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NOSMAIISATION
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Petrnleum products and lubricants * Deterrnination
of flash point
- pansky-Ma.t*n* "to""U cup ;ed;;
*oduits pdtrdiers et bfuifiants ^ oebrnination du point d,6crair
Pens*y-Matens en vase dos - Mfuthode
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ilr.,Fi :;r.,r: ;ii1s, Chr;nngf
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.Dtteatv^t lapcoc.har't
Rctercrcl tuBbcf
l$O 2719: t98t {E}
ISO 2719 : 1388 lEl
1 $cope thio{rgh m opding {ltett cbssd sr other frnes} inro !h€ cup at
rsg{rlar t*mpe.aiorc interyals with 3irndtaneot s int*rupti,On oi
Ihls tntemation€l Slandard specifi€s n€thods. using the stirring. The Sash point is rhe lowsst tetnp€ralue dt which
Pensw-Martens closed cup tpsaratus, for detsrminins the appticatiofr of the tqst flarne causes the !"pona ibor8 the rest
lladr point ol combustible liquids. liquids with $r*snded gortim lo ignhe.
solid*. lubricating oils, liquids that lsnd lo form a sudaca ffm
onder tll€ r€fi condilisns, and othat SquUs'
4 Apparatus
$r Op*n anp ltash and lito points cl pelroleurn products fiaY be
dasminsd by th€ use ot ISO 2592 : 1973, futrabum prcduets ll,l Thsrrnonrot{rr, partial inrnersbn, c,oftfotming te th€
- De,enination ol ltdsh nd lire points CtalebM open cw
- appropriate specification in annex A:
fierAod. RaEh points of peihls aild varnkhes tnd &ying oits
r€t ba detetrninad by the riss ol ISO 15ffi: 1S; firitts, 16r - low ranga. for saxrples gtving a tlash poiil b€tw€en
DslPJntiirrat&.n o{ 'lg oC and I !0 oC j
dishes, pgl{otevffi and rchted ,f6,dacts -
Itashpoint -
Closed cup equilibilum method.
- medium rangre, such 8s ASTM 88C or lP l01C thor
fitoT!s rnornetefs;
Y lioTEs
'I The snple i3 dsmcd lo h3w ittslte{l w+En 3 laroe fla re appearc
6 Preparation of tspsratus
ffd irFaan:dreoqsly yopalieter itslt ovs $! slt{acE cf the ${}Sle. SupDort lhe apparaius m a lsel, SteadY table. Unles€ le3ts ere
rnadg in a Crtught'trce rerri sr cotn!3i"lnrint. it is gcad pr3e-
2 Occasiomny. garticrrla(tv rea' ilE sctud flsh poinl, itr ap,plicrlbn lice. but n:t cbligalory, to 3$rround rhe l?ster- ol} tluee sidrs
ol the te$l tltoa pifi Hse a bls! b6lo ot m etsst3sd ftan€; lh:s is tr{ 'Nith a shield aptroxitnsiely 400 mm wide arxi 0d) mm high,
r firsh lnd slnttt be igMed.
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ISO 2719: lS {El
It it i3 rwtgct€d that a tsst smpl6 contsins vola(il,s con- thg heatrng cha'Ilxx ior eoolihg bath in the case of r\nrc,ed
t mincnts, th6 trsatment d*cribed in E.l and i.2 strall be flash point below srl$;mt lenrperature ..- s€e 6 3i.^r,
omltted_ [:r r rp. 1,11g
the cup is tlropgrly seated. lnsgt lhe ll)4illterrqler. l_;{ht tt,}
tesl flam and adirs.t it to a diamsler of d rrrr 1 0.S fl ),,,. I i,,at
ol a (ale Such thal the temnefi}frtre as i${iiofii{)d i*. i;rr !J/r
6.1 lest samples of very viscous notaials may be s,annsj mon)ete{ inc'eas€ls 5,'C..rdrr to $ oClnrifl. Ii,fi} ri{: r.ii?(r; ,tt
sntil they sr€ rcasonably lluid before lhey are lestcd. llowever, 90 r/rnin to 120 r/nrirr, so tlrat rlrc tost frr:rtiorr ie rila.ft: t,, ttr,*j
r no test sample shatl be heated rllor€ lhm is sbsotutsly frm top to bottffl,
necessary. A test sample shall never be heated above I
temperaturo 17 oC belw its exp*ted f|a!fi point.
7.2 For produets whose fiash point is expecie{t ro be equai to
ll th€ rempaBlu.e difference b"tween the nrelting pokrr and s
bpJov t lO dC, apply lhe flare at each degree up to ti0
_
"C,
!!eh Ooinr ot r liquid k tes than 20 oC, hert the sarpte to beginningat a tmperaturelretwafl lg aC andZg dgbelow th€
3 oC + I oC above its trrelting pojnt ond immediarety trarisfcr a exoected flash point. Appily rhe test flarc by operating rhe
lG! poriion ir:to the cup and proceed as in clailsc g. negteclir,q nrc*hanisrr orr lhe lid which controls the shufier and tllst ilgrre
mininrurn tsrrperatures specif ied in this clgus. brttur so linl tlr: lldtE is k)w,yu, into tln v;{rlrr sFru r, t:l ttrn
cup in 0,5s; lelt in its lowerccJ pssj{ion lor I s, anl q*ir:$y
tetracled. Do_ not stk the rcst porrlon while applyrng tlre resi
8,2 Tcst samplc containing dieeolved or free water may be {lame. {See also 6.1, sgcmd paragraph.}
detrydrated with calcium chhride or by tift*ing rhroqgh a
qualitative fitt€r paper or a lmse plug of dry absu-bent coiton.
Warmhg th€ test sample is permitted, but it sh€ll not be heated 7"3 lf rhs rert portion is 6'@ecrcd ro have a flash rirint abo"" @l
{or prolong€d pedods o aborre a temperature 17 oC below its l'10'C, apply ttre test Rarne in rhe nranoer iust iesc*Oea at
expected tlesh point. each tmpsatws thar is a multiplg of 2 "C. beginning at a
lelnpsature baween lZ oC and 29 oC below tie exfoc&d
On removing wrt6r, rny watcr.solubte llammable ma- flash point.
tetisl pf6sant is also likely to bo rcmoved.
I{OTE -" The pr6ed$e dE gibed in 7.2 sftt ?.3 is not mcexarily
ap"
pllrble e*[n the !€9t iE m
to dstgrmire the poqsibls prssce ot
6.3 for erp€ded nash pdnts bdow arntrient tmtps.tuts, volatih cmteminmr.
p.epare fte appontus as lc6o!vs. ,
53t Renrne d|e tset cup ss€ntuy finduding lkt, th$- 7.4 Racocd as th€ flNstr point tfiE l€rEle€ture rsad on the.
tndlrcfs ad s|irrerl horn rhe epoaratus. lhernonptcr at the tk?le the gecclld sr sub$€$rent €pdiea$olr
cl &e lest flame. up to the &rrlrtblt dcation, c&lJs€s a
dbdnct 0'3h in rhe ir*€rior et ttls c*tp. Do F6t coni{m rtt' t'ua
63.t Plaa th6 t€sil ct p a$.rr.fv flash poinr with Ur6 bkrish halo thar somerinrcs sunounds the
in a slltaue coctingbath
{r€ter o! r 1 + 1 rixture of *€tsr tnd e$yene glfrcot ,*V U" test flarp at applications preceding ttle one thaf csusas th€ sc-
tus€dl. Thr bafh ahd irrclt& a srbra aqd covef. proride sup. tual flasft.
port fsr lherest slrpassen$ly in fhe both so that thg lid srd oF
ll a lbsh b obsarved on ttg irrititl rst llonle sBplic€riol. or it no \
lsr Edgs are horhond a.d thc ct p b i|n|r:€r!€d in direct coa-
tla€h has be€n otserved by{he tvy€nrierh ap;iicatian, rhc ur '
€c{ rrdth thc b,rrh tiqrid l} srcft I positbn thnt the l€d of rh€ -,,* '\
test pottion in the cup b the sarne as fi* of rhe tiquid in rhe cedure shall be statted again with r new t+)sl portion, rtis ii,f._jrtF
waler baih. firhrg a lower or a higficrixpected flaslt r-int, ,esx,"iiv"lv. tl ;'- -"i i
llash is obser\red at th€ initial tesl flafll€ application lrut no flsitr
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ISO:719: 1S l€)
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8.2 lf tfie lemperatilre diff*rerrce betwc{r lhe lilrtilg tx,i}t NO I I f Iit.' nr ca$rre i3 rrf n$rr{ra i[ I r]illiil {rl{f i ot rrr, r,;." thr,
and flash puint of a tfrl |ratelinl i8 lcss lhail'14 "C. lreitt ltr(l
saqiple to 3tC I I oC ab6v6 ii9 m€lting goint and iffidiately
transls a test Foition irlto the cup and prrceed as in clauso 7, coriecled llash po;rt . Cr 0.O33 {7$0 i''i
neglecling n*ninum t?,np€ratures specified in the clalss.
wfqte p' is th€ pregsure in silliwtre.s Df rurcury.
I 9.2 ll th€ tlash point obtained with p-xytsns is not within rhe
limits stated in 9.1, check th€ cofldilion ard op€rstion ol the
The ditlerencs b€tw€gn successive test residts.obtainod by the
same olrerator wirh the sarne appar?tus under constant opgl.
ating condidons on identical r€st mat€ri6l, wuld, in the tong
run, in the normal gnd correct operation of the fe$ method,
apparelus lo ensure contormily with th€ defaih listed in an- exceed lh€ values shown in table 1 only in one case in Z!-
nex B, especially with regard to th! tighrness of the lid, th€
action ol the shuttet and the positlon of th€ tsst flanr€. Aft6t Tsble I - fiaportability
adjustmerlt, if neceseary, rapeat lhe tast. f-Xylere having a
llaslr point ol 27,26c 1 l,l oc
is not a $irabte ret€?ance
material in the high-remperalure range ol rh€ Pensky-Martans
Closed Trster, \ivhich may be as high as 370 tC,
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Annex A
tnormative)
llish rt'r*e
q) 'c ro 370 "c
SaFge 5?
lrFwdm,.fin
G€d6lio€: 0.5oc i 0.5 "c
Subdivisior$
1"card5eC I loCBnd5oC 10 "c
Long liffi st each 5oc 20 0c
fl each
5"c I ! oC ro 260 oC
'NuF&€ti
Ssl€ stg, ffix-
o,rsc I 0.5"c
2 oC der 260
!C
ExtFGis sl6sba: oc 3m oc
Peril'l($ hstiitrg to
160 I ?05 "c
tgs iq 295
sro296
v ,f Torsl l,eBgttr,
Slem dian€l€r' m
Bulb lengrh. mm
Butb diarcrer, rrrn
m
6,0 to 7.0
srot3
not l*s and I
lhan 5,t
ieastom
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e,o to r'o
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ISO Zt19 : 1S8 lEl
F,nnex B
{normative}
::'l
Pensky-Martens clcsed cup apparatus I
8,1 A typical assembly of the appa.atus, gas hea&d, is 8.3.4 .{ pilot ltarne tor aulornatic relighting ol the exposure.
shown ir! figure 8..l- {leme. A bmd { mm * S,5 mm in ahmeteimay le ,nounfeO
on rhe lid so rhar the size of the test ilame csn U.,ug"frrJ'by
]he.apparatus slrsll consist ot a test dp, lid asmbly and c€mparison. The tip of lhe rilot {tame jet shall haveair ope*lni
heating chsmber as described b*low.
the sam siee as the tip ct tlB fiam€ erposure Oevhe,
to 0,8 mm in diaruler.
di .roi
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lower propelle* shall measure approxirrrate! 3g mj tron
chamber. A handle atuehed to the flango ol lhe cop is ; tip ro
tlp, each ol its two hlades being g mnr w;dth and hrviric-a
desirable accessory, but shail not be so h€avy as to lip over
empty cup.
the pitch ol 45o. The uppet propelbi shail ,**rr,
'n ffi,,
t9 nm |rom rip to tip, each ot its two blades also "pluorii*,"ur"
beino g mmin
width and having a pitch of 4So. Borh propellers ar" foot O
-
tho stifter shatt in suct a fflanner thgt, when vietved from
rfidGmeath the glirer. the blad€6 s{ ofte p.opatter are at go
8,3 The covw essernbly shall campdse th? foltowing items.
l80o whil6 th€ btades of rts othel propeiler are at 90o
and
"JZZOT
The stirrer sfEft may be coupled to a rnoto, bv a flexi.bb shalt
8.3,1 A lid, made ol brass or olher non-rusting,retal ot or a suilablo arang€m€at of putleys.
eguivalent lFat conductjvity, and with a rim prdacting
downward almo3t to lhe flange of the cup, as shom in liguri
8.3. Thc rim shall fir th€ ourside ol rh€ cup with a clearancJnot
exceeding 0,36 mm on iho dtar$oter- Thae shell tre a loeating
or locking device, or both, engaging with a corregondin!
devicc on rhe cup. Three opedngs in rhe l;d, A, B and C. ari
8.rl Heat shall ue supplied to the crp by means of a
nr(pe!ly
Crovn in ligure 8.3. The upper edge of fts cup sfiall b€ in clos€ desi$Ed heating chOrnber wfiich is equivalent ro an ah bath.
The heatirp cfwrrber ehall consist of m air bsth and rop piar?
cofl€ct wift rhe innef face ot the lid ,ound the whcte of its ciF a
crnnlsm- ofi which the tlange of th€ cup r"s-ls.
v
this account. it shall be no! less tlran 5 mnl thick. ll flarne,
thutter exaetly etoses the lhree openifigs" Vl.,lren the heated. the caging shall be dmigoed so that rhe produets
machanism is operated to the etfier cxtreme, the three cwer of
con*ustion of the fldfi€ cannot pass up and come into eontact
opdnings shall be exactly open and tho tip of the llams, whh the cup.
expeure-device {see 8.3.3} shafl ba fully depressod.
lf the air barh has an eleclrical-resislance elffint. it shalt be
oongtrucled so that all parls of rh? interio, surface are hp.ated
8.3.3 A flanre-expocure devicg having a tip with an opetdilg onitornty. The wslls and bollorn of tt]e sir birih shail l)e n{rt lr}ss
0.7 mm to 0,8 mm in diamakr, as shown in figure g.{. fhis tf
than 6 lrm thick.
ie made prelerably of stainless sreet, although othal euira$L
m.tals msy b€ used. The flame"exposure device shall bo egr.rip- The top plate shail be mrd€ o{ rnotal and mounted with
ped $irh sn operating mechanism radrich, whsn the shutrer an ai,
i, in gap ltetiveen it and the air bath, l( may be afached
the'"open" positim, depresses the rip so thar ihe c€nt e lid of to rhe air
bath-by nrears of three screws and spacing buehings. The
lho ori{ics is between ttre plaoes of rh6 lowcr and rrpper sur.
bushings shall bg of silrllicient thickness to deine an aiiesp
faces of the tid at a point on a radius passing through tire centr* oi
4,8 mm * 0,2 mm, and they shall be nor msa ftan g,S
of the targesi opening A {see figure 9.3}, ;; ;
diameter.
5
ISO lng : 1988 (E)
O{rensFlls in nliliil!'cllr'q
Flotittlt *'-*-
"h"lt
el p6u.e d*is 1
v He'tiosch.ns€r
{
'::""
.:
g3r
\t
or l€tt'hsndsd'
Lid asnlbly mav be poqhioned oiihs right'
HoTE -
o 503
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FitttnSro:\
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Figure 8'3 - Lid
Fguro B'i - To3t cop
ISO 2719 : 1W lEl
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Fltne erF6ure dsice
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68,1
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Annex C
{normativei
Dlmgnsi06 ;n ryiiirrutres
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1
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Clasp rot
!
$
Packing ring I
$
t.
6?.16
69.79
69.71
Dirlsions in millifi8lres
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