Polymers

Time: 1 Hrs. XII (NEET/JEE-MAIN) M.M.: 260

Q.1 Which of the following is not a copolymer- Q.13 Neoprene rubber is obtained by the
(A) Plexiglass (B) Buna-S polymerization of :
(C) Nylon-66 (D) Dacron (A) 1, 3-Butadiene
Q.2 Polymerisation in which two or more chemically (B) 2- Methyl -1, 3-butadiene
different monomers take part is called- (C) 2- Chloro -1, 3 butadiene
(A) Addition polymerisation (D) Styrene and butadiene
(B) Copolymerisation Q.14 Which of the following is not a natural polymer
(C) Chain polymerisation (A) Starch (B) Cellulose
(D) Homopolymerisation (C) Glyptal (D) Glycogen
Q.3 Chemical name of melamine is- Q.15 Which of the following is natural polymer:
(A) 2,4-Diamino-1,3,5-triazine (A) Polyisoprene
(B) 2-Amino-1,3,5-triazine (B) Polybutadiene
(C) 2,4,6 -Triamino-1,3,5-triazine (C) Polyethylene terephthalate
(D) 1,3,5-Triamino-2,4,6-triazine (D) Polyethylene
Q.4 Carprolactum is used to prepare which of the Q.16 The example of thermosetting plastic and
polymer- thermoplastic polymer respectively is-
(A) Nylon – 66 (B) Melamine (A) Polystyrene, polyvinyl chloride
(C) Nylon – 6 (D) PMMA (B) Bakelite, polystyrene
Q.5 The fibre obtained by the condensation of (C) Polythene, polyacrylonitrile
hexamethylene diamine and adipic acid is- (D) Polystyrene, urea formaldehyde resin
(A) Dacron (B) Nylon 66 Q.17 Which of the following is wrong:
(C) Rayon (D) Teflon (A) PMMA is called plexiglass
Q.6 Of the following which is a step growth polymer- (B) PTFE is called teflon
(A) Bakelite (B) Polyethylene (C) SBR is called natural rubber
(C) Teflon (D) PVC (D) LDPE is called low density polyethylene
Q.7 Bekelite is: Q.18 Which is not a rubber polymer-
(A) Addition polymer (B) Elastomer (A) Neoprene (B) Gutta percha
(C) Thermoplastic (D) Thermosett (C) Buna-S (D) P.M.M.A.
Q.8 Perlon is: Q.19 Match List – I [polymers] with List – II
(A) Rubber (B) Nylon [monomers] and choose the correct answer
(C) Terylene (D) Orlon from the codes given below the list-
Q.9 Nylon-6, 6 is made by the polycondensation of: List–I [Polymer] List–II [Monomer]
(A) Adipic acid + Hexamethylene diamine A. P.A.N. a. Chloroethene
(B) Phthalic acid + Glycerol B. Natural rubber b. Caprolactum
(C) Phenol + Formaldehyde C. Nylon–6 c. Isoprene
(D) Urea + Formaldehyde D. P.V.C. d. Acrylonitrile
Q.10 An example of a natural biopolymer is- Code is-
(A) Teflon (B) Neoprene A B C D
(C) Nylon-66 (D) DNA (A) d c b a
Q.11 Natural silk is a- (B) a b c d
(A) Polypeptide (B) Polyacrylate (C) c d a b
(C) Polyester (D) Polysaccharide (D) b a c d
Q.12 Peptide bond is a key feature in- Q.20 Which of the following is an addition polymer:
(A) Polysaccharide (B) Proteins (A) SBR (B) Glyptals
(C) Nucleotide (D) Vitamins (C) Terylene (D) Nylons
Q.21 Which of the following fibres is a polyamide- Q.35 Which of the following is not the addition
(A) Orlon (B) Nylon-6 homopolymer-
(C) Dacron (D) Rayon (A) Teflon (B) Buna-S
Q.22 Which of the following fibres is not a polyamide- (C) P.V.C. (D) P.A.N.
(A) Wool (B) Silk Q.36 Phenol is used in the manufacture of-
(C) Nylon-6 (D) Orlon (A) Bakelite (B) Polystyrene
Q.23 Formaldehyde is not used in the manufacture (C) Nylon (D) PVC
of the following polymer- Q.37 In vulcanisation of rubber-
(A) Bakelite (B) Nylon-6 (A) Sulphur reacts to form new compound
(C) Urea resin (D) Melamine resin (B) Sulphur cross-links are introduced
Q.24 Which is a naturally occuring polymer- (C) Sulphur forms a very thin protective layer
(A) Polyethene (B) PVC over rubber
(C) Teflon (D) Protein (D) All of the statements are correct
Q.25 Natural fibre is- Q.38 Which is a homopolymer-
(A) Starch (B) Cellulose (A) Isotactic poly vinylchloride
(C) Rubber (D) Nylon-6 (B) Atactic polypropylene
Q.26 Monomer of polystyrene is- (C) Syndiotactic polystyrene
(A) Vinyl benzene (B) Divinyl benzene (D) All of these
(C) Ethyl benzene (D) Butyl benzene Q.39 Glyptal polymer is obtained from glycol by
Q.27 The fibre used for the manufacture of chords reacting with-
and carpets is- (A) Malonic acid (B) Phthalic acid
(A) Polyethylene (B) Polypropylene (C) Maleic acid (D) Acetic acid
(C) Polyacrylonitrile (D) Polyvinyl chloride Q.40 W hich of the following is a homopolymer
Q.28 Synthetic polymer which resembles natural obtained from single monomer under the
rubber is- condensation process-
(A) Neoprene (B) Chloroprene (A) Nylon – 6 (B) Terylene
(C) Glyptal (D) None of these (C) Glyptal (D) Bakelite
Q.29 Which one of the following pairs is not correctly Q.41 Orlon is a polymer of-
matched- (A) Styrene
(A) Terylene-condensation polymer of (B) Tetrafluoroethylene
terephthalic acid and ethylene glycol (C) Vinyl chloride
(B) Teflon-thermally stable cross linked (D) Acrylonitrile
polymer of phenol and formaldehyde Q.42 Which one of the following is not an example of
(C) Plexiglass homopolymer of methyl chain growth polymer-
methacrylate (A) Neoprene (B) Buna-S
(D) Synthetic rubber-A copolymer of (C) PMMA (D) Glyptal
butadiene and styrene Q.43 Ebonite is-
Q.30 Which is not the example of addition polymer- (A) Natural rubber
(A) Glyptal (B) Polypropylene (B) Synthetic rubber
(C) Polystyrene (D) Polyvinyl chloride (C) Highly vulcanized rubber
Q.31 Caprolactam is obtained by the Beckmann (D) Polypropene
rearrangement of the compound- Q.44 F2C = CF2 is a monomer of-
(A) Cyclohexanone-oxime (A) Teflon (B) Glyptal
(B) Benzophenone-oxime (C) Nylon-6 (D) Buna-S
(C) Acetone-oxime Q.45 P.V.C. is formed by polymerisation of-
(D) Propionaldehyde-oxime (A) 1-Chloroethene (B) Ethene
Q.32 Teflon is a polymer of: (C) Propene (D) 1-Chloropropene
(A) Tetra-fluoroethylene Q.46 Which of the following polymers do not involve
(B) Tetra-bromoethylene cross linkages-
(C) Tetra-iodoethylene (A) Melmac (B) Bakelite
(D) Tetra-chloroethylene (C) Polythene (D) Vulcanised rubber
Q.33 Symbolic name for teflon is- Q.47 Ziegler-Natta catalyst is-
(A) PTFE (B) PCTFE (A) K[PtCl3(C2H4)] (B) (Ph3P)3RhCl
(C) PVC (D) None (C) Al(C2H5)3+ TiCl4 (D) Fe(C5H5)2
Q.34 The S in Buna-S stands for-
(A) Sodium
(B) Sulphur
(C) Styrene
(D) Just a trade name
Q.48 Which of the following is not correctly matched? (II) Phenol B. Dacron
(III) Phthalic acid C. Glyptal
  (IV) Terephthalic acid D. Melamine
(A) Neoprene;  — CH 2 — C  CH — CH 2 —  E. Nylon
 | 
 Cl  Codes:
n
(A) I–E, II–A, III–B, IV–C
(B) Nylon -6; (B) I–E, II–A, III–C, IV–B
(C) I–D, II–C, III–A, IV–B
O (D) I–D, II–C, III–A, IV–B
|| Q.52 Which compound/set of compounds is used in
– NH – (CH2)6 – NH – CO – (CH2)4–C – O–
the manufacture of nylon-66?
n (A) HOOC(CH2)4COOH+H2N(CH2)6NH2
(B) CH2 = CH–C(CH) = CH2
(C) CH2 = CH2
O O
|| || (D) HOOC COOH
(C) Terylene; –OCH2– CH2– O –C C
+ HOCH2 – CH2OH
n
Q.53 Teflon, styron and neoprene are all-
(A) Copolymers
(B) Condensation polymers
CH3
| (C) Homopolymers
(D) PMMA; – CH2 – C  (D) Monomers
| Q.54 A condensation polymer among the following
COOCH3 n
is-
Q.49 Acrilan is a hard, horny and a high melting (A) Dacron (B) PVC
material. Which of the following represents its (C) Polystyrene (D) Teflon
structure? COMPREHENSION BASED QUESTIONS
CH3 Passage (Q.No. 55 to 56)
|
(A) CH2 – C  A natural elastomer polymer when heated with
| sulphur got stiff and resistant to action of
COOCH3 n common solvents and wear & tear.
Q.55 The natural polymer is:
(A) Rubber (B) Cellulose
CH2 – CH  (C) silk (D) starch
(B) | Q.56 Heating of polymer with sulphur is called:
COOC2H5 (A) Galvanisation (B) saponification
n
(C) vulcanisation (D) None of these

STATEMENT BASED QUESTION

CH2 – CH
(C) | Each of the questions given below consist of
Cl Statement – I and Statement – II. Use the
n
following Key to choose the appropriate answer.
(A) If both Statement- I and Statement- II are
true, and Statement - II is the correct explanation
CH2 – CH of Statement– I.
(D) | (B) If both Statement - I and Statement - II are
CN n true but Statement - II is not the correct
explanation of Statement – I.
Q.50 Which one of the following is used to make’non-
(C) If Statement - I is true but Statement - II is
stick’ cookware?
false.
(A) PVC
(D) If Statement - I is false but Statement - II is
(B) Polystyrene
true.
(C) Polyethylene teraphthalate
Q.57 Statement - I Starch is a homopolysaccharide.
(D) Polytetrafluoroethylene
Statement - II It is composed of only D Glucose.
Q.51 Match list-I (Monomer) with list-II (Polymer) and
Q.58 Monomers are converted to polymer by –
select the correct answer using the codes given
(A) Hydrolysis of monomers
below the lists:
(B) Condensation reaction between monomers
List-I List-II
(C) Protonation of monomers
(I) Hexamethylenediamine A. Bakelite
(D) None is correct
Q.59 Nylon threads are made of – Q.64 This question contains statements given in two
(A) Polyamide polymer columns which have to be matched, Statements
(B) Polyethylene polymer (A, B, C, D) in column I have to be matched
(C) Polyvinyl polymer with statements (p, q, r, s) in column II The
(D) Polyster polymer answers to this question have to be
Q.60 Which of the following is a polyamide ? appropriately bubbled as illustrated in the
(A) Nylon-66 (B) Teflon following example.
(C) Bakelite (D) Terylene If the correct matches are
Q.61 Which of the following is fully fluorinated polymer- A-p, A-s, B-q, B-r, C-p, C-q and D-s, Then the
(A) Teflon (B) Neoprene correctly bubbled 4×4 matrix should be as
(C) PVC (D) Thiokol follows
Q.62 Bakelite is obtained from phenol by reacting with p q r s
(A) CH3CHO (B) CH3COCH3
(C) HCHO (D) (CH2OH)2 A p q r s
Q. 63 Buna-N synthetic rubber is a copolymer of - B p q r s
C p q r s
Cl D p q r s
|
Match the chemical substances in Column I with
(A) H 2 C  CH  C  CH 2 and type of polymers/type of bonds in
Column II. Indicate your answer by darkening
H 2 C  CH  CH  CH 2
the appropriate bubbles of the 4×4 matrix given
(B) H 2 C  CH  CH  CH 2 and H5 C 6  CH  CH 2 in the OMR.
(C)H2C = CH – CN and H2C = CH – CH = CH2
Column-I Column-II
(D) H 2 C  CH  CN and H 2 C  CH  C  CH 2 (A) cellulose (p) natural polymer
| (B) nylon-6,6 (q) synthetic polymer
CH 3 (C) protein (r) amide linkage
(D) Sucrose (s) glycoside linkage
Q. 65 Among cellulose, poly(vinyl chloride), nylon and
natural rubber, the polymer in which the intermo-
lecular force of attraction is weakest is -
(A) Nylon (B) Poly(vinyl chloride)
(C) Cellulose (D) Natural Rubber
 ANSWER KEY

Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. A B C C B A D B A D A B C C A B C D A A

Ques. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. B D B D B A B A B A A A A C B A B D B A

Ques. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. D D C A A C C B D D B A C A A C A B A A
Ques. 61 62 63 64 65
Ans. A C C A-ps; B-qr; C-pr; S-s D