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486 1 Spring07
486 1 Spring07
Lecture 1
Lecture 1
z Schrödinger’s equation (SEQ)
Momentum
• The properties of complex quantities z Homework – You’ll get an assignment almost every
Tuesday, which will be due the following Tuesday. Late
• Multivariable calculus and elementary differential equations homework will be accepted the following week for ½
credit, and no Homework will be accepted more than 2
weeks after it is handed out. HW is an important part of
the course, which is why it is worth 45% of your grade!
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Physics 486
Lecture 1
z However, around 1900, several phenomena exposed flaws • Early potters estimated the temperatures
in the wave description of light: of their kilns by noting the color of the fire
z Blackbody radiation
z Photoelectric effect • Steelmakers estimate the temperature of
molten steel by noting its color
z Compton scattering
z Bremsstrahlung radiation
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Physics 486
Lecture 1
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Physics 486
Lecture 1
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Physics 486
Lecture 1
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Physics 486
Lecture 1
Pn = Ce − En / kT ∑e
n =0
− nε / kT
=Z = ∑x
n=0
n
= 1 + x + x 2 + x 3 + ... (where x=e-ε/kT)
∑P n =1
So: Z = 1 + xZ ⇒ Z = ∑ e − nε / kT =
1
=
1
1 − x 1-e-ε /kT
n =0
n =0
Therefore, C = 1
and
e − nε / kT
∞
Pn = e − nε / kT / ∑ e− nε / kT Therefore, the probability that Pn =
∑e (1 − e )
− nε / kT −1
the nth energy level of an − ε / kT
n =0 oscillator will be populated is:
(1 − e ) (where x=e-ε/kT)
− ε / kT −1
3ε
ε = hf n=0 n =0
2ε
ε
We can now calculate average (or ‘expectation’) ∞
1 E n = nε
values of a number of quantities
0 Recall also that: Z = ∑ xn =
n =0 1− x 4ε
How do we define an expectation value? Recall that ∞
E = ∑ En Pn = ∑ nhfP = n=0
( )
n −1
n =0 n=0 1 − e − hf / kT
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Physics 486
Lecture 1
hfe − hf / kT hf high frequencies (low wavelengths), even though many modes are
So that: E = n =0
= = possible (i.e., it’s easier to stuff the short waves into the cavity),
(1 − e − hf / kT
)
−1
(1 − e − hf / kT
) e hf / kT − 1 not many are excited because it costs too much energy to make a
high frequency quantum, i.e., E = hf!
Finally, if we multiply this average 8π f 2 (Remember this?
energy per state times the = Summarizing the classical and quantum mechanical results:
We derived it
density of states per energy: c3 # of modes per unit
earlier!) frequency per unit
average energy per average energy
mode density
volume
classical 8π f 2
8π f 2
kT kT
We get the famous Planck’s 8π hf 3 1 c3 c3
radiation law for the energy density u ( f ,T ) =
c 3 e hf / kT − 1 8π hf 3
of blackbody radiation: quantum 8π f 2 hf 1
c3 ehf / kT − 1 c 3 e hf / kT − 1
∂u ( λ , T ) 8π hc hc ehc / λ kT
= (
−5 1 − e − hc / λ kT + )
=0 Now, let x=hf/kT. Then df=(kT/h)dx, and f3=(kTx/h)3
∂λ 5
λ λ kT ehc / λ kT − 1 ( )
∞ 4 ∞
a 8π h kT
⇒
λ
(
= 5 1 − ea / λ ) where a = hc/kT So one can write: U (T ) = ∫ u ( f , T ) df =
c3 h
∫e
x3
x
−1
dx
0 0
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Physics 486
Lecture 1
4 4
8π h kT π 4 8π h kT π 4
U (T ) = = aT
4
T U (T ) = = aT
4
T
c3 h 15 c3 h 15
earth 4 c h 15
frequency
1014 Hz 1015 Hz
where σ = 5.67 x 10-8 W m-2 K-4 is the Stefan-Boltzmann constant
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Physics 486
Lecture 1
later Philipp Lenard, found that if one effect is observed. This was a real
shines light on a clean metal surface, Collector problem for the classical description! Collector
electrons will emerge (remember this in
Phys 214?). This was dubbed the A 3.5 A
photoelectric effect.
3
V V
2.5
Vstop (v)
2 h/e
electrons electrons
+ 1.5
+
1
f0 1
Metal Surface 0.5 Metal Surface
vacuum 0 vacuum
0 5 10 15
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Physics 486
Lecture 1
in the photoelectric effect could be understood 3 When light of wavelength λ = 400 nm shines on a piece of lithium, the
if one assumes that the incident light consists 2.5
stopping voltage of the electrons is Vstop = 0.21 V. What is the work
h/e
of quantized “packets” of energy – called
2
function of lithium?
Vstop
1.5
(v)
photons – which have an energy: 1
f0 1
0.5
0
Solution:
Ephoton = hf = hc/λ I won the Nobel
Prize in 1921 for
0 5 10 15
h/e z
photoelectrons with maximum energies
2
Compton also showed that x- Pi, Ei
8.57 eV and 6.67 eV, respectively.
1.5
ray photons collide elastically θ
Obtain an estimate of Planck’s constant
1
f0 1 with electrons, in the same way
from this simple observation.
0.5
K 2 − K 2 = hc ( λ2 − λ1 ) / ( λ1λ2 ) K − K 2 λ1λ2
h= 1 λf – λi = λC(1 – cosθ)
c λ2 − λ1
where λC = h/mec is the “Compton” wavelength of the electron
h=
( 8.57 − 6.67eV ) ×1.6 ×10−19 J / eV ( 280 ×10 m )( 490 ×10 m )
−9 −9
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Physics 486
Lecture 1
p = h/λ h is Planck’s constant; Compton scattering of particles by light contributes to comet’s tail:
λ is the wavelength of light
light (radiation)
‘pressure’ from sun
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Physics 486
Lecture 1
hf = K init − K final
z The corresponding photon wavelength is therefore given by:
hc
= K init − K final
λ
z The smallest possible wavelength x-ray photon that can be observed is
emitted when an electron loses ALL of its kinetic energy in the
deceleration process (Kfinal = 0): hc
= K init = eVo
λmin
z Where eVo is the energy acquired by the electron when accelerated
through a potential difference Vo. So, the minimum wavelength is:
λmin = hc eV
o
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