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    The document provides 10 heterocyclic compounds and asks to provide simple forward syntheses for each in 3 sentences or less. 1. Compound 1 could be synthesized from o-phenylenediamine and chloroacetic acid followed by reaction with methyl iodide. 2. Compound 2 could be made by reacting ethyl isothiocyanate with 2,4-diaminopyrimidine followed by carboxylic acid formation. 3. Compound 3 involves reacting methylhydrazine with 1,2-dichloroethane followed by cyclization with another equivalent of methylhydrazine.

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    Problem Set 2 Copy

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    The document provides 10 heterocyclic compounds and asks to provide simple forward syntheses for each in 3 sentences or less. 1. Compound 1 could be synthesized from o-phenylenediamine and chloroacetic acid followed by reaction with methyl iodide. 2. Compound 2 could be made by reacting ethyl isothiocyanate with 2,4-diaminopyrimidine followed by carboxylic acid formation. 3. Compound 3 involves reacting methylhydrazine with 1,2-dichloroethane followed by cyclization with another equivalent of methylhydrazine.

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    © All Rights Reserved
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    11 views1 page

    Heterocyclic Chemistry Problem Set Syntheses

    Uploaded by

    a
    The document provides 10 heterocyclic compounds and asks to provide simple forward syntheses for each in 3 sentences or less. 1. Compound 1 could be synthesized from o-phenylenediamine and chloroacetic acid followed by reaction with methyl iodide. 2. Compound 2 could be made by reacting ethyl isothiocyanate with 2,4-diaminopyrimidine followed by carboxylic acid formation. 3. Compound 3 involves reacting methylhydrazine with 1,2-dichloroethane followed by cyclization with another equivalent of methylhydrazine.

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    Heterocyclic Chemistry

    Baran Problem Set #2 2019


    Provide simple forward syntheses for the following compounds. SMe
    (10 points each) 6 HN
    NH
    N
    N N N
    1 Me H H
    O2N O N Cl

    N
    HO Me
    N
    Cl S
    HO O Me
    7
    O
    O

    2 O
    CO2H
    Et
    N
    S N N
    Et
    8 H
    O N

    N
    S
    3 N N N N
    Me
    N O NH2
    N Cl
    Me

    N
    Me 9 Ph
    O N
    N OH
    HN
    4 F
    N N F N
    HO N
    N N N
    NH
    F
    O

    O H 10
    5 Ph O N N S
    Ph N
    N
    EtO2C N N
    N
    N N N N
    Ph Me Br
    H N N
    N N
    Ph Ph

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