Chemical Bonding

1
Q- For which of the following molecule significant µ ≠ 0?

JEE Main 2014

A B

C D

A Only (a) B (a) and (b)

C Only (c) D (c) and (d)

Q- For which of the following molecule significant µ ≠ 0?

JEE Main 2014

A B

C D

A Only (a) B (a) and (b)

C Only (c) D (c) and (d)

Solution:
2 Q- Among the following molecules/ions,
C22-, N22-, O22-, O2
Which one is diamagnetic and has the shortest bond length? JEE Main 2019

A O2

B O22-

C N22-

D C22-
Q- Among the following molecules/ions,
C22-, N22-, O22-, O2
Which one is diamagnetic and has the shortest bond length? JEE Main 2019

A O2

B O22-

C N22-

D C22-
Solution:
3
Q- The number of species below that have two lone pairs of electrons in their
central atom is____.
(Round off to the Nearest Integer).
SF4, BF4-, CIF3, AsF3, PCl5, XeF4 , SF6
JEE Main 2021
Q- The number of species below that have two lone pairs of electrons in their
central atom is____.
(Round off to the Nearest Integer).
SF4, BF4-, CIF3, AsF3, PCl5, XeF4 , SF6
JEE Main 2021

Ans: 2
Solution:
4
Q- Consider, PF5, BrF5, PCl3, SF6, [ICI4]-, CIF3 and IF5. Amongst the above
molecule(s)/ ion(s), the number of molecules(s)/ion(s) having sp3d2 hybridisation
is JEE Main 2022
Q- Consider, PF5, BrF5, PCl3, SF6, [ICI4]-, CIF3 and IF5. Amongst the above
molecule(s)/ ion(s), the number of molecules(s)/ion(s) having sp3d2 hybridisation
is JEE Main 2022

Ans: 4
Solution:
5 Q- For OF2 molecule consider the following
(A) Number of lone pairs on oxygen is 2.
(B) FOF angle is less than 104.5°
(C) Oxidation state of O is -2.
(D) Molecule is bent ‘V’ shaped.
(E) Molecular geometry is linear.
Correct options are: JEE Main 2023

A C, D, E only

B B, E, A only

C A, C, D only

D A, B, D only
Q- For OF2 molecule consider the following
(A) Number of lone pairs on oxygen is 2.
(B) FOF angle is less than 104.5°
(C) Oxidation state of O is -2.
(D) Molecule is bent ‘V’ shaped.
(E) Molecular geometry is linear.
Correct options are: JEE Main 2023

A C, D, E only

B B, E, A only

C A, C, D only

D A, B, D only
Solution:
Hydrogen
6

Q: The one that is NOT suitable for the removal of permanent hardness of water is :

JEE Main 2020

A Treatment with sodium carbonate

B Calgon's method

C Clark's method

D Ion-exchange method
Q: The one that is NOT suitable for the removal of permanent hardness of water is :

JEE Main 2020

A Treatment with sodium carbonate

B Calgon's method

C Clark's method

D Ion-exchange method
Solution:

Temporary hardness of water is removed by clark method and boiling. While

permanent hardness of water is removed by treatment with sodium carbonate
(Na2CO3), calgons method and ion-exchange method
7
Q: The INCORRECT statement(s) about heavy water is (are)
(A) used as a moderator in nuclear reactor
(B) obtained as a by-product in fertilizer industry.
(C) used for the study of reaction mechanism
(D) has a higher dielectric constant than water
Choose the correct answer from the options given below : JEE Main 2021

A (B) only

B (C) only

C (D) only

D (B) and (D) only

Q: The INCORRECT statement(s) about heavy water is (are)
(A) used as a moderator in nuclear reactor
(B) obtained as a by-product in fertilizer industry.
(C) used for the study of reaction mechanism
(D) has a higher dielectric constant than water
Choose the correct answer from the options given below : JEE Main 2021

A (B) only

B (C) only

C (D) only

D (B) and (D) only

Solution:

The dielectric constant of H2O is greater than heavy water.

8
Q: Consider the following reaction :

The dihedral angle in product A in its solid phase at 110 K is :

JEE Main 2022

A 104°

B 111.5°

C 90.2°

D 111.0°
Q: Consider the following reaction :

The dihedral angle in product A in its solid phase at 110 K is :

JEE Main 2022

A 104°

B 111.5°

C 90.2°

D 111.0°
Solution:
9 Q- Match List-I with List-II
List - I List - II

A. Cobalt catalyst I. (H2 + Cl2) production

B. Syngas II. Water gas production

C. Nickel catalyst III. Coal Gasification

D. Brine solution IV. Methanol production

Choose the correct answer from the options given below: JEE Main 2023

A A-IV, B-I, C-II, D-III

B A-IV, B-III, C-I, D-II

C A-II, B-III, C-IV, D-I

D A-IV, B-III, C-II, D-I

Q- Match List-I with List-II
List - I List - II

A. Cobalt catalyst I. (H2 + Cl2) production

B. Syngas II. Water gas production

C. Nickel catalyst III. Coal Gasification

D. Brine solution IV. Methanol production

Choose the correct answer from the options given below: JEE Main 2023

A A-IV, B-I, C-II, D-III

B A-IV, B-III, C-I, D-II

C A-II, B-III, C-IV, D-I

D A-IV, B-III, C-II, D-I

Solution:
10

Q: The starting material for convenient preparation of deuterated hydrogen

peroxide(D2O2) in laboratory is:

JEE Main 2023

A K2S2O8

B 2-enthyanthraequinol

C BaO

D BaO2
Q: The starting material for convenient preparation of deuterated hydrogen
peroxide(D2O2) in laboratory is:

JEE Main 2023

A K2S2O8

B 2-enthyanthraequinol

C BaO

D BaO2
Solution:
s-block
11
Q- Which one of the following alkaline earth metal sulphates has its hydration
enthalpy greater than its lattice enthalpy?
JEE Main 2015

A CaSO4

B BeSO4

C BaSO4

D SrSO4
Q- Which one of the following alkaline earth metal sulphates has its hydration
enthalpy greater than its lattice enthalpy?
JEE Main 2015

A CaSO4

B BeSO4

C BaSO4

D SrSO4
Solution:
12

Q: On combustion Li, Na and K in excess of air, the major oxides formed,

respectively, are :

JEE Mains 2019

A Li2O, Na2O and K2O2

B Li2O, Na2O2 and K2O

C Li2O, Na2O2 and KO2

D Li2O2, Na2O2 and K2O2

Q: On combustion Li, Na and K in excess of air, the major oxides formed,

respectively, are :

JEE Mains 2019

A Li2O, Na2O and K2O2

B Li2O, Na2O2 and K2O

C Li2O, Na2O2 and KO2

D Li2O2, Na2O2 and K2O2

Solution:
13

Q:-The correct order of melting point is :

JEE Mains 2022

A Be > Mg > Ca > Sr

B Sr > Ca > Mg > Be

C Be > Ca > Mg > Sr

D Be > Ca > Sr > Mg

Q:-The correct order of melting point is :

JEE Mains 2022

A Be > Mg > Ca > Sr

B Sr > Ca > Mg > Be

C Be > Ca > Mg > Sr

D Be > Ca > Sr > Mg

14
Q:- BeO reacts with HF in presence of ammonia to give [A]
which on thermal decomposition produces [B] and ammonium
fluoride. Oxidation state of Be in [A] is_____.
JEE Mains 2022
Q:- BeO reacts with HF in presence of ammonia to give [A]
which on thermal decomposition produces [B] and ammonium
fluoride. Oxidation state of Be in [A] is_____.

Ans: 2
Solution:

Oxidation State of Be in (A) is (+2)

15 Q- Match List - I with List - II

List-I Elements List-II Colour imparted to the flame

A. K I. Brick Red

B. Ca II. Violet

C. Sr III. Apple Green

D. Ba IV. Crimson Red

Choose the correct answer from the options given below: JEE Main 2023

A A-II, B-I, C-III, D-IV

B A-II, B-IV, C-I, D-III

C A-II, B-I, C-IV, D-III

D A-IV, B-III, C-II, D-I

Q- Match List - I with List - II

List-I Elements List-II Colour imparted to the flame

A. K I. Brick Red

B. Ca II. Violet

C. Sr III. Apple Green

D. Ba IV. Crimson Red

Choose the correct answer from the options given below: JEE Main 2023

A A-II, B-I, C-III, D-IV

B A-II, B-IV, C-I, D-III

C A-II, B-I, C-IV, D-III

D A-IV, B-III, C-II, D-I

Solution:
Solutions
16

Q- 18 g glucose (C6H12O6) is added to 178.2 g water. The vapor pressure of water (in
torr) for this aqueous solution is

JEE (Main)-2016
A 76.0

B 752.4

C 759.0

D 7.6
Q- 18 g glucose (C6H12O6) is added to 178.2 g water. The vapor pressure of water (in
torr) for this aqueous solution is

A 76.0

B 752.4

C 759.0

D 7.6
Solution:
17
Q- The freezing point of benzene decreases by 0.45oC when 0.2 g of acetic acid is
added to 20 g of benzene. If acetic acid associates to form a dimer in benzene,
percentage association of acetic acid in benzene will be (K f for benzene = 5.12 K kg
mol–1)

JEE (Main)-2017
A 74.6%

B 94.6%

C 64.6%

D 80.4%
Q- The freezing point of benzene decreases by 0.45oC when 0.2 g of acetic acid is
added to 20 g of benzene. If acetic acid associates to form a dimer in benzene,
percentage association of acetic acid in benzene will be (K f for benzene = 5.12 K kg
mol–1)

A 74.6%

B 94.6%

C 64.6%

D 80.4%
Solution:
18
Q- For the solution of the gases w, x, y and z in water at 298 K, the Henry’s law
constants (KH) are 0.5, 2, 35 and 40 kbar, respectively. The correct plot for the given
data is :
JEE (Main)-2019

A B

C D
Q- For the solution of the gases w, x, y and z in water at 298 K, the Henry’s law
constants (KH) are 0.5, 2, 35 and 40 kbar, respectively. The correct plot for the given
data is :

A B

C D
Solution:
19
Q- Which one of the following 0.06 M aqueous solutions has lowest
freezing point?

A JEE mains 2021

Kl

B Al2(SO4 )3

C C6H12O6

D K2SO4
Q- Which one of the following 0.06 M aqueous solutions has lowest
freezing point?

A JEE mains 2021

Kl

B Al2(SO4 )3

C C6H12O6

D K2SO4
Solution:
Chemical Kinetics
21 Q- Two reactions R1 and R2 have identical pre-exponential factors. Activation
energy of R1 exceeds that of R2 by 10 kJ mol-1. If k1 and k2 are rate constants for
reactions R1 and R2 respectively at 300 K, then In(k2/k1) is equal to
(R = 8.314 J mole-1 K-1) JEE Main 2017

A 6

B 4

C 8

D 12
Q- Two reactions R1 and R2 have identical pre-exponential factors. Activation
energy of R1 exceeds that of R2 by 10 kJ mol-1. If k1 and k2 are rate constants for
reactions R1 and R2 respectively at 300 K, then In(k2/k1) is equal to
(R = 8.314 J mole-1 K-1) JEE Main 2017

A 6

B 4

C 8

D 12
Solution:
22
Q- NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as
per the equation, 2N2O5(g) → 4NO2(g) + O2(g). The initial concentration of N2O5 is
3.00 mol L-1 and it is 2.75 mol L-1 after 30 minutes. The rate of formation of NO2 is
JEE Main 2019

A 1.667 × 10-2 mol L-1 min-1

B 4.167 × 10-3 mol L-1 min-1

C 8.333 × 10-3 mol L-1 min-1

D 2.083 × 10-3 mol L-1 min-1

Q- NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as
per the equation, 2N2O5(g) → 4NO2(g) + O2(g). The initial concentration of N2O5 is
3.00 mol L-1 and it is 2.75 mol L-1 after 30 minutes. The rate of formation of NO2 is
JEE Main 2019

A 1.667 × 10-2 mol L-1 min-1

B 4.167 × 10-3 mol L-1 min-1

C 8.333 × 10-3 mol L-1 min-1

D 2.083 × 10-3 mol L-1 min-1

Solution:
23 Q- The rate constant (k) of a reaction is measured at different temperatures (T),
and the data are plotted in the given figure. The activation energy of the reaction in
kJ mol-1 is (R is gas constant) JEE Main 2020

A 1/R

B 2/R

C 2R

D R
Q- The rate constant (k) of a reaction is measured at different temperatures (T),
and the data are plotted in the given figure. The activation energy of the reaction in
kJ mol-1 is (R is gas constant) JEE Main 2020

A 1/R

B 2/R

C 2R

D R
Solution:
24
Q- At 30 ℃, the half life for the decomposition of AB2 is 200 s and is independent of
the initial concentration of AB2. The time required for 80% of the AB2 to decompose is
(Given: log 2 = 0.30, log 3 = 0.48) JEE Main 2022

A 200 s

B 323 s

C 467 s

D 532 s
Q- At 30 ℃, the half life for the decomposition of AB2 is 200 s and is independent of
the initial concentration of AB2. The time required for 80% of the AB2 to decompose is
(Given: log 2 = 0.30, log 3 = 0.48) JEE Main 2022

A 200 s

B 323 s

C 467 s

D 532 s
Solution:
25 Q- A student has studied the decomposition of a gas AB3 at 25℃. He obtained the
following data.
The order of the reaction is JEE Main 2023

p (mm Hg) 50 100 200 400 A 0.5

Relative 4 2 1 0.5
t1/2(s) B 2

C 1

D 0(zero)
Q- A student has studied the decomposition of a gas AB3 at 25℃. He obtained the
following data.
The order of the reaction is JEE Main 2023

p (mm Hg) 50 100 200 400 A 0.5

Relative 4 2 1 0.5
t1/2(s) B 2

C 1

D 0(zero)
Solution:
GOC
26
Q- Which of the following molecules is least resonance stabilized?
JEE Main 2017
2019

A B

C D
Q- Which of the following molecules is least resonance stabilized?
JEE Main 2017
2019

A B

C D
Solution:
27
Q- The increasing basicity order of the following compounds is
Q-
JEE Main 2019

JEE Main 2019

A (D) < (C) < (B) < (A)

B (A) < (B) < (C) < (D)

C (A) < (B) < (D) < (C)

D (D) < (C) < (A) < (B)

Q- The increasing basicity order of the following compounds is
Q-
JEE Main 2019

JEE Main 2019

A (D) < (C) < (B) < (A)

B (A) < (B) < (C) < (D)

C (A) < (B) < (D) < (C)

D (D) < (C) < (A) < (B)

Solution:
28

Q- Which of the following carbocations is most stable :

JEE Main 2022

A B

C D
Q- Which of the following carbocations is most stable :

JEE Main 2022

A B

C D
 Solution:

Is most stable carbocation

29
Q- Which of the following structures are aromatic in nature?

JEE Main 2022

A A, B, C and D

B Only A and B

C Only A and C

D Only B, C and D
Q- Which of the following structures are aromatic in nature?

JEE Main 2022

A A, B, C and D

B Only A and B

C Only A and C

D Only B, C and D
Solution:

Here A, B aromatic and C, D is non-aromatic.

30
Q- What is the correct order of acidity of the protons marked A-D in the given
Q-
compounds?
JEE Main 2019

A HC > HD > HB > HA

B HC > HD > HA > HB

C HD > HC > HB > HA

D HC > HA > HD > HB

Q- What is the correct order of acidity of the protons marked A-D in the given
Q-
compounds?
JEE Main 2019

A HC > HD > HB > HA

B HC > HD > HA > HB

C HD > HC > HB > HA

D HC > HA > HD > HB

Solution:
Isomerism
31

Q- 3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide

forms an addition product. The number of possible stereoisomers for the
product is :

Jee Main 2017

A 0

B 2

C 4

D 6
Q- 3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide
forms an addition product. The number of possible stereoisomers for the
product is :

Jee Main 2017

A 0

B 2

C 4

D 6
Solution:

Stereoisomers = 2n = 22 = 4
32

Q- The number of acyclic structural isomers (including geometrical

isomers) for pentene are ____

Jee Main 2021

Q- The number of acyclic structural isomers (including geometrical
isomers) for pentene are ____

Jee Main 2021

Ans 6
Solution:
 Q- Assertion A : Enol form of acetone [CH3COCH3] exists in < 0.1% quantity.
33
However, the enol form of acetyl acetone [CH3COCH2OCCH3] exists in
approximately 15% quantity.
Reason R : enol form of acetyl acetone is stabilized by intramolecular
hydrogen bonding,
which is not possible in enol form of acetone. Choose the correct
statement : Jee Main 2021

A A is false but R is true

Both A and R are true and R is the correct

B
explanation of A

Both A and R are true but R is not the

C
correct explanation of A

D A is true but R is false

Q- Assertion A : Enol form of acetone [CH3COCH3] exists in < 0.1% quantity.
However, the enol form of acetyl acetone [CH3COCH2OCCH3] exists in
approximately 15% quantity.
Reason R : enol form of acetyl acetone is stabilized by intramolecular
hydrogen bonding,
which is not possible in enol form of acetone. Choose the correct
statement : Jee Main 2021

A A is false but R is true

Both A and R are true and R is the correct

B
explanation of A

Both A and R are true but R is not the

C
correct explanation of A

D A is true but R is false

Solution:
34
Q- Observations structures of the following compounds

The total number of structures/compounds which posses asymmetric

carbon atoms is ___.
Jee Main 2022
Solution:

Number of compounds containing asymmetric carbons are three.

35 Q- Match List I with List II
List I - Isomeric Paris List II - Type of Isomers

A. Propanamine and N- I. Metamers

Methylethanamine

B. Hexan-2-one and Hexan-3- II. Positional isomers

one

C. Ethanamide and III. Functional isomers

Hydroxyethylamine

D. p-nitrophenol and p- IV. Tautomers

nitrophenol

JEE Main 2023

Choose the correct answer from the options given below:-

A A - III, B - IV, C - I, D- II

B A - IV, B - III, C - I, D- II

C A - II, B - III, C - I, D- IV

D A - III, B - I, C - IV, D- II
Q- Match List I with List II
List I - Isomeric Paris List II - Type of Isomers

A. Propanamine and N- I. Metamers

Methylethanamine

B. Hexan-2-one and Hexan-3- II. Positional isomers

one

C. Ethanamide and III. Functional isomers

Hydroxyethylamine

D. o-nitrophenol and p- IV. Tautomers

nitrophenol

JEE Main 2023

Choose the correct answer from the options given below:-

A A - III, B - IV, C - I, D- II

B A - IV, B - III, C - I, D- II

C A - II, B - III, C - I, D- IV

D A - III, B - I, C - IV, D- II
Solution:
Equilibrium
36
Q- The equilibrium constant at 298 K for a reaction,
A + B ⇌ C + D is 100. If the initial concentrations of all the four species were 1 M each,
then equilibrium concentration of D (in mol L -1 ) will be :
JEE Main 2016

A 0.818

B 1.818

C 1.182

D 0.182
Q- The equilibrium constant at 298 K for a reaction,
A + B ⇌ C + D is 100. If the initial concentrations of all the four species were 1 M each,
then equilibrium concentration of D (in mol L -1 ) will be :
JEE Main 2016

A 0.818

B 1.818

C 1.182

D 0.182
Solution:
37
Q- Addition of sodium hydroxide solution to a weak acid (HA) results in a buffer of
pH 6. If ionisation constant of HA is 10–5 , the ratio of salt to acid concentration in the
buffer solution will be :
JEE Main 2017

A 10 : 1

B 4:5

C 1 : 10

D 5:4
Q- Addition of sodium hydroxide solution to a weak acid (HA) results in a buffer of
pH 6. If ionisation constant of HA is 10–5 , the ratio of salt to acid concentration in the
buffer solution will be :
JEE Main 2017

A 10 : 1

B 4:5

C 1 : 10

D 5:4
Solution:
38
Q- Consider the following reaction :
N2O4(g) ⇌ 2 NO2(g); ΔH0 = + 58 kJ
For each of the following cases (a,b), the direction in which the equilibrium shifts is
(a) Temperature is decreased
(b) Pressure is increased by adding N2 at constant T.
JEE Main 2020

A (a) Towards product, (b) towards reactant

B (a) Towards reactant, (b) no change

C (a) Towards reactant, (b) towards product

D (a) Towards product, (b) no change

Q- Consider the following reaction :
N2O4(g) ⇌ 2 NO2(g); ΔH0 = + 58 kJ
For each of the following cases (a,b), the direction in which the equilibrium shifts is
(a) Temperature is decreased
(b) Pressure is increased by adding N2 at constant T.
JEE Main 2020

A (a) Towards product, (b) towards reactant

B (a) Towards reactant, (b) no change

C (a) Towards reactant, (b) towards product

D (a) Towards product, (b) no change

Solution:

● Given reaction is endothermic

● On decreasing temperature backward reaction will be favoured.
● On adding N2, pressure is increased at constant T, and volume would also be
constant so no change in observed.
39

Q- The pH of ammonium phosphate solution, if pka of phosphoric acid and pkb of

ammonium hydroxide are 5.23 and 4.75 respectively, is _____.

JEE Main 2021

Q- The pH of ammonium phosphate solution, if pka of phosphoric acid and pkb of

ammonium hydroxide are 5.23 and 4.75 respectively, is _____.

JEE Main 2021

Ans
7.00
Solution:
40
Q- At 298 K, the solubility of silver chloride in water is 1.434 × 10-3 g L-1.
The value of -log Ksp for silver chloride is____.
(Given mass of Ag is 107.9 g mol-1 and mass of Cl is 35.5 g mol-1)
JEE Main 2023
Q- At 298 K, the solubility of silver chloride in water is 1.434 × 10-3 g L-1.
The value of -log Ksp for silver chloride is____.
(Given mass of Ag is 107.9 g mol-1 and mass of Cl is 35.5 g mol-1)
JEE Main 2023

Ans: 10
Solution:
Thermodynamics
41 Q- A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to
375 mL at a constant temperature of 37.0°C. As it does so, it absorbs 208 J of heat.
The values of q and w for the process will be
(R=8.314 J/mol K) (In 7.5= 2.01) JEE Main 2013

A q = + 208 J, w = - 208 J

B q = - 208 J, w = - 208 J

C q = - 208 J, w = + 208 J

D q = + 208 J, w = + 208 J
Q- A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to
375 mL at a constant temperature of 37.0°C. As it does so, it absorbs 208 J of heat.
The values of q and w for the process will be
(R=8.314 J/mol K) (In 7.5= 2.01) JEE Main 2013

A q = + 208 J, w = - 208 J

B q = - 208 J, w = - 208 J

C q = - 208 J, w = + 208 J

D q = + 208 J, w = + 208 J
Solution:
42
Q- For silver, Cp(JK-1 mol-1) = 23 + 0.01 T. If the temperature (T) of 3 moles of silver is
raised from 300 K to 1000 K at 1 atm pressure, the value of ΔH wil be close to
JEE Main 2019

A 21 kJ

B 13 kJ

C 62 kJ

D 16 kJ
Q- For silver, Cp(JK-1 mol-1) = 23 + 0.01 T. If the temperature (T) of 3 moles of silver is
raised from 300 K to 1000 K at 1 atm pressure, the value of ΔH wil be close to
JEE Main 2019

A 21 kJ

B 13 kJ

C 62 kJ

D 16 kJ
Solution:
43
Q- Data given for the following reaction is as follows:
FeO(s) + C(graphite) → Fe(s) + CO(g)

Substance ΔfH0 (kJ mol-1) ΔS0 (J mol-1 K-1)

FeO(s) -266.3 57.49

C(grapjhite) 0 5.74

Fe(s) 0 27.28

CO(g) -110.5 197.6

The minimum temperature in K at which the reaction becomes spontaneous

is___. (Integer answer)
JEE Main 2021
Solution:
44
Q- The molar heat capacity for an ideal gas at constant pressure is 20.785 J K -1 mol-
1. The change in internal energy is 5000 J upon heating it from 300 K to 500 K. The
number of moles of the gas at constant volume is____. (Nearest integer) (Given: R
= 8.314 J K-1 mol-1)
JEE Main 2022
Q- The molar heat capacity for an ideal gas at constant pressure is 20.785 J K -1 mol-
1. The change in internal energy is 5000 J upon heating it from 300 K to 500 K. The
number of moles of the gas at constant volume is____. (Nearest integer) (Given: R
= 8.314 J K-1 mol-1)
JEE Main 2022

Ans: 2
Solution:
45
Q- One mole of an ideal monatomic gas is subjected to changes as shown in the
graph. The magnitude of the work done
(by the system or on the system) is ____ J (nearest integer).
Given: log 2 = 0.3, ln 10 = 2.3 JEE Main 2023
Solution:
P- block
46

Q- XeF6 on partial hydrolysis with water produces a compound 'X'. The same

compound 'X' is formed when XeF6 reacts with silica. The compound 'X' is :
Jee Main 2017

A
XeO3

B XeF4

C XeF2

D XeOF4
Q- XeF6 on partial hydrolysis with water produces a compound 'X'. The same

compound 'X' is formed when XeF6 reacts with silica. The compound 'X' is :
Jee Main 2017

A
XeO3

B XeF4

C XeF2

D XeOF4
Solution:

XeF6 + H2O ⟶ XeOF4 +2HF

2XeF6 + SiO2 ⟶ 2XeOF4 + SiF4

47
Q- Diborane (B2H6) reacts independently with O2 and H2O to produce, respectively
JEE Main 2019

A H3BO3 and B2O3

B HBO2 and H2BO3

C B2O3 and H3BO3

D B2O3 and [BH4]-

Q- Diborane (B2H6) reacts independently with O2 and H2O to produce, respectively
JEE Main 2019

A H3BO3 and B2O3

B HBO2 and H2BO3

C B2O3 and H3BO3

D B2O3 and [BH4]-

Solution:
48

Q- The total number of acidic oxides from the following list is

NO, N2O, B2O3, N2O5, CO, SO3, P4O10

JEE Main 2022

A 3

B 4

C 5

D 6
Q- The total number of acidic oxides from the following list is

NO, N2O, B2O3, N2O5, CO, SO3, P4O10

JEE Main 2022

A 3

B 4

C 5

D 6
Solution:

NO, N2O, CO – neutral oxides

B2O3, N2O5, SO3, P4O10 – acidic oxides
49

Q- White phosphorus reacts with thionyl chloride to give

JEE Main 2022

A PCl5, SO2 and S2Cl2

B PCl3, SO2 and S2Cl2

C PCl3, SO2 and Cl2

D PCl5, SO2 and Cl2

Q- White phosphorus reacts with thionyl chloride to give

JEE Main 2022

A PCl5, SO2 and S2Cl2

B PCl3, SO2 and S2Cl2

C PCl3, SO2 and Cl2

D PCl5, SO2 and Cl2

Solution:
50
Q- Given below are two statements, one is labelled as Assertion A and The other is
labelled as Reason R.
Assertion A : Beryllium has less negative value of reduction potential compared to
the other alkaline earth metals.
Reason R : Beryllium has large hydration energy due to small size of Be 2+ but
relatively large value of atomization enthalpy.
In the light of the above statements, choose the most appropriate answer from the
options given below.
JEE Main 2023

A A is correct but R is not correct

B Both A and R are correct and R is the

correct explanation of A.

C A is not correct but R is correct

D Both A and R are correct and R is NOT the

correct explanation of A
Q- Given below are two statements, one is labelled as Assertion A and The other is
labelled as Reason R.
Assertion A : Beryllium has less negative value of reduction potential compared to
the other alkaline earth metals.
Reason R : Beryllium has large hydration energy due to small size of Be 2+ but
relatively large value of atomization enthalpy.
In the light of the above statements, choose the most appropriate answer from the
options given below.
JEE Main 2023

A A is correct but R is not correct

B Both A and R are correct and R is the

correct explanation of A.

C A is not correct but R is correct

D Both A and R are correct and R is NOT the

correct explanation of A
Solution:

Be has less negative value compared to other Alkaline earth

metals.
However it’s reducing nature is due to large hydration energy
associated with the small size of Be2+ ion and relatively large value
of the atomization enthalpy of metal.
Reagents
51
Q- The major product of the following reaction:

JEE Main 2019

A B

C D
Q- The major product of the following reaction:

JEE Main 2019

A B

C D
Solution:
52
Q- The major product obtained in the following reaction is

JEE Main 2019

A B

C D
Q- The major product obtained in the following reaction is

JEE Main 2019

A B

C D
Solution:
53
Q- Choose the correct option for the following reactions.

JEE Main 2022, 2023

A ‘A’ and ‘B’ are both Markovnikov addition products

B ‘A’ is Markovnikov product and ‘B’ is anti-Markovnikov

product

C ‘A’ and ‘B’ are both anti-Markovnikov products

D ‘B’ is Markovnikov and ‘A’ is anti-Markovnikov product

Q- Choose the correct option for the following reactions.

JEE Main 2022, 2023

A ‘A’ and ‘B’ are both Markovnikov addition products

B ‘A’ is Markovnikov product and ‘B’ is anti-Markovnikov

product

C ‘A’ and ‘B’ are both anti-Markovnikov products

D ‘B’ is Markovnikov and ‘A’ is anti-Markovnikov product

Solution:
54
Q- Most stable product of the following reaction is :

JEE Main 2022

A B

C D
Q- Most stable product of the following reaction is :

JEE Main 2022

A B

C D
Solution:
55 Q-An organic compound ‘A’ on reaction with NH3 followed by heating gives
compound B. Which on further strong heating gives compound C(C8H5NO2).
Compound C on sequential reaction with ethanolic KOH, alkyl chloride and
hydrolysis with alkali gives a primary amine. The compound A is :
JEE Main 2022

A B

C D
Q-An organic compound ‘A’ on reaction with NH3 followed by heating gives
compound B. Which on further strong heating gives compound C(C8H5NO2).
Compound C on sequential reaction with ethanolic KOH, alkyl chloride and
hydrolysis with alkali gives a primary amine. The compound A is :
JEE Main 2022

A B

C D
Solution:
5
6 Q- The major product ‘P’ for the following sequence of reactions is:

JEE Main 2023

D
Q- The major product ‘P’ for the following sequence of reactions is:

JEE Main 2023

D
Solution:
57 Q- Compound (X) undergoes following sequence of reactions to given the Lactone
(Y).
JEE Main 2023

Compound (X) is

A B

C D
Q- Compound (X) undergoes following sequence of reactions to given the Lactone
(Y).
JEE Main 2023

Compound (X) is

A B

C D
Solution:
D and f block
58
Q- Which of the following arrangements does not represent the correct order of the
property stated against it?
JEE Main 2013

A V2+ < Cr2+ < Mn2+ < Fe2+ : paramagnetic behaviour

B Ni2+ < Co2+ < Fe2+ < Mn2+ : ionic size

C Co3+ < Fe3+ < Cr3+ < Sc3+: stability in aqueous solution

D Sc < Ti < Cr < Mn : number of oxidation states

Q- Which of the following arrangements does not represent the correct order of the
property stated against it?
JEE Main 2013

A V2+ < Cr2+ < Mn2+ < Fe2+ : paramagnetic behaviour

B Ni2+ < Co2+ < Fe2+ < Mn2+ : ionic size

C Co3+ < Fe3+ < Cr3+ < Sc3+: stability in aqueous solution

D Sc < Ti < Cr < Mn : number of oxidation states

Solution:
59
Q-
JEE Main 2019

In the above sequence of reactions, A and D, respectively, are

A Kl and K2MnO4

B KlO3 and MnO2

C MnO2 and KlO3

D Kl and KMnO4
Q-
JEE Main 2019

In the above sequence of reactions, A and D, respectively, are

A Kl and K2MnO4

B KlO3 and MnO2

C MnO2 and KlO3

D Kl and KMnO4
Solution:
60
Q- What is the correct order of the following elements with respect to their density?
JEE Main 2021

A Cr < Zn < Co < Cu < Fe

B Cr < Fe < Co < Cu < Zn

C Zn < Cu < Co < Fe < Cr

D Zn < Cr < Fe < Co < Cu

Q- What is the correct order of the following elements with respect to their density?
JEE Main 2021

A Cr < Zn < Co < Cu < Fe

B Cr < Fe < Co < Cu < Zn

C Zn < Cu < Co < Fe < Cr

D Zn < Cr < Fe < Co < Cu

Solution:
61
Q- In following pairs, the one in which both transition metal ions are colourless is:
JEE Main 2022
2019

A Sc3+, Zn2+

B Ti4+, Cu2+

C V2+, Ti3+

D Zn2+, Mn2+
Q- In following pairs, the one in which both transition metal ions are colourless is:
JEE Main 2022
2019

A Sc3+, Zn2+

B Ti4+, Cu2+

C V2+, Ti3+

D Zn2+, Mn2+
Solution:
62
Q- The magnetic moment of a transition metal compound has been calculated to
Q-
be 3.87 B.M. The metal ion is
JEE Main 2023
2019

A Cr2+

B Mn2+

C V2+

D Ti2=
Q- The magnetic moment of a transition metal compound has been calculated to
Q-
be 3.87 B.M. The metal ion is
JEE Main 2023
2019

A Cr2+

B Mn2+

C V2+

D Ti2=
Solution:
Coordination Compounds
63

Q- The number of bridging CO ligand(s) and Co-Co bond (s) in Co2(CO)8,

respectively are :
JEE Main 2019

A 4 and 0

B 0 and 2

C 2 and 1

D 2 and 0
Q- The number of bridging CO ligand(s) and Co-Co bond (s) in Co2(CO)8,

respectively are :
JEE Main 2019

A 4 and 0

B 0 and 2

C 2 and 1

D 2 and 0
Solution:
64

Q- The number of geometrical isomers found in the metal complexes

[PtCl2(NH3)2], [Ni(CO)4], [Ru(H2O)3Cl3] and [CoCl2(NH3)4]+ respectively, are

JEE Main 2021

A 2, 1, 2, 1

B 2, 1, 2, 2

C 2, 0, 2, 2

D 1, 1, 1, 1
Q- The number of geometrical isomers found in the metal complexes

[PtCl2(NH3)2], [Ni(CO)4], [Ru(H2O)3Cl3] and [CoCl2(NH3)4]+ respectively, are

JEE Main 2021

A 2, 1, 2, 1

B 2, 1, 2, 2

C 2, 0, 2, 2

D 1, 1, 1, 1
Solution:
Solution:
6
5 Q- Arrange the following metal complex/compounds in the increasing order of

spin only magnetic moment. Presume all the three, high spin system.

(Atomic numbers Ce = 58, Gd = 64 and Eu = 63.)

(a) (NH4)2[Ce(NO3)6]

(b) Gd(NO3)3 and

(c) Eu(NO3)3 JEE Main 2021

A (a) < (c) < (b)

B (a) < (b) < (c)

C (c) < (a) < (b)

D (b) < (a) < (c)

Q- Arrange the following metal complex/compounds in the increasing order of

spin only magnetic moment. Presume all the three, high spin system.

(Atomic numbers Ce = 58, Gd = 64 and Eu = 63.)

(a) (NH4)2[Ce(NO3)6]

(b) Gd(NO3)3 and

(c) Eu(NO3)3 JEE Main 2021

A (a) < (c) < (b)

B (a) < (b) < (c)

C (c) < (a) < (b)

D (b) < (a) < (c)

Solution:
66
Q- Match List - I with List - II
List I (Complex) List II (Hybridization)

A. Ni(CO)4 I. sp3

B. [Ni(CN)4]2- II. sp3d2

C. [Co(CN)6]3- III. d2sp3

D. [CoF6]3- IV. dsp2

Choose the correct answer from the options given below : JEE Main 2022

A A - IV, B - I, C - III, D - II

B A - I, B - IV, C - III, D - II

C A - I, B - IV, C - II, D - III

D A - IV, B - I, C - II, D - III

Q- Match List - I with List - II
List I (Complex) List II (Hybridization)

A. Ni(CO)4 I. sp3

B. [Ni(CN)4]2- II. sp3d2

C. [Co(CN)6]3- III. d2sp3

D. [CoF6]3- IV. dsp2

Choose the correct answer from the options given below : JEE Main 2022

A A - IV, B - I, C - III, D - II

B A - I, B - IV, C - III, D - II

C A - I, B - IV, C - II, D - III

D A - IV, B - I, C - II, D - III

67
Q- The primary and secondary valencies of cobalt respectively in [Co(NH 3)5Cl]Cl2
Q-
are:
JEE Main 2023
2019

A 3 and 5

B 2 and 6

C 2 and 8

D 3 and 6
Q- The primary and secondary valencies of cobalt respectively in [Co(NH 3)5Cl]Cl2
Q-
are:
JEE Main 2023
2019

A 3 and 5

B 2 and 6

C 2 and 8

D 3 and 6
Solution:
Amines
68

Q- A compound with molecular mass 180 is acylated with CH3COCl to get a

compound with molecular mass 390. The number of amino groups present per
molecule of the former compound is

JEE Main 2013

A 2

B 5

C 4

D 6
Q- A compound with molecular mass 180 is acylated with CH3COCl to get a
compound with molecular mass 390. The number of amino groups present per
molecule of the former compound is

JEE Main 2013

A 2

B 5

C 4

D 6
Solution:
69 Q-The Kjeldahl method of Nitrogen estimation fails for which of the following
reaction products?

JEE Main 2020

A (a), (c) and (d)

B (a) and (d)

C (c) and (d)

D (b) and (c)

Q-The Kjeldahl method of Nitrogen estimation fails for which of the following
reaction products?

JEE Main 2020

A (a), (c) and (d)

B (a) and (d)

C (c) and (d)

D (b) and (c)

Solution:
70 Q-An organic compound ‘A’ on reaction with NH3 followed by heating gives
compound B. Which on further strong heating gives compound C(C8H5NO2).
Compound C on sequential reaction with ethanolic KOH, alkyl chloride and
hydrolysis with alkali gives a primary amine. The compound A is :
JEE Main 2022

A B

C D
Q-An organic compound ‘A’ on reaction with NH3 followed by heating gives
compound B. Which on further strong heating gives compound C(C8H5NO2).
Compound C on sequential reaction with ethanolic KOH, alkyl chloride and
hydrolysis with alkali gives a primary amine. The compound A is :
JEE Main 2022

A B

C D
Solution:
71
Q- Identify the product formed (A and E)

JEE Main 2023

A B

C D
Q- Identify the product formed (A and E)

JEE Main 2023

A B

C D
Solution:
72
Q- How many of the transformation given below would result in aromatic amines ?

JEE Main 2023

Solution:

3
Biomolecules
73
Q- The increasing order of pKa of the following amino acids in aqueous solution is
Gly , Asp , Lys , Arg
JEE Main 2019

A Gly < Asp < Arg < Lys

B Arg < Lys < Gly < Asp

C Asp < Gly < Arg < Lys

D Asp < Gly < Lys < Arg

Q- The increasing order of pKa of the following amino acids in aqueous solution is
Gly , Asp , Lys , Arg
JEE Main 2019

A Gly < Asp < Arg < Lys

B Arg < Lys < Gly < Asp

C Asp < Gly < Arg < Lys

D Asp < Gly < Lys < Arg

Solution:
74 Q- A, B and C are three biomolecules. The results of the tests performed on them
are given below.
JEE Main 2020
Molisch’s Test Barfoed Test Biuret Test

A Positive Negative Negative

B Positive Positive Negative

C Negative Negative Positive

A, B and C are respectively.

A A=Lactose, B = Fructose, C = Alanine

B A=Lactose, B = Glucose, C = Alanine

C A=Glucose, B = Fructose, C = Albumin

D A=Lactose, B = Glucose, C = Albumin

Q- A, B and C are three biomolecules. The results of the tests performed on them
are given below.
JEE Main 2020
Molisch’s Test Barfoed Test Biuret Test

A Positive Negative Negative

B Positive Positive Negative

C Negative Negative Positive

A, B and C are respectively.

A A=Lactose, B = Fructose, C = Alanine

B A=Lactose, B = Glucose, C = Alanine

C A=Glucose, B = Fructose, C = Albumin

D A=Lactose, B = Glucose, C = Albumin

Solution:
75

Q-The mass percentage of nitrogen in histamine is _____.

JEE Main 2020

Q-The mass percentage of nitrogen in histamine is _____.

JEE Main 2020

Ans 37.84
Solution:
76 Q-Match List-I with List-II.

List-I List-II

(a) Sucrose (i) β -D-Galactose and

β - D - Glucose

(b) Lactose (ii) α - D - Glucose and

β - D - Fructose

(c) Maltose (iii) α - D - Glucose and

α - D - Glucose
JEE Main 2021
Choose the correct answer from the options given below :

A (a) → (i), (b) → (iii), (c) → (ii)

B (a) → (iii), (b) → (ii), (c) → (i)

C (a) → (ii), (b) → (i), (c) → (iii)

D (a) → (iii), (b) → (i), (c) → (ii)

76 Q-Match List-I with List-II.

List-I List-II

(a) Sucrose (i) β -D-Galactose and

β - D - Glucose

(b) Lactose (ii) α - D - Glucose and

β - D - Fructose

(c) Maltose (iii) α - D - Glucose and

α - D - Glucose
JEE Main 2021
Choose the correct answer from the options given below :

A (a) → (i), (b) → (iii), (c) → (ii)

B (a) → (iii), (b) → (ii), (c) → (i)

C (a) → (ii), (b) → (i), (c) → (iii)

D (a) → (iii), (b) → (i), (c) → (ii)

Solution:

Disaccharides Monomer present

Sucrose α - D - Glucose and

β - D - Fructose

Lactose β -D-Galactose and

β - D - Glucose

Maltose α - D - Glucose and

α - D - Glucose
77 Q- A short peptide on complete hydrolysis produces 3 moles of glycine (G), two
moles of leucine (L) and two moles of valine (V) per mole of peptide. The number of
peptide linkages in it are _________ . JEE Main 2019
Solution:
Atomic Structure
78

Q- Energy of an electron is given by E = - 2.178 × 10-18 J Wavelength of light

required to excite an electron in an hydrogen atom form level n = 1 to n = 2 will be

(h = 6.62 × 10-34 Js and c = 3.0 × 108 ms-1)

JEE Main 2013

A 1.214 × 10-7 m

B 2.816 × 10-7 m

C 6.500 × 10-7 m

D 8.500 × 10-7 m
Q- Energy of an electron is given by E = - 2.178 × 10-18 J Wavelength of light

required to excite an electron in an hydrogen atom form level n = 1 to n = 2 will be

(h = 6.62 × 10-34 Js and c = 3.0 × 108 ms-1)

JEE Main 2013

A 1.214 × 10-7 m

B 2.816 × 10-7 m

C 6.500 × 10-7 m

D 8.500 × 10-7 m
Solution:
79
Q- The graph between and r(radial distance) is shown below. This represents

JEE Main 2019

A 1s orbital

B 2s orbital

C 2p orbital

D 3s orbital
Q- The graph between and r(radial distance) is shown below. This represents

JEE Main 2019

A 1s orbital

B 2s orbital

C 2p orbital

D 3s orbital
Solution:

The given probability density curve is for 2s orbital because it has only one radial node.
80
Q - If the radius of the 3rd Bohr’s orbit of hydrogen atom is r3 and the radius of 4th

Bohr’s orbit is r4. Then :

JEE Main 2022

D
Q - If the radius of the 3rd Bohr’s orbit of hydrogen atom is r3 and the radius of 4th

Bohr’s orbit is r4. Then :

JEE Main 2022

D
 Solution:

and

Therefore
81

Q- The wave function (Ψ) of 2s is given by

At r = r0, radial node is formed. Thus, r0in terms of a0

JEE Main 2023

A r0 = a0

B r0 = 4a0

D r0 = 2a0
Q- The wave function (Ψ) of 2s is given by

At r = r0, radial node is formed. Thus, r0in terms of a0

JEE Main 2023

A r0 = a0

B r0 = 4a0

D r0 = 2a0
Solution:
82
Q- Arrange the following orbitals in decreasing order of energy?
(A) n = 3, l = 0, m = 0
(B) n = 4, l = 0, m = 0
(C) n = 3, l = 1, m = 0
(D) n = 3, l = 2, m = 1
The correct option for the order is: JEE Main 2023

A B>D>C>A

B D>B>C>A

C A > C >B > D

D D>B>A>C
Q- Arrange the following orbitals in decreasing order of energy?
(A) n = 3, l = 0, m = 0
(B) n = 4, l = 0, m = 0
(C) n = 3, l = 1, m = 0
(D) n = 3, l = 2, m = 1
The correct option for the order is: JEE Main 2023

A B>D>C>A

B D>B>C>A

C A > C >B > D

D D>B>A>C
Solution:
Electrochemistry
83
Q- Resistance of 0.2 M solution of an electrolyte is 50Ω. The specific conductance of
the solution is 1.4 S m-1. The resistance of 0.5 M solution of the same electrolyte is
280 Ω. The molar conductivity of 0.5 M solution of the electrolyte in S m 2 mol-1 is
JEE Main 2014

A 5 × 10-4

B 5 × 10-3

C 5 × 103

D 5 × 102
Q- Resistance of 0.2 M solution of an electrolyte is 50Ω. The specific conductance of
the solution is 1.4 S m-1. The resistance of 0.5 M solution of the same electrolyte is
280 Ω. The molar conductivity of 0.5 M solution of the electrolyte in S m 2 mol-1 is
JEE Main 2014

A 5 × 10-4

B 5 × 10-3

C 5 × 103

D 5 × 102
Solution:
84 Q- Given the equilibrium constant:
KC of the reaction:
Cu(s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag(s) is
10 × 1015, calculate the E0cell of this reaction at 298 K

JEE Main 2019

A 0.4736 mV

B 0.4736 V

C 0.04736 V

D 0.04736 mV
Q- Given the equilibrium constant:
KC of the reaction:
Cu(s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag(s) is
10 × 1015, calculate the E0cell of this reaction at 298 K

JEE Main 2019

A 0.4736 mV

B 0.4736 V

C 0.04736 V

D 0.04736 mV
Solution:
85 Q- For the reaction
2Fe3+(aq) + 2I-(aq) → 2Fe2+(aq) + I2(s)
The magnitude of the standard molar free energy change ΔrG°m = - ___ kJ
(Round off to the Nearest Integer).

JEE Main 2021

Q- For the reaction
2Fe3+(aq) + 2I-(aq) → 2Fe2+(aq) + I2(s)
The magnitude of the standard molar free energy change ΔrG°m = - ___ kJ
(Round off to the Nearest Integer).

JEE Main 2021

Ans: 45
Solution:
86
Q- The conductivity of a weak acid HA of concentration 0.001 mol L -1 is
2.0 × 10-5 S cm-1.
If 𝛬°m(HA) = 190 S cm2 mol-1, the ionization constant (Ka) of HA is equal to ____ × 10-
6. (Round off to the Nearest Integer)
JEE Main 2019
Q- The conductivity of a weak acid HA of concentration 0.001 mol L -1 is
2.0 × 10-5 S cm-1.
If 𝛬°m(HA) = 190 S cm2 mol-1, the ionization constant (Ka) of HA is equal to ____ × 10-
6. (Round off to the Nearest Integer)
JEE Main 2019

Ans: 12
Solution:
87
Q- Consider the cell
Pt(s)|H2(g, 1 atm)|H+(aq, 1M)| |Fe3+(aq), Fe2+(aq)|Pt(s)
When the potential of the cell is 0.712 V at 298 K, the ratio [Fe 2+] / ]Fe3+] is______.
Given: Fe3+ + e- = Fe2+, E0Fe3+, Fe2+ |Pt = 0.771 2.303 RT/F = 0.06 V JEE Main 2023
Solution:
Environmental Chemistry
88
Q- The concentration of fluoride, lead, nitrate and iron in a water sample from an
underground lake was found to be 1000 ppb, 40 ppb, 100 ppm and 0.2 ppm,
respectively. This water is unsuitable for drinking due to high concentration of

JEE Main 2016

A Lead

B Nitrate

C Iron

D Fluoride
Q- The concentration of fluoride, lead, nitrate and iron in a water sample from an
underground lake was found to be 1000 ppb, 40 ppb, 100 ppm and 0.2 ppm,
respectively. This water is unsuitable for drinking due to high concentration of

JEE Main 2016

A Lead

B Nitrate

C Iron

D Fluoride
Solution:
89
Q- The greenhouse gas/es is (are):
(A) Carbon dioxide
(B) Oxygen
(C) Water vapour
(D) Methane
Choose the most appropriate answer from the options given below: JEE Main 2021

A (A) , (C) and (D) only

B (A) and (B) only

C (A) and (C) only

D (A) only
Q- The greenhouse gas/es is (are):
(A) Carbon dioxide
(B) Oxygen
(C) Water vapour
(D) Methane
Choose the most appropriate answer from the options given below: JEE Main 2021

A (A) , (C) and (D) only

B (A) and (B) only

C (A) and (C) only

D (A) only
Solution:
90
Q- The gas ‘A’ is having very low reactivity reaches to stratosphere. It is non-toxic
and non-flammable but dissociated by UV-radiations in stratosphere. The
intermediates formed initially from the gas ‘A’ are: JEE Main 2019

. .
A ClO + CF2Cl

. .
B Cl + CF2Cl

. .
C CH3 + CF2Cl

. .
D ClO + CH3
Q- The gas ‘A’ is having very low reactivity reaches to stratosphere. It is non-toxic
and non-flammable but dissociated by UV-radiations in stratosphere. The
intermediates formed initially from the gas ‘A’ are: JEE Main 2019

. .
A ClO + CF2Cl

. .
B Cl + CF2Cl

. .
C CH3 + CF2Cl

. .
D ClO + CH3
Solution:
91 Q- Given below are two Statements:

Statement I: Classical smog occurs in cool humid climate. It is a reducing mixture

of smoke, fog and sulphur dioxide.

Statement II: Photochemical smog has components, ozone, nitric oxide, acrolein,
formaldehyde, PAN etc.

In the light of the above statements, choose the most appropriate answer from the
options given below. JEE Main 2022

A Both Statement I and Statement II are correct

B Both Statement I and Statement II are incorrect

C Statement I is correct but Statement II is incorrect

D Statement I is incorrect but Statement II is correct

Q- Given below are two Statements:

Statement I: Classical smog occurs in cool humid climate. It is a reducing mixture

of smoke, fog and sulphur dioxide.

Statement II: Photochemical smog has components, ozone, nitric oxide, acrolein,
formaldehyde, PAN etc.

In the light of the above statements, choose the most appropriate answer from the
options given below. JEE Main 2022

A Both Statement I and Statement II are correct

B Both Statement I and Statement II are incorrect

C Statement I is correct but Statement II is incorrect

D Statement I is incorrect but Statement II is correct

92 Q- Formation of photochemical smog involves the following reaction in which A, B
and C are respectively.

Choose the correct answer from the options given below:

JEE Main 2019

A O, NO & NO3-

B O, N2O & NO

C N, O2 & O3

D NO , O , & O3
Q- Formation of photochemical smog involves the following reaction in which A, B
and C are respectively.

Choose the correct answer from the options given below:

JEE Main 2019

A O, NO & NO3-

B O, N2O & NO

C N, O2 & O3

D NO , O , & O3
Solution:
Polymers
93

Q- Which polymer is used in the manufacture of paints and lacquers?

JEE Main 2015

A Bakelite

B Glyptal

C Polypropylene

D Poly vinyl chloride

Q- Which polymer is used in the manufacture of paints and lacquers?

JEE Main 2015

A Bakelite

B Glyptal

C Polypropylene

D Poly vinyl chloride

Solution:

Glyptal is used in manufacture of paints and lacquers.

94
Q- The correct match between Item-I and Item-II is
Item-I Item-II
(a) High density polythene (I) Peroxide catalyst
Condensation at high temperature and
(b) Polyacrylonitrile (II)
pressure
(c) Novalac (III) Ziegler - Natta Catalyst
(d) Nylon 6 (IV) Acid or Base Catalyst

JEE Main 2019

A (a) - (III), (b) - (I), (c) - (IV), (d) - (II)

B (a) - (III), (b) - (I), (c) - (II), (d) - (IV)

C (a) - (IV), (b) - (II), (c) - (I), (d) - (III)

D (a) - (II), (b) - (IV), (c) - (I), (d) - (III)

Q- The correct match between Item-I and Item-II is
Item-I Item-II
(a) High density polythene (I) Peroxide catalyst
Condensation at high temperature and
(b) Polyacrylonitrile (II)
pressure
(c) Novalac (III) Ziegler - Natta Catalyst
(d) Nylon 6 (IV) Acid or Base Catalyst

JEE Main 2019

A (a) - (III), (b) - (I), (c) - (IV), (d) - (II)

B (a) - (III), (b) - (I), (c) - (II), (d) - (IV)

C (a) - (IV), (b) - (II), (c) - (I), (d) - (III)

D (a) - (II), (b) - (IV), (c) - (I), (d) - (III)

Solution:
95

Q- Match List-I with List-II

Choose the correct answer from the options given below:

JEE Main 2021

A (a) - (ii), (b) - (i), (c) - (iv), (d) - (iii)

B (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)

C (a) - (iii), (b) - (i), (c) - (iv), (d) - (ii)

D (a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)

Q- Match List-I with List-II
Choose the correct answer from the options given below:

JEE Main 2021

A (a) - (ii), (b) - (i), (c) - (iv), (d) - (iii)

B (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)

C (a) - (iii), (b) - (i), (c) - (iv), (d) - (ii)

D (a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)

Solution:
96
Q- Match List I with List II:
List I - Polymer List II - Used for items
A. Nylon 6, 6 I. Buckets
B. Low density polyethene II. Non-stick utensils
C. High density polythene III. Bristles of brushes
D. Teflon IV. Toys
Choose the correct answer from the options given below:
JEE Main 2022

A A - III, B - I, C - IV, D - II

B A - III, B - IV, C - I, D - II

C A - II, B - I, C - IV, D - III

D A - II, B - IV, C - I, D - III

Q- Match List I with List II:
List I - Polymer List II - Used for items
A. Nylon 6, 6 I. Buckets
B. Low density polyethene II. Non-stick utensils
C. High density polythene III. Bristles of brushes
D. Teflon IV. Toys
Choose the correct answer from the options given below:
JEE Main 2022

A A - III, B - I, C - IV, D - II

B A - III, B - IV, C - I, D - II

C A - II, B - I, C - IV, D - III

D A - II, B - IV, C - I, D - III

Solution:
97

Q- Caprolactam when heated at high temperature in presence of water, gives

JEE Main 2023

A Teflon

B Decron

C Nylon 6, 6

D Nylon 6
Q- Caprolactam when heated at high temperature in presence of water, gives

JEE Main 2023

A Teflon

B Decron

C Nylon 6, 6

D Nylon 6
Solution:
Drugs
98
Q- The correct match between item (I) and item (II) is

Item-I Item-II

A. Norethindrone P. Anti-biotic

B. Ofloxacin Q. Anti-fertility

C. Equanil R. Hypertension

S. Analgesics JEE Main 2019

A A → R; B → P; C → R

B A → R; B → P; C → S

C A → Q; B → P; C → R

D A → Q; B → R; C → S
Q- The correct match between item (I) and item (II) is

Item-I Item-II

A. Norethindrone P. Anti-biotic

B. Ofloxacin Q. Anti-fertility

C. Equanil R. Hypertension

S. Analgesics JEE Main 2019

A A → R; B → P; C → R

B A → R; B → P; C → S

C A → Q; B → P; C → R

D A → Q; B → R; C → S
Solution:
99
Q- The structure shown below is of which well-known drug molecule?

JEE Main 2022

A Ranitidine

B Seldane

C Cimetidine

D Codeine
Q- The structure shown below is of which well-known drug molecule?

JEE Main 2022

A Ranitidine

B Seldane

C Cimetidine

D Codeine
100
Q- Match List I with List II
List I List II

Antimicrobials Names

A. Narrow spectrum antibiotic I. Furacine

B. Antiseptic II. Sulphur dioxide

C. Disinfectants III. Penicillin-G

D. Broad spectrum antibiotic IV. Chloramphenicol

JEE Main 2019

A A-III, B-I, C-II, D-IV

B A-I, B-II, C-IV, D-III

C A-II, B-I, C-IV, D-III

D A-III, B-I, C-IV, D-II

Q- Match List I with List II
List I List II

Antimicrobials Names

A. Narrow spectrum antibiotic I. Furacine

B. Antiseptic II. Sulphur dioxide

C. Disinfectants III. Penicillin-G

D. Broad spectrum antibiotic IV. Chloramphenicol

JEE Main 2019

A A-III, B-I, C-II, D-IV

B A-I, B-II, C-IV, D-III

C A-II, B-I, C-IV, D-III

D A-III, B-I, C-IV, D-II

Solution:
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