200 Best Questions (P-Block Elements)

INORGANIC CHEMISTRY
200 Most Expected

Questions For
JEEMain-2022
Part-2
ASHWANI TYAGI
Question-1 200 Best Questions for JEE Main 2022
Consider the following statements for diborane:
1. Boron is approximately sp3 hybridized
2. B–H–B angle is 180°
3. There are two terminal B–H bonds for each boron atom
4. There are only 12 bonding electrons available
Of these statements:
A 1, 3 and 4 are correct B 1, 2 and 3 are correct
C 2, 3 and 4 are correct D 1, 2 and 4 are correct

Ans. : A
X and Y are:
A Na3BO3 and Cr(BO2)3 B Na2B4O7 and Cr(BO2)3
C B2O3 and Cr(BO2)3 D B2O3 and CrBO3
Ans. : C
Borax is converted into crystalline boron by the following steps:
X and Y are respectively:
A HCl, Mg B HCl, C
C C, Al D HCl, Al
Ans. : D
The incorrect statement regarding above reactions is:
Al shows amphoteric
A character
B Gas ‘P’ and ‘Q’ are different
Both X and Y are water

C soluble
D Gas Q is inflammable
Ans. : B
A Dimer silicone B Linear silicone
Polymerisation of (A) does

C Cross linked silicone D not occur
Ans. : B
Ans. : D
Choose the correct order of C – C bond length in the given compounds:
A Acetylene < ethylene < graphite < benzene < ethane
B Acetylene < ethylene < benzene < graphite < ethane
C Acetylene < graphite < ethylene < benzene < ethane
D Acetylene < benzene < graphite < ethylene < ethane
Ans. : B
The correct code for stability, of oxidation states for given cations is:
(i) Pb2+ > Pb4+ , Tl+ < Tl3+ (ii) Bi3+ < Sb3+ , Sn2+ < Sn4+
(iii) Pb2+ > Pb4+ , Bi3+ > Bi5+ (iv) Tl3+ < In3+ , Sn2+ > Sn4+
(v) Sn2+ < Pb2+ , Sn4+ > Pb4+ (vi) Sn2+ < Pb2+ , Sn4+ < Pb4+
A (v) and (vi) B (i), (iii) and (vi)
C (iii) and (v) D (ii) and (iv)

Ans. : C
Two oxides of nitrogen, NO and NO2 are allowed to react together at 243°
K and form a coloured compound of nitrogen (X). When compound (X)
reacts with water to yield another compound of nitrogen (Y). The shape of
the anion of (Y) molecule is:
A triangular planar B triangular pyramidal
C tetrahedron D square planar

Ans. : A
Consider the following sequence of reaction.
Identify [Z] gas :
A N2 B NH3
C O2 D H2
Ans. : A
Which of the following equation is incorrectly written?
D None of the above
Ans. : B
A PCl5, POCl3, H3PO3 B PCl5, POCl3, H3PO4
C SOCl2, POCl3, H3PO3 D PCl3, POCl3, H3PO4
Ans. : B
In which of the following acids, P – P bonds is present?
A Tetra poly phosphoric acid (H6P4O13)
B Pyrophosphoric acid (H4P2O7)
C Hypophosphoric acid (H4P2O6)
D Polymetaphosphoric acid (HPO3)n

Ans. : C
A, B and C are:
A N2O, NO2 and HNO3 B NO, NO2 and HNO3
C NO2, NO and HNO3 D N2O, NO and HNO3

Ans. : B
Which is the correct sequence in the following properties? For the correct
order mark (T) and for the incorrect order mark (F):
(a) Lewis acidity order : SiF4 < SiCl4 < SiBr4 < SiI4
(b) Melting point : NH3 > SbH3 > AsH3 > PH3
(c) Boiling point : NH3 > SbH3 > AsH3 > PH3
(d) Bond dipole order : NH3 > SbH3 > AsH3 > PH3
A FTFT B TFTF
C FFTT D FFTF
Ans. : A
Calcium imide on hydrolysis will give gas (B) which on oxidation by

bleaching powder given gas (C). Gas (C) on reaction with magnesium gives
compound (D). (D) on hydrolysis gives again gas (B). (B), (C) and (D) are:
A NH3, N2, Mg3N2 B N2, NH3, MgNH
C N2, N2O5, Mg(NO3)2 D NH3, NO2, Mg(NO2)2
Ans. : A
The incorrect statement regarding 15th group hydrides (EH3). [E = N, P, As,

Sb, Bi]
A NH3 > PH3 > AsH3 > SbH3 > BiH3 : Thermal stability
B N–H > P–H > As–H > Sb–H > Bi–H : E–H bond dissociation enthalpy
C NH3 > PH3 > AsH3 > SbH3 > BiH3 : Reducing character
D NH3 > PH3 > AsH3 > SbH3 > BiH3 : Basicity
Ans. : C
A I > II > III B I > III > II
C III > II > I D III > I > II
Ans. : A
In which of the following reaction product does not contain ‘Peroxy’

linkage?
A B
C D None of these
Ans. : A
A During the (i) reaction the hybridisation of 15th group element does not change
B During the (ii) reaction the hybridisation of 16th group element has been change
C During the (iii) reaction the hybridisation of 13th group element does not change
D During the (iv) reaction the hybridisation of 18th group element does not change
Ans. : D
Consider the oxy acids HClOn series, here value of n is 1 to 4. Then incorrect
statement regarding these oxy acids is:
A Acidic character of oxy acids increases with increasing value of n.
B oxidising power of oxy acids increases with decreasing value of n.
C Thermal stability of oxy acids decreases with increasing value of n.
D ‘Cl–O’ bond order decreases with decreasing value of n

Ans. : C
A P : sp2; > 120° B Q : sp3; 109°28’
C P : sp3; 109°28’ D Q : sp3; > 109°28’
Ans. : B
Predict the correct product when Cl2 passed through solution.
A H+ + Cl– + O2 (both oxygen having 18)
B HOCl and HClO2 (all oxygen having 18)
C HClO4 and HCl (all oxygen having 18)
D Cl2O and H2O (all oxygen having 18)
Ans. : A
Y and Z are respectively:
A HClO4, ClO2 B HClO3, ClO2
C HClO3, ClO6 D HClO4, Cl2O7

Ans. : B
Which is incorrectly matched?
A B
C D None of these
Ans. : D
The incorrect order is :
A HF < HCl < HBr < HI : Acidic strength
B HF > HCl > HBr > HI : Thermal stability
C HF > HCl > HBr > HI : Boiling point
D HF > HCl > HBr > HI : Bond dissociation enthalpy
Ans. : C
XeF2 and XeF6 are separately hydrolysed then:
A both give out O2 B XeF6 gives O2 and XeF2 does not
C XeF2 alone gives O2 D Neither of them gives HF
Ans. : C
A I, II, III B I, III
C I, II D II, III
Ans. : A
Incorrect statement regarding following reactions is:
A ‘X’ is explosive B ‘Y’ is an oxyacid of xenon
Both are example of

C non-redox reaction D XeF6 can undergo partial hydrolysis
Ans. : B
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INORGANIC CHEMISTRY

200 Most Expected

A 1, 3 and 4 are correct B 1, 2 and 3 are correct

C 2, 3 and 4 are correct D 1, 2 and 4 are correct

A Na3BO3 and Cr(BO2)3 B Na2B4O7 and Cr(BO2)3

C B2O3 and Cr(BO2)3 D B2O3 and CrBO3

Borax is converted into crystalline boron by the following steps:

X and Y are respectively:

The incorrect statement regarding above reactions is:

Both X and Y are water

A Dimer silicone B Linear silicone

Polymerisation of (A) does

Choose the correct order of C – C bond length in the given compounds:

A Acetylene < ethylene < graphite < benzene < ethane

B Acetylene < ethylene < benzene < graphite < ethane

C Acetylene < graphite < ethylene < benzene < ethane

D Acetylene < benzene < graphite < ethylene < ethane

A (v) and (vi) B (i), (iii) and (vi)

C (iii) and (v) D (ii) and (iv)

A triangular planar B triangular pyramidal

C tetrahedron D square planar

Consider the following sequence of reaction.

Identify [Z] gas :

Which of the following equation is incorrectly written?

D None of the above

A PCl5, POCl3, H3PO3 B PCl5, POCl3, H3PO4

C SOCl2, POCl3, H3PO3 D PCl3, POCl3, H3PO4

In which of the following acids, P – P bonds is present?

A Tetra poly phosphoric acid (H6P4O13)

B Pyrophosphoric acid (H4P2O7)

C Hypophosphoric acid (H4P2O6)

D Polymetaphosphoric acid (HPO3)n

A N2O, NO2 and HNO3 B NO, NO2 and HNO3

C NO2, NO and HNO3 D N2O, NO and HNO3

Calcium imide on hydrolysis will give gas (B) which on oxidation by

A NH3, N2, Mg3N2 B N2, NH3, MgNH

C N2, N2O5, Mg(NO3)2 D NH3, NO2, Mg(NO2)2

The incorrect statement regarding 15th group hydrides (EH3). [E = N, P, As,

A I > II > III B I > III > II

C III > II > I D III > I > II

In which of the following reaction product does not contain ‘Peroxy’

A Acidic character of oxy acids increases with increasing value of n.

B oxidising power of oxy acids increases with decreasing value of n.

C Thermal stability of oxy acids decreases with increasing value of n.

D ‘Cl–O’ bond order decreases with decreasing value of n

A P : sp2; > 120° B Q : sp3; 109°28’

C P : sp3; 109°28’ D Q : sp3; > 109°28’

Predict the correct product when Cl2 passed through solution.

A H+ + Cl– + O2 (both oxygen having 18)

B HOCl and HClO2 (all oxygen having 18)

C HClO4 and HCl (all oxygen having 18)

D Cl2O and H2O (all oxygen having 18)

Y and Z are respectively:

A HClO4, ClO2 B HClO3, ClO2

C HClO3, ClO6 D HClO4, Cl2O7

Which is incorrectly matched?

The incorrect order is :

A HF < HCl < HBr < HI : Acidic strength

B HF > HCl > HBr > HI : Thermal stability

C HF > HCl > HBr > HI : Boiling point

D HF > HCl > HBr > HI : Bond dissociation enthalpy

XeF2 and XeF6 are separately hydrolysed then: