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Roll Number: Name: Group:

Thapar Institute of Engineering and Technology, Patiala

School of Chemistry and Biochemistry
BE/Btech (II Semester) QUIZ-II UCB008: Applied Chemistry-
June 08, 2022
Time: 10 MM; MM: 10 -- Name of Faculty: Satnam Singh,- Ranjana Prakash,
Manmohan Chhibber, Vijay Luxami, Diptiman Choudhary, Bhupesh Goyal, Mily Bhattacharya, Davinder
Kumar, Priya Vashist
Note: Students are advised to attempt the Quiz on this sheet only.

1. Amongst isotactic, syndiotactic and atactic forms of polymer, which one tends to be
amorphous?

2. Write the name(s) of monomers used for synthesis of nylon-66.

3. Arrange the following bonds in order of decreasing vibrational frequency:

C-C, C-H, C=C

4. The number of peak(s) observed in primary amine and tertiary

amine due to N-H streching.

5. For a strong electrolyte, the molar conductance with dilution and

specific conductance with dilution.

6. In the electrode of second kind, the emf of cell is dependent upon of the
electrolyte.

7. Mention the total number of phases and component(s) present in a CHC13 and water
mixture.

8. Name the invariant point for one- and two-component systems.

9. To remove 1 mole of Mg(HCO3)2 hardness, how many mole(s) of lime and soda are
required.

10. Which "anion" is responsible for temporary hardness?

 Roll Number:
Thapar Institute of Engineering and Technology, Patiala
School of Chemistry and Biochemistry
BE/Btech (II Semester) EST UCB008: Applied Chemistry
June 08, 2022 Time: 02 Hours; MM: 35
Name of Faculty: Satnam Singh, Ranjana Prakash, Manmohan Chhibber, Vijay Luxami, Diptiman Choudhary,
Bhupesh Goyal, Mily Bhattacharya, Davinder Kumar, Priya Vashisht
Note: I. Use structures and diagrams to explain wherever necessary to get full credit; 2. Attempt all parts
of a question at one place; 3. Be brief and to the point to save time; 4. Assume any missing data suitably.
1 (a) What is tacticity? Name and draw various Fischer projections of polypropylene showing (4)
the phenomena of tacticity.
(b) Calculate the number average and weight average molecular masses of polypropylene (3)
with the following composition:
CH3 CHs
CH3
—H2C—CH— = 35 % =40%
= 25 % —H2C—CH-
—H2C—CH—

- 800 600
—400
II III

Given atomic mass of C = 12 and H = 1

2 (a) Calculate the temporary and permanent hardness of a sample of water containing: (4)
Mg(HCO3)2 = 7.3 mg/1; Ca(HCO3)2 = 16.2 mg/1; MgC12 = 9.5 mg/1; CaSO4 = 13.6 mg/l.
Express your results in ppm of CaCO3 and °Clarke.

(b) Differentiate between cold and hot lime soda process for softening of hard water. Give (3)
atleast three different points. (Diagram is not required)

3 (a) Calculate the fundamental vibrational wavenumber (in cm-1) of I F11271 having a force (4)
constant of 300 N/m. Given: 1 a.m.u. = 1.66 x 10-24 g, c = 3 x 108 m/s.

(b) In a chemistry lab exam, you are given two unlabeled compounds by the instructor and (3)
it was mentioned that the compounds are ortho-nitrophenol and para-nitrophenol. How
will you distinguish between these two compounds using IR spectroscopy? Explain.

4 (a) You are given 0.1 M aqueous solutions of HC1 and NaCl. Which of these will have (4)
higher conductivity? Explain briefly with the help of Grotthus type mechanism.

(b) Draw a well-labelled plot for the conductometric titration of acetic acid against sodium (3)
hydroxide (taken in burette). Discuss the trend obtained during this titration.

5 (a) What do you understand by reduced/condensed phase rule? What is the requirement of (4)
reduced phase rule? Calculate the number of components in an aqueous solution
containing KBr and RbC1.
(b) An alloy of Sn and Pb contains 55% Sn. Find the mass of the eutectic in 700 g alloy if (3)
the eutectic contains 35% Sn.