pALHOC QUOC GIA HA NOI DE THI HQC KY TRUONG DALHOC KHOA HOCTY NHIEN NAM HOC 2015 - 2016 MON THI: HOA HOC PHAN TiCH S6 tin chi: 3 peso1 Mé6n hoc: CHE 1057 Thoi gian lam bai: 90 phi (khong ké thoi gian phat dé) eee (Cu I: C6 50 ml dung dich CHyCOOH 0,1M (pK njcooy =4.75)- a. Tinh pH cia dung dich axit trén. b. Néu thém vao dung djch trén 30,0; 50,0; 55,0 mL dung dich NaOH 0,1 dung dich bing bao nhiéu? C4u Ti: Tinh 49 tan cia két tia AgBr trong dung dich NH; 2.10°M. Cée p Ag(NH3):" ¢6 cdc hiing s6 bén lan Iugt 14 10°77 ya 10°, tich s6 tan ciia’ (CAu IM: Chun 49 25 mL dung dich Fe** 0,1M ¢6 pH =0 bing a. Tinh thé cla dung dich sau khi thém 20,0; 25,0 va 30,0 mL. b. Néu két thiic chudn 49 khi dur 2 giot dung dich KMnO, dung dich lac 46 bing bao nhiéu? Cho: Bip =0,68V3 Bo vengn =1,51V. Cu IV: Dé xéc dinh him lugng Co trong miu diu Cain 5,00 g dau thé dem xit ly theo phuong pl tich 500 mL. (dung dich A). Lay 20,0 mL dung d 46 hap thy quang & bude séng 400 nm duge gid 1 khdc, thém 5,0 mL dung dich chuin Co(II) 2.10% do duge 46 hap thy quang & bude song ‘PAI HQC QUOC GIA HA NOL bE THI : PU KHOAHQCIY NIN KET THUCHOCKY 11, NAM HOC 2012. 2013 MON THI: HOA PHAN TicH $6 tin chi: 3 MA mon hoc: CHE 1057 DESOL Thoi gian lam bal: 90 phuit (khong. ké thoi gian phat dé) Ci 1 2 diém). Chudn 49 25,00 mi dung dich HPO, 0,100M bing dung dich NaOH 100M. Tinh pH cia dung djch tai cée thivi diém thém Veson la: 10,00ml; 25,00 mi va 40,00 ml. Cho biét HsPQ, €6 pK; = 2,12; pK = 7,21; pK3 = 12,36 (Cau 2 (3 diém). Tinh ndng dd cin bing cia ion Pb** trong dung dich khi thém 22,13 mi EDTA 0,02527 M vao 20,00 mi dung dich Pb** 0,02500M_cé pH= 8. Biét hing sé bén phite Pb** voi EDTA a 10! ; Axit HyY 06 pK\= 2,0; pK> = 2,67; pK3 = 6,27; pK. = 10,95, Chiu 3 (2 aiém), Thém 45,00 ml dung dich KCN 1M vao Sml dung dich Cus** 0,01M aé wo phite hoan toan Cu(CN),* thu duge dung dich A. Thém vio dung dich A 50,00 ml dung dich Na;S 2M va khudy déu, Hoi Déng (1) sunfua cé két tia khong, Chimg minh» bling céich tinh. Cho biét Cu(CN),” ¢6 B,.« = 10°; Cus$ 06 T=2,5.10 HaS 6 pKys=7 ; pKa=13 Cau 4 (3 diém) ee) ecg picanbe mio cx ngudi ta can 9 Oe ere ike een Phin hily 8:0,” du. Bé ngudi dung dich dén nhigt 4) phong vi pha pee tS ue tome ioe de Ly 25 ml dung dich A oe aie! on Ei die isa FC 0S dich duge gach chin wrong gui tinh b = b- Gia thiét phan img chudn 46 xiy ra voi hing 96 can bang rit ton. Hay tinh the vin dung dich tai diém trong dvons © Chi thj dipheny! amin co miu tim @ dang oxi hoa va dyng Khir khong miu. 1% cho biét maw sic dung dich thay 461 thé nao trong qué trinh chudn 49 Fe” bing KxC107, d- Tinh him lwong % ci Cr” trong mau mudi noi trén. Cho Me 52 g/mol.pb THI KET THUC HOC KIT pAI HQC QUOC GIA HAN pRUONG DH KHOA HOC TY NHIEN NAM HQC 2020-2021 MON THE CO SO HOA HOC PHAN TICH Sé-tin chi: 3 Mn hoe: CHE 1082 pe sot "anh cho cdc lép sinh vien A, B, Dvd S- khoa Héa hoe ‘moi gian tam Boi 90 phe (RhOng ké thoi gian phat de) Dé thi gm 04 trang (Sinh vidn khong sie dung tai lieu khi tam bai) 2 gui trinh phan tich mot i twong thuc té. hank va tré loi ede edu hot bai déu c6 lién quan ¢ van tich (t6m tat) ma ky thudt vien da ti tron oc trinh Jing tin tra citu d sit dung cdc cong thntc tinh rit gon nhung cdin ghi rb diéu kién dé dp dung. Chit §: Cae cai Sink vin di kbm. Th weg cho & trang 1-2. -sV = Clic edu tra Idi C6/ Khong, Biing/ Sai hodic chi ghi dap 36 sé khong dieoe chm diém © Corndng d6 ban daw cia ede cht phan tich trong mau phan tich Id mong do xde dinh Shuce theo gui trinh phan tich Thé tich dung dich tam dteoe cot I tng the tich ede chat long dem trén. - Cae gid tri lién quan dén néng d6/ ham lirong etia chét phan tich trong mdu phan tich phii duge viét ding sé c6 nghia BANG TRA CUU CAC HANG SO VA PHY LUC 1. Khéi hrgng mol nguyén tir, phan ti: (CsHsCOOH: 122,12 g/mol, ZnO 81,38 g/mol ; 1: 126,9 g/mol |. Hing sé phan ly axit CcHsCOOH €6 pKs= 4,21 EDTA (HeY) c6 pKat = 2.005 pK: 2,69; pKas = 6,13; pKat = 10,37 aiye- tai pH= 514 3,5.107 Voi Be te VW ( —— ery ie K,K,K,K,, } 3. Chi thj mau: Chét chi thi Axite Bazo_Khodng pH ‘Mau dang bazo Bromophenol xanh 0. Xanh Cresol do 6 Methyl da eam "4 Methyl 46 a Phenol 46 we 6 Phenolphthal Thymolphi Doim foai: xy lenol da cam to phite mau 46 tim voi Zn? 6 dang ty do, Khi ni co mau vang; trong khoang pH ti: 6.47104 chi thj 6 mau a0 - da cam _ caren man eNom" peo) eer 4g Hing sn cia pte ed 5, Thé oxi hoa khir tiéu chuan pe ,08V 5 Bray, Bshos- /, 032 uae 6, Cong thie ‘cAu tgo chat hiru cova pKa = 0,54 V; E°10s/= 1.2 V- oH HO, Ly Rebaudioside A pKa= 11,75 Stevieside pka= 12,5 Cau 1 (2,5 4): Acid benzoic duge ding lam chat bao quan thye phim, chéng vi sinh vat, nam méc véi him long cho phép ti 0,05-0,1% trong thyc phim, Ham lwgng axit benzoic (CaFsCOOH) trong mau nguyen 1igu ding lam phy gia the phim duge xée dinh theo qui trinh sau: Can 1,3655 g mu thie da durge tam khO, hoa tan trong 15 ml etano! tric). Thém tiép 20 ml medic edi va chudn do bang ding dich nat} biglroxit 0,5036 M voi chi th la phenolphihalein dén kh dung dich 6 mau hong, née 21,10 ml. a) Tinh him lugng (2%) acid benzoic trong miu nguyén ligu (0,5 4). ») Tinh pH gin ding cla dung dich tai diém tong duong? (0.5 4). c) Tinh pH cia dung dich chuan 46 khi thém 99.9% va 100,1% hong NaOH can cho phin ting, tir d6 chon 1 chi thi khée phu hgp, thay henolphtalein va cho biét su di mau efa dung dich trong qué trinh chudn 46 khi ding chi thi nay. (1,54) Cau 2 (2,54): Hd mi nhiém khudn da, e6 (da duge trung hoa Dé xdc dinh the SO ml dung dich He rite dén vach bai< v 2 a $ F a 3 @ - Vai tré cia e6t sac ky 1a gi? Cot C18 chtta pha tinh phan cure hay khong phan eye? - Tai pH=3 chét 6 dang axit hay bazo? Nhém chire nao quyét inh tinh axit/ bazo? Detector phat hign chat phin tich dya trén qué trinh hap thy hay phat xa hay huynh quang? Chat cho tin higu tai detector 6 dang nguyen ti hay bin we? Pic ho dau tién trén sic 46 1a theo phuong phap dudng svioside va rebaudioside A). X ; trong dé y la dién tich side va Rebandioside AZ pH=5, mot it chdt chi 10 ml dung dich dém axit axetic/ axetat . déi mau dich A, them 10m e , pit aw ee si hun a6 bing dng ach chutn EDTA 0,02135 ‘Medén khi chi thi wee er, ra trong binh chuan d6 khi c6 chi thi xylenol da cam. Mau cia gidi thich sw chuyén mau 46. (0,54) anh hudng khéng dng phure Zn™* va Care ub a. viet cfc dung dich thay p, Hay gidi thich tai pH phan img xay 0 Khi gi thé nao trong qué trinh chuan 49, '=5, Zn? da phan tng hét voi EDTA, Ca” é dén phép xae dink kém (théng qua tinh hing sé bén diéu kign chia WiBDTA) va chi thi d6i mau x6 rét hom Ki chun d0 6 pH cao. (1,04) ¢, Tinh ham hrgng (%) ZnO trong hd nusc. (1,0 4) a Gar > Ham lung iot trong mau Ciu 3 (2,54): Mot mau b6t canh duge bé sung jofdudi di bot canh iod durge xéc dinh theo TCVN 6487: 1999 nhu sa Cén 10,020 ¢ mau b6t canh i6t vao cdc dung tich 100 mi, hoa tan bang 30. ml nude cat va dung tich 250 ml. Cho 5 ml dung dich KI lée cho tan hét mau. Loc ldy nude loc vao binh nén 16%, Lal dung dich H:SO. 10% vao dung dich trén, lie déu, déy binh bang nap kinh déng hé va dé yen khodng 5 philt, dung dich eé mau vang dam. Chuan a6 dung dich mau bang dung dich ‘hud NayS.0; 0,01377 M cho dén khi dung dich cd mau vang nist. Thém Iml dung dich ho tinh bot tiép tue chudn a6 cho dén khi dung dich mdt mau xanh hét 2,24 ml. a) Viét va giai thich vi sao ca shan ting xay ra durge trong qua trinh chuan d6 (1,04) ling gdp d0i luong da cho thi gay sai so thé na ©) Tinh ham luong iot (ppm) trong mau bot canh ban dau (1,04). Céu 4 (2,5 d): Rebaudioside A va Stevioside (¢6 vi nggt cao gp 150-280 lan saccharose) trong, cdy c6 ngot durge xde dinh dong théi bang phuong php HPLC/UV theo qui trinh sau: Cin 1,0568 gam méu b6t Id cd ngot kh vao binh nén, them 20ml nude cdt, lac aéu, dun ciich thuiy trong 30 philt. Chiét lap lai Tan hai nlc trén va g6p dich loc vao dinh mirc 50 ml, them nubc cét dén vach mite. Loc dung dich qua dau loc xy lanh réi bom vao hé HPLC/UV véi dieu sas OH kign nue sau: nitril (82:32; v/v),; Toc a6 dong pha