HK-51 Sodium Benchtop Huakeyi

HK-51 Benchtop Sodium Meter
Instruction Manual
Version: 3.9
Beijing Huakeyi Power Plant Instrument Research Institute

HK-51 Benchtop Sodium Meter PREFACE
PREFACE
HK-51 Benchtop Sodium Meter is the latest laboratory instrument developed by Beijing Huakeyi
Power Plant Instrument Research Institute. With the powerful technical superiority, Huakeyi
developed HK-51 Benchtop Sodium Meter. It incorporates practice experiences of about 10 years
and advanced technologies of the whole world, can measure sodium of aqueous solutions for
applications in institutes and universities, as well as electric power, chemical/petrochemical,
paper/paper pulp, pharmaceutical, food and environmental protection and other related fields. The
meter has such characteristics as fast response, accurate analysis and easy operation.
The indicator is 192×64 lattice back-lighted LCD displays in English or Chinese. There are 8
buttons on the instrument keypad; they can realize all operation and configuration. HK-51 has
four-digit security code for the meter programming in order to prevent accidental or unwanted
changes to program settings, display and calibration.
The Instruction Manual provides information about HK-51 Benchtop Sodium Meter. It is compiled
for users to familiarize the structure, principle of operation and operation procedures of HK-51
Benchtop Sodium Meter. The potentially fallible and easy-to-ignore problems during operation are
detailed for preventing unnecessary troubles and failures for long-term safe and reliable operation.
WARNING
Be sure to read this Instruction Manual carefully before proceeding with operation and
maintenance of this instrument.
Beijing Huakeyi Power Plant Instrument Research Institute
Dec 02, 2008

HK-51 Benchtop Sodium Meter CONTENT
CONTENT
1. INTRODUCTION ................................................................................................................................. 1
1.1 Brief introduction .......................................................................................................................... 1

1.2 Working principle ......................................................................................................................... 1
2. INSTALLATION .................................................................................................................................. 3
2.1 Basic Requirements ..................................................................................................................... 3

2.2 Mounting ...................................................................................................................................... 3
2.2.1 Power Supply ........................................................................................................................ 3
2.2.2 Mounting new sodium electrode ........................................................................................... 3
2.2.3 Mounting new reference electrode ....................................................................................... 3
2.2.4 Mounting new ATC temperature electrode ........................................................................... 3
3. SPECIFICATIONS .............................................................................................................................. 5
4. PROGRAMMING ................................................................................................................................ 6
4.1 Display and keypad ..................................................................................................................... 6

4.1.1 Update Parameters ............................................................................................................... 7
4.1.2 Update values ....................................................................................................................... 7
4.2 Power-on...................................................................................................................................... 7
4.3 User interface............................................................................................................................... 7
4.4 Program unit ................................................................................................................................ 8
4.4.1 Setting Security Code ........................................................................................................... 8
4.4.2 Main Menu ............................................................................................................................ 9
4.4.3 Setup Sub-menu ................................................................................................................... 9
4.4.4 Calibration Sub-menu ......................................................................................................... 10
4.4.5 Log Sub-menu .................................................................................................................... 11
5. OPERATION ..................................................................................................................................... 13
5.1 Power-on.................................................................................................................................... 13

5.2 Calibration (automatic stable-judgment function ENABLED) .................................................... 13
5.2.1 Na+ Standard Solution Calibration ...................................................................................... 13
5.2.2 Sample calibration .............................................................................................................. 16
5.2.3 Temperature Calibration ..................................................................................................... 18
5.2.4 Electrical Calibration ........................................................................................................... 20
5.3 How to measure sample ............................................................................................................ 22
6. MAINTENANCE ................................................................................................................................ 24
6.1 Meter Maintenance .................................................................................................................... 24

6.2 Routine Maintenance ................................................................................................................. 24
1
HK-51 Benchtop Sodium Meter CONTENT
6.3 Electrode maintenance .............................................................................................................. 24
Appendix I ............................................................................................................................................ 25
Appendix Ⅱ .......................................................................................................................................... 26
Appendix Ⅲ .......................................................................................................................................... 29
Appendix Ⅴ .......................................................................................................................................... 31
Products and Technical Support ....................................................................................................... 32
2
HK-51 Benchtop Sodium Meter INTRODUCTION
1. INTRODUCTION
1.1 Brief introduction
HK-51 Benchtop Sodium Meter is consisted of the meter, sodium electrode, reference electrode, ATC
temperature electrode and the electrode holder. It adopts the high sensible electrode system to make
sure the stability and accuracy of sodium measurement.
The meter has one temperature input channel. When automatic temperature compensation is needed,
the sample temperature can be measured by a Pt1000 thermometer, otherwise manual temperature
compensation will replace the automatic temperature compensation
1.2 Working principle
The effect of the sodium concentration variation to the electric potential of the sodium electrode can be
depicted by the Nernst equation:
RT
E = E 0 + 2.3 lg a Na +
nF
where:
E — The electric potential generated by the sodium electrode, mV；
a Na +
E0 —The electric protential of the electrode when is 1mol/L, mV;:
-1 -1
R — Ideal gas constant; 8.314JK mol ;
T — Absolute temperature of the sample water, K;
F — Faraday constant, 9.649×104C·mol-1
n — The electron number participating the reaction, for sodium ion it is +1;
a Na +
— The activity of the sodium ion in the solution, mol/L.
1
HK-51 Benchtop Sodium Meter INTRODUCTION
The above equation had indicated that, the measured electric potential will variate with the variation of
the temperature and the related ion concentration. In order to eliminate the errors caused by the water
temperature variation, HK-51 sodium meter will amend the temperature compensation value timely
according to the temperature measured by the ATC temperature electrode.
From the Nernst equation we can see that, at the temperature of 25℃, the theoretical response value
of the selected sodium electrode to the 10 times of ion concentration is 59.16mV, which is called
electrode slope (S). However, most of electrodes will not manifest as theoretical slope. So it is
necessary to calibrate the instrument to determine the actual slope of the electrode. In the actual
application, we calculate out the real slope value and the E0 of the electrode by using two kinds of
standard solution.
When the concentration of sodium ion is in a low level, the existence of the hydrogen ion will cause
magnificent interference. In order to eliminate this interference, basifier should be added in the sample
water and making the pH value be increased up to over 10.5.
2
HK-51 Benchtop Sodium Meter INSTALLATION
2. INSTALLATION
2.1 Basic Requirements
¾ The meter should be placed on smooth, spotless laboratory table.

¾ Put the meter in a site where vibrations are not too excessive.
¾ Keep the meter free from harmful gases and liquid drips.
¾ Ensure the cables and power line far from high temperature or frictional objects.
2.2 Mounting
Please read the instruction manual carefully before installing and pay attention to the treatment method
of the electrode.
2.2.1 Power Supply
(85~265)VAC, (45~65)Hz, ≤3W. Refer to the figure 2.1 below.
2.2.2 Mounting new sodium electrode
It is necessary to mount the new sodium electrode provided by Huakeyi. And the particular sodium
electrode is matched with the particular reference electrode.
1. Put the electrode on the bracket.
2. Insert BNC cable connector of sodium electrode into corresponding hole on the meter back panel,
then counterclockwise rotate and lock it. Refer to the figure 2.1 below.
2.2.3 Mounting new reference electrode
Every reference electrode is provided together with a filling liquid bottle of 60ml. The reference
electrode of the sodium meter is specially made and can not be alternated with other reference
electrodes.
Note: the sodium electrode and the reference electrode shall be used as a fitted couple.
1. Put the electrode on the bracket.

2. Connect the reference electrode with the REF input hole which is on rear panel of the meter. Refer
to the figure 2.1 below.
2.2.4 Mounting new ATC temperature electrode
Insert the temperature electrode into the ATC input hole on the back panel of the meter. Refer to the
figure 2.1 below.
3
HK-51 Benchtop Sodium Meter INSTALLATION
Hole for mounting Sodium Electrode Hole for mounting Temperature Electrode
Power Switch
Hole for mounting Reference Electrode Power Supply
Figure 2.1 Back Panel of Meter
4
HK-51 Benchtop Sodium Meter SPECIFICATIONS
3. SPECIFICATIONS
Display : 192 × 64 lattice LCD display in English or Chinese

Measurement Range : (1.00 ~ 8.00)pNa (0.23μg/L～2.3g/L)
Display Resolution : 0.01pNa or 0.01µg/L
Analysis Error : ± 0.03pNa or ±5μg/L, take the larger one
Input Impedance : ≥1012Ω
Response Time (T90) : 2min at 25℃ ambient temperature
Temperature electrode : Pt1000
Temperature Range : (0.0 ~ 99.9)℃
Temperature Accuracy : ± 0.5℃
Temperature Resolution : 0.1℃
Temperature Compensation :(0.1 ~ 60.0)℃ (manual or auto)
Sample Temperature :(5 ~ 60)℃
Ambient Temperature : (5 ~ 45)℃
Relative Humidity : ≤ 90%RH, no condensing
Storage Temperature : (-25 ~ 55)℃ (exclude the electrode, higher than 0℃ for the electrode)
Power Supply : (85～265)VA, (45~65)Hz
Power Consumption : ≤ 3W
Dimensions (D × W × H) : 270mm × 200mm × 65mm
Weight : 2kg
5
HK-51 Benchtop Sodium Meter PROGRAMMING
4. PROGRAMMING
4.1 Display and keypad
Display
ESC(QUIT) ENTER SAVE LOG DIRECTION KEYS
Figure 4.1 Displays and Keypad
DISPLAY: The indicator is 192×64 lattice back-lighted LCD display in English or Chinese.
KEYPAD: There are 4 function keys (SAVE, LOG, ENTER and ESC) and 4 direction keys (UP, DOWN,
RIGHT and LEFT) on the instrument keypad.
Function Keys:
SAVE : Press the key under measurement screen, “Now Saving, Waiting...” will display. The
meter saves the current data.
LOG : Press the key under the measurement screen, inquiry history data directly.
ENTER : a. During programming, press the key after select some menu or function, the meter will
enter the corresponding one.
b. After update some parameters, press the key to store numbers and settings, and return
to the previous operation screen.
ESC : a. Press the key under measurement screen, Security Code screen will appear. After input
the correct access code, press ENTER key to enter main menu.
b. During programming, press the key to return to the previous menu or screen without
storing changes
6
Direction Keys: UP, DOWN, RIGHT and LEFT,

¾ Under the measurement screen, press the UP or DOWN arrow key to transform indicating the
measured temperature (or manual compensated temperature) and voltage; press RIGHT or LEFT
arrow key to adjust the contrast of LCD display (LEFT is darker, RIGHT is lighter).
¾ Under all programming menu screens, press the arrow keys to move horizontally or vertically the
cursor to select menus or items required.
¾ After selecting the given parameter or datum, press the UP or DOWN arrow key to change
parameters or datum.
¾ When reviewing historical data, press the UP or DOWN arrow key to look over the data on the
adjacent pages.
4.1.1 Update Parameters
During programming, after select some parameter (display in reverse color), press UP and DOWN key
to update its value, and then press ENTER key to save the revision and return to the previous screen,
or press ESC key to return to the previous screen without saving the revision.
4.1.2 Update values
During programming, after select some digit of numerical value (display in reverse color) press UP and
DOWN key to increase or decrease the value of the digit, press LEFT and RIGHT key to move the
cursor from digit to digit. Then press ENTER key to save the revision and return to the previous screen,
or press ESC key to return to the previous screen without saving the revision.
4.2 Power-on
WARNING
· DO NOT apply power to the meter until all electrical connections are verified and secure.
· If the meter is used for the first time, its internal parameters should be set by programming
and the instrument calibration is necessary.
4.3 User interface
Apply power to the meter and turn on the power switch, the following welcome interface will appear
first:
This interface will last for 5s, then shift to the measurement interface automatically as the below screen:
7
Current time Stable Indication: All the

measured value will not
vary until “Stable”
disappears. When stable,
Concentration of Na+
press Enter to enter
Auto-stable again.
Press the UP or DOWN arrow key to transform indicating

the measured temperature (or manual compensated
temperature), voltage and pNa.
Storage of Measured Data

Under measurement screen, press SAVE key to save the current concentration of Na+ and temperature
values to data logger. The below screen will appear:
4.4 Program unit
Besides the measurement screen, HK-51 sodium meter also has a key unit－Program Unit. Almost all
the parameter setting, calibration, maintenance, information are realized by the program unit. It is
protected by the security code. Use the security code to prevent accidental or unwanted changes for
the program unit.
4.4.1 Setting Security Code
Access Method:
Under measurement screen, press ESC key to enter Security Code screen:
Operation:
After enter one code with the range from 0000 to 9999, press ENTER key. If the entry is correct, the
meter will move to the main menu screen, otherwise it will return to the measurement screen. Press
ESC key to return to the measurement screen.
8
4.4.2 Main Menu
Access Method:
Under measurement screen, press ESC key to enter Security Code screen. Enter correct code, press
ENTER key to move to the below main menu screen.
1. Setup
2. Calibration
3. Log
Choice:
The Main Menu includes 3 sub-menus; they are Setup, Calibration and Log.
Operation:
The meter only has four lines indication. Press UP and DOWN keys to show more choices. After select
some sub-menu, press ENTER key to enter corresponding one.
Press ESC key to return to the measurement screen.
4.4.3 Setup Sub-menu
Access Method:
Choose Setup under the main menu screen. Press ENTER key to enter the below screen:
1. Language
2. Password
3. Adjust Contrast
4. System Time ︾
5. Temp Comp Type: Manual

6. Setup Comp Temp: 05.0℃
7. Reset
Choice:
The Sub-menu includes 7 choices; they are Language, Password, Adjust Contrast, System Time,
Temp Comp Type, Setup Comp Temp and Reset.
The details as follows:
¾ Language: Two options, English and Chinese.
¾ Password: The security code prevents accidental or unwanted changes for the meter. It can be
changed.
9
¾ Adjust Contrast: Adjust the brightness of the screen, Darker or Lighter.

¾ System Time: Setup the internal clock of the meter for the validity of historical records. Setting
sequence: year, month, day, hour, minute, second. When finish the settings, the meter will return
automatically.
¾ Temp Comp Type: The fluctuation of the sample will affect the measured value, In order to
eliminate the effect the meter must be selected automatic or manual temperature compensation.
¾ Setup Comp Temp: When Manual (temperature compensation) is selected, the selectable
temperature range is (0.0～60.0)℃. If Auto (temperature compensation) is selected, the choice is
invalid.
¾ Reset: two options: Log and All. Select Log to clear the log records, and select All to clear all the
records.
Operation:
Press UP, DOWN, LEFT and RIGHT key to move the cursor to the requested place. Press ENTER key
to access the corresponding choice. Update parameters or values as mentioned method in 4.1.1 and
4.1.2. After complete changes, press ENTER key to store the revision and return to the previous
operation level.
Press ESC key to cancel the revision and return to the previous operation screen.
4.4.4 Calibration Sub-menu
Access Method:
Choose Calibration under the main menu screen. Press ENTER key to enter the below screen:
Choice：
The Sub-menu includes 4 choices; they are Na+ standard solution calibration, Sample calibration,
Temperature calibration and Electric calibration.
The details as follows:
¾ Na+ standard solution calibration：Use the Na+ standard solution to calibrate the meter;
¾ Sample calibration：Use the measuring solution as the standard solution to calibrate the
instrument;
¾ Temperature calibration：Calibrate the temperature measurement system of the meter.
¾ Electric calibration：Calibrate the electric elements of the meter.
Operation:
to access the corresponding sub-menu. According to the menu instruction, perform the corresponding
10
calibration.
Press ESC key to return to the main menu screen.
REMARK
The detail operating steps of several calibration or trim refer to chapter 5 OPERATION.
4.4.5 Log Sub-menu
Access Method:
Choose Data Log under the main menu screen. Press ENTER key to enter the below screen:
Choice：
The Sub-menu includes 3 choices; they are Data Log, Event Log and Calibration Log. The details as
follows:
¾ Data Log: Display the storage of measured data. It can record 256 items. Under the measurement
screen, press LOG key can also enter this interface.
¾ Event Log: Display the events of operation. These events include power-on, power-off, update
parameter and so on. It can record 256 items
¾ Calibration Log: Display the recorded calibration data. Include standard solution and temperature
calibration. It can record 64 items.
11
Operation:
to access the corresponding sub-menu and data.
Press ESC key to return to the main menu screen.
12
HK-51 Benchtop Sodium Meter OPERATION
5. OPERATION
5.1 Power-on
WARNING
1. Ensure to carefully read the chapter 4 PROGRAMMING of the instruction manual
before applying power to the meter.
2. Ensure all connections are correct and reliable.
3. The diisopropylamine is of hazardous goods, please wear protection glasses and
gloves while operating. Refer to the appendix for the detailed protection standard
¾ Power-on the meter, the measurement screen will appear.

¾ According to the application, to program and set the parameters.
5.2 Calibration (automatic stable-judgment function ENABLED)
After the meter is normal operation, it is necessary to perform the calibrations, including:
• Na+ standard solution calibration
• Sample calibration;
• Temperature calibration;
• Electric calibration
Among which, the Temp Cal and Electric Cal are factory calibrated, there is no need to recalibrate. In
order to ensure the accurate and reliable measurement, Na+ standard solution calibration (2-points Cal)
is necessary prior to the initial operation.
5.2.1 Na+ Standard Solution Calibration
Na+ standard solution calibration is based on the usage of a known pNa value standard solution. 1-point
or 2-points calibration is available, among which, 1-point calibration is to correct the curves stored in
the memory, while 2-points calibration is to create a curve for mV voltage values to pNa values.
During normal measurements, the meter results the measured mV voltage values in accordance with
the curves stored in the memory. And then it is necessary to perform temperature compensation, and
display the pNa value at 25℃.
CAUTION
2-points calibration is required for the initial operation, electrodes replacement and
long-term out of operation.
13
Preparation:
¾ According to the application to prepare the standard solutions, each solution is at least 500mL.
¾ If take two point calibration, the difference between the concentration of the two solution should be
at least 10 times, for example: 230μg/L and 2300μg/L;
¾ The beaker should be rinsed by the standard solution at least once;
¾ Basifier solution：diisopropylethylamine solution（the concentration not lower than 98%），every
30ml sample use one drop of the diisopropylethylamine solution, both the normal measurement
and calibration should take this proportion.
Note：DO NOT use Ammonia as the basifier solution, so as to avoid the interference brought by
NH4+.
Measurement interface
Press ESC key
Input Password
Security code prevents accidental or unwanted
changes for the meter. Enter correct code via UP,
DOWN, RIGHT and LEFT keys.
Press ENTER key to enter main menu.
1. Setup Main Menu

2. Calibration Move the cursor to Calibration via DOWN and UP
3. Log
keys.
Press ENTER key to enter Calibration Sub-menu.
Calibration Sub-menu
Move the cursor to Na+ std solution calibration
via DOWN and UP keys.
Press ENTER key to continue.
14
Standard solution 1
Use the basification standard solution 1 to rinse
the electrodes at least two times, then immerse
the electrode to the beaker that filled with the
basification standard solution 1
Press ENTER key to continue
Input the value of the standard solution 1

Use the direction keys to update the value of the
set parameter as the first standard solution.
Calibrating …
When to end calibration is decided by settings.
Na+ voltage and the temperature voltage are new
measured ones
Wait ……
Standard solution 1 calibration completed

1-Point Cal, press ESC to complete.
2-Point Cal, press ENTER to Continue.
1-point cal completed
Press ESC to return
Standard solution 2
Use the basification standard solution 2 to rinse
the electrodes at least two times, then immerse
the electrode to the beaker that filled with the
basification standard solution 2.
Press ENTER key to continue
15
Calibrating …
Na+ voltage and the temperature voltage are
new measured ones
Wait ……
Input the value of the standard solution 2

Use the direction key to update the value of the
set parameter as the second standard solution.
Cal Fail
Calibration success
If success, the meter will automatically return to
the calibration place.
Na+ standard solution calibration completed.
Na+ standard solution Cal completed

Press ESC to return
Calibration Fail
If this screen appears, the calibration is invalid,
without storing the calibration data.
Press ESC to return.
5.2.2 Sample calibration
Sample calibration is using the known concentration sample solution to do the 1-point calibration,
and has the feature of flexible and quicker.
Press ESC key
16
Input Password
changes for the meter. Enter correct code via UP,
DOWN, RIGHT and LEFT keys.
Main Menu
Move the cursor to Calibration via DOWN and UP
keys.
Move the cursor to Na+ std solution calibration
via DOWN and UP keys.
Input the concentration of the sample

Update the setting value as the concentration of
the sample.
Calibrating …
Na+ voltage and the temperature voltage are new
measured ones
Wait ……
Cal Fail
Calibration success
Sample Calibration place.
17
Calibration Fail
Press ESC to return
5.2.3 Temperature Calibration
Temperature calibration is factory calibrated, there is no need to recalibrate. If any large temperature
deviations are found during operations, it may use the temperature calibration to overcome the
resulting errors.
Press ESC key
Input Password
changes for the meter. Enter correct code via
UP, DOWN, RIGHT and LEFT keys.
Main Menu
keys.
Move the cursor to Temperature Calibration via
DOWN and UP keys.
18
Temperature Calibration Sub-menu

Enter the current temperature value via UP,
DOWN, REIGHT and LEFT keys.
Calibrating ……
The values of temperature & voltage are new
measured ones.
Waiting ……
End of Temperature 1 Calibration

Temp Cal Completed

Press ESC to return
Temperature Calibration Sub-menu

Enter the current temperature value via UP,
DOWN, REIGHT and LEFT keys.
(Temperature 2 should be different from
temperature 1 for at least 10℃)
Calibrating ……
When to end calibration is decided by settings. The
values of temperature & voltage are new measured
ones.
Waiting ……
Cal Fail
Temperature Calibration Success

temperature calibration place.
Two Point Cal Completed
Press Esc key to return.

19
Calibration Fail
5.2.4 Electrical Calibration
WARNING
The electrical calibration is completed prior to shipment, and it is no need to repeat this
operation. If necessary, the electrical calibration should be performed by qualified technicians
with proper equipment.
Preparations:
¾ Potentiometer (0 – 1.2000V, increment 0.0001V).
¾ Turn off power supply, and remove electrode from the meter.
¾ Connect the BNC connector with the potentiometer output. Wire the internal lead to positive (+),
the external lead to negative (-).The potentiometer will be used for simulating electrode input
signal.
¾ Turn on power switch.
Press ESC key
Input Password
changes for the meter. Enter correct code via
UP, DOWN, RIGHT and LEFT keys.
20
Main Menu
keys.
Move the cursor to Electric Cal via DOWN and UP
keys.
Volt1 Calibration
Enter Volt1 value with the potentiometer
(between ±190 mV), and then use direction keys
to make the screen reading match for that of the
potentiometer.
Calibrating…
The value of electric voltage is new measured one.
Please wait.
Volt1 Cal Completed

1-point Calibration completed

Press ESC to return
21
Volt2 Calibration
Enter Volt2 value with the potentiometer
(between ±190 mV), the difference of Volt1 &
Volt2 is more than 100mV. Then use direction
keys to make the screen reading match for that of
the potentiometer.
Calibrating ……
The value of electric voltage is new measured
one.
Waiting …………….
Cal Fail
Electric Calibration Success

electric calibration place.
Electric Cal completed.
Electric Cal Completed

Press ESC to return
Calibration Fail
5.3 How to measure sample
After calibrations completed, the meter can carry out normal measurements.
1. Dribble 3-4 drop of the basification solution to the plastic beaker, add about 100ml of the sample to
the beaker and then shake the beaker gently for several seconds;
2. Use the above sample to wash the electrode.
3. Repeat the procedure 1 and 2 to rinse the electrode for at least two times.
4. Prepare the sample solution got from procedure 1 and then immerse the electrode into the beaker
and wait for the measuring value become stable. (about 2 minutes).
5. When the reading is stable, the value can be used.
22
REMARK
+
When the concentration of Na is in a high level, rinse the electrode for two times; and if the
concentration is in a low level (less than pNa6), it is recommended to rinse the electrode for
more times so as to reduce the interference and get a more accurate result.
The newer the electrode is, the faster its stabilization. When the electrode has been used
for some time, its stabilizing time will correspondingly be increased.
23
HK-51 Benchtop Sodium Meter MAINTENANCE
6. MAINTENANCE
6.1 Meter Maintenance
When the meter is temporary out of use, the electrode should be immersed in the basified pNa4
solution. Place the meter and beakers in an area where is dustproof for future use.
When the meter is long time out of use, the following operation should be taken:
Power-off meter; remove the electrode, put it into the protection bottle which is filled with
immersion solution; Insert the short circuit cap into the hole for electrode connector.
6.2 Routine Maintenance
Weekly
1. Inspect the reference solution and refill immediately if necessary.
2. Do 1-point calibration once a week.
Monthly
Do 2-points calibration once a month.
6.3 Electrode maintenance
Usage and maintenance of the electrode refer to Electrode Instruction Manual for details.
24
HK-51 Benchtop Sodium Meter APPENDIX
Appendix I
Preparation of the standard solution

(According to GB 12156-89)
pNa4 standard solution (10-4mol/L) (2300μg/L)
1. Accurately weigh 1.1690g (NaCl) primary reagent (or high-grade pure) which has been baked for
1~2 hours under 250~350℃, dissolve it in 1st grade reagent water, and then shift into a 2 liter
volumetric flask and dilute to the scale, shake up.
2. Absorb 10mL above solution and dilute to 1L
Absorb pNa4 standard solution, by using the 1st grade reagent water and dilute to 10 times volume and
then get pNa5 standard solution.
Absorb pNa5 standard solution, by using the 1st grade reagent water and dilute to 10 times volume
and then get pNa6 standard solution.
With the same method, pNa7 (2.3μg/L) standard solution can be prepared according to actual use.
NOTE: Actually the 1st grade reagent water for preparing the standard solution is not really
contain no Na+, therefore, when the concentration is lower than 2.3μg/L(pNa7), the Na+
contained in the water should be deducted. When prepare for 2.3μg/L (pNa6) standard solution
or concentration below it, we should use plastic or quartz flask, all the standard solutions
should be stored in polythene plastic container to prevent any pollution.
25
Appendix Ⅱ
Security specifications of diisopropylamine

A2-1 Component/compose information
Main components : Content ≥95.0%
No. of CAS : 108-18-9
Relative Molecular Weight : 101.19
Molecular formula : C6H15N
Chemical category : Alicyclic amine
A2-1 Hazards identification

Hazards identification: Flammable and stimulating
Routes of invasion: Inhalation, ingestion, absorb by the skin
Health hazards: Simulative to respiratory tract, inhale of steam may cause pulmonary edema.
The steam may stimulate the eyes, the liquid may hurt the eyes and skin. Oral
intake may arouse nausea, throw up, diarrhea, bellyache, weakness and
prostration.
A2-3 First aid measures
Skin contact: if any contamination on the clothes, take them off immediately and wash it with large
flows of water for at least 15 minutes, then see the doctor.
Eyes contact: filed the eyelid immediately, and wash it with large flows of water or normal saline for at
least 15 minutes, then see the doctor.
Inhalation: leave the scene quickly and go to a place with fresh air, keep the smooth flow of
respiratory tract. If has difficulty in breathe, take oxygen therapy. If stop breathing, take
artificial respiration. Go to see the doctor.
A2-4 Fire protection
Combustibility : Flammable
Flash point (℃) : -1
Ignition temperature (℃) : 315
Low explosive limit [% (V/V)] : 1.1
High explosive limit [%( V/V)] : 7.1
Hazardous characteristics: Flammable, the steam and the gas may form explosive mixtures which will
cause explosion when meeting with naked flame and high calorie. Take
strong reaction with oxidizing agent. Since the stream is heavier than the air,
it can spread to a distant land when situates at a lower position, it will catch
fire whenever there is fire source, and it is corrosive.
Extinguish methods: Water spraying to cool the container and transfer it to an open space if possible.
Extinguishing agent: Alcohol resistant foam, carbon dioxide, dry powder, sandy soil, water is
unavailable to put out a fire.
26
A2-5 Leak emergency measure

Evacuated the staff from the polluted area, move to a safe place and isolated, forbidden any
entrance or exit.
Cut off the fire resource.
Wear positive pressure respirator and antitoxic clothing while carry out emergency treatment.
Cut off leakage source as possible. Avoid draining into the sewer or floodgate channel or any other
confined spaces.
Small leakage: Absorb by sandy soil or other non-combustible material. It can also wash with plenty of
water, dilute it and put into waste water system.
Large leakage: Construct the batardeau or make holes to take in. Spay water or foam to cool and dilute
steam so as to protect the site personnel. Transfer to the tank car or special holding
tank by using the anti-explosive pump, recycling or transport to waste processing site.
A2-6 Operation process and storage:

¾ Attention while operation:
Airtight operation, enhance ventilation.
The operators should be specialized training and obey the rules strictly. Non-power gas-mask,
chemical safe guarding glasses wear antitoxic clothing and oil resistance rubber glove.
Away from fire source and heat source, prohibit smoking.
Use anti-explosive ventilating system and equipment.
Avoid steam leak out to the air,
Prevent any contact with oxidizing agent and acids.
Control the flow speed and electrostatic accumulate.
Light install and remove while carrying to avoid damage to the package and container.
Prepare corresponding fire-fighting and emergency process equipment.
Empty out noxious substance that residual in the container.
¾ Attention items for storage:
Store in a cool and ventilate warehouse.
Far away from fire source and heat resource
Keep room temperature lower than 30℃.
Seal packing and avoid contact with the air.
Isolate the oxidizing agent and acids, prohibit mixing.
Adopt anti-explosive lighting, ventilate facility.
Forbid to use the mechanical equipment that generates the sparks.
Reserve emergency disposal equipments and moderate intake materials.
¾ Respiratory protection:
Wear non-power gas-mask if may contact with the steam.
Wear oxygen respirator and air respirator when doing emergency rescue or evacuate.
¾ Eyes protection: Wear chemical safe guarding glasses.
27
¾ Body protection: Wear antitoxic clothing

¾ Hand protection: Wear oil resistance rubber glove
¾ Other protection: Prohibit smoking, eating and drinking at the scene. Take a bath after work. Do
regular physical examination.
A2-7 Physical and Chemical properties:

Appearance and character: achromatism, volatile liquid with ammoniacal odour.
Melting point (℃) : -61
Boil point (℃) : 84.1
Relative density (water) : 0.72
Relative density (atmosphere=1) : 3.49
Saturated vapor pressure (kPa) : 6.67 (20℃)
Solubility: Slight soluble in water and soluble in most organic solvent.
Main application: rubber accelerant, medical intermediates and herbicide, surfactant etc.
A2-8 Stability and active reaction:

Stability: stable
Polymerization hazard: dispolymerization
Contraindications: strong oxidizing agent and acids
Combustion product: carbon monoxide, carbon dioxide and nitrogen oxide
A2-9 Bioecology material:

This material may cause damage to the environment, pay particular attention to the solution.
A2-10 Antiquate treatment:

Antiquate method: Burning disposal. The nitrogen oxides that exported by the incinerator should be
eliminated by the scrubber.
NOTE: The description above are our understanding of the product, only refer to the
characteristic of safety precautions, but not guarantee the behalf of product feature. Huakeyi
assumes no responsibility for any hazard caused by the product usage.
28
Appendix Ⅲ
Safety rule of HF (40%)

A3-1 Physical and chemistry characteristics
Shape : Liquid
Color : Achromatism
Flash point : No
Steam pressure : 25mm mercury column (20℃)
Steam density : 1.27 g/cm3
A3-2 Hazard characteristic

Inhalation or skin contact may cause death. This product may cause serious damage to mucosa,
breathing system, eyes and histocyte of skin. Inhalation may lead to spasm, inflammation, bronchial
edema, pneumonia and emphysema. The consequence of exposing is: high fever, cough, asthma,
laryngitis, rapid breathe, nausea and vomit. The chemical, physical and toxicity of this matter have not
been researched thoroughly. Long-term consequence: genetic mutation may occur.
Organ: liver—kidney
A3-3 First aid methods

Touch skin or eyes: Wash immediately with plenty of water and soap for at least 15 minutes, take off
the clothes and shoes which have been contaminated, keep the eyes open and
wash with plenty water.
Inhalation: Go out for fresh air.
If asphyxia, artificial respiration is needed;
If have any difficulty in breathing, carry out oxygen therapy;
If the injured is awake, let him or her drink 125~250ml water or milk.
Wash the contaminated clothes and take off the shoes.
A3-4 Fire protection

Moderate extinguish media: dry chemical powder
Extinguish method: put on the breathing equipment and protective clothing to avoid any contact with
the eyes or skin.
Extinguish and explosion dangerous: It may release poisonous gas and cause explosion once contact
with fire.
A3-5 Leak protection

Withdraw from emergency scene, wear the automatic respirator, high boot and glove, sip up with sand
or vermiculite and store in seal container for convenient transportation. Ventilate and wash the scene.
29
A3-6 Deal and storage

Any contact with the glass or other silica product may separate out silicon tetrafluoride. The contact of
chloride and sulfide may release cyanide and hydrogen sulphide which are very poisonous. React with
carbonate will release carbon dioxide. React violently with N-phenyl, potassium manganate, fluoride,
metallic oxide, also react with water. It may release hydrogen gas which may lead to fire and explosion.
The mixture of hydrofluoric acid and nitric acid, glycerin, lactic acid or acrylic nitrile glycol (1:1) would
increase the pressure for the container and will explode in between 30 minutes and 12 hours.
A3-7 Personal protection

Wear gas mask and gloves, safety goggles and protective clothing, it can only operate in the fume hood
and anti-chemical gas.
Avoid any contact with skin, eyes and clothes, avoid expose frequently, and wash carefully after
operation.
Poisonous and corrosive: genetic mutation may occur.
Seal storage in a dry and cool place.
A3-8 Stabilization
Incompatibility: acid
Don’t contain in the glassware, avoid any contact with the metal. And it is sensitive to light, heat and
alkali metal.
Burn and decomposed product. Hydrofluoric gas
A3-9 Suggested process

Breakdown in the water, neutralize with sodium carbonate immediately, add calcium chloride to
sediment the fluoride or carbonate if it can not break down completely. Filter the sediment and treat as
hazardous waste.
NOTE: The description above are our understanding of the product, only refer to the
characteristic of safety precautions, but not guarantee the behalf of product feature. Huakeyi
assumes no responsibility for any hazard caused by the product usage.
30
Appendix Ⅴ
Meter accessory
Name Code Specification

Sodium electrode 04.14.01.02.01 5101S-BNC-0.6m
Sodium reference electrode 04.14.01.01.01 5102S-L9-0.6m
Standard temperature electrode 04.11.01.05 Pt1000
Standard electrode nip accessory 01.02.14.03
pNa2 standard solution 04.06.22 60ml for one bottle
Sodium electrode immersion solution 04.06.23 60ml for one bottle
Electrode activation solution 04.06.03 1% HF
Sodium reference electrode filling solution 04.06.02 60mL
LCD 04.11.01.08 MSC-G19264DBSW-071W
31
HK-51 Benchtop Sodium Meter PRODUCTS & TECHNICAL SUPPORT
Products and Technical Support
Laboratory Instruments
Technical Support
PHS-3C Benchtop pH Meter

Beijing Huakeyi Power Plant Instrument
HK-3C Benchtop pH Meter
Research Institute
DDS-307 Benchtop Conductivity Meter
Add: Nancun Industrial Field, Qiliqu, Shahezhen,
HK-307 Benchtop Conductivity Meter
Changping District, Beijing, P.R. China
DWS-51 Benchtop Sodium Meter
Tel: 86-10-80705660
HK-51 Benchtop Sodium Meter
Fax: 86-10-80705682
HK-208 Phosphate Meter
Email: hky@huakeyi.com
HK-218 Silica Meter
Website: http://www.hky.com.cn
HK-228 Hydrazine Meter
http://www.huakeyi.com
HK-258 Portable Dissolved Oxygen Meter
HK-268 Acid/Alkali Concentration Meter
HK-508 Iron Meter
HK-518 Copper Meter
Essential Instruction!
On-line Instruments
1. Read all instruction manual prior to

HK-108C Phosphate Analyzer
installing, operating and servicing the
HK-108W Phosphate Analyzer
product.
HK-118C Silica Analyzer
2. The Instrument should be stored in an
HK-118W Silica Analyzer
area where is clean and dry.
HK-128W Hydrazine Analyzer
3. Regularly check the status of meter.
HK-318 Dissolved Oxygen Analyzer
4. If Meter is failed during warranty, please
HK-328 pH Analyzer
submit the following documents:
HK-338 Conductivity Analyzer
a. Alarm logger on failure;
HK-358 Sodium Analyzer (Cation Bed)
b. Operation records;
HK-358 Sodium Analyzer (Steam)
c. Maintenance records.
HK-368 Acid/Alkali Concentration Meter
HK-600 Channel Distributor
32

HK-51 Sodium Benchtop Huakeyi

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

HK-51 Sodium Benchtop Huakeyi

Uploaded by

Copyright:

Available Formats

HK-51 Benchtop Sodium Meter

Beijing Huakeyi Power Plant Instrument Research Institute

Beijing Huakeyi Power Plant Instrument Research Institute

Dec 02, 2008

1.1 Brief introduction .......................................................................................................................... 1

2.1 Basic Requirements ..................................................................................................................... 3

4.1 Display and keypad ..................................................................................................................... 6

5. OPERATION ..................................................................................................................................... 13

5.1 Power-on.................................................................................................................................... 13

6. MAINTENANCE ................................................................................................................................ 24

6.1 Meter Maintenance .................................................................................................................... 24

6.3 Electrode maintenance .............................................................................................................. 24

Appendix I ............................................................................................................................................ 25

Appendix Ⅱ .......................................................................................................................................... 26

Appendix Ⅲ .......................................................................................................................................... 29

Appendix Ⅴ .......................................................................................................................................... 31

Products and Technical Support ....................................................................................................... 32

1.1 Brief introduction

1.2 Working principle

2.1 Basic Requirements

¾ The meter should be placed on smooth, spotless laboratory table.

2.2.1 Power Supply

(85~265)VAC, (45~65)Hz, ≤3W. Refer to the figure 2.1 below.

2.2.2 Mounting new sodium electrode

2.2.3 Mounting new reference electrode

1. Put the electrode on the bracket.

2.2.4 Mounting new ATC temperature electrode

Figure 2.1 Back Panel of Meter

Display : 192 × 64 lattice LCD display in English or Chinese

4.1 Display and keypad

ESC(QUIT) ENTER SAVE LOG DIRECTION KEYS

Figure 4.1 Displays and Keypad

Direction Keys: UP, DOWN, RIGHT and LEFT,

4.1.1 Update Parameters

4.1.2 Update values

4.3 User interface

Current time Stable Indication: All the

Press the UP or DOWN arrow key to transform indicating

Storage of Measured Data

4.4 Program unit

4.4.1 Setting Security Code

4.4.2 Main Menu

Press ESC key to return to the measurement screen.

4.4.3 Setup Sub-menu

5. Temp Comp Type: Manual

¾ Adjust Contrast: Adjust the brightness of the screen, Darker or Lighter.

4.4.4 Calibration Sub-menu

4.4.5 Log Sub-menu

¾ Power-on the meter, the measurement screen will appear.

5.2 Calibration (automatic stable-judgment function ENABLED)

5.2.1 Na+ Standard Solution Calibration

Press ESC key

1. Setup Main Menu

Press ENTER key to continue.

Input the value of the standard solution 1

Press ENTER key to continue.

Standard solution 1 calibration completed

1-point cal completed

Press ESC to return

Input the value of the standard solution 2

Na+ standard solution Cal completed

Press ESC to return.

5.2.2 Sample calibration

Press ESC key