IUPAC Nomenclature (DPP)

Introduction, Classification, common name, homologous series

1) General formula of paraffin is
1) Cn H2n 2) Cn H2n-2 3) Cn H2n + 2 4) C2n H2n

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2) Cyoloalkane has the formula
1) Cn H2n + 2 2) Cn H2n-2
3) Cn H2n 4) C2n H2

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3) The number of π bonds and 𝜎 bonds in the structure
respectively are:

a) 8, 5 2) 8, 6 3) 3, 8 4) 5, 13

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4) The hybrid state of C-atoms which are attached to a single bond with each
other in the following structure are: CH2 = CH – C ≡ CH
1) sp2, sp 2) sp3, sp 3) sp2, sp2 4) sp2, sp3

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5) The geometry of the compound is- CH2 = CH – CH = CH2
1) Tetrahedral 2) Linear
3) Planar 4) pyramidal

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6) Molecular formula C4H8O2 represent
1) An acid only 2) An ester only
3) An alcohol only 4) An acid and an ester also

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7) The number of olefinic bonds in the given compound is/are
CH2 = CH – C – CH = CH – C ≡ N

O
1) 2 2) 3 3) 1 4) 1

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8) The number of acetylinilic bonds in the given compound is/are
HC ≡ C – C – CH = CH – C ≡ N

O
1) 2 2) 3 3) 1 4) 4

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9) The number of hetroatoms present in the following compound is/are:

1) 2 2) 3 3) 1 4) 4

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10) Which of the following have only 2o H-atom:

Correct code is:

a) a and b b) a, b and d
c) a, c and d d) a, b, c and d

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11) Which of the following are tertiary radicals
CH3

1) CH3 – C - 2) CH3 – CH –

CH3 CH3

CH3 CH3

3) CH3 – C – C2H5 4) CH3 – C – CH2 –

CH3
1) a and b 2) b and c c) a and c d) b and d

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12) Which of the following compound has sp-hybridised carbon atom:-
a) CH3COOH b) CH3COCH3
c) CH3CH2CN d) CH2 = CH – CH = CH2

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13) Which of the following homologous series has incorrect general formula
1) Alkyne – Cn H2n – 2 2) Alkanol – Cn H2n + 2O
3) Alkanal – Cn H2n + 1O 4) Carboxylic acid – Cn H2n O2

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14) Which of the following is gem- dihalide
Cl

1) CH2 – C – CH3 2) CH3 – CH – CH2

Cl Br Cl

3) CH2 – CH – CH3 4) CH2 – CH – CH3

Cl Cl Br Br

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15) Which of the following organic compounds is prepared from inorganic
compound in first time in lab
1) CH ≡ CH 2) CH3COOH
3) NH2 – C – NH2 4) CH4

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16) IUPAC name of the (CH3) 2 CHCH (CH3) is
1) 1, 1, 2, 3- tetramethylethane
2) 1, 2- di-isopropyethane
3) 2, 3- dimethylbutane
4) 2, 3, 3- trimethylbutane

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17) The IUPAC name of CH3C ≡ CCH (CH3)2 is
1) 4-methyl – 2 – pentyne
2) 4, 4-dimethyl-2-butne
3) Methyl isopropyl acetylene
4) 2-methyl-4-pentyne

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18) 2-methyl-2-butene will be represented as
1) CH3 – CH – CH2 – CH3

CH3
2) CH3 – C = CH – CH3

CH3
CH3

3) CH3 – CH2 – C = CH2

4) CH3 – CH – CH = CH2

CH3
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19) The IUPAC name of the following compounds is
CH3 – CH – CH2 CH2 CH3

CH(CH3)2
1) 2- isopropylpentane
2) 2, 3-dimethylhexane
3) Isononane
4) 2, 4-dimethylhexane

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20) Which is correct IUPAC name of the following compounds
CH3 CH3

CH3 – CH – CH – CH – CH3

CH2 – CH3
1) 3-isopropyl-2-methylpentane
2) 3-ethyl-2, 4-dimethylpentane
3) 2, 4-dimethyl-3-ethylpentane
4) 3-isopropyl-4-methylpentane

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 H C4H9

21) IUPAC name of CH3 – C – C – CH3 is

C2H5 CH3
1) 2-butyl -2-methyl-3-ethylbutane
2) 2-ethyl-3, 3-dimethylheptane
3) 3, 4, 4-trimethylheptane
4) 3, 4, 4-trimethylloctane

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22) IUPAC name of the compound CH3 – CH2 – CH2 – C (CH3)2 – CH3
1) 1, 1-dimethyl pentane
2) 2, 2-dimethyl pentane
3) 1, 2-dimethyl pentane
4) None of these

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23) The correct IUPAC name of H2C = CH – CH – CH2C ≡ CH

CH3
1) 3-methyl-1-hexen-5-yne
2) 4-methyl – hexen -1-yen
3) 4 – (ethenyl) - 1- pentyne
4) 3-(2-propenyl) butane-1

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24) The IUPAC name of CH3 C ≡ CCH (CH3)2 is
1) 4 methyl-2-pentyne
2) 4, 4-dimethyl-2-butyne
3) Methyl isopropyl acetylene
4) 2-methyl-4-pentyne

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25) IUPAC name of CH2 = CH – CH (CH3 CH2) C = CH2 is……

Br
1) 4-bromo-3-ethyl-1, 4-pentadiene
2) 2-bromo-3-ethyl-1, 4-pentadiene
3) 2-bromo-3-ethyl-1, 5-pentadiene
4) None of these

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26) What will be the IUPAC name of the given compound
CH3 CH2 – CH3

CH3 - CH – CH – CH2 –CH – CH3

CH2 – CH3
1) 2, 5-diethyl – 4 – methylexane
2) 3, 4, 6 – trimethyloctane
3) 2, 5, 6 – trimethyloctane
4) 3, 5 – dimethyl -6-ehtylhetane

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27) IUPAC name of given compound
H3C – C = CH – CH – CH3

Cl CH3
1) 2-chloro-4-methyl-2-pentane
2) 4-chloro-2-methyl-3-pentane
3) 4-methyl-2-chloro-2-pentane
4) 2-chloro-4, 4-dimethyl-2-butane

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28) The IUPAC name of the structure is

1) 2, 4, 5-Triethyl-3-nonene
2) 5, 6-Diethyl-2-methyl-4-decene
3) 2, 4, 5-Triethyl-3-octane
4) 3-Ethyl-5-methyl-3-heptane

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29) The IUPAC of is:
1) 2, 3-Dimethyl hexane
2) 2-Ethyl-4-methyl pentane
3) 3-Ethyl-2-methyl pentane
4) 2, 4-Dimethyl hexane

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30) CH3 – CH = CH – C ≡ CH has IUPAC name:
1) pent-2-ene-4-yne
2) pent-4-ene-2-yne
3) pent-3-ene-1-yne
4) pent-3-ene-1-yne

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Naming of mono functional group
31) The systematic name of CH3 – CHBr – CH2OH is
1) 3-hydroxy-2-bromopropane
2) 2-bromopropanol
3) 2-bromo-3-propanol
4) 3-hydroxy isopropyl bromide

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32) IUPAC name of acetyl salicylic acid is
1) m-benzoic acid 2) 2-acetoxy benzoic acid
3) p-benzoic acid 4) p-acetyl benzoic acid

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33) IUPAC name of CH3CHO is
1) Acetaldehyde 2) Methyl aldehyde
3) Ethanol 4) Ethanal

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34) IUPAC name of CH3 – O – C2H5 is
1) Ethoxymethane 2) Methyl aldehyde
3) Methylethyl ether 4) Ethylmethyl ether

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35) IUPAC name of the compound
CH3 – CH – CH2 – CH (OH) – CH3 is

CH2

CH3
1) 4-ethyl-2-pentanol 2) 4-methyl-2-hexanol
3) 2-ethyl-2-pentanol 4) 3-methyl-2-hexanol

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36) The IUPAC name of CH3 ≡ N is
1) Acetonitrile 2) Ethanenitrile
3) Methyl cyanide 4) Cyanoethane

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37) The IUPAC name of CH3 CH2 COCH2 CH3 is
1) 3-pentanone 2) 2-pentanone
3) Diethyl ketone 4) All the above

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38) The IUPAC name of CH3COOC2 H5 will be
1) Ethyl acetate 2) Ethyl ethanoate
3) Methyl propanoate 3) None of these

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39) IUPAC name of CH3 – CH2 – CH – NH2 is

CH3
1) 1-methyl-1-aminopropane
2) 2-butanamine
3) 2-methyl-3-aminopropane
4) None of the above

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40) The IUPAC of CH3 CH (CH3) COOH is
1) Dimethyl acetic acid
2) 2-methyl propanoic acid
3) Propanoic acid
4) Butyric acid

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41) IUPAC name of CH3 – CH – CHO is

CH2CH3
1) Butan-2-aldehyde
2) 2-methylbutanal
3) 3-methyl isobutyraldehyde
4) 2-ethylpropanal

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42) What is the correct IUPAC name for
H O

CH3 – C – CH = CH – CH2 – C – OH

CH3
1) 5-methyl-3-hexenoic acid
2) 5-carboxyl-2-methylpentane
3) 4-isopropyl-3-butenoic acid
4) None of above

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43) Which is the correct structure of the compound 3-hexyn-1-oic acid
1) CH3 – CH2 – CH2 – C ≡ C – COOH
2) CH3 – CH2 – C ≡ C – CH2 – COOH
3) CH3 – C ≡ C – CH2 – CH2 – COOH
4) CH3 – CH2 – CH = CH – CH2 – COOH

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44) The IUPAC name of crotonaldehyde is
1) Prop-2-ene-1-al 2) Propenal
3) But-2-ene-1-al 4) Butenal

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45) Write the IUPAC of
H Br

CH3 – C – CH2 – CH2 – CH2 – C – CH3

OH Br
1) 6, 6-dibromohptane-2-ol
2) 2, 2-dibromohptane-6-ol
3) 6, 6-dibromohptane-3-ol
4) None of these

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46) The IUPAC name of
OH OH

CH3 – C – CH2 – CH – CH3 is

CH3
1) 4-methyl-2, 4, pentanediol
2) 1, 1-dimethyl 1, 1, 3 butanediol
3) 2-methyl-2, 4 pentanediol
4) 1, 2, 3-trimethyl-1, 3 propanediol

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47) The IUPAC name of the compound
CH3 – C = CH2 CH2 OH is

CH2
1) 2-methyl-2-butenol
2) 2-methyl-3-butenol
3) 3-methyl-2-butenol
4) 2-methyl-but-2-ene-4-ol

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48) Which of the following compound have wrong IUPAC name.
1) CH3 – CH2 – CH2 – COO – CH2CH3 → ethyl butanoate
2) CH3 – CH – CH2 – CHO → 3-methyl-butanal

CH3
3) CH3 – CH – CH – CH3 → 2-methyl-3-butanol

OH CH3
O

4) CH3 – CH – C – CH2 – CH3 → 2 –methyl-3

CH3
Pentanone
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49) The IUPAC name of the following compounds is
HOOC – CH2 – CH – CH2 – CH2 – COOH

COOH
1) 2-(Carboxy methyl)-pentane-1, 5-dionic acid
2) 3-Carboxy hexane -1, 6 dioic acid
3) Butane-1, 2, 4,-tricarboxylic acid
4) 4-Carboxy hexane-1, 6 dioic acid
5) 1, 2 dicarboxypentanoic acid

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50) The IUPAC name of
CH3

CH3 – CH – CH2 – C – CH3 and CH2 – CH – CH2

OH OH CN CN CN
1) 1, 1-dimethyl-1, 3-butanediol and propanetricarbyl amine
2) 4-methyl-2, 4-pentanediol and 1, 2, 3 propanetrinitrile
3) 2-methyl 2, 4-pentanediol and 1, 2, 3-Propantricarbonitrite
4) 1, 3, 3-trimethyl 1, 3-propanediol and 1, 2, 3 tricyano propane

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 Answer Key
Exercise –I
1. 3 2. 3 3. 4 4. 1 5. 3
6. 4 7. 1 8. 3 9. 1 10. 2
11. 3 12. 3 13. 3 14. 1 15. 3
16. 3 17. 1 18. 2 19. 2 20. 2
21. 4 22. 2 23. 1 24. 1 25. 2
26. 2 27. 1 28. 2 29. 4 30. 4
31. 2 32. 2 33. 4 34. 2 35. 2
36. 2 37. 1 38. 2 39. 2 40. 2
41. 2 42. 1 43. 2 44. 3 45. 1
46. 3 47. 3 48. 3 49. 3 50. 3

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