Student's Solution Copy [Code - 10847]

12th_ Batch (A* A1 to A9) Eng_ [Mains Pattern]

12th JEE (M) - Phase 1
KOTA

Date: 03-Nov-2022 Duration: 3 Hours Max Marks: 30

Maths - Section A
1. Answer: B 2. Answer: B

Sol: Sol:

Any normal to the ellipse is

2
2
y
Ellipse: ;
x
+ = 1
16 4
x  sec  θ 1
− y  cosec  θ = −
√2
2
Parabola: y
2
= 4(x + 1)

x y
⇒
−cosθ
+
sinθ
= 1
Put x + 1 = X and y = Y;  Y
2
= 4X , so
( ) ( )
√2 2

tangent, is
cos  θ 1 sin  θ
⇒ =  and  = β
2
√2 3√2 1 1
Y = mX + = m(x + 1) +
 m  m

√2
⇒  β =
   .......(1)
1
3 Y = mx + (m + )
 m

2
2 y
If is also a tangent on
x
(1) + = 1
16 4

then c
2
= a m
2 2
+ b
2

2
1 2
⇒ (m + ) = 16 m + 4
 m

2 1 2
⇒ m + 2
+ 2 = 16 m + 4
 m

2 1
⇒ 15m − 2
+ 2 = 0
m

m2 =  15

m = ±
1

√5

5x2 – 1 = 0
3. Answer: D 6. Answer: A

Sol: Sol:

Let P (x1 , log

2
(x1 + 3)) and ∣ →
→
∣ ∣ →
→
∣
∣2 a + 3 b ∣ = ∣3 a + b ∣
Q (x2 , log (x2 + 3)) ∣ ∣ ∣ ∣
2

−
−→ → → → →
∵ OP ⋅ î = 1 ⇒ x1 = 1 ⇒ P(1, 2)  4a2 + 9b
2 2 2
+ 12 a  .   b = 9a + b + 6 a . b

2 2
→ →
−
−→ 5a − 8b − 6 a . b = 0
∵ OQ ⋅ ĵ = 3 ⇒ log (x2 + 3) = 3 ⇒ x2 = 5 ⇒ Q(5, 3)
2
→ →
∣ ∣
∣ ∣ 2 1
∵ a = 8⇒5 × 64 − 8b − 6 .8 ∣ b ∣ × = 0
∣ ∣ ∣ ∣ 2

−−
→ −−→
∣ ∣ ∣ ∣
∣OQ − 2 OP ∣ = ∣5 î + 3 ĵ − 2( î + 2 ĵ )∣ 2
∣ ∣ ∣ ∣ 320 − 8b − 24b = 0

2
b + 3b − 40 = 0
=|3 î − ĵ ∣
∣ =
√10
→
∣ ∣
4. Answer: C (b + 8) (b − 5) = 0                 ∴ ∣ b ∣ = 5
∣ ∣

Sol: 7. Answer: C
p.V. of M = 4, −1, 4 Sol:
−−→
It is given that the angle between a and c is
now ˆ
AM = 4 î − ĵ + 4k
−1 1
cos
4
∣−−→∣
∣AM ∣ = √33
So, −1 1
∣ ∣ a ⋅ c =∣
∣a ∣
∣∣∣c ∣
∣ cos (cos )
4

 ...(i)
1
⇒ a ⋅ c =
4

Taking dot product by a,b and c we have,

2

Similarly, b.c  ...(iii)

λ λ
= 8 − −
2 4

and b.c −2 = λ(a ⋅ c)  ...(iv)

5. Answer: A From Eqs. (ii), (iii) and (iv), we get

Sol: λ
2
λ 1
8 − − − 2=λ ( )
2 4 4

⇒ λ = 3, −4

−
−→ −
−→
Projection of BA on BC is equal to

∣ →∣
= ∣B A ∣ cos θ
∣ ∣

49+9–25 11
cosθ = =
2.7.3 14

7×11
∴ BA cosθ =
14

11
=
2
8. Answer: C 11. Answer: A

Sol: Sol:

at x = 2 If  sinx = cosx x=

π
⇒
4

y=8−8+4=4 dy
If  y = sinx
1
⇒( ) =
dx
so point is (2,4)
√2
x = π/4

y = x3
dy
If y = cosx
2 −1
− 2x + 4 ⇒( ) =
dx √2
x = π/4
dy
∣ 2
= 3x − 4x= 12 − 8 = 4
dx ∣ m1 −m2
x=2 −1
tanθ = = 2√2⇒ θ = tan (2√2)
1+m1 m2

for normaly
Therefore, the correct answer is (A)
m1m2 = −1
12. Answer: D
m2 =− 14
Sol:
equation of normal 3 2
y = x ;   6y = 7 − x
−1
(y − 4)= (x − 2)
4 dy dy
2
= 3x ;   6 = 0 − 2x
dx dx
4y − 16=−x + 2
dy 2
m1 = ( ) = 3 × 1 = 3
x + 4y = 18 dx
(1,1)

Therefore, the correct answer is (C) dy

m2 = ( ) = −1/3
dx
9. Answer: C {1,1)

Sol: ∵ m1 m2 = 3 × (−1/3) = −1

xyn = an+1, a ≠ 0 ∴ θ = 90°

Therefore, the correct answer is (D)

yn + nxyn − 1
dy dy y
= 0  i.e.  = − nx
dx dx

13. Answer: B
∴ length of subnormal
dy
∣ y
2
∣ ∣ y .y
2 n
∣ ∣ y
n+2
∣ Sol:
=
∣
∣
y.
∣
∣
= = =  is
dx ∣ nx ∣ ∣ na
n+1
∣ ∣ na
n+1
∣

constant only if Equation of normal to x2 = 4y  is

n = − 2. x = my − 2m − m
3
and passing through (1, 2)
.
Therefore, the correct answer is (C)
3
∴ 1 = 2 m − 2 m − m
10. Answer: B
⇒ m
3
= −1  or  m = −1 
Sol:
Thus, the required equation of normal is,
It is given that (δr/r) × 100  = 1 .
x = −y + 2 + 1  or x + y − 3 = 0 is required
3
 
v =  (4/3)πr
; log  v  =   log  (4π/3)+3  log  r
equation.

Therefore option (B) is correct 

1 3
δv = δr
v r

1 1
⇒ . δv × 100= 3 ( δr × 100)= 3
v r

Hence, error in volume is with in 3%

Therefore, the correct answer is (B)

14. Answer: B 15. Answer: A

Sol: Sol:

Given,   st   =  1
Given, f(
x+y
) =
f(x)+f(y)
∀x, y ∈ R

2 2

According to the question,we know  that

Equation of Tangent at P to parabola ; on puttin by y = 0, we get

2

ty = x +   at
f(x)+f(0)
x 1
f( ) = = [1 + f (x)]

2 2 2
2

⇒ y =
x

t
+
at

t
   … . . (1)

x
⇒ 2f ( ) = f (x) + 1 .... (i)
2

Normal at S : y + x
=
2a
+
a
   … . . . . (2)

3
t t t x
⇒ f (x) = 2f ( ) − 1, ∀x, y ∈ R
2

Solving (1) & (2), we get

since, f ' (0) = -1 we get

2y = at +
2a
+
a
3

t t
f(0+h)−f(0)

4 2
lim = −1

4 2 a(t +2t +1) h

at +2 at +a h→0
2y = =
t
3
t
3

f(h)−1
2
a(t +1)
2
lim = −1 ....(ii)
y = 3
h→0
h

2t

Therefore, the correct answer is (B) Again, f' (x) = lim

f(x+h)−f(x)

h→0
h

2x+2h
f( )−f(x)
2

= lim

h
h→0

f(2x)+f(2h)
−f(x)
2
= lim

h
h→0

1 2x 2h
[2f( )−1+2f( )−1]−f(x)
2 2 2

= lim
h→0
h

                                              [Equation ..
(i)]

1
[2f(x)−1+2f(h)−1]−f(x)
2
= lim
h
h→0

f(h)−1
= lim = −1 [Equation .. (ii)]

h
h→0

∴ f' (x) = −1, ∀x ∈ R

⇒ ∫ f' (x) dx = ∫ −1dx

⇒ f (x) = −x + k

where, k is a constant

but f (0) = 1,

threfore f (0) = -0 + k

⇒ 1 = k

⇒ f (x) = 1 − x, ∀x ∈ R ⇒ f (2) = −1
16. Answer: D 19. Answer: B

Sol: Sol:

tangent of hyperbola α + β = −
b
,αβ =
c

a a

2
y = mx ± √9 m − 16             …(i) Let α', β' are the roots of px2 + qx + r = 0
which is a chord of circle with mid-point (h, k) α' = α + h ,  4A + 4B + 4C =
1 1 1 244
= 61 ,
4

so equation of chord T = S1 q 2
′ ′ ′ ′
α + β = − ,α β =
2 2 p p
hx + ky = h + k
2 2 α' − β'= (α + h) − (β + h)=(α + h)−
h +k
y = −
hx

k
+
k
              …(ii) (β + h)

by (i) and (ii) α' − β' = α − β⇒(α − β)

2
= (α − β)
2

2 2
h +k
m = −
h
    and √9 m2 − 16 =
(α' + β')
2
− 4α'β'⇒(α + β)
2
+ 4αβ
k k

2
(h +k )
2 2
Now put the value 
h
9 2
− 16 = 2
k k 2 2
−q r −b c
( ) – 4. =( ) − 4
locus 9x2 – 16y2 = (x2 + y2)2 p p a a

17. Answer: A
2
b −4 ac q −4 pr
2 2
2
= 2
⇒ k1 = a , k2 = p
a p

Sol:
then k1 + k2 = a
2
+ p
2

20. Answer: B

Sol:
n+1

Sn = 1 + q + q2 + .... + qn =
q −1

q−1

n+1
q+1
( ) −1 n+1 n+1
2 (q+1) −2
1 Tn = ⇒ n
2x ×2ae×b q+1
(q−1)×2
2Δ 2
−1
r = = ′
2
2S PS+PS +2 ae

2ae×b be
Let
= =
2a+2 ae 1+e
101 101 101
S= C1 + C2S1 + ........ + C101 S100
18. Answer: C 101
100
S= ∑ Cr+1 Sr
Sol: r=0

r+1
101 q −1
100
For intersection point = ∑
r=0
Cr+1 × (
q−1
)

−|x| −|x|
1 − e = e 101
100
=
1 r+1
  ∑ Cr+1  × q − 1
q−1 r=0
−|x| 1
e =
2

= [(1 + q)101 – 1 – (2101 – 1)]

1

q−1
−|x| = − ln 2
101 101
(1+q) −2
x = ln 2, − ln 2 = q−1

101 101
(1+q) −2
Now,  T100 = 100
(q−1)×2

Therefore, the correct answer is (B).

 Maths - Section B
1. Answer: 1 3. Answer: 75

Sol: Sol:
2 2 2
sinx cos2y = (k
2
− 1) + 1 ≥ 1 (not possible) x + 4y +2x+8y−λ=0


2
2
≥1 (x + 1) − 1+4 (y + 2y)−λ= 0

∵ sinx cos2y ≤ 1 (always) 2 2

(x + 1) − 1+4(y + 1) −4−λ=0

(k2-1)2+1=1⇒
2
2
∴ (k − 1) = 0 ⇒ k = ±1
2 2
(x + 1) +4(y + 1) −5−λ= 0

And
2 2
(x + 1) +4(y + 1) =5 + λ
cosx sin2y = k+1≤ 1 (always)
2 2
(x+1) (y+1)
–1 ≤ k ≤ 0
+ = 1
(5+λ) 5+λ

So, possible value of k is -1

( )
4

No. of possible value of k = 1

5+λ
2
2( )
4

Length of Latus Rectum =

2b
= = 4
a
2. Answer: 1 √(5+λ)

Sol: ⇒
√(5+λ)
= 4
2

(a + b + c) (b + c − a) = 3bc
⇒ 5 + λ = 64
2 2
⇒ (b + c) −a = 3 bc ⇒ λ = 59

⇒ b
2 2
+ c +2bc − a = 3 bc
2
Major axis = 2a = l

2 2 2
⇒ b + c − a =bc ⇒ 2√(5 + λ) = l

2 2 2
b +c −a 1
⇒ = l = 2√5 + 59
2 bc 2

1
⇒ cos A = l = 2√64
2

π ⇒ l = 16
⇒ A =
3

⇒ λ + l= 59 + 16= 75
π 3.14
⇒ [A] = [ ]=[ ] = 1
3 3 4. Answer: 2

Sol:

f (x) =[6x + 7]+cosπx–6x

⇒ f (x)= [6x + 7]+cosπx–(6x + 7)+7

f (x)=– {6x + 7}+cosπx+7

Thus period of and period of

1
{6x + 7} is
6

cosπx is 2.

Hence period of f is = L.C.M of and  2 = 2.

1

6
5. Answer: 39 6. Answer: 4

Sol: Sol:
P(x)
,x ≠ 2
Equation of the reflected ray BP can be taken
f (x) = {
sin(x–2)
as
7 ,x = 2
x − 2y − 3 + λ (3x − 2y − 5) = 0         ....
 P”(x) = const. ⇒ P(x) is a 2 degree (1)
polynomial Now perpendicular from Q (x1, y1) are (1)
f(x) is cont. at x = 2 and x − 2y − 3 = 0 should be equal
 f(2+) = f(2–) ∣ ∣
x1 −2y1 −3 x1 −2y1 −3+λ(3x1 −2y1 −5)
∣ ∣
=∣
∣

P(x)
∣ ∣ ∣ ∣
√5
lim = 7 2
√(3λ+1) +4(λ+1)
2

+ sin(x–2)
∣ ∣
x→2

(x–2)(ax+b)
lim = 7 ⇒ 2a + b = 7
+ sin(x–2)
x→2

P (x) = (x– 2) (ax + b)

P (3) = (3– 2) (3a + b) = 9 ⇒ 3a + b = 9

a = 2, b = 3

P (5) = (5– 2) (2 .5 +3) = 3 .13= 39

or (3λ + 1)2 + 4 (λ + 1)2 = 5]

9λ2 + 1 + 6λ + 4λ2 + 8λ + 4 = 5

13λ2 + 14λ = 0

⇒λ=− 14
(as λ ≠ 0)        
13

∴ required equation is

⇒x − 2y − 3 − 14

13
(3x − 2y − 5) = 0

⇒13 x − 26 y − 39 = 42 x − 28 y − 70

⇒ 29 x − 2 y = 31

7. Answer: 3

Sol:

Let equation of the circle 

2 2
x   +  y  + 2 gx   +  2 fy  + c  =  0 , it is
orthogonal to both circles so

2g1 g2 + 2f1 f2 =c1 + c2

from here g = −2,  c = −11

to radius = √4 + f 2 + 11

(radius)  min
= √15

 
8. Answer: 4 10. Answer: 2.5

Sol: Sol:
–1
Let sin (x + 2) = α ⇒ x + 2 = sin α Slope of the tangent is  3 = tanθ
4

–1
∴ 2α = cos (x + 3) Slope of the focal chord through P(3,  4) is 
2tanθ
cos 2α = x + 3 = (x + 2) + 1 = 1 + sin α tan 2θ =
2
1−tan θ

2
1 − 2 sin α = 1 + sin α

sin α (1 + 2 sin α) = 0

⇒ sin α = 0         or sin α = −
1

∴ x = − 2         or x = − 2.5 (rejected)

∴ x2 = 4
3
2( )
9. Answer: 1 i.e. tan 2θ =
4

=
24
9
7
1−
16

Sol:
cosecx
∞
Equation of the focal chord through P is 
(cosx−sinx)
L1 = lim e ⇒ 1 24
x→0
− (y − 4) = (x − 3)
7

cosx−sinx−1

Focus is S (
( ) 11
l = lim e
sinx
,  0)
6
−
x→0

2 x x x
Distance of the focus from the tangent is
1−2 sin −2 sin .cos −1
2 2 2
( x x
)
2 sin .cos ∣ 11 ∣
2 2 3( )−4(0)+7
= lim e ∣ 6 ∣ 5
− = = 2. 5
x→0 2 2 2
√3 +4

x x
sin +cos
2 2
( x
)
cos −1
= − lim e 2
= e
−
x→0

⇒ L1 = e–1 ∴ a = 1/e (as function is

continuous)
1/x 2/x 3/x
e +e +e
L2 = lim
2/x 3/x
+ a.e +b.e
x→0

Divided Nr & Dr by e3/x

−2/x −1/x
e +e +1 1
= lim =
+ a.e
−1/x
+b b
x→0

  by definition  b  ⇒ b = e
1 1 1
⇒ L2 = =
b e

∴ a.b = 1
 Physics - Section A
1. Answer: D 4. Answer: D

Sol: Sol:

As we know F =
ΔP
    Parallel axis theorem
Δt

ΔP = FΔt                 ........(1) I = ICM + Md

2
2
5 × Vf – 10 = 0.2 × 10 I =
Mr
+ M(
L
)
2 2

5Vf = 2 + 10 (0.2)
2
2
0.8
2 .7= M + M( )
2 2
Vf =
12

5
2 16
2 .7= M [ + ]
p 100 100
Initial velocity Vi =  m = 2m/s
10
=
5
M = 15 kg
So change in kinetic energy =
1 2 2
m (V − V )
2 f i M 15
⇒ ρ = 2
=
2
πr L π(0.2) ×0.8
2 2
= 1
× 5 {(
12
) − (2) }
 = 0.1492 × 10  kg/m3
2 5 3
ρ

=
1 44
× 5 ( ) = 4 .4 J
2 25 5. Answer: B

2. Answer: D Sol:

Sol: displacement

initially potential energy  = mgh = mg (10)

3

 
t
x =
3

as 40 % energy is lost on collision

speed
Let ball rebound to height h' afther striking
  dx
= t
2

dt
then,
at t = 2 sec       
mgh' = 0.6 (mg 10)
dx
v = = 4
⇒h=6m dt

  at t = 0, v= 0

3. Answer: A by work energy theorem

Sol: work done = change in kinetic energy

W = 2 mv2
1 1
= × 2 × 4 × 4 = 16J
2

Therefore, the correct answer is (B).

6. Answer: C

Sol:

R = 75×102 ±  5% of 7500

R = (7500 ± 375) Ω
M = 1.5 kg, r = 0.5 m, d = m
5

2 2 2
I = 2( Mr + Md )
5

= 19.05 kgm2
7. Answer: D 9. Answer: A

Sol: Sol:

(VD − V) C2 + (VD − 0) C3 = 0
Total energy at point A = Total energy at B
(VD − V) 6 + (VD − 0) 12 = 0
1 2
mgL = mv
2 B

VD − V + 2VD = 0

VB = √2 gL
V
VD =
3
2
mv
at B point T = mg + B

V L
q2 = (V − VD ) C2 = (V − ) (6μF)
3
m(2 gL)
= mg + = 3 mg
L
q2 = (4V) μF

V
10. Answer: C
q3 = (VD − 0) C3 = × 12μF = 4VμF
3
Sol:
q1 = (V − 0) C1 = V(2μF)
Potential difference across AB will be equal to
q1 : q2 : q3 = 2 : 4 : 4 battery equivalent across CD
E E E
1 2 3
q1 : q2 : q3 = 1 : 2 : 2 r
+
r
+
r
1
+
2
+
3

1 2 3 1 1 1
VAB = VCD = 1 1 1
= 1 1 1

8. Answer: D
+ + + +
r r r 1 1 1
1 2 3

Sol: =
6
         = 2 V
3

6
Ceq =
13
μF 11. Answer: C

Therefore three capacitors most be in parallel Sol:

to get 6 in
Forces acting on water are weight mg and the
1 1 1 1 1 1 → −
→
Ceq
=
3C
+
C
+
C
+
C
+
C force of pail on water F P . FP   may be termed
reaction of pail on water . Same force will be
exerted on pail by water .
3C 6
Ceq = = μF
13 13

Therefore correct option is (D).

(A)         At top of the circle,

2
mv
t
N + mg =
r

2
mv
t
N = − mg
r
12. Answer: A 16. Answer: D

Sol: Sol:
eV
0
h (ν−ν0 )=
2

ν
h( −ν0 )=eV0
  2

ν−ν0 1
ν
=
2
−ν0
2

Given:- I1 = 3A and I1 = 1A ν0 = 2ν −
ν

E1 +E2
= I = 3 3ν
R+r1 +r2 ν0 =
2

R + r1 + r2 = E1 + E3 /3 .....(1) Therefore, the correct answer is (D).

(E1 − E2 ) = (R + r1 + r2 ) ......(2) 17. Answer: C

Equating eqn  (1) and (2) Sol:

2
Z
3 (E1 − E2 ) = E1 + E2 En =– 13 .6 2
n

2E1 = 4E2
Enth of Carbon = E
1
st of Hydrogen
E1 /E2 = 2/1 2 2
6 1
– 13 .6 × =– 13 .6 ×
2 2
n 1
13. Answer: A
n=6
Sol:
18. Answer: B
P = I2R
4.4 = 4
× 10-6 R Sol:
R = 1.1 × 106 Ω

h h
λ = =
2 2 p

10–6      10–5
√2m(K⋅E)
P' = = × = 11 × W
11 11

R 1.1
1
λ ∝
14. Answer: A √m

Sol: me < mp < mn < mα

x 20 1 4x 1 λα < λn < λp < λe

= − 20 = ∴ =
4 100 4 4 100−P

1 R
19. Answer: C
or 4( ) = ∴ ℓ = 50 cm
4 100−ℓ
Sol:
15. Answer: B
For every large distance P.E. = 0 & total
Sol: energy = 2.6 + 0 = 2.6eV 
The pressure exerted by the photons Finally in first excited state of H atom total
I 2I
energy
P = 0. 75 × + 0. 25 ×

c c

(P =  pressure, c =  speed of light, I =  intensity )

= –3.4 eV

I
Loss in total energy = 2.6 – (–3.4)
P = 1. 25 ×
c

                                 = 6eV
We know the force can be computed using
It is emitted as photon
F = P × A  (F =  force, P =  pressure, A =  area )
 = 1.45 × 1015 Hz
1240
λ = = 206 nm
6
50×1
F = 1. 25 × ( )
= 1.45 × 109 MHz
8
3×10

−8
F = 20. 83 × 10  N
20. Answer: B Sol:

Centripetal acceleration of the particle is given

by the formula
2

=
v 2
= 4/r
r

on comparing

v = 2/√r

Now the momentum of the particle is the

product of mass and velocity
2
P = mv = m ×
√r

2m
P =
√r

Therefore correct answer is (B)

 Physics - Section B
1. Answer: 25 3. Answer: 5

Sol: Sol:

H = i2Rt At topmost point

10 × 10-3 = 4 × 10-6 R

=
3

10 ×   = R
10
∴
4

∴ R = 2500 W

2. Answer: 24.00

Sol:

Applying conservation of momentum

v0 v0
3m =−m + mvx ⇒ vx = 2v0
2 2

3v0 3v0
O= m
2
− m vy ⇒ vy =
2

2 2
v = √vx + vy
According to figure
5v0
2
⇒ v =
μ(2√3) 2

Tension acting on a plane T =

2
4. Answer: 8
2 4×3 24
T =
4
×
2
=
8
N
Sol:

Given, Tension in string just after it becomes Mechanical energy at point A = EA

taut is  8 N
X

EA = – GMm
– GMm
+  (1/2)mv20
R 9R

Value of  X = 24N

Mechanical energy at point B = EB
    
EB = –  – + mv2
GMm GMm 1

5R 5R 2

Using energy conservation EA = EB

– – + 2 mv0 = 2 mv2 – ×2
GMm GMm 1 2 1 GMm

R 9R 5R

GMm(10)
– + = mv2 – mv0
GMm 1 1 2
⇒
9R 5R 2 2

mv2 =
GMm[–50+18]
= mv20
1 1
⇒

45R 2 2

– + mv20 0
GMm 32 1
⇒ ≥

45R 2

1 2 32 GM 2 64 GM
⇒ v ≥ ⇒ v ≥√
2 0 45R 0 45R

∴ n=8
5. Answer: 1.12 8. Answer: 3

Sol: Sol:

I =
e
=
eω
=
eV
The relation between the potential and the
electric field is given by
T 2π 2πr

−19 6

I = 
1.6×10 ×2.2×10 ×7
→−
→
−10 r2
2×22×0.5×10
V = −∫ E. d r
r1

   = 1.12 mA
ℓ=0
→ →
𝓁=0
    112 × 10–2 mA − ∫ E . dl = ∫ dV = Vcenter − V∞

ℓ=∞ 𝓁=∞
6. Answer: 05.00
9 −10
Kq 9×10 ×1×10
Sol: Vcentre =
R
=
0.3
= 3V

The block begins to slide, if V∞ = 0

Fcos 37° = μ (mg − Fsin 37°) ℓ=0

→ →
− ∫ E . dt = 3V − 0 = 3V
5t [cos 37° + μsin37°] = μmg
ℓ=∞

9. Answer:
4 3
5t [ + ] = 70
5 5

or t = 10 second Sol:

7. Answer: 1 1 m2 ×C have energy in 1sec = 200

1 mm2× C have energy in 1sec =  200 × 10
−6

Sol: Energy
C

no of photons = 
By using potrntial energy and force relation, 
hc /λ

−6 −10
200×10 ×2640×10
F = – dU
dr
=
8
3×10 ×1240×1.6×10
−19
= 885

5β 10. Answer: 01.46

F = –[−
10α
11
+ 6
]
r r

Sol:
for equilibrium, F = 0 4
l 2 10 3 2
p = (1 + r) cos θ = 8
[1 + ] cos 60°
5β c 4
=
10α 3×10
11 6
r r
−4
10 7 1 7 −4 70 −5 2
5 = × × = × 10 = × 10  N/m
=r
2α
3 4 4 48 48
β

−5 −2
= 01. 46 × 10 Nm
1/5

r=
2α
( )
β

a/b

Given,( 2α )
β

a/b 1/5

= (
2α 2α
( ) )
β β

a=1
 Chemistry - Section A
1. Answer: C 6. Answer: A

Sol: Sol:

(A) and (B) have negative overlap while (C)

has positive overlap. Thus (C) will show
effective overlapping. 

2. Answer: C

Sol:
Therefore, the correct answer is (A).
In CCP lattice octahedral voids are present at
all edge centres and at bondy centre, where 7. Answer: C
as tetrahedral voids are present at body
digonals (1/4 th distance from the corner) Sol:

The plane is cut through are of the body
diagonal of the cube. so, the cross-section
would be as follows
A) To complete the octet of trivalent Al atom,
Cl donates one lone pair of electrons in the
vacant orbital of Al, forming a co-ordinate
bond. In one bond there are three atoms
involved, two are aluminum and one is
chlorine therefore 3 centered. Also, each
banana bond involves 4 electrons, two from
covalent bond and two from co-ordinate bond.
Therefore, 4 electrons. That’s why it is called
a 3C−4e− bond.

Ans (3)

3. Answer: A

Sol:
 
Draw F. P. formula B)  Al2 Me6   exists mostly as a  dimer  at room
temperature, the shared methyl groups bridge
4. Answer: D between the two aluminum atoms. All the C atoms
are singly bonded to Al and are sp3 hybridized. 
Sol:

Both molecules are non-superimposable mirror

image of each other

5. Answer: D

Sol:
 
 
C) Each I is sp3d2 hybridized and adopts a square
planar geometry and in order to  minimize the
repulsion of lone pair on I-atoms overall molecule
is planar. 
 

D)  Al2 Br6  consists of two AlBr4  tetrahedral that

share a common edge.
The atomic hybridization of aluminium is often
described as sp2 and it is non-planar.
 
8. Answer: B 11. Answer: C

Sol: Sol:

K3[Co(CN)6] (1) The van der Waals force increases with the
Co+3 → [Ar]18 3d6 increase in the size of the atom, and therefore,
the boiling point increase from He to Rn. So
order of boiling point is He < Ar < Rn.

(2) Strength of Hydrogen bonding depends on

The hybidization will be d2sp3 and geometry
will be octahedral. In octahedral complex
ligands approach the metal along x, y and z
axes, and the d-orbitals whose lobes are
oriented in x, y and z axes are dx2-y2 and dz2.
the size and electronegativity of atom. Smaller
the size of the atom, greater is the
electronegativity and hence stronger is the
hydrogen bond. Here each  H2 O2   molecule is
linked with 8 other  H2 O2   molecules through
hydrogen bonding. Also, each  HF  molecule is
linked with  2  other  HF​ molecules but each 
H2 O  molecules is linked with  4  other  H2 O

Hence, they face the ligands directly.   molecules through hydrogen bonding.  NH3
 has weakest hydrogen bonding. So, the order
9. Answer: C of boiling point is: H2 O2  > H2 O > HF > NH3 .
Sol: (3) In  CCl4 , bond polarity is present but not
in  Cl2 , so this increases the boiling point of 
D =  λ
hC

absorbed CCl4 .

          i.e. means  

Δ ↑ λabsorbed ↓    (4) In the Br2   molecules, only dispersion
forces  operate. Dispersion foces also operate
          Δ α strength of ligand in  ICl, and would be expected to be greater.
          Δ :C>N>O In  ICl, iodine atom has more polarizable
electron cloud, and also in  ICl there would be
          So, some bond polarity as chlorine is more
electronegative than iodine. So, boiling point
Δ : [Co(CN)6]3–  > [Co(NH3)6]3+ > of ICl is greater than Br2 .
[Co(H2O)6]3+
12. Answer: D
: [Co(CN)6]3– < [Co(NH3)6]3+ <
λabsorbed
[Co(H2O)6]3+ Sol:

10. Answer: B Dolomite is mixed carbonate of calcium and

magnesium i.e. CaCO3.MgCO3
Sol:
13. Answer: D

Sol:
Mass of SO2
40 ppm =   ⇒Mass of SO2 = 
6
× 10
Mass of air
40×Mass of air
6
10

2 gm
dair =  Mass of air
=
lit.
 ⇒ Mass of air = 2 ×
Vair (lit.)

100 = 200 gm

Mass of SO2 =  400×200  = 8 × 10–3 gm 6

⇒ 8 mg
10

Therefore, the correct option is (2) 14. Answer: B

Sol:

ΔG = ΔH − TΔS . If TΔS > ΔH , then 

ΔG < 0
15. Answer: A 18. Answer: A

Sol: Sol:

Given, wB = 13.44 gm Electron withdrwing groups (EWG)

increases acidic strength as they stabilize the
wA = 1kg conjugate base formed after. 
MB = 134.4 gm/mol The order of elctron withdrawing strength of
Kb = 0.52 K molal –1 the groups is: -NO2 > -CN > -F > -Cl
Therefore, the order of acidic strength is:
∵  ΔTb = i × Kb × m
NO2CH2COOH > NCCH2COOH > FCH2COOH >
for CuCl2         i=3 ClCH2COOH

Tb – T0b  = 3 × 0.52 × 
13.44
19. Answer: B
134.4×1 kg

Sol:
∵ T   0

b
 = 100°C

 ΔTb = 0 .156 K 

Therefore, the correct answer is (A)

16. Answer: D

Sol:
                            or
This is a heterogeneous equilibrium. The
equilibrium constant for it can be written as:
                
Kc = [CO2 ]

The concentration of CaCO3 and CaO are Therefore, the correct answer is (B).
assumed to be constant as they are present as
20. Answer: C
solid.
Sol:
Hence, CaCO3 has no effect on equilibrium
concentration. In reaction
17. Answer: A

Sol:

H2O(l) ➝         ΔH =
+ −
Haq + OHaq
following radicals can be formed
57.32kJ

H2 + 1

2
O2 ➝H2O (l)                ΔH = –386.2
kJ

57.32 = ΔH0f Haq

+
+ ΔH0f OHaq
−
– ΔH0f H2O
The order of stability of free radicals is as
= 0 + ΔH0fOH– = 57.32 – 286.2 follows
= –228.88 kJ. 3
o
> 2
o
> 1
o

Therefore, the correct answer is (A) Therefore, 3o  radical will be formed in major
quantity and all other radicals are formed in
minor quantities

Hence, the correct answer is (3)

 Chemistry - Section B
1. Answer: 2 3. Answer: 86.30

Sol: Sol:

[Fe(CN)3]3– ⇒ C. N. = 6 n = 5 ; T = 300 ; V1 = 10 L & V2 = 20 L

→  as in question it is mentioned inner d- W = − nRTln

V2
= −5 × 8.314 × 300 × 2.303  ln
complex V1

Means Hybridization is d2sp3 (octahedral) = – 5 × 8.314 × 300 × 2.303 × 0.3010

Splitting of octahedral complex = 8630 J

4. Answer: 4

Sol:

The addition of HCl on multiple bonds is an

electrophilic addition reaction. In this reaction,
carbocation is formed as an intermediate.
→ as ligand approaches along the axis in
octahedral complex ; so the orbitals which are
along the axis will get repulsion.

→ Hence along the axis orbitals i.e.   dz2& 

dx – y2  get more energy.
2

Now,     O.N of Fe here is

[Fe(CN)6]3–         ⇒  -3 – {–1 × 6}

                           ⇒ +3 All the four types of carbonation form 4

different types of products by reaction with
Fe        → [Ar]3d64s2 Cl–.
Fe+3     → [Ar]3d54s0

⇒ as here S.F.L. so Hund's rule will not

followed here, so Δo > P. E.

⇒ Hence t2g will first filled

5. Answer: 4

 CFSE  = 5 ×
−2
Δ0 = −2Δ0 Sol:
5

{here paring energy is said to ignore in

question}

2. Answer: 7

Sol:

In 1N H2O the [H+] = 10–7

                         [OH⊝] = 10–7 at 25ºC (i)  Chlorination at C-2 and C-4 produces no
∴ P
H =– log[H+] =– log[10–7] =7 chiral compounds

Therefore, the correct answer is (A) (ii) Chlorination at C-3 produces a chiral
carbon marked with a star (d and l form)

(iii) Chlorination at C-1 also produces a chiral

carbon marked with a star (d and l from)

Therefore, the correct answer is (B).

6. Answer: 2 9. Answer: 0.2

Sol: Sol:

Buffer → Basic buffer

[  salt  ]
OH
p = pk + log
b
[  base  ]

7. Answer: 5 Taking antilog,

Sol: [OH
−
] = kb ×
[  salt  ]
⇒ [OH
−
] = 10
−5
×
0.1
=
10

[  base  ] 0.2

(i) The covalent nature decreases with

increase in the size of cation since the Mg(OH) ⟶ Mg
2+
+ 2 OH
−

polarizing power decreases with increase in the 2

size. 2
2+ −
Ksp = [Mg ][OH ]
(ii) According to Fajan's rules, the greater the
charge the greater is the polarizing power of Ksp
−11
+2 10
cation. [Mg ] =
−
2
=
−5
2
(OH ) (10 /2)

(iii) The polarizability of halide ions increases

−1
with increase in their size and hence the = 4 × 10 = 0. 4

covalent nature also increases.

  Mole   =   conc. ×  volume  

(iv) According to Fajan's rule. as size of anion moles of MgCl2 = 0. 2  moles  

increases and charge on anion increases
polarisability of anion increasing and thus millimoles  =0.2×1000 = 200
covalent character increases. 10. Answer: 17.22
8. Answer: 4 Sol:
Sol: 2SO2(g) + O2(g) ⇌ 2SO3(g)

(PSO )
3(g)

KP = × PO
PSO 2(g)
2(g)

=
43×43

45×45
× 530 P a
−1
 = 172.28 × 10–5 Pa–1
Average
= 172.28 atm-1
O.S.  of   'S' : 2                          3
Hybridisation   = 17228 × 10-2 atm-1
of 'S'                      sp3 sp3
Due to more s-character in orbital containing lone Ans. is 17228
pair, S–O bond in S2O42– has more p-character &
hence longer bond length.