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oxaalzuur: 3.

1540 g 500
NaOH: 2.0000 g 500

citroensap in citroenlimonade (tönissteiner citroen): 7,5%

Bereiding 500 ml 0,05M oxaalzuur


massa (g) MM (g/mol) aantal mol
theoretisch 3.1518 126.07 0.025000
afgewogen 3.1540 126.07 0.025018

Bereiding 500 ml 0,1M NaOH


massa (g) MM (g/mol) aantal mol
theoretisch 2.0000 40 0.05
afgewogen 2.0000 40 0.05
mL
mL

aantal L oplossing molariteit (mol/L)


0.500 0.0500
0.500 0.0500

aantal L oplossing molariteit (mol/L)


0.5 0.1
0.5 0.1
volume (mL) pH 1ste afgeleide 2de afgeleide
0.00 1.62 ΔpH/Δv Δ2pH/Δv Titratiecurve oxaalz
0.50 1.61
1.00 1.61 0.00 14.00
1.50 1.60 -0.02 -0.04 12.00
2.00 1.61 0.02 0.08 10.00
2.50 1.63 0.04 0.04 8.00

pH
3.00 1.65 0.04 0.00 6.00
3.60 1.68 0.05 0.02 4.00
4.00 1.70 0.05 0.00
2.00
4.50 1.73 0.06 0.02
0.00
5.00 1.76 0.06 0.00 23.50 24.00 24.50 25.0
5.50 1.79 0.06 0.00
6.05 1.83 0.07 0.02
6.50 1.87 0.09 0.04
7.00 1.90 0.06 -0.06
7.50 1.94 0.08 0.04
8.00 1.99 0.10 0.04 1ste afgeleide titra
8.50 2.04 0.10 0.00
9.00 2.09 0.10 0.00
10.00
9.50 2.17 0.16 0.12 9.00
10.00 2.24 0.14 -0.04 8.00
10.50 2.32 0.16 0.04 7.00
6.00

ΔpH/Δv
11.00 2.40 0.16 0.00 5.00
11.50 2.52 0.24 0.16 4.00
12.00 2.63 0.22 -0.04 3.00
2.00
12.50 2.75 0.24 0.04 1.00
13.00 2.91 0.32 0.16 0.00
13.20 2.94 0.15 -0.85 23.50 24.00 24.50
13.50 3.03 0.30 0.50
14.00 3.16 0.26 -0.08
14.20 3.21 0.25 -0.05
14.50 3.27 0.20 -0.17
14.80 3.32 0.17 -0.11
15.00 3.37 0.25 0.42 2de afgeleide titratie
15.50 3.44 0.14 -0.22
16.00 3.53 0.18 0.08 20.00
16.50 3.62 0.18 0.00 15.00
10.00
17.00 3.69 0.14 -0.08 5.00
Δ2pH/Δv

17.50 3.76 0.14 0.00 0.00


18.00 3.83 0.14 0.00 -5.00
18.50 3.90 0.14 0.00 -10.00
-15.00
19.00 3.97 0.14 0.00
-20.00
19.50 4.03 0.12 -0.04 -25.00
20.05 4.11 0.15 0.05 23.50 24.00 24.50
20.50 4.17 0.13 -0.03
21.10 4.26 0.15 0.03
21.50 4.33 0.18 0.06
22.00 4.42 0.18 0.01
22.50 4.51 0.18 0.00
2de afgelei

20.00
15.00
f(x) = − 123.7
10.00
5.00
/Δv

0.00
2de afgelei
23.00 4.62 0.22 0.08
23.50 4.75 0.26 0.08
20.00
24.00 4.91 0.32 0.12
15.00
24.30 5.04 0.43 0.38 f(x) = − 123.7
10.00
24.50 5.17 0.65 1.08
5.00
24.80 5.41 0.80 0.50

Δ2pH/Δv
0.00
25.00 5.62 1.05 1.25
-5.0025.45 25.50 25.55
25.50 10.09 8.94 15.78 kleuromslag
-10.00
25.80 10.85 2.53 -21.36
-15.00
26.10 11.14 0.97 -5.22
-20.00
26.50 11.35 0.53 -1.10
-25.00
27.00 11.52 0.34 -0.37

123.79

oxaalzuur NaOH
factor concentratie (M) volume (mL) factor concentratie (M) volume (mL)

EP2 2 0.0500 25 1 0.0976 25.63


Titratiecurve oxaalzuur - NaOH

23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50


V NaOH (mL)

1ste afgeleide titratie oxaalzuur - NaOH (gebied rond EP2)

10.00
9.00
8.00
7.00
6.00
ΔpH/Δv

5.00
4.00
3.00
2.00
1.00
0.00
23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50
V NaOH (mL)

2de afgeleide titratie oxaalzuur - NaOH (gebied rond EP2)

20.00
15.00
10.00
5.00
Δ2pH/Δv

0.00
-5.00
-10.00
-15.00
-20.00
-25.00
23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50
V NaOH (mL)

2de afgeleide titratie oxaalzuur - NaOH (EP2)

20.00
15.00
f(x) = − 123.785185185187 x + 3172.30222222227
10.00
5.00
/Δv

0.00
2de afgeleide titratie oxaalzuur - NaOH (EP2)

20.00
15.00
f(x) = − 123.785185185187 x + 3172.30222222227
10.00
5.00
Δ2pH/Δv

0.00
-5.0025.45 25.50 25.55 25.60 25.65 25.70 25.75 25.80 25.85
-10.00
-15.00
-20.00
-25.00
V NaOH (mL)

y = -5.05 x + 65.81

y = -123.79 x + 3172.3
0 = -123.79 x + 3172.3
x = 3172.3
x = 25.63 mL

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