MM.40 S. S.

1-6=1marks 7-9=2marks 10-12=3marks

Set O CHEMISTRY Date:06 JAN 2023 13-15=5marks 16=4marks

1.How many ions are produced from the complex [Co(NH3)5Cl] Cl2 in solution ?
(a) 4 (b) 2 (c) 3 (d) 5
2. In a lead storage battery
(a) PbO2 is reduced to PbSO4 at the cathode.
(b) Pb is oxidised to PbSO4 at the anode.
(c) Both electrodes are immersed in the same aqueous solution of H2SO4.
(d) All the above are true.
4. How many coulombs are required for the oxidation of 1 mol of H2O to O2

(a) F (b) 2F (c) 3F (d) 0.5F

5. 3.Predict the order of reaction in the given graphs :

(a) First (b) Second (c) Zero (d) Order cannot be determined

6. Assertion (A) :[Pt(en)2 Cl2]2+ complex is less stable than[Pt(NH3)4 Cl2]2+ complex.
Reason (R) : [Pt(en)2 Cl2]2+ complex shows chelate effect.

7.What is a fuel cell ? Write its one advantage over other ordinary cell?

8.For a reaction A + B P, the rate is given by Rate = k [A]2[B]

a. How is the rate of reaction affected if the concentration of a is doubled ?
b. What is the overall order of reaction if B is present in large excess ?
9.Why is [NiCl4]2paramagnetic while [Ni(CN)4]2is diamagnetic ?also find no of unpaired
electron in both comlex compound (Atomic number of Ni = 28)

10.The conductivity of 0.001 mol L1 solution of CH3COOH is 4.95 105 S cm1.
Calculate its molar conductivity and degree ofdissociation (). Given :(H+) = 349.6 S
cm2 mol1 and (CH3COO) = 40.9 S cm2 mol1.
OR
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using
a current of 5.0 ampere for 20 minutes. What mass of nickel will be
deposited at the cathode ?
(Given : At. Mass of Ni = 58.7 g mol–1, 1 F = 96500 C mol–1)

11.A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when
75% of the reaction will be completed. (Given : log 2 = 0·3010, log 3 = 0·4771)
12.(i) Define Spectrochemical series.
(ii) On the basis of crystal field theory, write the electronic configuration for d 5 ion
if o > P.
MM.40 S. S. 1-6=1marks 7-9=2marks 10-12=3marks

Set O CHEMISTRY Date:06 JAN 2023 13-15=5marks 16=4marks

(iii) Write the use of cis- platin and also write its IUPAC.
13. (a) Calculate emf of the following cell at 25 C :
Fe | Fe2+(0.001 M) || H+(0.01 M) | H2(g) (1 bar) | Pt(s)
E(Fe2+ | Fe) = –0.44 V E(H+ | H2) = 0.00 V
(b) Write all anode and cathode reaction of lead storage battery.
OR
.(a) The cell in which the following reaction occurs :
2 Fe3+ (aq) + 2 I (aq) 2 Fe2+ (aq) + I2 (s) has Ecell + 0·236 V at 298 K. Calculate
standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol1)
(b) How many electrons flow through a metallic wire if a current of 0·5 A is passed for 2
hours ? (Given : 1 F = 96,500 C mol1)
(c) Derive the relation between conductivity and and conductance.

14. (a)What type of isomerism is exhibited by the complex [Co(NH3)5NO2] 2+

(b) Write the state of hybridization,shape, magnetic moment and IUPAC name of the
complex [Co(NH3)6 ] 3+. (Atomic no. of Co = 27)
(c) Which element present in Chlorophyll, Vitamin B12, Haemoglobin and Adam’s catalyst.

15.(i) The decomposition of a hydrocarbon has value of rate constant as

2·5 X 104 s–1 at 27C. At what temperature would rate constant be
7·5X 104 s–1 if energy of activation is 19·147X103 J mol–1 ?
(II) Define order of reaction. How does order of a reaction differ from
molecularity for a complex reaction ?
16. Read the passage given below and answer the following
questions:
The concentration of potassium ions inside a biological cell is at least
twenty times higher than the outside. The resulting potential difference
across the cell is important in several processes such as transmission of
nerve impulses and maintaining the ion balance. A simple model for
such a concentration cell involving a metal M is M(s) | M+(aq.; 0.05 molar)
|| M+(aq; 1 molar) |M(s).
The following questions are multiple choice questions. Choose the
most appropriate answer:
(i) For the above cell,
(a) Ecell <0;ΔG>0 (b) Ecell >0;ΔG<0 (c) Ecell <0;ΔG∘>0 (d) Ecell >0;ΔG∘<0
(ii) The value of equilibrium constant for a feasible cell reaction is
(a) < 1 (b) = 1 (c) > 1 (d) zero
(iii) What is the emf ofthe cell when the cell reaction attains equilibrium?
(a) 1 (b) 0 (c) > 1 (d) < 1
(iv) The potential of an electrode change with change in
(a) concentration of ions in solution (b) position of electrodes
(c) voltage of the cell (d) all of these