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P O LY M E R S
Q.1 What kindof polymerisation, cationic oraninoic or vinyl polymerisation,would be suited forthe preparation
of
(a) Polypropylene (b) Poly acrylonitrile (c) Polystyrene
Q.3 Write the formulae, type of polymer (addition or condensation) and one method of preparation of the
following.
(a) Polymethyl methacrylate (b) Poly (ethylene terephthalate) (c) Styrene butadiene rubber
Q.4 What is Zieglar - Natta polymerisation? What are its advantages over free-radical vinyl polymerisation?
IA
Q.5 Give the information asked for the following polymers:
(a) Bakelite : materials used for preparation
(b) Neoprene : materials required for preparation
D
(c) High-density polythene: mode of preparation, free-radical or ionic vinyl polymerisation or
Zieger-Natta polymerisation.
IN
S
O
O
T
E
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P O LY M E R S
IA
|
NH 2
D
Cu2Cl2 HCl (1 eq.) polymerisation
2HC CH (A) (B) (C)
NH4Cl
(A) Saran (B) PVC (C) Neoprene (D) Chloroprene
IN
Q.4 Protein is a polymer of:
(A) Glucose (B) Terephthalic acid (C)Amino acid (D) Glycol
S
Q.5 Enzymes are:
(A) Minerals (B) Oils (C) Fatty acids (D) Proteins
O
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P O LY M E R S
IA
Q.17 Which of the following is a thermosetting polymer?
(A) Bakelite (B) Nylon-6, 6 (C) Polyethylene (D) Teflon
D
(A) 102 to 105 u (B) 103 to 107 u (C) 10 to 103 u (D) None
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P O LY M E R S
IA
(A) (i) – B, (ii) – A, (iii) – A, (iv) – B, (v) – B (B) (i) – B, (ii) – A, (iii) – B, (iv) – A, (v) – A
(C) (i) – A, (ii) – A, (iii) – B, (iv) – B, (v) – B (D) (i) – B, (ii) – B, (iii) – B, (iv) – A, (v) – A
D
(i) Elastomers (A) High tensile strangth
(ii) fibers (B) Weak intermolecular forces
(iii) Thermoplastic polymer (C) Bond strength is b/w Elastomer and fibers
IN
(iv) Thermosetting polymer (D) Cannot be reused
(A) (i) – B, (ii) – A, (iii) – D, (iv) – C (B) (i) – A, (ii) – B, (iii) – C, (iv) – D
(C) (i) – B, (ii) – A, (iii) – C, (iv) – D (D) (i) – D, (ii) – C, (iii) – B, (iv) – A
S
Q.30 Match the following :
(i) neoprene (A) Fibers
(ii) polyesters (terylene (B) Thermoplastic polymer
O
(C) (i) – D, (ii) – A, (iii) – B, (iv) – C (D) (i) – C, (ii) – D, (iii) – A, (iv) – D
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P O LY M E R S
IA
Q.37 For make teflon suitable condition is :
(A) Low pressure and per-sulphate catalyst (B) High pressure and absence of catalyst
(C) Low pressure and per-sulphate catalyst (D) High pressure and per-sulphate catalyst
D
Q.38 Polyacrylonitrile (PAN) is made by :
(A) Tetra fluoroethene (B)Acrylonitrile
IN
(C) Ethene (D) Propene
(A) Low pressure, high temperature (B) High pressure, low temperature
(C) Low pressure , low temperature (D) High pressure, high temperature
T
(C) Caprolactum, with water, low temperature (D) Caprolactum, without water, low temperature
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P O LY M E R S
IA
OH
D
What can be used as X or Y and give the structures of A , B and C ?
OH
IN
CH2OH
(A) x = y = H+, (A) = =B=C
S
OH OH
CH2OH CH2OH
O
(B) x = y = H+ , A = B = ,C=
O
CH2OH
OH OH
T
OH
CH2OH OHCH2 CH2OH
CH2OH
(C) x=H+,y= OH¯A = ,B= ,C=
E
CH2OH CH2OH
(D) None
OH OH
CH2OH
H
Q.50 + CH2O OH
X Y
Z, Give the name of Yand Z respectively
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P O LY M E R S
IA
(A) Ethylene glycol only (B) Phthalic acid only
(C) Both (A) and (B) (D) None
D
(A) Making computer discs (B) Electrical switches
(C) Making combs (D)All of these
IN
Q.56 Nylon–2–nylon–6 is formed by :
(A) Glycine [H2N–CH2–COOH] only
(B) Amino Caproic acid [H2N(CH2)5COOH] only
(C) Glycine +Amino caproic acid
S
(D) None
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P O LY M E R S
Q.64
(a) Arrange the following polymer increasing order of intermolecular forces :
(i) Nylon 6, 6 (ii) Buna–S (iii) Polythene
(A) (i) > (iii) > (ii) (B) (ii) > (iii) > (i) (C) (iii) > (ii) > (i) (D)All are equal
(b) (i) Nylon 6 (ii) Neoprene (iii) PVC
(A) (ii) > (iii) > (i) (B) (i) > (ii) > (iii) (C) (iii) > (ii) > (i) (D)All are equal
Q.65 To improve physical property of natural rubber, a process is carried out called vulcanisation, then sutable
conditions for process is :
IA
(A) heat, raw rubber with sulphur, temperature range 373 K to 415 K
(B) heat, raw rubber without sulphur, temperature range 300 K to 400 K
(C) heat, raw rubber with sulphur, temperature range 300 K to 400 K
(D) None
D
Q.66 In the manufacture of tyre rubber, how much % of sulphur is used :
(A) 50 % (B) 10 % (C) 95 % (D) 5 %
IN
Q.67 Which of the following polymer is biodegradable ?
(A) —( CH 2 – C CH – CH 2 —
)n
|
Cl
S
CN
O
|
(B) —( CH 2 – CH CH CH 2 – CH 2 – C H —
)n
O
(C) —( O – C H CH 2 C– O – CH – CH 2 C —)n
| || | ||
CH 3 O CH 2 CH 3 O
T
H H O O
| | || ||
(D) —( N – (C H2 ) 6 N C – (CH 2 ) 4 C —
)n
E
CH 3 CH 3
| |
Q.68 —( CH 2 – C CH 2 C —)n is a polymer having monomer unit :
| |
CH 3 CH 3
H
(A) (B) (C) (D)
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P O LY M E R S
Q.69 Which of the follwoing polymer can be formed by using the following monomer :
H
(A) Nylon 6, 6 (B) Nylon 2– nylon 6 (C) melamine polymer (D) Nylon 6
IA
(A) High density polythene is a linear polymer.
(B) Low density polythene is a branched chain polymer.
(C) Chain growth polymers are also known as addition polymer.
(D) Step growth polymer is also known condensation polymer.
D
Q.71 Choose natural polymers among the following:
(A) Proteins (B) Cellulose (C) Starch (D) Nylon
IN
Q.72 Choose synthetic polymer :
(A) polythene (B) Nylon 6, 6 (C) Buna-S (D) Bakelite
S
Q.73 Choose homopolymer :
(A) Butadiene-styrene (Buna-S) (B) Polythene
(C) Polypropene (D) Buna-S and Buna-N
O
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P O LY M E R S
IA
(B) Natural Rubber (Q) Condensation
(C) Terylene (R) Linear Polymer
(D) Proteins (S) Co-Polymer
D
Q.83 Match the column.
Column I Column II
(A) Addition polymer (P) Buna-S
IN
(B) Condensation polymer (Q) Buna-N
(C) Homopolymer (R) Polythene
(D) Copolymers (S) Nylon 6,6
S
|
(ii) Polystyrene (b) —(CH 2 C C H CH 2 —
)n
CN
T
|
(iii) Neoprene (c) —(CH 2 CH C H CH 2 CH 2 CH —
)n
(iv) Novolac (d) —(CH 2 CH —
)n
E
|
CN
OH OH
CH2 CH2
(v) Buna–N (e)
n
(f) —(CH 2 CH —
)n
|
Cl
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P O LY M E R S
IA
(iv) Natural rubber (d) Low density polymer
(v) LDP (e) Cis–Polyisoprene
D
Q.87 Column I Column II
(i) Nylon–66 (a) Free radical Polymerisation
IN
(ii) PVC (b) Ziegler–Natla Polymerisation
or co-ordination Polymerisation
(iii) HDP (c) Anionic–Polymerisation
S
(d) Condensation Polymerisation
Plot No. 46, Rajeev Gandhi Nagar, Kota, (Rajasthan) Pin code : 324005. 12
P O LY M E R S
EXERCISE-3
SECTION-A
(JEE ADVANCED Previous Year's Questions)
Q.1 Give the structures of the products in each of the following reactions. [JEE 2000]
NOH
Polymerisation
H C [D]n
Q.2 MonomerAof a polymer on ozonolysis yields two moles of HCHO and one mole of CH3COCHO.
(a) Deduce the structure of A. [JEE 2005]
IA
(b) Write the structure of “all cis” – form of polymer of compoundA.
D
(C) polypropylene IN (D) polybutylene
S
O
O
T
E
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P O LY M E R S
SECTION-B
(JEE Main Previous Year's Questions)
Q.1 Monomers are converted to polymer by – [AIEEE-2003]
(A) Hydrolysis of monomers
(B) Condensation reaction between monomers
(C) Protonation of monomers
(D) None is correct
Q.2 Nylon threads are made of – [AIEEE-2003]
(A) Polyamide polymer (B) Polyethylene polymer
(C) Polyvinyl polymer (D) Polyster polymer
Q.3 Which of the following is a polyamide ? [AIEEE-2005]
IA
(A) Nylon-66 (B) Teflon (C) Bakelite (D) Terylene
Q.4 Which of the following is fullyfluorinated polymer- [AIEEE-2005]
(A) Teflon (B) Neoprene (C) PVC (D) Thiokol
D
Q.5 Bakelite is obtained from phenol by reacting with [AIEEE 2008]
(A) CH3CHO (B) CH3COCH3 (C) HCHO (D) (CH2OH)2
IN
Q.6 Buna-N synthetic rubber is a copolymer of - [AIEEE 2009]
Cl
|
(A) H 2C CH C CH2 and H 2 C CH CH CH 2
S
(B) H 2 C CH CH CH 2 and H5 C 6 CH CH 2
(C) H2C = CH – CN and H2C = CH – CH = CH2
O
(D) H 2 C CH CN and H 2 C CH C CH 2
|
O
CH 3
Q.7 The species which can best serve as an initiator for the cationic polymerization is
T
[AIEEE 2012]
(A)AlCl3 (B) BuLi (C) LiAlH4 (D) HNO3
E
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P O LY M E R S
IA
n
cis-poly-1,3-butadiene
Q.2 The Zieglar-Natta catalyst is
(A) TiCl4 (B) R3Al (C) R3 Al / TiCl4 (D) R3 B/TiCl4
D
Cl
Q.3 The polymer obtained when monomeric unit used is CH2=C–CH=CH2
IN
(A) Neoprene (B) Stilbene (C) Styrene (D) Chloropicrin
Q.4 Which of the following statement is not true considering the process given above.
(A) The general class of polymer formed is known as homopolymer
(B) The polymer obtained is stereoregular
S
(C) Buna–N can be prepared using above process
(D) Synthetic rubber can be formed by above process using 1,3- butadiene.
[MULTIPLE CORRECT CHOICE TYPE]
O
OH OH
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P O LY M E R S
ANSWER KEY
EXERCISE-2
Q.1 B Q.2 D Q.3 C Q.4 C Q.5 D Q.6 B Q.7 A
Q.8 A Q.9 A Q.10 A Q.11 D Q.12 B Q.13 C Q.14 D
Q.15 A Q.16 C Q.17 A Q.18 B Q.19 B Q.20 B Q.21 B
Q.22 B Q.23 B Q.24 C Q.25 A Q.26 C Q.27 C Q.28 C
Q.29 C Q.30 C Q.31 D Q.32 D Q.33 C Q.34 C Q.35 C
Q.36 A Q.37 D Q.38 B Q.39 C Q.40 B Q.41 D Q.42 B
Q.43 D Q.44 D Q.45 D Q.46 B Q.47 C Q.48 B Q.49 C
Q.50 C Q.51 C Q.52 D Q.53 D Q.54 C Q.55 D Q.56 C
Q.57 C Q.58 D Q.59 A Q.60 A Q.61 D Q.62 C Q.63 D
Q.64 (a) A, (b) A Q.65 A Q.66 D Q.67 D Q.68 A Q.69 D
Q.70 ABCD Q.71 ABC Q.72 ABCD Q.73 BC
Q.74 ABC Q.75 ABCD Q.76 ABC Q.77 AB
IA
Q.78 ABC Q.79 ABC Q.80 ABC Q.81 AB
Q.82 (A) R (B) P,R (C) Q,R,S (D) P,Q,S Q.83 (A) P,Q,R (B) S, (C) R, (D) P,Q,S
Q.84 (i) – d, (ii) – a, (iii)–b, (iv) – e, (v) – c Q.85 (i) – e, (ii) – c, (iii) – a, (iv) – b, (v) – d
Q.86 (i) – c, (ii) – a, (iii) – b, (iv) – e, (v) – d Q.87 (i) – d, (ii) – a, (iii) – b
D
Q.88 (i) – b, (ii) – d, (iii) – a, (iv) – d, (v) – c
Q.89 (i) – f, (ii) – e, (iii) – a, (iv) – c, (v) – b, (vi) – d
IN
EXERCISE-3
SECTION-A
O O O
CH3
S
Ozonolysis +
CH2
Q.2 (a)
H2 C H H H3 C H
O
A
H3 C H H3C H
CH2 CH2
O
Q.3 A
SECTION-B
Q.1 B Q.2 A Q.3 A Q.4 A Q.5 C Q.6 C Q.7 A
E
EXERCISE-4
Q.1 B Q.2 C Q.3 A Q.4 C Q.5 ABC
Q.6 (A) S, (B)R, (C)P, (D) Q
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