Chemistry 2 Answer Key

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Answer Key
1. (A) 2. (A) 3. (B) 4. (B) 5. (B) 6. (C) 7. (B)
8. (D) 9. (D) 10. (D) 11. (A) 12. (B) 13. (B) 14. (C)
15. (B) 16. (B) 17. (A) 18. (C) 19. (D) 20. (A) 21. (D)
22. (B) 23. (D) 24. (B) 25. (C) 26. (D) 27. (A) 28. (C)
29. (C) 30. (B) 31. (B) 32. (A) 33. (B) 34. (C) 35. (A)
36. (D) 37. (C) 38. (A) 39. (B) 40. (B) 41. (B) 42. (D)
43. (C) 44. (B) 45. (B)
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1. (A) By Heisenberg’s uncertainty principle
h
x  p x 
4
h
or  x  p (mVx ) 
4
h
 x   Vx 
4m
p = uncertainty in momentum
x = uncertainty in position
v = uncertainty in velocity
m = mass of particle
Given that,
x = 0.1 A = 0.1 × 10–10 m
m = 9.11 × 10–31 kg
h = Plank’s constant = 6.623 × 10–34 Js
 = 3.14
Thus,
6.623 1034
v  0.1 1010 
4  3.14  9.11 1031
6.626 1034
v  ms 1
4  3.14  9.11 1031  0.1 1010
= 5.79 × 106 m/s
2. (A) According to molecular orbital theory.

* * * *
O22– = (8 + 8 + 2 = 18)  1s 2 ,  1s 2 ,  2s 2 ,  2s 2 ,  2pz 2 , 2p 2x   2p 2y ,  2p 2x   2p 2y
N b  N a 10  8
Bond order (BO) =  1
2 2
* *
B2 (5  5  10)  1s 2 ,  1s 2 ,  2s 2 ,  2s 2 ,  2p1x  2p1y
6 4
BO  1
2
Thus, O22– and B2 have the same bond order.
3. (B) In A3(BC4)2
3× oxidation number of A +2 [oxidation number of B + 4 × oxidation number of C] = 0
3×(+2)+2[5+4×(–2)] = 0
6+2[–3] = 0
4. (B) The fraction of unoccupied site in sodium chloride crystal
X ray density  pyknometric density


X ray density
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2.178 103  2.165  103 0.013 103

 
2.178 103 2.178 103
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  5.96  10 3
2178
5. (B) G° is related to Ksp by the equation,

G° = –2.303 RT log Ksp
Given, G° = + 63.3kJ
= 63.3×103 J
Thus, substitute G° = 63.3×103 J,
R = 8.314 JK–1 mol–1 and T= 298 K
from the above equation we get,
63.3×103 = – 2.303 × 8.314 × 298 log Ksp
 log Ksp = – 11.09
 Ksp = antilog (–11.09)
Ksp = 8.0×10–12
6. (C) 
BaO 2 (s) 
1

r
 BaO(s)  O2 (g) , H = + ve
r 2
According to law of mass action,

the rate of forward reaction = r1
r1 [BaO2]
or r1 = k1[BaO2]
BaO2 is is solid substance in pure state concentration = 1 m
then, r1=k1
Similarly the rate of backward reaction = r2
r2 [BaO] [O2]
or r2 = k2 [BaO][O2]
 Concentration of solid [BaO] =1
 r2 = k2 [O2]
At equilibrium,
r 2 = r2
K1 = K2[O2]
or K1 = K2 Po2.
where, Po2 = partial pressure of O2
K1
or  Po 2 (equilibrium constant)
K2
K1
 K or K = Po2
K2
So, from the above it is clear the pressure of O2 does not depend upon the concentration of reactants. The given
equation is an endothermic reaction, If the temperature of such reaction is increased, then dissociation of BaO2
would increase and more O2 is produced
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7. (B) The change is Gibbs free energy is given by
G = H – TS
where, H= change in enthalpy of the reaction
S = change in entropy of the reaction
Thus, in order to determine G, the values of H must be known, The value of H can be calculated by using
equation
H = U + ngRT
where, U = change in internal energy
ng = number of moles of gaseous reactants–number of moles of gaseous reactants
=2–0=2
R = gas constant = 2 cal
given, U = 2.1 kcal
= 2.1 × 103 cal [1 kcal = 103 cal]
By putting the values,
 H = (2.1 × 103) + (2 × 2 × 300) = 3300 cal
Hence, G = H – TS
G = (3300) – (300×20)
G = – 2700 cal
 G = – 2.7 kcal.
8. (D) By Nernst equation,
2.303RT
E cell  E cell  log10 K
nF
At equilibrium, Ecell = 0
Given that,
R = 8.314 JK–1 mol–1
T = 25°C + 273 = 298 K
F = 96500 C and n = 2
 2.303  8.314  298 0.0591

  E cell  log10 K   log10 K
nF 2
Given that E°cell = 0.295 V
0.0591
 0.295  log10 K
2
0.295
log10 K   10
0.0591
antilog log10 K = antilog 10
K = 1 × 1010
9. (D) According to Hardy-Schulze law,

coagulation  charge of ion
So, coagulation is affected by both magnitude of charge and nature of charge. For coagulation of a positive sol,
negative ions are required and for coagulation of negative sol, positive ion are required. Greater the magnitude of
charge. quicker will be the coagulation. The ions having opposite charge to sol particle causes coagulation.
Coagulation power of an electrolyte is directly proportional to the fourth power of the valence of the ions causing
the coagulation.
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10. (D) Compound X is CaCO3

CaCO3   CaO  CO 2 
X Residue
CaO  H 2 O  Ca(OH) 2
Residue Y
Ca(OH) 2  CO 2 + H 2 O  Ca(HCO 3 ) 2
Y Excess Z

Ca(HCO 3 ) 2 
 CaCO 3 + H 2 O  CO 2 
Z X
11. (A) Silicon chloride is easily hydrolysed to given white fumes. so it is used as a smoke screen in warfare.
SiCl4 + 4H2O  Si(OH)4 + 4HCl
(4 unpaired
Cr2+ : d4 electrons)
(5 unpaired
Mn2+ : d5 electrons)
(4 unpaired
12. (B) Fe2+ : d6 electrons)
(3 unpaired
Co2+ : d7 electrons)
[Co(H2O)6]2+ has minimum number of unpaired electrons and thus, shows minimum paramagnetic behaviour.
Higher the magnetic moment
µ  n(n  2)
n = Number of unpaired e–
13. (B) Optical isomerism is exhibited only by those complexes in which plane of symmetry are absent. Octahedral com-
plexes of the types [M(aa)3], [M(aa)x2, y2] and [M(aa)2x2] have absence of plane of symmetry, thus exhibit optical
isomerism. Here, (aa) represents bidentate ligand, x or y represents monodentate ligand and M represents central
metal ion. Hence, [Co(NH3)3Cl3]0 due to presence of symmetry elements does not exhibits does not exhibit optical
isomerism.
14. (C) A metal with more negative electrode potential is more easily oxidised than a metal with less negative electrode
potential. Thus, zinc with E°= – 0.76 V is more easily oxidised by O2 and moisture of the atmosphere than iron with
E°= – 0.44 V and thus protects, is not beneficial since Fe with less–ve electrode potential cannot protect zinc. with
more –ve electrode potential from corrosion.
15. (B) Acidity increases or pKa values decrease as the H—M bond strength decreases from O to Te. Thus, option (b) is
not correct.
16. (B) Explanation given in the question itself.
17. (A) Hyperconjugation in free radicals occurs only when the a-carbon to the carbon atom carrying the odd electron has
a hydrogen atom, i.e., option (a) is correct.
H
H
CH3 CH3
III
Radicals (I and II) do not have hydrogen/s on the a-carbon/s and hence do not show hyperconjugation.
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18. (C) The o-and p-nitrophenols are separated by steam distillation sine o-isomer is steam-volatile due to chelation
(intramolecular H—bonding) while p- isomer is not steam –volatile due to association of molecules by intermolecu-
lar H-bonding.
19. (D)
20. (A)
Thus, option (a) is correct
21. (D) Pyrrole has two different types of hydrogens, viz.,2(or 5) and 3(or 4). Obviously, electrons density is high where
electrophilic substitution occurs predominantly. To decide this, let us compare the stabilities of carbocations
resulting from attack of the electrophile at C2(or C5) or at C3 (or C4) positions.
Attack At C2 (or C5)
Attack at C3 (or C4)
Since carbocation resulting from electrophilic attack at C2 or C5 is stabilized by there resonance structure (I–III)
while that resulting from attack at C3 or C4 is stabilized by only two resonce structure (IV—V), therefore, electron
density is maximum at C2 and C5 position, i.e., option (d) is correct.
22. (B) Explanation given in the question itself.
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23. (D) Paschen series
n1 = 3; n2 = 4, 5, 6
Now
He +  1e– (one electron)
Z= 2
longest  = m (given)
 minimum energy is for n1 = 3 and n2 = 4
Now
1 1 1
V  R H Z2  2  2 
  n1 n 2 
1 1 1 
  R H (2)2   
m  9 16 
1 16  9 
  4R H  
m  16  9 
1 7 7R H
  4R H  
m 16  9 36
Now
For Be3+, Z = 4
Shortest  = 1
i.e. Maximum Energy . (n1 = 3; n2 = )
1 1 1
  R H Z2  2  2 
1 n
 1 n 2 
1 1 1 
 1
 R H (4)2  2  2 
 3  
1 1
 1
 16R H 
 9
Now,
1 7R H

m 36
(36)
RH 
7m
9
 1 
16R H
9
 1 
 36 
16  
 7m 
9  7m 7m
 1  
16  36 64
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24. (B) By looking of the graph, we can easily conclude that option (a) is correct because for the gas A, the graph is linear
at all pressure. option (b) is incorrect because for the gas B, b=0 and its dependence, on p in not linear at all pressure.
25. (C) Liquid  vapour

vapour  Liquid
The given equation is clausius – clapayron relation
dlnp H v
 (important formula)
dT RT 2
26. (D) Let the no. of oxide ion O2– = x
2 1 r
the no.of divalent metal A   2x 
4 2
the no of. monovalent metal B = x.

the formula is A: B: O A: B: O
x 1
:x:x :1:1
2 2
AB2O2.
27. (A) AxBy  xAy+ + yBx–

t=0 1 0 0
t=t 1- x y
1    x  y
i
1
i – 1 =  (–1 + x + y)
i 1

x  y 1
28. (C) Rate = K [A]n [B]m

now,
1
A = 2A; B  B
2
m
B
R1  K[2A]n  
2
eq (ii)  eq (i)
m
1
K(2) n [A]n [B]m  
R1 2

R K[A]n [B]m
R1
  (2) n  m
R
R1 = (2)n–m R
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29. (C) P4 + 3NaOH + 3H2O  PH3 + NaH2PO2
NaH2PO2  Na2HPO4 + PH3
30. (B) Pyrometallurgy  which is done by using Heat

Hydrometallurgy  It is used for low grade on less reactive metals.
Electrometallurgy  It is used too metals which are highly reactive
210  206
31. (B) 84 P  82 Pb  24 He
As per group displacement law, the position of “Po” is VI A”
32. (A)
–CHO groups gets higher priority over > = O and group in numbering carbon chain.
IUPAC name = 3-keto-2-methylhex-4-enal.

33. (B) Greater the s-character of C-atom in hydrocarbons, greater the electronegativity of that carbon and thus greater the
acidic nature of the H attached to electronegative carbon.
CH  CH CH2 = CH2 CH3 – CH3
2
Hybridisation sp sp sp3
s-character : 50% 33% 25%
Electronegativity :
Acidic character
of terminal H
Thus,
> CH2 = CH2 > CH3 – CH3
34. (C) The said reactions can be visualised as
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Thus, option (c) is correct.
35. (A) In tautomerism, –hydrogen must be present in the molecule. Thus, molecule II will not show tautomerism. As at
bridge, double bond is highly unstable. Thus, molecule I will also not show tautomerism.
For III molecule.
So only, III molecule will show tautomerism. Thus, correct option is (a).
36. (D) Deuterium, the isotope of hydrogen is heavier(more atomic mass) than protium. That is why it is known as heavy
water.
O O
B
37. (C) Borate ion is triangular planer geometry..
O
38. (A) (i) CH3CH2CH2Br + KOH  CH3CH = CH2 + KBr + H2O

Elimination reaction
(ii)
(iii)
39. (B) A = CH3COONH4 B = CH3COONH2

C = CH3CONH2 D = CH3CH2NH2
40. (B)
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41. (B) (a) The medicines which are used to reduce pain are known as analgesics. For example paracetamol, ibuprofen,
morphine, etc.
(b) The chemicals which either prevent the growth of microorganisms or kill them but are not antiseptics. e.g. savlon,
dettol. Dettol is one of the most commonly used antiseptics. It is a mixture of chloroxylenol and a-terpineol.
42. (D) Na2S and NaCN, if present in the extract, will be decomposed to H2S and HCN by HNO3.
NaCN + HNO3  NaNO3 + HCN
Na2S + 2HNO3  2NaNO3 + H2S
These will escape from the solution and will not interfere with the test for halogens.
43. (C) SO2 is the oxidising agent here.

Equivalent Mass = Molar Mass/Change in the electron
SO2 --> S
+4 0
Therefore, Molar mass of SO2 = 32+32 = 64
Equivalent Mass = 64/4 = 16.
44. (B)
45. (B) Microorganisms present in the soil act as a sink for CO.
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Chemistry 2 Answer Key

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1. (A) 2. (A) 3. (B) 4. (B) 5. (B) 6. (C) 7. (B)

43. (C) 44. (B) 45. (B)

2. (A) According to molecular orbital theory.

4. (B) The fraction of unoccupied site in sodium chloride crystal

X ray density  pyknometric density

2.178 103  2.165  103 0.013 103

5. (B) G° is related to Ksp by the equation,

According to law of mass action,

8. (D) By Nernst equation,

 2.303  8.314  298 0.0591

9. (D) According to Hardy-Schulze law,

16. (B) Explanation given in the question itself.

Thus, option (a) is correct

Attack at C3 (or C4)

22. (B) Explanation given in the question itself.

25. (C) Liquid  vapour

26. (D) Let the no. of oxide ion O2– = x

27. (A) AxBy  xAy+ + yBx–

28. (C) Rate = K [A]n [B]m

30. (B) Pyrometallurgy  which is done by using Heat

IUPAC name = 3-keto-2-methylhex-4-enal.

34. (C) The said reactions can be visualised as

Thus, option (c) is correct.

38. (A) (i) CH3CH2CH2Br + KOH  CH3CH = CH2 + KBr + H2O

39. (B) A = CH3COONH4 B = CH3COONH2

43. (C) SO2 is the oxidising agent here.

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