1. If a current of 0.

5 ampere flows through a metallic wire for 2 hours, then how many electrons
would flow through the wire?
2. Write the chemistry of recharging the lead storage battery, highlighting all the materials that are
involved during recharging
3. Write the Nernst equation and emf of the following cells at 298 K:
(i) Mg(s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu(s)
(ii) Fe(s) | Fe2+ (0.001 M) || H+ (1 M) | H2(g) (1 bar) | Pt(s)
(iii) Sn(s) | Sn2+ (0.050 M) || H+ (0.020 M) | H2(g) (1 bar) | Pt(s)
(iv) Pt(s) | Br– (0.010 M) | Br2(l) || H+ (0.030) | H2(g) (1 bar) | Pt(s)

Given,
4. Conductivity of 0.00241 M acetic acid is 7.896 × 10–5 S cm–1 Calculate its molar conductivity. If
λm0 for acetic acid is 390.5 S cm2 mol–1, what is its dissociation constant?
5. How much charge is required for the following reduction:
(i) 1 mol of Al3+ to Al? (ii) 1 mol of Cu2+ to Cu? (iii) 1 mol of MnO4- to Mn2+
6. Predict the products of electrolysis in each of the following
(i) An aqueous solution of AgNO3 with silver electrodes.
(ii) An aqueous solution of AgNO3 with platinum electrodes.
(iii) A dilute solution of H2SO4 with platinum electrodes.
(iv) An aqueous solution of CuCl2 with platinum electrodes.
7. Three electrolytic cells A, B and C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively
were connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g
of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper
and zinc were deposited?
8. Explain how rusting of iron is envisaged as setting up of an electrochemical cell.
9. Why does the conductivity of a solution decrease with dilution?
10. Can you store copper sulphate solutions in a zinc pot?
11. The activation energy for reaction, 2HI(g) H2(g) + I2(g), is 209.5 kJ mol–1 at 581 K. Calculate the
fraction of molecules of reactants having energy equal to or greater than activation energy.
12. Time required to decompose SO2Cl2 to half of its initial amount is 60 minutes. If the
decomposition is a first order reaction, calculate the rate constant of the reaction.
13. For a reaction, A + B → Product, the rate law is given by 𝑟 = 𝑘[𝐴]1/2 [𝐵]2 . What is the order of
the reaction?
14. For the reaction 2A + B → A2B, the 𝑟𝑎𝑡𝑒 = 𝑘[𝐴][𝐵]2 with k = 2.0 × 10–6 mol–2 L2 s–1. Calculate the
initial rate of the reaction when [A] = 0.1 mol L–1 and [B] = 0.2 mol L–1. Calculate the rate of
reaction after [A] is reduced to 0.06 mol L–1.
15. A reaction is first order in A and second order in B. (i) Write the differential rate equation. (ii)
How is the rate affected on increasing the concentration of B three times? (iii) How is the rate
affected when concentration of both A and B are doubled?
16. The following results have been obtained during the kinetic studies of the reaction:
2A+B→ C+D
 Determine the rate law and the rate constant for the reaction.
17. The reaction between A and B is first order with respect to A and zero order with respect to B.
Fill in the blanks in the following table:

18. The rate constant for a first order reaction is 60 s –1. How much time will it take to reduce the
initial concentration of the reactant to its 1/16th value?
19. For a first order reaction, show that time required for 99% completion is twice the time required
for the completion of 90% of reaction.
20. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate
the energy of activation of the reaction assuming that it does not change with temperature.