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1. Which of the following has maximum number of unpaired electrons ?
(A) Mg2+ (B) Ti3+ (C) Fe2+ (D) Cu2+
3. Solids are attracted by magnetic field due to the presence of atoms, ions or molecules with unpaired electron, called
paramagnetic. Which among the following is paramagnetic ?
(A) Cl2O7 (B) Cl2O (C) ClO2 (D) Cl2O5
4. Count the total number of S––O bonds, which are having equal length in bisulphate ion ?
(A) 3 (B) 4 (C) 5 (D) 6
6. What will be the product when phenol is treated with CO2 at 140-220° C ?
(A) o and p-salicylic acid (B) m and p-salicylic acid
(C) o and m-salicylic acid (D) Benzoic acid
7. Which of the following compound produces acetaldehyde on ozonolysis followed by acidic hydrolysis ?
CH3 C C CH3
P. Q.
H H
R. CH3CH2CH == CH2 S. CH3 C C CH3
Choose the correct choice out of the following
(A) P and R (B) P and Q (C) P, Q and R (D) Only P
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10. Aspartame is one of the good artificial sweeteners whose use is limited to cold foods and soft drinks because
(A) It has very low boiling point
(B) It gets dissociated at cooking temperature
(C) It is sweetener at low temperature only
(D) It is insoluble at high temperature
11. Bakelite with low degree of polymerisation is used in making glues, in varnishes and lacquers and bakelite with high
degree of polymerisation is widely used for making electric goods, fountain pen barrels, combs, etc. It is an example
of
(A) condensation polymerisation
(B) addition polymerisation
(C) free radical polymerisation
(D) None of these
12. Which of the following reagent is used to convert glucose to gluconic acid ?
(A) H2SO4 (B) Br2/H2O (C) HNO3 (D) dil.HCL
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16. What will be the product obtained when A reacts with heavy water,
Mg/ether D2 O
A ?
17. The AfF5 molecules is trigonal bipyramidal. The hybrid orbitals used by the As atoms for bonding are
(A) d x 2 y2 , dz2, s, px, py (B) dxy, s, px, py, pz
19. Those polymers which get decomposed by the process of biodegradation are known as biodegradable polymer.
Among the folloiwng, the biodegradable polymer is
(A) Cellulose (B) polyethene (C) PVC (D) nylon 6
21. Compare the acidic strength of reaction product, B with respect to phenol, A and choose the correct order.
Chemical reaction is
22. What will be correct stereochemistry of product obtained on reaction of but-2-ene with OSO4 ?
(A) (B)
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23. Product obtained on reaction 2-methyl cyclohexene with mCPBA followed by hydrolysis is
CH2N+(CH3)2 OH
28. When benzene is heated with chlorine in the presence of sunlight, it forms
(A) BHC (B) cyclopropane (C) p-dichlorobenzene (D) None of these
29. The product formed when toluene is heated in light with Cl2 and in absence of halogen carrier is
(A) chlorobenzene (B) gammexane (C) benzotrichloride (D) DDT
30. In IF7 molecule, central atom has all the bonded electrons i.e., no lone pair is present on the central atom. Structure
of IF7 is
(A) pentagonal bipyramidal (B) octahedral
(C) square pyramidal (D) octahedral monpyramidal
31. On dissolving moderate amount of sodium metal in liquid NH3 at low temperature, which of the following does not
occur ?
(A) Na+ ions are formed in the solution
(B) Blue coloured solution is obtained
(C) Liquid NH3 becomes good conductor of electricity
(D) Liquid NH3 remains diamagnetic
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32. Most of the compounds of transition metals are coloured in solid state or solutions. The transition metals which
have either completely filled d-orbitals or completely empty d-orbitals are colourless. The colour of transition metal
is due to
(A) presence of unpaired d-electrons (B) small size
(C) metallic nature (D) all of these
33. What amount of current will be required to evolve 20g of chlorine in 6 h from HCl solution ?
(A) 10 A (B) 15 A (C) 5 A (D) 2.45 A
34. Which of the following is not the assumption of kinetic theory of gases ?
(A) The actual volume of the gaseous molecules is negligible as compared to the total volume of the gas
(B) Molecules are perfectly elastic
(C) The critical temperature is the measure of the kinetic energy of the molecule
(D) The effect of gravity on motion of molecules is negligible
35. A solid is made of two elements P and Q. Atoms P are in ccp arrangement and atoms Q occupy all the octahedral
voids and half o the tetrahedral voids, then the simplest formula of the compound is
(A) PO2 (B) P2Q (C) PQ (D) P2Q2
3 2
(A) (B) (C) (D)
2 8 6 6
37. 50 mL each of 1 M CH3COOH and 0.50 M NaOH are mixed (Ka for CH3COOH = 1.8 × 10–5). The pH of the mixture is
(A) 6.27 (B) 2.67 (C) 1.67 (D) 4.74
38. Chlorobenzene reacts with chlorine in the presence of Anhyd. FeCl3 gives ortho and para dichlorobenzene. Which
of the following order is correct regarding dipole moment of o, m and p dichloro benzene ?
(A) o > p > m (B) p > o > m (C) m > o > p (D) o > m > p
39. A compound obtained by the hydrolysis of the substance A, on reduction forms 2-hexanol. Hence the substance
A is
(A) 3, 3-dichlorohexane (B) 2, 3-dichlorohexane
(C) 2, 2-dichlorohexane (D) 1, 1-dichlorohexane
40. A metal is said to be diamagnetic if it does not have any unpaired electron. Among the following, which one is
diamagnetic ?
(A) Co2+ (B) Cu2+ (C) Mn2+ (D) Sc3+
41. Metals are generally hard, opaque, shiny and good conductor of heat and electricity. Which of the following
elements has highest density ?
(A) Os (B) Ir (C) Fe (D) Ru
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42. Propyl nitrile may be converted into butyl amine by using reduction. Which of the following reagent can do this ?
(A) Sn/HCl (B) LiAlH4 (C) conc. HCl (D) All of these
H
OH OH OH OH
(I) (II) (III) (IV)
(A) I < II < III < IV (B) III < IV < II < I
(C) I < II < IV < III (D) II < III < IV < I
44. A common nitrate test is known as brown ring test. An organic compound which give possible brown ring test and
chiral is
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India’s No.1 Online Coaching Plot No. 38, Near Union Bank Of India, Rajeev Gandhi Nagar, Kota,
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