Mock Test-2

Amongst the following, the linear species is :

A N3-

B Cl2O

C O3

D NO2
For the coagulation of a negative sol, the species below, that
has the highest flocculating power is :

A SO42-

B Na+

C Ba2+

D PO43-
Match List-I with List-II
List-I List-II
(a) Haematite (i) Al2O3. xH2O
(b) Bauxite (ii) Fe2O3
(c) Magnetite (iii) CuCO3. Cu(OH)2
(d) Malachite (iv) Fe3O4
Choose the correct answer from the options given below:

A (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)

B (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

C (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)

D (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)

The set that represents the pair of neutral oxides of nitrogen
is:

A NO and N2O

B NO and NO2

C N2O and NO2

D N2O and N2O3

One of the by-products formed during the recovery of NH3
from Solvay process is:

A NaHCO3

B Ca(OH)2

C CaCl2

D NH4Cl
A central atom in a molecule has two lone pairs of electrons
and forms three single bonds. The shape of this molecule is :

A trigonal pyramidal

B T-shaped

C see-saw

D planar triangular
Which of the following compound CANNOT act as a Lewis
base?

A ClF3

B PCl5

C NF3

D SF4
Out of the following, which type of interaction is responsible
for the stabilisation –helix structure of proteins ?

A Ionic bonding

B Hydrogen bonding

C Vander Waals forces

D Covalent bonding
Which one of the following 0.06 M aqueous solutions has
lowest freezing point ?

A Al2(SO4)3

B C6H12O6

C KI

D K2SO4
Sodium stearate CH3(CH2)16COO–Na+ is an anionic surfactant
which forms micelles in oil.
Choose the correct statement for it from the following :

It forms spherical micelles with CH3(CH2)16 – group pointing towards

A
the centre of sphere

B It forms non–spherical micelles with –COO– group pointing outwards

on the surface.

C It forms spherical micelles with CH3(CH2)16 –group pointing outwards

on the surface of sphere

D It forms non–spherical micelles with CH3(CH2)16–group pointing

towards the centre.
At 298.2 K the relationship between enthalpy of bond
dissociation (in kJ mol–1) for hydrogen (EH) and its isotope,
deuterium (ED), is best described by :

A EH =½ ED

B EH = ED

C EH ~ ED -7.5

D EH =2ED
For the following graphs,

Choose from the options given below, the correct

one regarding order of reaction is :

(b) zero order (c) and (e) First

A
order

B (a) and (b) Zero order (e) First

order

C (b) and (d) Zero order (e) First

order

D (a) and (b) Zero order (c) and (e)

First order
Identify products A and B.

D
Which of the following compound gives pink colour on
reaction with phthalic anhydride in conc.H2SO4 followed by
treatment with NaOH ?

D
The product formed in the first step of the reaction of

D
In the following reaction the reason why meta–nitro product
also formed is:

A Formation of anilinium ion

B –NO2 substitution always takes place at meta–position

C low temperature

D –NH2 group is highly meta–directive

Which is the final product (major) ‘A’ in the given reaction?

D
What is the major product formed by HI on reaction with

D
Which of the following reagent is used for the following
reaction ?

A Potassium permanganate

B Molybdenum oxide

C Copper at high temperature and pressure

D Manganese acetate
‘A’ and ‘B’ in the following reactions are :

D
The ionization enthalpy of Na+ formation from Na(g) is 495.8 kJ
mol–1, while the electron gain enthalpy of Br is –325.0 kJ mol–1. Given
the lattice enthalpy of NaBr is –728.4 kJ mol–1. The energy for the
formation of NaBr ionic solid is (–)_____ × 10–1 kJ mol–1.
Consider the following chemical reaction.

The number of sp2 hybridized carbon atom(s) present in the product

is _______.
A car tyre is filled with nitrogen gas at 35 psi at 27°C. It will burst if
pressure exceeds 40 psi. The temperature in °C at which the car tyre
will burst is ______. (Rounded-off to the nearest integer)
Among the following, the number of halide(s) which is/are inert to
hydrolysis is ______.
(A) BF3 (B) SiCl4 (C) PCl5 (D) SF6
1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The
boiling point of the solution at 1 atm is _____ K. (Rounded-off to
the nearest integer)
[Given Kb for (H2O) = 0.52 K kg mol–1]
Solutions
Amongst the following, the linear species is :

A N3-

B Cl2O

C O3

D NO2
Solution :
For the coagulation of a negative sol, the species below, that
has the highest flocculating power is :

A SO42-

B Na+

C Ba2+

D PO43-
Solution :
For a negative sol, positive ion is required for flocculation.
Greater the valency of the flocculating ion added, the greater is
its power to cause precipitation. This is called Hardy-Schulz
law. So, Ba+2 has highest flocculating power.
Match List-I with List-II
List-I List-II
(a) Haematite (i) Al2O3. xH2O
(b) Bauxite (ii) Fe2O3
(c) Magnetite (iii) CuCO3. Cu(OH)2
(d) Malachite (iv) Fe3O4
Choose the correct answer from the options given below:

A (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)

B (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

C (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)

D (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)

The set that represents the pair of neutral oxides of nitrogen
is:

A NO and N2O

B NO and NO2

C N2O and NO2

D N2O and N2O3

Solution : NO and N2O are neutral oxides and N2O3 , NO2 and
N2O5 are acidic oxides.
One of the by-products formed during the recovery of NH3
from Solvay process is:

A NaHCO3

B Ca(OH)2

C CaCl2

D NH4Cl
Solution :
Recovery of NH3
2NH4Cl + Ca(OH)2 ⟶ CaCl2 + 2NH3 + 2H2O
byproduct
A central atom in a molecule has two lone pairs of electrons
and forms three single bonds. The shape of this molecule is :

A trigonal pyramidal

B T-shaped

C see-saw

D planar triangular
Which of the following compound CANNOT act as a Lewis
base?

A ClF3

B PCl5

C NF3

D SF4
Solution :
NF3 has no vacant orbital neither in nitrogen nor in fluorine so
it cannot accept the electron & hence cannot acts as lewis acid
and but for PCl5 ,P has no L.P & hence it cannot acts as base but
ClF3 (3 B.P + 2 L.P) & SF4 (4 B.P +1 L.P)
Out of the following, which type of interaction is responsible
for the stabilisation –helix structure of proteins ?

A Ionic bonding

B Hydrogen bonding

C Vander Waals forces

D Covalent bonding
Solution: The 𝝰-helix is stabilized by hydrogen bond between
the NH and CO group of the main chain.
Which one of the following 0.06 M aqueous solutions has
lowest freezing point ?

A Al2(SO4)3

B C6H12O6

C KI

D K2SO4
Solution :
Sodium stearate CH3(CH2)16COO–Na+ is an anionic surfactant
which forms micelles in oil.
Choose the correct statement for it from the following :

It forms spherical micelles with CH3(CH2)16 – group pointing towards

A
the centre of sphere

B It forms non–spherical micelles with –COO– group pointing outwards

on the surface.

C It forms spherical micelles with CH3(CH2)16 –group pointing outwards

on the surface of sphere

D It forms non–spherical micelles with CH3(CH2)16–group pointing

towards the centre.
Solution :
Forms spherical micelles with CH3(CH2)16 group
pointing towards the centre of sphere
At 298.2 K the relationship between enthalpy of bond
dissociation (in kJ mol–1) for hydrogen (EH) and its isotope,
deuterium (ED), is best described by :

A EH =½ ED

B EH = ED

C EH ~ ED -7.5

D EH =2ED
Solution :
Enthalpy of bond dissociation (kJ/mole) at 298.2K
For , hydrogen = 435.88
For , Deuterium = 443.35
∴EH ~ ED – 7.5
For the following graphs,

Choose from the options given below, the correct

one regarding order of reaction is :

(b) zero order (c) and (e) First

A
order

B (a) and (b) Zero order (e) First

order

C (b) and (d) Zero order (e) First

order

D (a) and (b) Zero order (c) and (e)

First order
Solution :
Identify products A and B.

D
Solution:
Which of the following compound gives pink colour on
reaction with phthalic anhydride in conc.H2SO4 followed by
treatment with NaOH ?

D
Solution:
The product formed in the first step of the reaction of

D
Solution:
In the following reaction the reason why meta–nitro product
also formed is:

A Formation of anilinium ion

B –NO2 substitution always takes place at meta–position

C low temperature

D –NH2 group is highly meta–directive

Solution:

In acidic medium the –NH2 group in aniline converts into

anilinium ion which is meta directing.
Which is the final product (major) ‘A’ in the given reaction?

D
Solution:
What is the major product formed by HI on reaction with

D
Solution:
Which of the following reagent is used for the following
reaction ?

A Potassium permanganate

B Molybdenum oxide

C Copper at high temperature and pressure

D Manganese acetate
Solution:
‘A’ and ‘B’ in the following reactions are :

D
Solution:
The ionization enthalpy of Na+ formation from Na(g) is 495.8 kJ
mol–1, while the electron gain enthalpy of Br is –325.0 kJ mol–1. Given
the lattice enthalpy of NaBr is –728.4 kJ mol–1. The energy for the
formation of NaBr ionic solid is (–)_____ × 10–1 kJ mol–1.

Answer: 5576 kJ
Solution:
Consider the following chemical reaction.

The number of sp2 hybridized carbon atom(s) present in the product

is _______.

Answer: 7
Solution:

All carbon atoms in benzaldehyde are sp2 hybridised

A car tyre is filled with nitrogen gas at 35 psi at 27°C. It will burst if
pressure exceeds 40 psi. The temperature in °C at which the car tyre
will burst is ______. (Rounded-off to the nearest integer)

Answer: 69.85°C ≃ 70°C

Solution:
Among the following, the number of halide(s) which is/are inert to
hydrolysis is ______.
(A) BF3 (B) SiCl4 (C) PCl5 (D) SF6

Answer: 1
Solution: Due to crowding SF6 is not hydrolysed.
1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The
boiling point of the solution at 1 atm is _____ K. (Rounded-off to
the nearest integer)
[Given Kb for (H2O) = 0.52 K kg mol–1]

Answer: 375 K
Solution:
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