 = 0 distribution with parameters n, p = 1/2. Given that P(X ³ 1) ³ 0.8
Þ 1 – P(X = 0) ³ 0.8 Þ P(X = 0) £ 0.2
-15 ± (15)2 - 4 ´ (5000)( -16)
\ x= = 0.055m = 5.5cm. 1 1
2 ´ 5000 Þ nC0 (1/2)n £ 0.2 Þ £ Þ 2n ³ 5.
2n 5
\ the least value of n is 3.
C-24 Mock Test
OM72. (3) The given circle is x2 + y2 – 2x – 6y + 6 = 0 with centre C (1,
Vs Ns
3) and radius = 1 + 9 - 6 = 2 . Let AB be one of its diameter OP24. (120) Since =
Vp N p
which is the chord of other circle with centre at C1 (2, 1).
Where Np = 50 Ns = 1500
df d 1500
and Vp = = (f0 + 4t) = 4 Þ Vs = ´ 4 = 120 V
dt dt 50
C1(2,1) OP25. (32) mg = 72 N (body weight on the surface)
GM
r
And, g=
A
2
B R2
C(1,3)
R g¢ = GM 4 GM
At a height H = , 2 =
2 æ Rö 9 R2
Then in DC1CB, çR + ÷
è 2ø
C1 B 2 = CC12 + CB 2 R
r2 = [(2 – 1)2 + (1 – 3)2] + (2)2 Body weight at height H = ,
Þ r2 = 1 + 4 + 4 Þ r2 = 9 Þ r = 3. 2
4 GM 4 4 4
OM73. (0.33) mg¢ = m ´ = m ´ ´ g = mg = ´ 72 = 32 N
OM74. (11.25) Let total no. of obs = 18 9 R2 9 9 9
Let mean of one group = a1 = 15 and mean of other group = a2 CHEMISTRY PART - II
40
Given : Combined mean = w 1000
3 OC46. (17.3) DTb = Kb ´
M W
( a1 ´10 ) + ( a2 ´ 8) 3 1000
Now, combined mean =
18
0.52 = 0 .6 ´ ´ (W = 200 ´ 1))
M 200
40 150 + 8a2 45 1.8 ´ 5
Þ = Þ a2 = M= = 17.3g mol -1
3 18 4 0.52
1 OC47. (3.2) Number of equivalents of silver formed = Number of
OM75. (2) f ( x ) = a sin x + sin 3 x equivalent of copper formed.
3 In AgNO3, Ag is in +1 oxidation state.
1
Þ f ¢ ( x ) = a cos x + 3cos 3 x
In CuSO4, Cu is in +2 oxidation state.
3 108
Þ f ¢ ( x ) = a cos x + cos3x = 0 Equivalent weight of Ag =
1
= 108
æp ö p a 63.6
Þ f ¢ ç ÷ = a cos + cos p = - 1 = 0 Þ a = 2. Equivalent weight of Cu = = 31.8
è 3ø 3 2 2
M1 E 10.79 108
MOCK TEST 8 = 1 ; =
M2 E 2 M Cu 31.8
PHYSICS PART - II
10.79 ´ 31.8
OP21. (1) Note that the given angles of projection add upto 90°. So, MCu = = 3.2 g.
the ratio of horizontal ranges is 1 : 1. 108
OC48. (2)
2
F1 æ r2 ö
1 0.1 (200)1- n 1 é4ù
1- n
é1ù
n -1
OP22. (11.25) F µ 2 Þ =ç ÷ t1/ 2 µ a1- n Þ = Þ =ê ú =ê ú
r F2 è r1 ø 0.4 (50)1- n 4 ë1û ë4û
2 1 1
5 æ 0.04 ö Þ = n -1 \ n - 1 = 1; n = 2
Þ =ç ÷ = F2 = 11.25 N
F2 è 0.06 ø 41 4
OP23. (2) Here, Moment of inertia, I = 3 × 102 kg m2 Z2
Torque, t = 6.9 × 102 Nm OC49. (9) E3 = – E = - 13.6 ´
Initial angular speed, w0 = 4.6 rad s–1 32
Final angular speed, w = 0 rad s–1 Z2
As w = w0 + at Þ – E = E0 ´ [where E0 = – 13.6]
9
w - w0 0 - 4.6 4.6
a= = =- rad s–2 - 9E
t t t Þ E0 =
Z2
Negative sign is for deceleration torque, t = Ia According to question,
4.6 3 ´ 10 2 ´ 4.6 Z2 - 9E
Þ 6.9 × 102 = 3 × 102 × Þt= = 2s. E1 = - 13.6 ´ = E0 ´ Z 2 = 2 ´ Z 2 Þ E1 = - 9 E.
t 6.9 ´ 10 2 12 Z
Mock Test C-25
OC50. (200) Applying Boyle's law P1V1 = P2V2 for both gases
500 Q2 Q2 Q2 é 1 1ù
´ 400 = P ´ 3 Þ P =
200 OP22. (3.75 × 10–6) - = êc ' - c ú
1000 3 2c ' 2c 2 ë û
666.6 400
( 5 ´ 10-6 )
2
600 ´ = P¢ ´ 3 Þ P¢ = é 1 1 ù
1000 3 = - –6
ê -6 ú =3.75 × 10 J
200 400 600 2 ë 2 ´ 10 5 ´ 10 -6 û
Þ PT = P + P¢ = + = = 200 torr
3 3 3 OP23. (3)
MATHEMATICS PART - II vf 2 2
vf = Weff
3 3
2
ò
OM71. (10) Required area = [2 - (2 x - x )]dx
x 2
0
Weff = vf
2
é 2 x
x ù 3
4 8 1
=ê - x2 + ú = -4+ -
ë log 2 3 û 0 log 2 3 log 2 Weff
Weff
When the When the ball attains
ball is released When the ball attains
3 4 terminal velocity
2/3 of terminal velocity
= - . \ a + b + c = 3 + 4 + 3 = 10.
log 2 3 When the ball is just released, the net force on ball is
OM72. (12) Weff = (mg - buoyant force)
101 The terminal velocity vf of the ball is attained when net force
OM73. (33) Since, (n + 1)p = is not an integer, on the ball is zero.
3
\ Viscous force 6phr vf = Weff
é101ù
therefore, P(X = r) is maximum when r = ê = 33. 2
ë 3 úû When the ball acquires rd of its maximum velocity vf the
3
7 7 2
OM74. (6) | a 2 - b 2 | = | (a + b ) | | a - b | Þ = | a – b| · viscous force is = Weff
4 2 3
1 1 2 1
Þ |a – b|2 = Þ |(a + b)2 – 4ab| = Hence net force is Weff - Weff = Weff
4 4 3 3
\ required acceleration is a/3
49 4c 1 48
Þ - = Þ 49 - 8c = 1 Þ c = =6 OP24. (4)
4 2 4 8
OM75. (1.25) Two circles x2 + y2 + 2g1x + 2f1y + c1 = 0 m
and x 2 + y 2 + 2g 2x + 2f2y + c2 = 0 cuts orthogonally
if 2g1g2 + 2f1f2 = c1 + c2 (2/p) r
Given equations of two circles are z
r
x2 + y2 + 2 l x + 6y + 1 = 0 ... (i)
x2 + y2 +4x + 2y = 0 .... (ii)
On comparing with original equation, we get
g1 = l, f1 = 3, c1 = 1 and g2 = 2, f2 = 1, c2 = 0
Moment of inertia about z-axis, Iz = mr2 (about centre of mass)
So, from orthogonality condition, we have Applying parallel axes theorem, Iz = Icm + mk2
-5 5 2
4l + 6 = 1 Þ 4 l = - 5 \ l = Þ l = = 1.25 æ2 ö 2 m4r 2 æ 4ö
4 4 Icm = Iz – m ç r÷ = mr - = mr 2 ç1 - 2 ÷
è p ø p 2 è p ø
MOCK TEST 9 i.e., k = 4
OP25. (2) Maximum number of beats = (f + 1) – (f – 1) = 2
PHYSICS PART - II
CHEMISTRY PART - II
1mm
OP21. (3.38) Pitch = = 0.5 mm
2 OC46. (3) N3– = 10e –
pitch 10 N A
Least count of screw gauge = 4.2 g of N3– ions have < ´ 4.2 < 3 N A
number of divisions 14
0.5
= mm = 0.01mm 1 é1 1ù
50 OC47. (3.08) n = ´ IE ´ ê 2 - 2ú
\ Reading = [Main scale reading + circular scale h ëê n1 n2 ûú
reading × L.C] – (zero error)
= [3 + 35 × 0.01] – (– 0.03) = 3.38 mm 2.18 ´ 10-18 é1 1 ù
= ´ê - ú 15 -1
6.625 ´ 10 -34 ë1 16 û = 3.08 ´ 10 s
C-26 Mock Test
OC48. (44.8) PbS + 4H2O2 ® PbSO4 + 4H2O OM75. (2) Intersection of 3x + 4y = 9 and y = mx + 1.
Water Calculation for x co-ordinate, 3x + 4 (mx + 1) = 9 Þ (3 + 4m) x = 5
4H2O2 ® 4H2O + 2O2 5
4(2+32) 2×22.4 litre Þ x=
= 136 g at NTP. 3 + 4m
From the above equation we can derive that For x to be an integer 3 + 4m should be a divisor of 5
1 mole of PbS reacts with 0.01 × 4 i.e. 0.04 moles of H2O2. Thus, i.e., 1, – 1, 5 or – 5.
Now, 3 + 4m = 1 Þ m = – 1/2 (not integer)
0.04 ´11.2
volume of H2O2 needed = = 0.0448 L or 44.8 mL. 3 + 4m = – 1 Þ m = – 1 (integer)
10
3 + 4m = 5 Þ m = 1/2 (not an integer)
+ r r +
OC49. (1.123) Na = 0.55 and K = 0.74 3 + 4m = – 5 Þ m = – 2 (integer) \ There are 2 integral values of m.
r r -
Cl- Cl
r r
MOCK TEST 10
+
Na
+ 1 = 0.55 + 1 and K+
+ 1 = 0.74 + 1
r - r - PHYSICS PART - II
Cl Cl
r + +r - r + +r - 3u 3
Na Cl
= 1.55 and K Cl
= 1.74 OP21. (6.9) Given, u cos q = Þ cos q = Þ q = 30°
r - r - 2 2
Cl Cl
Now edge length ratio of KCl and NaCl is u 2 sin 2q u 2 sin 60° 3 u2
Range (R) = = =
1.74 rK + + rCl- r
Cl-
g g 2g
= ´ = 1.123.
1.55 r - r +r u 2 sin 2 q u 2 sin 2 30° u 2
Cl Na + Cl- Maximum height = = =
OC50. (500) 2g 2g 8g
MATHEMATICS PART - II 3 u2 u2
Now, Range = P × H Þ = P´ Þ P = 6.9
OM71. (10) Equation of line through (5, 1, a) and 2g 8g
x – 5 y –1 z – a OP22. (5) The formula for modulating index is given by
(3, b, 1) is = = =l
–2 b –1 1– a d Frequency deviation 10 ´ 103
\ any point on this line is a [–2l + 5, (b – 1) l + 1, (1– a) l + a] mf = = = =5
It crosses yz plane where –2l + 5 = 0 vm Modulating frequency 2 ´ 103
5 2 gh 2 ´ 10 ´ 3 = 2 ´ 10 ´ 3 = 40
l= OP23. (2.23) v = = 3
2 I mr 2
1+ 2 1+
mr 2 2
æ 5 5 ö æ 17 –13 ö 2 ´ mr
\ ç 0, (b –1) + 1, (1 – a ) + a ÷ = ç 0, , ÷
è 2 2 ø è 2 2 ø
v 40 40
5 17 5 13 Þ v = rw Þ r = = = = 5 m.
Þ (b – 1) + 1 = and (1 – a ) + a = - Þ b = 4 and a = 6 w 2 2 8
2 2 2 2 OP24. (45) If T is the tension in the string , Then
1 w w2 1 + w + w2 w w2 T = mg (For outer masses)
OM72. (0) w w2 1 = 1 + w + w2 w2 1 2T cos q = 2mg (For inner mass)
2
w2 1 w 1+ w + w 1 w Eliminating T, we get 2(mg) cos q = 2mg
[Applying C1 ® C1 + C2 + C3]
or cos q = 1/ 2 Þ q = 45°
0 w w2
OP25. (2.23) f = 10t 2 - 50t + 250
= 0 w2 1 = 0.
0 1 w df
e=- = -(20t - 50) Þ et = 3 = -10 V
OM73. (0.45) dt
OM74. (9) Let the number of sides of the polygon be n. CHEMISTRY PART - II
Then the sum of interior angles of the polygon
p æ Z ö -1
= (2n - 4) = (n - 2)p = ( n - 2)180° OC46. (9.96) Velocity of e– in orbit = Vn = 2.88 ´ ç ÷ ms
2 ènø
Since the angles are in A.P. and a = 120°, d = 5°
h 6.62 ´ 10 -34
n and l = = as n = 3
Therefore, [2 ´ 120 + ( n - 1)5] = ( n - 2)180 mV -31 é 2.88 ´ 10 ù
6
2 9.1 ´10 ´ ê ú
Þ 5n2 – 125n + 720 = 0 ëê 3 ûú
Þ n2 – 25n + 144 = 0 Þ (n – 9)(n – 16) = 0 Þ n = 9, 16
-8 -10
But n = 16 gives T16 = a + 15d = 120° + 15(5°) = 195°, on solving l = 9.96 ´ 10 cm = 9.96 ´ 10 m
which is impossible as interior angle cannot be greater OC47. (–0.28) Mn2+ + 2e– ® Mn ...(i)
than 180°. Hence n = 9. DGº = – nFEº = 2.36 F
Mock Test C-27
Mn3+ + e– ® Mn2+ ...(ii) n ( n + 1)

DGº = – nFEº = 1.51 F 1 + 2 + 3 + ...n
OM75. (0.5) Consider lim = lim
Add eqns. (i) and (ii), Mn3+ + 3e– ® Mn n®¥ 2
n + 100 n ®¥ 2( n 2 + 100)
DGº = 2.36 F + (– 1.51 F) = 0.85 F
n (n + 1)
DGº = – nFEº (By using sum of n natural number 1+ 2 + 3 + .... + n = )
0.85 F = – 3 × F × Eº Þ Eº = – 0.28 V. 2
OC48. (4) æ 1ö
OC49. (60.2) Since each Sr2+ ion provides one cation vacancy, n2 ç1 + ÷
\ Number of cation vacancies è nø = 1
Take n2 common from Nr and Dr = lim
= mole % of SrCl2 added = 10–4 mole % n ®¥ æ 100 ö 2
2n 2 ç 1 + 2 ÷
10 -4 è n ø
= ´ 6.023 ´ 1023 = 6.023 ´ 1017 mol–1
100 MOCK TEST 11
= 60.23 ´ 1016 mol–1
OC50. (28) The concerned chemical reactions are
PHYSICS PART - II
(i) CaC 2 + 2H 2 O ® Ca ( OH) 2 + C 2H2
64 kg Ethyne , 26kg OP21. (50) Let the velocity given by the cricketer to the ball = u
(ii) C 2 H 2 + H 2 ® u2
C2H 4 Then, maximum horizontal distance = = 100m
Ethylene , 28 kg g
Also, when thrown vertically upwards, maximum height
(iii) nC2 H 2 ® [-CH 2 - CH 2 -]n
n´28 kg n´28 kg polythene u 2 100
or 28 kg or 28 kg
h= = = 50 m
2g 2
Thus 64 kg of CaC2 gives 26 kg of acetylene which in turn
gives 28 kg of ethylene whose 28 kg gives 28 kg of the polymer, (2) Cspherical = 4pe0r; 8 ´
4 3 4 3 Þ R = 2r
OP22. pr = pR
polythene. 3 3
MATHEMATICS PART - II Cbig drop R 2r
= =
OM71. (0.75) Required probability Csmall drop r r =2
1 2 2 1 OP23. (2) For the block to remain stationary with the wall f = W
3 æ1ö æ1ö æ1ö æ1ö 3 3 6 3
= C1 ç ÷ . ç ÷ + 3 C2 ç ÷ .ç ÷ = + = = f = mN
è2ø 2
è ø è2ø è2ø 8 8 8 4
OM72. (750) Let edge of the cube be x cm.
10N 10N 10N
Volume of the cube be x 3cm 3 .
dx W
Given, = 10 cm/sec
dt mN = W
dv dx 0.2 × 10 = W Þ W = 2N
3
Now, v = x Þ = 3x 2 OP24. (400) R1 = R0 [1 + a × 100] = 100 ....(i)
dt dt R2 = R0 [1 + a × T] = 200 ....(ii)
dv On dividing we get
= 3 ( 5 ) (10 ) cm3 sec = 750 cm 3 sec.
2
Þ
dt 200 1 + aT 1 + 0.005 T
r r r = Þ2= Þ T = 400°C
OM73. (3.33) Since a1 , a2 & a3 are non-coplanar vectors 100 1 + 100a 1 + 100 ´ 0.005
OP25. (111)
\ x+y –3=0 .... (i)
2x – y + 2 = 0 .... (ii) CHEMISTRY PART - II
2x + y + l = 0 .... (iii)
OC46. (0.8) 2KI + HgI 2 ¾¾ ® K 2 HgI 4
From (i) & (ii), x = 1/3, y = 8/3
Moles of KI required to produce 0.4 moles of K2HgI4
10 10 = 2 × 0.4 = 0.8
\ From (iii), l = – Þ l =
3 3 H∗ ∗ HA,
OC47. (5) H 2 A
OM74. (6) 3 lines, a1x + b1y + c1 = 0, a2x + b2y + c2 = 0
+ -
and a3x + b3y + c3 = 0 are said to be concurrent if \ K1 = 1.0 × 10–5 = [H ][HA ] (Given)
a1 (b2 c3 – c2b3) –b1(a2c3 – c2a3) + c1(a2b3 – b2a3) = 0 [H 2 A]
Given equation of lines are
3y + 4x = 1 ...(i)
HA- ¾¾
® H+ + A2 -
y–x=5 ...(ii) [H + ][A -- ] (Given)
\ K 2 = 5.0 ´ 10 -10 =
and 5y + bx = 3 ...(iii)
[HA - ]
Now, 4 (–3 + 25) –3(3 + 5b) –1 (–5 –b) = 0
Þ 4 (22) – 9 – 15b + 5 + b = 0 [H + ]2 [A 2 - ]
Þ 88 – 4 – 14b = 0 Þ 84 – 14b = 0 Þ 14b = 84 Þ b = 6 K= = K1 ´ K2
[H 2 A]
= (1.0 × 10–5) × (5 × 10–10) = 5 × 10–15
C-28 Mock Test
OC48. (2) In haemoglobin, Fe is in +2 oxidation state. OP22. (0.5)
OC49. (78.54) Packing efficiency d px d py
Area occupied by circles within the square OP23. (90) Fx = = - 2sin q. Similarly, Fy = = 2cos q.
= dt dx
Area of square Fx p x + Fy p y
Angle q between two vectors cos q = r r
2pr 2 2pr 2 | F || p |
= ´100 = ´ 100 = p ´100 = 78.54%
L2 (2 2 r )2 4 ( -2sin q) (2 cos q) + (2 cos q) (2sin q)
= r r
OC50. (3.75) | F|| p|
MATHEMATICS PART - II Þ cos q = 0 Þ q = 90° .
r uuur r uuur tD
OM71. (9) å F = 2 ˆj - kˆ, AB = 2iˆ + 4 ˆj - kˆ, \ å F × AB = 8 + 1 = 9. OP24. (24) Shift of fringe pattern = (m - 1)
d
OM72. (5) -10
OM73. (1.25) The given lines are, \ 30D (4800 ´ 10 ) = (0.6)t D
d d
y – 1 = x, x ³ 0; y – 1 = – x, x < 0
-10
30 ´ 4800 ´ 10 = 0.6 t
1 1
y = 0; x =- , x < 0; x = , x ³ 0 30 ´ 4800 ´ 10 -10
1.44 ´ 10-5
2 2 t= = = 24 ´ 10-6 m = 24 mm
so that the area bounded is as shown in the figure. 0.6 0.6
Y OP25 (50) The various forces acting on the block are as shown in the figure.
D B
Here, m = 1 kg, q = 30°, F = 10 N
C N
F
q q q
sin mg cos
(–1/2,0) O (1/2,0)
X mg f mg
q
Required area m = 0.1, d = 10 m

2 ö1 2 Work done against gravity is Wg = mgdsinq
æ x ÷ æ1 1ö 5
12 ç = (1 kg) × (10 m s–2) × 10 × sin30° m = 50 J
= 2 ò (1 + x ) dx = 2ç x + 2 ÷ = 2 ç 2 + 8 ÷ = 4
0 è ø0 è ø
CHEMISTRY PART - II
OM74. (12) z 2 + z + 1 = 0 Þ z = w or w 2 OC46. (0.3328) For electron in the ground state,
1 2
So, z + = w + w = -1 mvr =
h
Þ mv =
h
z
2p 2pr
1 1
z 2 + 2 = w 2 + w = -1, z 3 + 3 = w3 + w3 = 2 h h h
z z Now, mv = . So, = Þ l = 2pr
l l 2pr
1 1 1
z + 4 = -1, z + 5 = -1 and z 6 + 6 = 2
4 5
l = 2 ´ 3.14 ´ 0.53Å = 3.328Å
z z z
-9
\ The given sum = 1+1 + 4 + 1 + 1 + 4 = 12 = 3.328 ´ 10 -10 m = 0.3328 ´ 10 m = 0.3328 nm
OC47. (50)
x - sin x
OM75. (1) lim f (x) = lim OC48. (1.26) For complete neutralization, equivalent of oxalic acid
x®¥ x ®¥ x + cos 2 x = equivalent of NaOH
sin x w NV w 0.2 ´ 100
1- = = \ = Þ w = 1.26 g
x 1- 0 Ew 1000 63 1000
= lim 2 = =1
x ®¥ cos x 1+ 0 H
1+
x OC49. (5)
[1] C
é sin x cos 2 x ù |||
êQ ® 0, ® 0 as x ® ¥ ú C
êë x x úû
O
MOCK TEST 12 O O
O
PHYSICS PART - II
[3]
HO NO 2
1 -1 1 -1
é L1 ù é T1 ù é meter ù é sec ù
OP21. (180) n2 = n1 ê ú ê ú = 50 ê ú ê ú [1]
ë L2 û ë T2 û ë km û ë hr û
1 -1 OC50. (2)
é m ù é sec ù
n 2 = 50 ê 3 ú ê ú = 180
ë10 m û ë 3600sec û
Mock Test C-29
MATHEMATICS PART - II \ I × 280 = 1.40 e r

OM71. (0.14) Given : Probability of aeroplane I, scoring a target 1.4
correctly i.e., P(I) = 0.3 probability of scoring a target correctly I= = 5 ´ 10-3 A 1.55V
280
by aeroplane II, i.e. P(II) = 0.2
I I
\ P( I ) = 1 – 0.3 = 0.7 e 1.55 Voltmeter
Also I = =
\ the required probability 280 + r 28 + r 280W
= P ( I Ç II ) = P( I ).P ( II ) = 0.7 × 0.2 = 0.14 1.55
5 × 10–3 =
280 + r
x-5 y z x-a y z 1.4 + 5 × 10–3r = 1.55
OM72. (10) Lines = = and = =
0 3 - a -2 0 -1 2 - a 0.15
5 × 10–3r = 0.15 Þ r = = 30W
5 -a 0 0 5 ´10 -3
will be coplanar if 0 3-a -2 =0 According to maximum power theorem, Load resistance, R =
r = 30W
0 -1 2 -a fs
OP23. (2)
Þ (5 - a )((3 - a )(2 - a ) - 2) = 0 N
Þ (5 - a )(a 2 - 5a + 6 - 2) = 0
mg
Þ (a - 5)(a - 5a + 4) = 0 Þ a = 1, 4,5.
2
30°
OM73. (0.5)
mg sin q = f s ( for a body to be at rest)
256 - r
OM74. (33) Tr +1 = 256Cr ( 3)256 - r ( 8 5) r = 256Cr (3) 2 (5) r / 8 Þ m ´ 10 ´ sin 30° = 10 Þ m ´ 5 = 10 Þ m = 2.0 kg
OP24. (5 × 10–5) (1)
256 - r r
Terms will be integral if & both are +ve integer, which
2 8
is so if r is an integral multiple of 8. As 0 £ r £ 256
(2)
\ r = 0,8,16, 24,........256 , total 33 values.
OM75. (2485) Consider the series
112 + 122 + 132 + ....... + 202 The magnetic field due to circular coil,
Tn = [n term of 11, 12, 13,.....]2
= (11 + (n – 1) 1)2 = (11 + n – 1)2 µ0 i1 m 0 i1 m ´ 3 ´ 102
B1 = = = 0
= (10 + n )2 = 100 + n2 + 20 n 2r 2 (2 p ´ 10 -2 ) 4p
Now, Sn = Sn2 + 20 Sn + 100 n
m0 i2 m0 ´ 4 ´ 10 2
n (n + 1) (2n + 1) 20 n (n + 1) B2 = =
= + + 100 n 2(2p ´ 10 -2 ) 4p
6 2
Put n = 10 in Sn, we get m0
B= B12 + B22 = . 5 × 102
10(10 + 1)(20 + 1) 20.10(10 + 1) 4p
S10 = + + 100 ´ 10
6 2 Þ B = 10 - 7 ´ 5 ´ 10 2 Þ B = 5 × 10–5 Wb / m2
10 ´ 11 ´ 21 OP25. (60)
= + 100 ´ 11 + 1000 = 385 + 1100 + 1000 = 2485
6 CHEMISTRY PART - II
MOCK TEST 13 OC46. (9.525)
OC47. (6.3) Number of Eq. of NaOH = Number of Eq. of oxalic acid
PHYSICS PART - II 100 ´ 1 wt.of oxalic acid \ W= 6.3 g
Then =
æ DR ö 1000 63
OP21. (7) \ ç ´100 ÷
..
è R ø max
DV DI 5 0.2 Pp .dp Xc
= ´ 100 + ´ 100 = ´ 100 + ´ 100 = (5 + 2)% = 7 % OC48. (3) O
I 100 10 O
Pp
.dp
V
O
.dp
Pp
OP22. (30) Let e be emf and r be internal resistance of the cell. When no
current drawn from the cell, the potential difference between its
r TN2 M SO2 TN2 64
terminals is the emf of the cell. It is this quantity which the OC49. (373.15) N2 = . = ´
potentiometer measures. Therefore, emf of the cell, e = 1.55V. rSO TSO2 MN2 323 28
2
When the 280W voltmeter is connected across the cell as shown in
adjacent figure, current flows from the cell. The potential difference TN2 16
between its terminals is just the voltmeter reading, 1.40V. 1.625 = .
323 7
C-30 Mock Test
(1.625) 2 ´ 323 ´ 7 t 3´10 -3

TN = = 373.15 K
2 16
OC50. (2) Zn + H2SO4 ® ZnSO4 + H2
\ Impulse = ò Fdt = ò (600 – 2 ´ 105 t ) dt
0 0
Zn + 2NaOH ® Na2ZnO2 + H2
3´10 –3
\ Ratio of volumes of H2 evolved is 1 : 1 = 1 + 1 = 2 é 2 ´105 t 2 ù
= ê600t – ú
MATHEMATICS PART - II êë 2 úû
OM71. (0.94) We have mean (X) = np = 2 = 600 × 3 × 10–3 – 105 (3 × 10–3)2 = 1.8 – 0.9 = 0.9 Ns
1 1 OP22. (50,000) Carrier frequency > audio frequency
and variance (X) = npq = 1 Þ q = Þp= and n = 4 OP23. (24) When no external torque acts on the system the angular
2 2 momentum of the system remains constant.
4 L = I w = constant
æ1ö 15 4
Thus p(X ³ 1) = 1 – p(X = 0) = 1 – C0 ç ÷ = \ I1w1 = I2 w2
è2ø 16
1 é1 2 2ù
2 Mr 2 w1 = ê Mr + mr ú w 2
{ }
-1
OM72. (0) I = ò é f g ( x ) ù f' éë g ( x ) ùû g' ( x ) dx 2 ë2 û
1
ë û
Þ M w = (M + 2m) w 2 Þ 2 × 30 = (2 + 2 × 0.25) w2
Let f { g ( x )} = z Þ f' { g ( x )} g' ( x ) dx = dz 1
60
When x = 1, z = f { g (1)} Þ w2 = = 24 rad/s
2.5
When x = 2, z = f { g ( 2 )} OP24. (2) eE = mew2r
f { g ( 2 )}
1 f { g ( 2 )} e
\I = ò dz = log z f { g (1)} m w2
R
r
f { g (1)}
z
ò
Þ V = E dr = e
e ò rdr
Þ I = log f { g ( 2 )} - log f { g (1)} = 0, (Q g ( 2 ) = g (1) ) .
0
OM73. (8) Let P (a, b , g ), Q (0, 0, g ) and R (a, b , -g )

x - a y - b z - g -2(a + b - 3) me w 2 R 2
= = = Þ V= Þ A= 2
1 1 0 2 2e
OP25. (1.5)
x = 3 - b , y = 3 - a, z = g
CHEMISTRY PART - II
Q (3 - b ,3 - a, g ) lies on z-axis \ b = 3, a = 3
OC46. (10) Given, power = 600 W
P (3,3, g ) distance from x-axis is 5 l = 331.3 nm = 331.3 × 10 –9 m
9 + g 2 = 25 Þ g 2 = 16 Þ g = 4 h = 6.626 × 10 –34 Js
c = 3 × 108 m s –1
P (3, 3, 4) and R (3, 3, - 4) \ PR = 02 + 00 + 82 = 8 t = 1sec
Energy nhc
3 | z |2 3 3z . z Power = =
3
OM74. (4) z + =0, Þz + = 0 Þ z 3 + 3z = 0 Time l´t
z z
Let z = reiq
n ´ 6.626 ´ 10-34 ´ 3 ´ 108
600 =
Þ r3ei3q + 3re–iq = 0 Þ ei4q =-1 [Q r = 3] 331.3 ´ 10-9 ´ 1
Þ cos 4q + i sin 4q = -1
600 ´ 331.3 ´ 10-9
Þ cos 4q = -1 ...(i) Þn= = 1 ´ 1021.
6.626 ´ 10-34 ´ 3 ´ 108
Now 0 £ q < 2p Þ 0 £ 4q < 8p \ q = p, 3p, 5p, 7p
OM75. (1) . .. ..
Xe Xe
MOCK TEST 14 OC47. (7) O O O O
O O
PHYSICS PART - II XeO4(4pp .dp ) XeO3(3pp .dp )
OP21. (0.9) Given F = 600 – 2 ´ 105 t OC48. (88.9) P1 = P; T1 = 273 K
The force is zero at time t, given by 3 T 4
P2 = P ; T2 = T1 + 1 = × 273 K
0 = 600 – 2 × 105t 2 3 3
600 PV
1 1T2
Þ t= = 3 ´ 10 – 3 seconds V2 =
2 ´ 105 P2T1
Mock Test C-31
2 P 4 273 800 1 + tan q 1 – tan q

V2 = ´ ´ ´100cc = cc = 88.888cc = 88.9 cc Þ + = p sec 2q
3P 3 273 9 1 – tan q 1 + tan q
OC49. (1845) Radioactive decay follows first order kinetics. therefore,
(1 + tan q) 2 + (1 – tan q) 2
0.693 0.693 Þ = p sec 2q
Decay constant ( l) = = 1 – tan 2 q
t1/2 5730
Given, R 0 = 100 \ 1 + tan 2 q + 2 tan q + 1 + tan 2 q – 2 tan q
R = 80 Þ = psec 2q
1 – tan 2 q
2.303 [R]0 2.303 100
and t = log = log
l [R] æ 0.693ö 80 2(1 + tan 2 q)
çè ÷ Þ = p sec 2q
5730 ø (1 – tan 2 q)
2.303 ´ 5730 1 é 1 - tan 2 q ù
= ´ 0.0969 = 1845 years Þ 2 = p sec 2q êQ cos 2q = ú
0.693 cos 2q
ëê 1 + tan 2 q ûú
OC50. (176.66) Normality of 3% Na2CO3.
Þ 2 sec 2q = p sec 2q Þ p = 2.
3 ´ 1000
N= = 0.566N OM75. (0) Q AM : BM = b : a
53 ´ 100 \ M divides AB externally in the ratio b : a
For H2SO4 sol. N1 = 0.1, V1 = 100 ml M
1For Na2CO3 sol. N2 = 0.566, V2 ? (x, y)
Now apply N1V1 = N2V2

B
N1V1 0.1 ´ 1000ml (acosb, asinb)
V2 = = = 176.66ml
N2 0.566
A
MATHEMATICS PART - II (bcosa, bsina)
Hence, by sectional formula,
1
1 b × a cos b - a × b cos a
OM71. (0.125) Let I = ò x x - 2 dx x=
b-a
...(i)
0
b × a sin b - a × b sin a
1/ 2 1 and y = ...(ii)
1 1 b-a
= ò x x - dx +
2 ò x x - dx
2 Dividing equation (i) by (ii),
0 1/ 2
a+b a-b
1/ 2 1 2sin sin
æ 1ö æ 1ö x cos b - cos a 2 2
= - ò xç x - ÷dx +
è 2ø ò x ç x - ÷dx
è 2ø
= =
y sin b - sin a -2cos a + b sin a - b
0 1/ 2 2 2
1/ 2 1 a +b a+b
é x3 x 2 ù é x3 x 2 ù 3 1 Þ x cos + y sin = 0.
= -ê - ú +ê - ú = = 2 2
êë 3 4 úû êë 3 4 úû 24 8
0 1/ 2
r r
MOCK TEST 15
OM72. (12) 4a + 3b
PHYSICS PART - II
r r r r r r2 rr
= (4a + 3b ).(4a + 3b ) = 16 a 2 + 9 b + 24 a.b
v2 v2
OP21. (0.70) The centripetal acceleration, a = Þr=
æ 1ö r a
= 144 + 144 + 24 ´ 3 ´ 4 ´ ç - ÷ = 12
è 2ø \ r µ v 2 or v µ r (if a is constant),
OM73. (16)
v1 r1 1
æp ö æp ö Þ = =
OM74. (2) Given : tan ç + q ÷ + tan ç – q ÷ = p sec 2q v2 r2 2
è4 ø è4 ø
OP22. (9.03) Here, T1 = 38°C = 38 + 273 = 311 K
p p T2 = 7° C = 7 + 273 = 280 K
tan + tan q tan – tan q \ coefficient of performance of the refrigerator,
Þ 4 + 4 = psec 2q
p p T2 280
1 – tan .tan q 1 + tan . tan q = = = 9.03
4 4 T1 - T2 311 - 280
C-32 Mock Test
OC50. (0.1) 3CaCl2 + 2Na3PO4 ® Ca3(PO4)2 + 6NaCl

2T cos q 1 h r 2
OP23. (1.5) h = Þhµ Þ 2 = 1 = \ 2 Moles of Na3PO4 = 3 mole of CaCl2
rrg r h1 r2 3
= 1 mole Ca3(PO4)2
æ 3 ö \ 0.2 mole of Na3PO4 = 0.3 mole of CaCl2
çQ r1 = r, r2 = r + 50% of r = r ÷
è 2 ø = 0.1 mole of Ca3(PO4)2
2
2 æ3 ö æ2 ö MATHEMATICS PART - II
New mass m2 = pr2 h 2 r = p ç r1÷ ç h1 ÷ r
è 2 ø è3 ø OM71. (0.33) Let X denotes the number of tosses required. Then
P(X = r) = (1 – p)r – 1 . p, for r = 1, 2, 3 ......
=
3
2
( 3
2
)
pr12 h1 r = m Let E denote the event that the number of tosses required is even.
Then P(E) = P[(X = 2) È (X = 4) È (X = 6) È ......]
1 P(E) = P(X = 2) + P(X = 4) + P(X = 6) + ......
OP24. (1638) Here, n = , c = 3 J g–1 K–1, M = 4g mol–1
2 V 1- p
P(E) = (1 – p) p + (1 – p)3 p + (1 – p)5 p + ...... =
\ CV = McV = 4 × 3 = 12 J mol–1 K–1 2- p
At constant volume P µ T.
2 1
P2 T2 But we are given that P(E) = , then we get p = .
\ = = 2, T2 = 2T1 5 3
P1 T1
OM72. (7) 4 x + 7 y + 4 z + 81 = 0 ...(i)
Rise in temperature DT = T2 – T1 = 2T1 – T1 = T1 = 273 K
5 x + 3 y + 10 z = 25 ...(ii)
1
Heat required, DQ = nCV DT = × 12 × 273 = 1638 J Equation of plane passing through their line of intersection is
2
(4 x + 7 y + 4 z + 81) + l(5x + 3 y + 10 z - 25) = 0
l
OP25. (660) From Dx = Df, or (4 + 5l ) x + (7 + 3l ) y + (4 + 10l ) z + (81 - 25l ) = 0 ...(iii)
2p
plane (iii) ^ to (i), so
Dx 2p(0.4) 4(4 + 5l) + 7(7 + 3l) + 4(4 + 10 l) = 0 Þ l = -1
l = 2p = = 0.5 m
Df 1.6 p From (iii), equation of plane is
v 330 - x + 4 y - 6 z + 106 = 0 ...(iv)
f= = = 660 Hz Distance of (iv) from (0, 0, 0)
l 0.5
106 106
CHEMISTRY PART - II = = » 14.6
1 + 16 + 36 53
OC46. (3) MnO2 , PbO2 and BaO will not give H2O 2 with HCl.
é14.6 ù
MnO2 and PbO2 will give Cl2 and BaO will react with HCl to
\ê = [ 7.3] = 7.
give BaCl2 and water. ë 2 úû
OC47. (0.8481) g–form fcc Z = 4 a = 386 pm OM73. (17)
b–form bcc Z = 2 a = 290 pm 4x
OM74. (2) lim (On rationalization)
rg 4M / N A (386)3 2(290)3 x ®¥ æ 2 2 ö
= = = 0.8481 ç x + 8x + 3 + x + 4x + 3 ÷
rb 2M / N (290)3 è ø
A (386)3
OC48. (70.31) 4
= lim =2
2 x ®¥ æ 8 3 4 3 ö
13.6 Z eff
OC49. (3.08) Eionisation = E¥ – En = eV çç 1 + + 2 + 1 + + 2 ÷÷
n2 è x x x x ø
OM75. (8.6) Arrange the given data in ascending order,
é13.6 Z 2 13.6 Z 2 ù
= ê - ú We have 34, 38, 42, 44, 46, 48, 54, 55, 63, 70
ë n22 n12 û
46 + 48
2 2
Here, median = M = = 47
13.6 ´ 1 13.6 ´ 1 2
E = hn = - ; hn = 13.6 – 0.85 (Q n = 10, median is the mean of 5th and 6th term)
(1)2 (4)2
Q h = 6.625 × 10–34
S | xi – M | S | xi – 47 |
\ Mean deviation = =
13.6 - 0.85 n 10
n= ´ 1.6 ´ 10-19 = 3.08 × 1015 s–1.
6.625 ´ 10-34 13 + 9 + 5 + 3 + 1 + 1 + 7 + 8 + 16 + 23
= = 8.6.
10
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Mock Test-1 A-1 A-121

Mock Test-2 A-9 A-130

Mock Test-3 A-17 A-139

Mock Test-4 A-25 A-148

Mock Test-5 A-33 A-157

Mock Test-6 A-41 A-166

Mock Test-7 A-49 A-174

Mock Test-8 A-57 A-183

Mock Test-9 A-65 A-192

Mock Test-10 A-73 A-202

Mock Test-11 A-81 A-212

Mock Test-12 A-89 A-222

Mock Test-13 A-97 A-232

Mock Test-14 A-105 A-242

Mock Test-15 A-113 A-251

Past JEE Advanced Numerical Value/Integer B-1–B-44

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Q Q OM75. Let the straight line x = b divide the area enclosed by

placed at right angles to each other. 3 ampere and 4

OM75. (325) CHEMISTRY PART - II

T T cos 30º (cos x - 1) (cos x - e x )

1 ± tan 45° MOCK TEST 3

OP25. (8) Inside pressure must be

® C( g ) + 4H( g ) ; DH = 320 cal

Re al depth (R1 ) MATHEMATICS PART - II

Two products are formed. Þ2 2 £ x- y+ x+ y £ 4 2 Þ 2£ x£2 2

Mn3+ + e– ® Mn2+ ...(ii) n ( n + 1)

Required area m = 0.1, d = 10 m

MATHEMATICS PART - II \ I × 280 = 1.40 e r

(1.625) 2 ´ 323 ´ 7 t 3´10 -3

OM73. (8) Let P (a, b , g ), Q (0, 0, g ) and R (a, b , -g )

2 P 4 273 800 1 + tan q 1 – tan q

Now apply N1V1 = N2V2

OC50. (0.1) 3CaCl2 + 2Na3PO4 ® Ca3(PO4)2 + 6NaCl

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Past JEE Advanced Numerical Value/Integer B-1–B-44