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M =0.

1 M NaOH
V =500mL=0.5 L
Used 0.35 g KHP
NaOH MW =39.997 g /mol
KHP MW =204.22 g /mol
moles of solute
Molarity=
Litre of Solution
NaOH Standardization
mol 39.997 g NaOH
0.1 NaOH ×0.5 L × =1.99985 g NaOH 2 g NaOH
L 1 mol NaOH

KHP Solution
- 0.35g KHP
- 75ml Distilled Initial burette reading Final burette reading
mL, NaOH consumed
water (ml) (ml)
- 5 drops of
phenolphthalein
1 Trial (25ml)
st
0 6.8 6.8 Purple
2nd Trial (25ml) 6.8 14.2 7.4 Purple
3rd Trial (25ml) 14.2 19.75 5.55 Light Pink

NaOH + KHP → NaKP + H 2 O(1 :1)


1 mol KHP 1 mol NaOH mol NaOH
weighed KHP ( g ) × × =
204.22 g KHP 1mol KHP L NaOH (dispensed)
−6
1mol KHP 1 mol NaOH 9.51× 10 mol NaOH
0.35 g KHP × × =
204.22 g KHP 1mol KHP 0.00555 L NaOH ( dispensed)
Titration

Methyl Orange Phenolphthalein indicator


Initial Final Final
Sample Details mL, mL,
burette burette Initial burette burette
Source/Volume NaOH NaOH
reading reading reading (ml) reading
consumed consumed
(ml) (ml) (ml)
Surface Water 0 22.9 22.9 2.3 2.9 0.6
(100ml)
Tap Water 22.9 22.9 0 3.4 3.5 0.1
(100ml)
Mineral Water 22.9 22.9 0 3.5 3.6 0.1
(100ml)

Methyl Orange Phenolphthalein indicator


Initial Final No. of drops Initial Final No. of drops of
Sample Details mL, mL,
burette burette of Methyl burette burette Phenolphthalein
Source/Volume NaOH NaOH
reading reading Orange readin reading
consumed consumed
(ml) (ml) g (ml) (ml)
Surface Water 0 22.9 22.9 More than 7 2.3 2.9 0.6 5
(100ml)
Tap Water 22.9 22.9 0 3 3.4 3.5 0.1 5
(100ml)
Mineral Water 22.9 22.9 0 3 3.5 3.6 0.1 5
(100ml)

C sample V sample =C NaOH V NaOH

C NaOH V NaOH
C sample =
V sample
Sample computation

Phenolphthalein
Initial Final No. of drops of
mL,
Sample Details burette burette Phenolphthalein
NaOH
Source/Volume reading reading
consumed
(ml) (ml)
Surface Water 2.3 2.9 0.6 5
(100ml)

( 9.51 ×10−6 mol NaOH ) (0.0006 L NaOH )


C surface water=
0.1 L Surface Water
−8
C surface water=5.706 ×10
−6
C NaOH =9.51× 10 mol NaOH=computed ¿ standardization
V NaOH =0.6 mL=.0006 L=NaOH consumed

V sample =100 mL=0.1 L

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